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Schematic cross section of a NMOS transistor. (a) The transistor shown in the schematic cross section is the basic building block of microcomputers. (b) When there is no voltage applied to the gate electrode, no current can flow through the semiconductor. (c) However, when voltage is applied to the gate electrode, the electrons (negative circles) segregate from the holes (positive circles) to form a “channel” which permits current (large white hatched arrows) to flow between the source and the drain. 

Schematic cross section of a NMOS transistor. (a) The transistor shown in the schematic cross section is the basic building block of microcomputers. (b) When there is no voltage applied to the gate electrode, no current can flow through the semiconductor. (c) However, when voltage is applied to the gate electrode, the electrons (negative circles) segregate from the holes (positive circles) to form a “channel” which permits current (large white hatched arrows) to flow between the source and the drain. 

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This paper provides an overview of research developments toward nanometer-scale electronic switching devices for use in building ultra-densely integrated electronic computers. Specifically, two classes of alternatives to the field-effect transistor are considered: (1) quantum-effect and single-electron solid-state devices and (2) molecular electron...

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... metal-oxide semiconductor FET (MOSFET) has been by far the most common type of transistor in modern microelectronic digital circuits, since Shockley's explana- tion of the device in 1952 [134], [135]. Properly designed MOSFET circuits use very little power and are economical to fabricate. As shown in Fig. 1, the field effect transistor has three terminals which are called the source, the drain, and the ...
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... of the MOSFET, whose voltage and associated electric field controls the flow of current from the source to the drain [27]. This is why the device is called a "field- effect" transistor. When the voltage on the gate is low, the region between source and drain contains few mobile negative charges, and very little current can flow. This is shown in Fig. 1(b). However, as illustrated in Fig. 1(c), increasing this voltage sufficiently attracts electrons to the region under the gate, opening the channel and allowing masses of electrons to flow from the source to the drain. This corresponds to a dramatic rise in current. This distinct change in conductivity makes the MOSFET a two-state device. ...
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... electric field controls the flow of current from the source to the drain [27]. This is why the device is called a "field- effect" transistor. When the voltage on the gate is low, the region between source and drain contains few mobile negative charges, and very little current can flow. This is shown in Fig. 1(b). However, as illustrated in Fig. 1(c), increasing this voltage sufficiently attracts electrons to the region under the gate, opening the channel and allowing masses of electrons to flow from the source to the drain. This corresponds to a dramatic rise in current. This distinct change in conductivity makes the MOSFET a two-state device. Since small changes of gate voltage ...
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... an actual experiment that approximates this design, Eigler et al. created a bistable atom switch with the aid of an STM. In their switch, a xenon atom transfers back and forth between the tip of an STM and a substrate [128], [160]. The location of this switching atom greatly affects the tunneling current that flows from the STM tip to the Fig. 10. Refined molecular switch, Type 1. The atom switch depicted in Fig. 9 might be refined by attaching the switching atom to a rotating molecular group. The orientation of the rotating group is to be controlled by a nearby gate molecule, to which a voltage can be applied for that ...
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... (b) Fig. 11. Refined molecular switch, Type 2. Switching atom might be attached to a "rotamer" that permits the atom to (a) be swung into position to turn the switch "on" by filling the gap in the atom wire, or (b) the switching atom is swung up out of the wire to turn "off" the current in the wire. Orientation of the rotamer is to be controlled ...
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... use the rotation of a molecular group to affect an electric current. We suggest that the atom relay discussed in the last section might be refined and made more reliable by attaching the switching atom to a rotating group, or "rotamer." This rotamer would be part of a larger molecule, perhaps affixed to the same surface as the atom wires. See Fig. 10 for a conceptual diagram of this arrangement (based upon a methyl-like group) and Takeda et al. [165] for a discussion of rotamers. The electric field of a nearby gate would force the switching atom to rotate in or out of the atom wire. When the switching atom is in the atom wire, the conductance of the atom wire is high-i.e., the ...
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... switch positions associated with the three groups attached to the rotamer. A more suitable molecule might be one that moves back and forth between only two distinct states. Cyclohexane, a simple example of this type of molecule, can bend into two different forms, commonly known as the "boat" and "chair" conformations [143], [163]. As shown in Fig. 11, a voltage on a nearby gate might force the cyclo- hexane switch into one of its two configurations, affecting the conductivity of a nearby atom wire. The cyclohexane- type molecule could link to a molecular framework while the remaining ring carbons would be replaced by groups tailored to use steric repulsions or chemical attractions ...
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... Molecular Shuttle Switch: A research group at the University of Miami-Coral Gables reports the synthesis of a "shuttle switch" [121]. This switch consists of two interlocking molecules of the type developed and refined in the pioneering work of the British chemist Stoddart [111], [113]. As seen in Fig. 12, the "shuttle" is a ring shaped molecule that encircles and slides (i.e., "shuttles") along a shaft-like chain molecule. Two large terminal groups at the end of the shaft prevent the shuttle ring from coming off the shaft. The shaft contains two other functional groups, a biphenol group and a benzidine group, which serve as natural ...

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