... During the day, it is related to the non-uniformity of the absorbed solar radiation [15], as well as the evaporation process of the PCM [9]. The setup that facilitates the effective measuring of relevant water temperatures is achieved by employing a grid of thermocouples suitably positioned inside the inner storage vessel, as indicated in Fig. 3 (positions: plane 1 (1,1), (1,2), (1,3), plane 2: (2,1), (2,2), (2,3) and plane 3: (3,1), (3,2), (3,3), for the measurement of the corresponding temperatures of the stored water: T 1;1 , T 1;2 , T 1;3 , T 2;1 , T 2;2 , T 2;3 , T 3;1 , T 3;2 , and T 3;3 ). Within the annulus, three thermocouples were placed in positions (i), (ii) and (iii) (for the measurement of the corresponding vapor temperatures: T v;i , T v;ii and T v;iii ). ...