January 1967
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27 Reads
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59 Citations
Acta Chemica Scandinavica
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January 1967
·
27 Reads
·
59 Citations
Acta Chemica Scandinavica
January 1967
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7 Reads
·
43 Citations
Acta Chemica Scandinavica
... Although not quite as widely relevant from a geological perspective, the sulphide mineral pyrrhotite (Fe1-xS) also has the potential to preserve a valuable palaeomagnetic signal [6][7][8], including for meteorites and the crust of Mars [9,10]. However, it has an even more remarkable diversity of magnetic properties over a narrow composition range (0 < x ≤ 0.125) due to the fact that small changes in iron content lead to a variety of superstructures associated with ordering of vacancies on the cation site [11][12][13][14][15][16]. There is a uniform Néel temperature of ~590 K across the pyrrhotite solid solution, Fe1-xS with 0 < x ≤ 0.125, [12,14] above which the structure is hexagonal with the space group P63/mmc (NiAs structure). ...
January 1967
Acta Chemica Scandinavica
... Furthermore, the vanadium compound with the atomic structure very close to that of γ*-V 2 O 5 was experimentally found before. This is the mixed oxide of vanadium and molybdenum crystallized as monoclinic C2 (5) (V 0.7 , Mo 0.3 ) 2 O 5 [28]. The difference between the structure of this mixed oxide and that corresponding to C2/m is minor. ...
January 1967
Acta Chemica Scandinavica