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December 2010
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16 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
December 2010
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5 Reads
ChemInform
N-substituted-N-glycolyl-1,2-diphenylaminoethanol derivatives were synthesized from the related N-substituted-1,2-diphenylaminoethanols by transformation into N-substituted-2,3-dioxo-5,6-diphenylmorpholines, and subsequent reduction with NaBH4/EtOH.
December 2010
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17 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
November 2010
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7 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
September 2010
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15 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
August 2010
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4 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
August 2010
·
7 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
August 2010
·
7 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
August 2010
·
14 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
August 2010
·
4 Reads
ChemInform
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
... It could be unequivocally excluded that the products 3 and 4 contain an arylglyoxal alkylimine in situ ( Figure 6). By contrast, the NMR spectra of 4 in [D 5 ]pyridine (Figure 2A and Additional file 1) revealed the presence of (2E)-2-(1-adamantylimino)-1-(4-fluorophenyl) ethanone, an arylglyoxal alkylimine [56,57,58]. Its formation must be induced by [D 5 ]pyridine, since 4 dissolved in CDCl 3 gave spectra (Additional file 1) typical for 1-adamantyl nitrene-containing materials. ...
August 1984
Chemischer Informationsdienst
... The 1 H and 13 C data were consistent with those reported in the literature. 28 N-Benzyl-2-(thiophen-2-yl)acetamide (17a). The title compound is known and described. ...
January 2001
Helvetica Chimica Acta
... Although there have been a variety of solid reducing reagents, 1 most of them prefer the reduction of a carbonyl group to that of an imino group due to the lower electrophilicity of an imino group. 2 Recently developed dibutylchlorotin hydride 3 and trichlorosilane (1) 4,5 can also reduce an imino group. The former reducing reagent is not suitable from the viewpoint of green chemistry because of its non-catalytic nature, as well as the requirement of HMPA as a ligand, while the latter liquid reagent might be useful for industrial use because of the relatively easy handling in operation and low cost. ...
January 1983
Chemischer Informationsdienst
... [9] It has been noticed that the configuration around the C= N double bond may have an influence on the rotational flexibility of C substituents in imines, [10] and the mutarotation of optically active benzil monoimines was explained by hindered rotation around the internal C-C bond. [11] α-Bisimines based on benzil can exist in either (E,E), (E,Z) or (Z,Z) configuration around the C=N double bonds (Figure 1). The bond-rotation barrier around the internal C-C bond should be strongly dependent on the position of the N substituent, with strongest hindrance in the (Z,Z) isomer and the lowest in the (E,E) configuration. ...
December 1979
Tetrahedron Letters
... 12 Considerable efforts have been made to develop synthetic methods for chiral nitro compounds. For example, the diastereoselective nitroaldol reaction with chiral aldehydes, 13 the stereoselective Michael addition reaction of nitroalkanes or nitroalkenes, 14-20 the [4+2] or [3+2] cycloaddition reaction of nitroalkenes, 21,22 and nitroolefination reactions using chiral nitroenamines 23,24 have been reported. However, the use of chiral auxiliaries is necessary in these reactions, and a catalytic method of chiral induction would be preferable. ...
December 1989
Tetrahedron Letters
... They are significant from the point of view of organic synthesis -a series of α,β-unsaturated carbonyl compounds as well as vinyl derivatives have been obtained by the functionalisation of one or both formyl groups. (Scheme 23)A number of papers155,156 have described the synthesis of various ethynyl furan derivatives substituted in positions '2' and '5'. FDC, according to authors is the best starting material for this purpose. ...
May 1991
Synthetic Communications
