Joshodeep Boruwa's research while affiliated with Universität Konstanz and other places

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Publication (1)

Synthesis of the Core Structure of the Lipoteichoic Acid of Streptococcus pneumoniae
Article
  • Nov 2010
Streptococcus pneumoniae LTA is a highly complex glycophospholipid that consists of nine carbohydrate residues: three glucose, two galactosamine and two 2-acetamino-4-amino-2,4,6-trideoxygalactose (AATDgal) residues that are each differently linked, one ribitol and one diacylated glycerol (DAG) residue. Suitable building blocks for the glucose and...
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Citations

... Reaction of 89 with glucose imidate donor 90 was performed under TMSOTf catalysis at −45 • C in propionitrile as a participating solvent to afford the desired β linked trisaccharide intermediate 91 with selectivity of 5:1 β/α ratio. This trisaccharide fragment was also synthesized by the same group, specifically to study its biological property [57]. Phosphorylation of this trisaccharide with bis(diisopropylamino)cyanoethoxyphosphine in the presence of diisopropylammonium tetrazolide furnished phosphorylated trisaccharide 92 in good yield as outlined in Scheme 11. ...
Reference: Chemical Synthesis of Rare, Deoxy-Amino Sugars Containing Bacterial Glycoconjugates as Potential Vaccine Candidates
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