Chinmoyee Das's research while affiliated with Michigan Technological University and other places

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Publications (2)


Newly developed biocarbon to increase electrical conductivity in sustainable polyamide 12 composites
  • Article
  • Full-text available

September 2022

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68 Reads

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3 Citations

Polymer Composites

Chinmoyee Das

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Debbie Mielewski

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Sustainable manufacture caused shift in automotive manufacturing practices. Polymer‐based composites make up almost 15% mass of the entire vehicle, most importantly the fuel system of the vehicle. Poor electrical conductivity of the polymer composites leads to electrostatic deposition, which can lead to issues. Carbon based synthetic fillers like carbon fiber and carbon nanotubes are attractive options to develop electrically conductive composites, owing to their excellent electrical and mechanical properties. However, the production process of these reinforcements is highly time and energy intensive making it quite expensive and not quite sustainable. Lignocellulosic feedstock can be carbonized at a high treatment temperature of ≥1000°C to produce electrically conductive biocarbon filler. In this study biocarbon fibers developed using Douglas fir pulp, were incorporated into polyamide 12 matrix to develop composites. The composites were fabricated using hot compression mounting. At a filler loading of 7.5 wt% the composites reported log electrical conductivity value of −6.67 S/cm and at 35 wt% filler loading rate the composite conductivity was −0.31 S/cm. An electrical conductivity of −8.70 S/cm for polyamide 6 composites filled with 20 wt% carbon fiber and −1.03 S/cm were reported for 40 wt% carbon fiber concentration in reviewed literature. The electrical conductivity values for the samples with 20 and 40 wt% carbon fibers are significantly lower compared to the biochar fiber filled composites at 25 and 35 wt% biochar filler loading rates, indicating the effectiveness of the biochar filler as a conductive filler in developing electrically conductive, sustainable composites.

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Figure 1. The number of studies based on biochar filled polymer composites published each year between 2015 and 2021. This image is taken from Web of Science (https://www.webofscience.com/ 05 August 2021). Certain data included herein are derived from Clarivate Web of Science. © Copyright Clarivate 2021. All rights reserved.
Figure 2. SEM images showing biochar produced from different lignocellulosic feedstocks (a) corncob (b) cassava rhizome (c) cassava stem. Each feedstock source has a distinctive morphology which is retained in the biochar after carbonization. This image is taken from [29] from Applied Sciences Open Access journal MDPI publications.
Figure 3. An illustration showing the development of biochar filled polymer composites.
Figure 4. The figures here show the mechanical properties of biochar filled polypropylene composites (a) Tensile strength, (b) tensile modulus and (c) percentage elongation. Figure is taken from [40] with permission to reuse from Elsevier Publications 2016.
Figure 5. The tensile properties of biochar filled composites, (a) neat polymer, (b) and (c) LtBioC filled composites and (d) and (e) HtBioC filled composites. The tensile properties of composites filled with HtBioC were shown to be better than neat polymer and composites filled with LtBioC. Figure is taken from [36] with permission to reuse from Elsevier publications 2017.

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Incorporation of Biochar to Improve Mechanical, Thermal and Electrical Properties of Polymer Composites

August 2021

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528 Reads

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69 Citations

Polymers

The strive for utilization of green fillers in polymer composite has increased focus on application of natural biomass-based fillers. Biochar has garnered a lot of attention as a filler material and has the potential to replace conventionally used inorganic mineral fillers. Biochar is a carbon rich product obtained from thermochemical conversion of biomass in nitrogen environment. In this review, current studies dealing with incorporation of biochar in polymer matrices as a reinforcement and conductive filler were addressed. Each study mentioned here is nuanced, while addressing the same goal of utilization of biochar as a filler. In this review paper, an in-depth analysis of biochar and its structure is presented. The paper explored the various methods employed in fabrication of the biocomposites. A thorough review on the effect of addition of biochar on the overall composite properties showed immense promise in improving the overall composite properties. An analysis of the possible knowledge gaps was also done, and improvements were suggested. Through this study we tried to present the status of application of biochar as a filler material and its potential future applications.

Citations (2)


... With calibration, additional properties such as electrical conductivity can also be introduced [19]. The electrical conductivity of biochar increases with higher pyrolysis operating temperatures due to changes in its microstructure [10,[20][21][22][23]. Biochar can be used as a filler material in thermosets, thermoplastic, and ceramic polymer composites to improve their mechanical, thermal, and electrical properties. ...

Reference:

Enhancing the Potential of Polymer Composites Using Biochar as a Filler: A Review
Newly developed biocarbon to increase electrical conductivity in sustainable polyamide 12 composites

Polymer Composites

... The stiffness of biochar filler is often higher than that of the matrix material. The composite gets stiffer as the wt % of biochar filler rises, improving flexural performance and resistance to deformation [28,29]. The flexural strength of biochar composites decreases marginally over 3 wt%. ...

Incorporation of Biochar to Improve Mechanical, Thermal and Electrical Properties of Polymer Composites

Polymers