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As I know, Near IR peak intensity is much lower and complexity than FT-IR.
However, many researcher using NIR for quantitative analysis.
What is the advantage of using it?
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I believe Massimiliano highlights some very interesting properties of NIR spectroscopy. Additionally, there are other motivations behind the use of NIR spectroscopy, especially when compared to FT-IR. These include:
Instrumentation and Cost: NIR spectrometers are often more compact and less expensive than FTIR spectrometers. This can be advantageous for laboratories with budget constraints or those requiring multiple instruments for different applications.
Sample Presentation: NIR spectroscopy is less sensitive to the physical state of the sample. It can analyze samples in various forms, including powders, granules, liquids, and solids, without the need for extensive sample preparation. In contrast, FT-IR might require specific sampling devices or sample preparation.
Penetration Depth: NIR radiation penetrates further into samples than mid-infrared (MIR) radiation used in FTIR spectroscopy. This property allows NIR to analyze thicker samples, providing more representative measurements, especially in heterogeneous materials.
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IR: International Relations;
RC: Regional Cooperations
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Europe has already set its own path in IR and RC, a long time ago.
As far as the European Union (EU) is concerned it has already developed the Common Foreign and Security Policy (CFSP) launched in 1992 by the Maastricht Treaty, aiming to preserve peace and strengthen international security in accordance with the principles of the United Nations Charter. It has also developed the European Neighboorhood Policy (ENP), launched in 2004 and reviewd in 2015. ENP builds on the commitment of the EU and its neighbours to work together on key priority areas, and is based on shared values, the promotion of democracy, rule of law, respect for human rights and social cohesion. 
As far as the European states are concerned, they have also developed the Union for the Mediterranean (EfM), an intergovernmental organisation bringing together 43 states that was aunched in 2008 as a direct continuation of Barcelona Process. EfM's goal is to strengthen regional cooperation and dialogue through specific projects and initiatives that address inclusive and sustainable development, stability and integration in the Euro-Mediterranean area.
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The solubility test showed that the polymer has been crosslinked since it didn't dissolve; however, The FTIR spectrum doesn't show the ester peak (which is the proof of crosslinking of my polymer).
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The chemistry involved or the method needs to be shared in order to suggest something significant. Until then, there can be number of factors which led to disappearing of ester signal.
1. It might have hydrolyzed under the provided conditions (iff acid or base was used).
2. Ester group might have been involved in the cross linking process or transformed into any other.
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in particular DES and Ionic liquides system?
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thank you, It was helpful!!
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I want to make a thin section of rock transparent to IR. CaF2 slides can be used as substrate for the thin section but I need to find a glue able to whistand the polishing and that is transparent to IR in the 1000-4000 cm-1 range. Any suggestions? Thank you!
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One possible option for achieving infrared transparency in rock thin sections is to use an epoxy resin that is specifically designed for optical applications. Epoxy resins have been widely used in geological thin section preparation due to their excellent adhesive properties and ability to withstand polishing.
In order to ensure infrared transparency in the range of 1000 to 2000 nanometers, it is important to choose an epoxy resin that is specifically formulated for optical purposes. One such epoxy resin is the "Clearfuge" series from SPI Supplies. This epoxy resin is designed to be optically clear and has been used for various infrared applications, including thin section preparation.
When using an epoxy resin like Clearfuge, it is crucial to properly mix and apply the resin between the rock sample and the CaF2 substrate. Following the manufacturer's instructions for mixing ratios and curing times is important to achieve strong adhesion and uniformity. Additionally, it is advisable to choose a resin that has a low viscosity, which allows for easier penetration and filling of the thin section.
After the epoxy resin has cured, the thin section can undergo the polishing process. Using progressively finer abrasive materials, such as diamond paste or alumina powders, and following standard thin section polishing procedures, the epoxy resin should be able to withstand the polishing process without affecting its infrared transparency.
Remember to choose a reputable supplier and consult the technical specifications and instructions provided by the epoxy resin manufacturer to ensure proper usage and compatibility with the specific infrared range required for your application.
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I have Hplc and IR for the sample
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Lamis Saleh polymerisation degree you can search tables and index from internet or books. Like you don't have molecular formula, only IR can predict the monomer with peaks (e.g. between 2800-3200 nm it's OH group). i hope i could help you
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IR & AI
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The correlation between the variable of "peace" in the field of international relations and artificial intelligence (AI) is complex and dynamic. Artificial intelligence (AI) possesses the capacity to make valuable contributions to the promotion of peace through its ability to improve conflict prediction, optimize diplomatic techniques, and provide support for post-conflict reconstruction endeavors. Nevertheless, the proliferation of artificial intelligence (AI) also presents significant problems, as the intense competition to achieve AI dominance has the potential to further escalate global conflicts. Additionally, the utilization of artificial intelligence-driven autonomous weapons systems gives rise to ethical and strategic quandaries, which have the ability to disrupt established conventions and doctrines of warfare. Therefore, although artificial intelligence (AI) provides resources that can enhance peacekeeping and diplomatic endeavors, its unregulated spread and utilization inside the armed sphere can also present potential threats to global peace and security.
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I have taken the % of Absorbance (FTIR data) of PVDF film. The following formula is used to calculate the fraction of Beta phase
fbeta= Abeta/(1.3Aalpha+Abeta) (ref: RSC Adv., 2016, 6, 20089–20094)
Where, as per literature Aalpha and Abeta are the IR absorbance at 762 and 840 cm-1. Here I don't know , how to calculate Aalpha and Abeta from my FTIR data.
help me to solve it.
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Is it necessary to select only these two peaks for fractional beta content
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Can anyone recommend a paper about the specific working temperature of the Globar infrared light source used in FTIR spectrometers? Thanks!
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working temperature is 1000 to 1650°C
Please see for example:
Best regards
G.M.
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In doing a meta-analysis using articles done with time-to-event analysis, I faced the problem that some authors reported the effect size (incidence density) with person-year observations, while others reported person-month observations. Some also reported the incidence density for only the exposed group (single arm). Others reported the rate ratio (the ratio of IR in the exposed group to IR in the unexposed group).
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If you are interested only on the observation time, divide it by 12. But if you are interested in the IR, multiply it by 12.
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Identify the following compound on the basis of the spectral data
UV: 257 nm
IR: 1745, 1225, 749, 697 cm-1
Proton NMR (δ): 7.22 (singlet); 5 (singlet); 1.96 (singlet)
C13NMR (δ): 172, 130, 40, 13
MS: 108, 91, 43.
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organic compound formula C9H10O2
Phenylmethyl acetate (IUPAC NAME)
Benzylacetate (Common name)
IR 1745 cm-1 Carbonyl group ester
singlet all (NMR)
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We have collected the IR spectra of two samples, one prepared with commercial graphite (Sigma Aldrich) and with a sonothermal treatment of 2h, the second with the same apparatus Vibracell Bioblock 500 W but in 5 min. We know that the first sample contains larger graphene sheets than the second, as established by TEM. The second is a mixture of 1 to 5 sheets and remaining graphite.
We have been surprised to detect that a strong absorption peak was detected at 7325 cm-1 but only with the smallest sheets. Do you agree with me, it corresponds to a border functionality? The infrared irradiation is removing absorbed water.
In that position, we are no longer in the IR range. Which range are we observing?
Can attributions to OH and peroxyde OOH groups be propose?
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Thomas has pointed out a major problem. Instrument vendors say that they will sell a diamond (or ZnSe) ATR and it is a universal sampling accessory.
Not true!
From those spectra it is obvious that you violated the critical angle constraint on ATR. I just finished recording a webcast for Spectroscopy, where this will be discussed. Single bounce (45° AOI) diamond ATR is not appropriate and even a Ge ATR element at a 45° AOI will still violate the critical angle constraint.
You may get usable spectra with germanium at a very shallow AOI. I would try a GATR or a VeeMax with a Ge element with a face angle of 60°. That should give you a large enough AOI to have it be greater than the critical angle for graphene.
You cannot interpret anything from these spectra until you get usable spectra. If you decide to do an external reflection experiment (which I don't think will work very well) you will need to correct them for the effects of the complex refractive index before you can interpret them.
As to your 7325 cm-1 feature you mention. That is still very much the infrared. It is the near infrared. And your spectra do not show it anyway.
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Hollo to all
I want to know in which region the vibrational frequency of the functional group of azomethine appears in the IR spectrum.
Especially in the case of the azomethine functional group in 4,7-diphenyl-1,10-phenanthroline (bathophenanthroline)
I need to know if bathophenanthroline is coordinated to a metal ion, does the vibrational frequency of azomethine shift to a higher or lower region?
Thank you all in advance for your answers
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You can find IR investigations on the variation of the of coordination on the stretching vibration of the C=N group in azomethine derivatives in the following papers:
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A project I am working on is the evaluation of stigma temperature in outdoor conditions (solar radiation up to 800-900 W/m2 and air temperature varying between 10-30 degrees).
I am utilizing three different instruments,
1. Thermal Camera that can be attached to a cell phone (thermal expert Q1)
2. Type T thermocouples 32 AWG (0.008 inches in diameter or 0.3255 mm2)
3. IR thermometer
The instruments were calibrated with a certified digital thermometer.
When all three methods are pooled together, we notice that IR camera and thermocouples have near consistent results while the IR thermometer is nearly systematically cooler than the two other methods (of about 1.5 degrees Celsius). This is odd and difficult to explain. Also, these values for the IR thermometer always make stigma cooler than air, which would not make much physical sense as the stigmas don't have any cooling mechanisms to our knowledge. Consequently, I am wondering if anybody has had any experience with any of these three instruments in order to help me get a better understanding of what could be the issue, but most importantly which instrument is actually the best to measure temperature.
Thank you for your time,
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I am sharing with you our latest research publication regarding the apple cultivars as follows:
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I am currently doing my master thesis and I have to analyse an IR spectrum of multiple samples. The given sample is supposed to be a specific polymer whose individual monomers i know. It is PBAT (polybutylene adipate terephthalate) which is a random co-polymer made of adipic acid, 1,4-butanediol and terephthalic acid.
Since I have a biology background and not that much chemistry i am struggling a little bit to do the IR spectrum analysis. I read that there are programs or tool with which one can simulate or predict an IR spectrum to compare that with experiment data of actual FTIR scans of the sample.
Anyone has a suggestion what to use or any other tips for me?
Thanks alot for helping out!
Best regards Dominik
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I've used with great success for everything IR search: KnowItAll Analytical Edition Software - Wiley Science Solutions
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I am doing electrochemical studies for my nanocatalyst. From the research paper, I found that, for accurate results CV/LSV should be IR compensated. So I did ZIR compensation. I have attached the results that I got. Does it affect my results? If yes how to compensate it?
Please let me know...
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ZIR compensation can affect the result. You can use a low-noise potentiostat to reduce the effect.
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I'm a Chemistry student currently working on a thesis that involves phytoremediation of Lead in aqueous solution using a specific plant.
The FTIR results for both the stems and leaves of the plant after phytoremediation are almost identical, having the presence of O-H stretch and C-H stretch on both IR spectrum.
The FTIR result for the roots after phytoremediation, however, showed a possible trace amount of H2O at 3457.1 cm-1 (it was a tiny peak, therefore it cannot be called an O-H stretch), along with the presence of a C-H stretch and C=O stretch.
I need help in understanding what caused this deviation from the two other samples (stems and leaves). Could it be the presence of the metal in the root sample or are there any factors that I need to consider?
Thank you to anyone who'd be willing to give their insight/s on this, it would really help me a lot.
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Princess Olivar Tuquero , as you noted previous researchers identified the IF band shift when affected by metals. Assuming that is correct, then the only thing necessary to correlate your FTIR results with the metal content is a graph of the amount of observed band shift to the amount of lead found.
Secondary correlations are not generally preferred analytically, but are sometimes necessary. If you are trying to identify the particular chemical/structure actually doing the adsorption of the lead I can see how combining both might seem simpler. However, as long as you have an AAS it would be better to use it for the metal analysis instead of trying to infer it from the IR. If that is just to explain why your IR peaks are shifted a bit, the metal content would explain that via reference to the paper you mentioned.
As normal growth in plants transports nutrients from the roots ultimately to the leaves it is not surprising to find the highest concentrations of any other compound taken up there as well. I would not expect to find them in the same concentrations evenly throughout the plant structure.
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Dear colleagues,
MGIMO University is conducting the International Hierarchy Expert Survey-2022 (IHES-2022). The survey is aimed at tracking how the status and roles of states have changed since last year. We invite International Relations scholars, as well as practitioners and experts in IR and related fields to join.
To complete the questionnaire, please access the following link:
It will take an estimated 20-25 minutes to fill out the form.
This the second expert survey on international hierarchy conducted by our research team. Results of IHES-2021 have been published in an open access research paper and are attached to this discussion. However, to avoid the anchoring effect, we kindly ask participants to complete this year's survey before reading the previous results.
We guarantee confidentiality of all participants, only aggregated results will be published.
We gratefully thank you,
Research Team on International Hierarchy
Institute for International Studies,
MGIMO University
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Своевременный
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i couldn't find enough references for that, please any one can help me
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I doubt that there is any reference. The reason why certain bands are characteristic for functional groups is that if the masses of the atoms are very different, than you can for simplification assume that only the lighter atom moves. For the same lighter atom, the oscillator frequency is then a function of the bond strength alone. E.g., the mass ratios for carbon or oxygen atoms against the hydrogen atom are 12:1 and 16:1, respectively. In the range you are interested in, you usually find only vibrations of heavier atoms. But, e.g., for a SiO2 compound the mass ratio for Si and O is much smaller, namely 1.75:1. Therefore, the simplifying assumption that only one atom moves is no longer valid. This means that the concept of group vibrations ceases to exist, which explains why you cannot find any references...
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Infrared spectroscopy measures the infrared (IR) radiation after interacting with a sample, which is directed to the spectrometer’s detector. Thus, the sample absorbs part of the IR radiation, and the difference between the IR signal before and after the interaction with the sample generates the IR spectrum. The sample’s molecules vibrate while the IR radiation interacts with them, reaching a higher energy state. However, how do the molecules stop vibrating and return to their original energy state? I’ve searched for this information in the literature, but I’ve not found a clear answer.
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There are many "dark" channels where the molecular vibraional energy can be transfered to. Typically for infrared energy the vibrations are transfered to phonon energy of the bulk material and propagate from the original excitation into the bulk. Think of it as conversion to heat energy in the bulk material. If there are levels between the excited vibrational state and the ground state the molecule can emit a photon and transition to a lower vibrational state - this is not a dark channel. There are many other ways an excited molecule can relax to its ground state. Any book on molecular spectroscopy should go into detail on this topic.
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The compound is double perovskite, and belongs to monoclinic system.
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Please Bilbao crystallography website (https://www.cryst.ehu.es/) give your space group and Wyckoff positions then it will calculate give the no. of IR modes and Raman modes. Of course once you know the IR mode you can find the FTIR modes also.
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I would be eager to familiarize myself with your beloved journal articles or book chapters dealing with how political agency is constructed, transformed, and negotiated in IR through communication.
I am particularly interested in the contributions that focus on:
- performative approaches to agency;
- moral agency;
- constructing agency in times of security crises.
Thank you in advance!
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I am particularly intarested in the contribuations that focus on:
Agency deals human rights in education.
Human feeling,feeling pesples equal without discremanstin on color,religen and race.
Agency dealing with enviroments
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HI,
How can I normalize the IR spectrum of different yeast species? In literature, I usually see "Amide I" peak used to normalize. However, I am wondering, in this way don't we risk losing the differences on this peak?
Thanks
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Normalizing FTIR spectra of different yeast species can be challenging because the spectra can vary due to differences in cell morphology, biochemical composition, and growth conditions. The Amide I peak is a common peak used for normalization because it is a strong, broad peak that is associated with the protein backbone vibrations, which are present in most biological samples.
However, you are correct that using Amide I peak for normalization can potentially mask differences in this peak between different yeast species, especially if the protein composition is significantly different.
One alternative approach is to use the so-called "internal standard" method, which involves choosing a peak that is present in all the spectra and does not vary significantly between samples. This peak can be used as a reference peak to normalize the spectra.
One example of an internal standard peak in yeast spectra is the beta-glucan peak, which is present in the 1100-1200 cm^-1 range and is associated with the polysaccharide component of the yeast cell wall. This peak is relatively constant between different yeast species and can be used for normalization, especially if the cell wall composition is not significantly different between the samples.
Another option is to use a multi-peak normalization method, where several peaks in the spectra are used for normalization to ensure that the differences in individual peaks are not masked. This approach can be more robust but requires careful selection of peaks that are stable across different samples.
It's important to keep in mind that the choice of normalization method can depend on the specific research question and the variability of the samples.
It's always a good idea to test different normalization methods and compare the results to ensure that the normalization does not introduce artifacts or bias into the data.
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I am working on HER and OER. I use Ni foam as working electrode substrate. While running EIS for my sample, I have the impedance spectrum starting from the negative side. i.e. The semi-circle starts at minus values of Re(Z) and ends near 1 ohm or 2 ohms on the positive side. So, I am left only with Rct value. Why does this occur? Also, for what is the Rs value in this case. How should I do IR correction, without knowing Rs?
Kindly help!
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you might like to implement:
1) a] a somehow lower AC-values of Vrms ~ 2 mV ('amplitude was 7.07 mV')
and you might like to show (at least) 2-more, illuminative, (EIS-) graphs at b] somehow lower DC-values of (absolute values of) VDC polarizations (Voverp., overpotentials) values, e.g. at VDC
VHER + Voverp. and/or VOER - Voverp.
2) a] Voverp.=100mV, and at, b] Voverp.=50mV.
Then re-measure (3rd-EIS), near at the critical[1] Voverp.~ 0 V.
Note: include the 1 MHz range, also, upon using lower AC-values of Vrms.
1. due to mainly, some new phase(s) on WE (-'coating') , either big bubbles, e.g. naked eye-visible or even very small, e.g. invisible-nanobubbles, (new gaseous phases '(s)') bubbles.
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I need to assign some FT-IR spectra of inorganic compounds in terms of their vibration modes.
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The KnowItAll Academic edition is no longer available. The bet resources are to go back to the literature. These are the bet resources for interpretation. The Nakamoto book is particularly good for inorganics. You can find more information on the Coblentz website. www.coblentz.org
•Larkin, P.J. Infrared and Raman Spectroscopy. Principles and Spectral Interpretation, second edition; Elsevier: Cambridge MA, 2018
•Mayo, W.M., Miller, F.A., Hannah, R.W. Course Notes on the Interpretation of Infrared and Raman Spectra: Deducing Structures of Complex Molecules, first edition; John Wiley & Sons: New York, 2004
•Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A: Theory and Applications in Inorganic Chemistry, Part B: Applications in Coordination, Organometallic, and Bioinorganic Chemistry, fifth edition;John Wiley & Sons: New York, 1997
•Socrates, G. Infrared Characteristic Group Frequencies, second edition;John Wiley & Sons: New York, 1994
•Lin-Vien, D.; Colthup, N.B.; Fateley, W.G.; Grasselli, J.G. Infrared and Raman Characteristic Frequencies of Organic Molecules, Academic Press: San Diego, 1991
•Colthup, N.B.; Daly, L.H.; Wiberley, S.E. Introduction to Infrared and Raman Spectroscopy, third edition; Academic Press: New York, 1990
•Bellamy, L.J.; The Infrared Spectra of Complex Molecules, Vol 1, third edition; Chapman and Hall: New York, 1975
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Colleagues! Please help with information on methods for identifying somatotropin in a contraband substance. Our customs officers confiscated presumably somatotropin in ampoules. The object is new to them. They don't know how to identify it by simple methods. Does anyone have an IR spectrum of a somatotropin sample?
Sincerely!
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Good evening!
Thanks for the answer!
I absolutely agree with you! I understand that my question is not correct. BUT in this case, the meaning was that the colleagues did not have at their disposal the equipment recommended by you.
If there is no other way, we will use your recommendations.
Thank you very much!
Tomorrow I will study your publications.
Sincerely, Ruslan Yurchenko.
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I have done the FT-IR characterization, but the wavenumber I get from this is not included in the IR table data. How do I know if the compound is not present in the literature?
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So, if I understood correctly, you have a powder sample of known composition, and one of the main absorption bands is shifted to lower wavenumbers compared to the literature. What band? Could this peak be affected by the particle size of your sample?
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In IR spectrum, each polymer have number of absorption bands. From those bands, how can I find the Characteristic band or a band that can be used to find out the presence of a particular polymer? Or Is there any important absorption bands or a band that best describes a polymer?
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IR spectroscopy
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What makes you think so? The signature lines of a methylene groups are 1470, 2850 and 2925cm-1. All these areas are covered here:
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Hello everyone,
I'm working on IR camouflage project and I want to mesure the radiation power using the FLIR camera, can someone help me to know how to do it ? is there anyway to get it directly from the cameras or I have to use other softwares like Imagej?
Thank you for your help.
Regards,
Myriam.
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Thank you Aprana for your answer.
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The IR spectral characteristics of semiconductor structures have been measured. How the LO and TO peaks are separated on the graph.
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There are no separate TO and LO peaks, in contrast to Raman spectra. If you want to identify LO positions in infrared spectra, you can find related information in section 4.6 of
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I know that NIR can be direct and diffuse, but I would like to know if the same happens with the rest of IR.
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I'm not an expert, but diffuse radiation is the one affected by atmospheric dispersion mechanisms, like Rayleigh dispersion. This mechanism is effective on wavelengths that are similar to the size of the molecules causing it. I think from some graphs like the one attached that some NIR may be dispersed also, i don't know what'll be the case for longer wavelengths. Besides this, the leaf wil be emitting on other IR wavelengths energy quantities related to it's temperature and emissivity. Hope some of this helps. Regards
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I have a very thin sample of BNNT that is heated up and I need to measure it's temperature using a long wavelength IR camera. This BNNT is of unknown emissivity and I currently unable to measure it using a spectrometer. My thinking is that I can attach or apply a layer of a material of known optical properties to the bottom of the paper so I can measure it's temperature instead. Since I will be applying a think layer, I am assuming the temperature would be the same. I am expecting the temperature of the sample to be between 300 and 500 degrees Celsius.
Now my question is what can I use? I found one Thermographic paint that I can use but the distributor is in Europe and I am in Canada, so it would take some time to obtain the paint. I am looking for other alternatives before making a decision.
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Hello, the absolute temperature measurement of your material with a thermal camera will be quite tricky. It's designed for non transparent object with emissivity spectra similar to "perfect grey body". You can use a really thin paint layer of known emissivity just like you have mentioned. Just be carefull. This paint will change the mechanical properties of your material and can break when temperature changes. At 500degrees you can expected also some chemical reactions between paint and material.
You can also carry on with another aproach:
Heat your material to known temperature and measure it with IR camera as fast as you can. You can create a calibration table for different temperature and then it will be easy to calculate aprroximate temp. of your material.
You can also use really small SMD thermistor connected to your material with silverpaste and some glue and then use IR camera just for relative temperature measurement.
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If a thermal camera specifies minimum focusing distance as 20m/50m (based on the lens), it means that the bare minimum distance required to provide parallel beam on to the lens is 20m/50m to form image on to FPA.
As collimators with off-axis parabolic mirror provides parallel beam of cavity sources, is it possible to use the IR collimators for calibrating thermal imagers?
Research paper/ technical note, if available in this regard is requested
Thanks
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Hi Nagarajan, Theoretically, you can move the target closer to the off-axis parabola to replicate a finite conjugate. However, the further the conjugate is away from infinity, the larger the aberrations become. The magnitude of the aberrations depend on the focal length of the collimator and the aperture of the camera lens you are using. You really need optical design software to quantify the aberrations. A simpler option is to not use the collimator but to set the target 20m from your camera. If you do not have access to a controlled area this long, it is generally easier anyway to set up a flat mirror approximately half the distance required and then the target can be placed close to the camera.
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I run the CD spectra of the modified and non-modified protein and the 2ndary are the same. However, there is a change in amide I in the FTIR results. Thus, the functionalization might be expected to change the secondary structure. Kindly any suggestions with references.
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I want to know the best technique that provides exact and reliable results on the chemical composition of a plastic product (geosynthetic product) with the concentration of each compound
what is the best technique among these techniques to detect the chemical composition of a plastic product based on PP: Chromatography, Thermogravimetry analysis (ATG) or Fourier transform IR spectroscopy (FTIR).
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I’ve been doing some DFT calculations for the glyphosate molecule gaussian 09 program, and I need to have a reference FT IR spectrum in gas phase, thank you all
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I think you may find the experimental data from literature . For reference ir spectrum you can draw it with the gabedit or gausssum program from your frequency output file.
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Dear community,
we are trying to "debug" a liquid cleaning product formulation (substances added are known, s. below), which has developed crystals over time. We isolated, washed these and got IR spectra of the crystals and all ingredients that we use (see attachments). We are however still struggling to identify what our crystals could be and what could be reacting.
We know IR is limited in identifying a complete structure. But any further help in the interpretation is appreciated. In particular with regard to the strong, semi-sharp peak at 3281 cm-1. We interpret the main peaks with the bonding types O-H, C-H, C=O and C-O. The structure is similar to triethanolamine, except for the sharp O-H peak and the peak at 1738 cm-1. However, if the triethanolamine reacted with the esters or lactone we would expect a more intense peak.
Ingredients (in order of concentration):
  • Dimethyl glutarate (1,5-dimethyl pentanedioate)
  • Fatty acid esters
  • γ-Butyrolactone (Oxolan-2-on)
  • Ethers (3-butoxypropan-2-ol, [2-(2-methoxymethylethoxy)methylethoxy]propanol) and 2-methoxy-1-(2-methoxypropoxy)propane; 2-methoxy-1-[(1-methoxypropan-2-yl)oxy]propane)
  • Triethanolamine
Thanks for the support,
Nikolai
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That is the range for water molecules.
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Dears,
I face a technical issue of how to measure uniformity of infrared radiation on the target surface.
Namely, the setup is as follows. A halogen lamp is mounted at the end of the pipe-lightguide (see Fig. 1). When halogen is on radiation (visible light and infrared) is delivered to the target surface (c.a. 4x4cm). Total power of the radiation delivered to the surface is high (c.a. 200W which gives 13W per cm2). What I need to know is spatial distribution of the radiation on the target surface (to be able to find out how uniform it is). The measuring unit must withstand several seconds of measuring.
Several ideas and related issues:
1. IR camera could be placed at the end of the pipe. However, any reasonable camera will be burnt at once, at least oversaturated, as the power delivered is extreme.
2. Cover IR camera with a filter. This solution does not really work as the filter heats up and further emits radiation, i.e., I do not observe real distribution which would take place with no filter applied.
3. IR photodiodes. I imagine I could place several IR photodiodes at the end of the pipe but, again, they are highly oversaturated at once and filtering, again, does not really work.
4. Thermal-reactive paper/material(?). I am in trouble to find such a material which could withstand the power needed and provide any reasonable resolution.
5. ...?
Do you have any ideas on that?
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Gerhard, Aparna, thank you for the suggestions!
First, bolometers. As far as I have gone through the topic, it looks like a bolometer can measure the power of incident radiation, but not really its distribution. For the power mesurement we successfully use much cheaper equipment (water cooled sensors are enough).
The chopper wheel - it makes sense of course. However, to use such a wheel I need some space around the output of the pipe, so the wheel shall be mounted not under the pipe but at its side. This is very problematic as the system presented in Fig 1 is an internal part of the greater machine and access to the output of the pipe is very limited in terms of space.
A pinhole diaphragm - this idea we have tested in real. However, here, we faced several issues (e.g., mirrored surface of the diaphragm may change the distribution of radiation as it changes the lightpaths inside the pipe, so the real target may "see" other light distribution than the detector beside the pinholed diaphragm). But we will test that further.
Thank you!
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I have just started using ORCA and was following a YouTube tutorial series by Dr. S. Kishor => https://www.youtube.com/playlist?list=PLJIwRG-f5Gjd95jUG4cGjfSxs2gQfQAza
I'm using ORCA 5.0.3 on windows 10 with an i5 9400 processor and 500 GB A2000 Kingston RAM. In the 16th video of the series, I was introduced to IR frequencies calculation with geometry optimization with the following input -
# avogadro generated ORCA input file
# Basic Mode
# GeomOpt + Freq for Acetone
! RHF OPT FREQ 6-311++G**
* xyz 0 1
C -3.50986 2.85550 -0.14979
C -2.02053 3.03306 -0.02862
H -3.77767 1.82632 0.10157
H -3.82355 3.06176 -1.17685
H -4.01762 3.55239 0.52151
C -1.41776 2.78670 1.32795
H -1.61034 1.75505 1.63245
H -1.85017 3.48112 2.05247
H -0.33688 2.94710 1.28593
O -1.32971 3.36340 -0.99127
*
Now, when I'm opening the output file (.out) using Avogadro 1.2.0, the molecule was loading, but the frequencies were not loading. I checked the output file, and they were there but were not coming in Avogadro (should render automatically while opening the output file). I opened the Vibration toolbar from the settings of Avogadro to find they were not loaded. Can anyone help me how to view the IR frequencies generated from ORCA in Avogadro or other software?
N.B. - I found a discussion in the ORCA forum about OfakeG which can convert the ORCA output file into a Gaussian output file and I used that to covert as I have institutional access to Gaussian and GaussView (https://orcaforum.kofo.mpg.de/viewtopic.php?f=8&t=5018&p=21189&hilit=OfakeG#p21189). I followed the documentation but I was unable to convert the file type. I got an error saying the application couldn't find the file.
Enclosed:
1) Output File
2) Screenshot of Avogadro window
3) Screenshot of OfakeG application window
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As can be seen from the OfakeG screenshot, you didn't successfully convert the ORCA output file. You need to manually remove the double quotation marks from the automatically generated path, otherwise OfakeG cannot find it.
In addition, you can directly use Multiwfn (http://sobereva.com/multiwfn) to plot IR spectrum. See example in Section 4.11.1 of Multiwfn manual, you simply need to replace the Gaussian output file in this example with ORCA output file.
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My Hg/HgO standard electrode working properly . But It showing resultant current lesser than the Standard Calomel Electrode . Why ? drop your ideas ....TIA
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Arunkumar Gunasekaran you have not given much details of your experiment, electrode arrangement and electrochemical technique, but you should check the distance of your reference electrode, as well as the conductivity of the solution, also the sweep speed in case of CV. Because these are factors that can lead to a high iR drop. If you have the working and reference electrodes at a large distance, then the iR drop can be significant, same as at low conductivity and and very high sweep speed.
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As per literature,
"The net peak heights were determined by subtracting the height of the baseline directly from the total peak height. The same baseline was taken for each peak before and after exposure to UV.
The carbonyl index was calculated as: carbonyl index = IC/IR(100),
where IC represents the intensity of the carbonyl peak and IR is the intensity of the reference band."
Now, how do I substract the baseline height from the peak height???
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Dear Gitashree Gogoi,
I suggest you to calculate carbonyl index according to the method explained in the attached article. I hope it would be useful.
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Hello all,
I want some recommendations for spectrometers of UV to near IR (230 nm to 900 nm), with High resolution, have a good price, can distinguish between second and third harmonic, and are easy to use.
Thank you.
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Avantes spectrometer is highly recomnded in terms of product price and benfits
you can perform easily spectral scanning.
If you are interested in photon counting and high resolution Andor is one posibility, but you should know your need for that.
Good luck,
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I am preparing polymeric blends from recyclable materials. What are the characterization techniques that should be used and how to prepare the samples (IR, DRX, SEM, TEM, etc)? Could you suggest technical sources and papers/books?
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Thank your for your answer! I'm going to read te papers.
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Hello, I am a student researcher trying to export multiple spectra as .csv files (for graphing in Excel) in the Perkin-Elmer IR software. When I open an exported .csv file in Excel, it displays the y-values (%T) with only digits before the decimal point. I would prefer to have digits after the decimal point as well, as the graph is not very fine, and jagged. I have tried configuring the settings within the software, specifically changing "Decimal Places Y" in the Data options of the Export Setup. However this seems to have no effect on the exported data. How can I fix this? Thank you for your help.
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Very sorry for you having to use Excel for spectra processing. What about using the free optical spectroscopy software http://Spectragryph.com ? It will directly load the Original *.sp files from Perkin Elmer, and has plenty of functions for spectra visualization, processing and conversion. Just saying...
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Is OH bending IR band in PVA is related to inter/intermolecular hydrogen bond? why does it disappear on blending with another polymer?
Can anyone suggest a suitable reference?
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Sea surface temperature, chlorophyll, winds, altimetry observations are done by NASA, ESA, JAXA, ISRO and a few other government institutes. Commercial satellite data providers provide very high-resolution earth observation imageries in optical, IR or UV spectrum. Are there any commercial satellites that provide SST or Chlorophyll data?
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Hallo,
I've a HHG setup, but the IR filter is broken. This means that the entire IR intensity hits the CCD camera and would destroy it. Because a replacement filter needs a few weeks to arrive, I'm wondering if anyone has an idea how to cheaply/DIY block the IR in the vacuum before the CCD.
Many thanks in advance
Greetings
Konstantin
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I'm not too familiar with your setup, but would a sheet of aluminum foil do the trick?
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How can I observe moving cells without visible light? I tried with IR LED and an IR sensitive Bresser ocular camera, but the iR light was too weak.
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Primary answer :
The digital camera has Infrared blocking filters.
First, remove the filter which is on the digital camera close to the sensor.
The microscope must own hight quality optical elements.
Hope it solves the problem,
ALbert
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Pulse oximetry works by sending red and infrared light through blood vessels and measuring the absorption of the two wavelengths of light by hemoglobin. Blood also contains other proteins such as heme peroxidases which also absorb light at slightly different wavelengths. However, given that Hemoglobin is present in a much larger concentration, would it even be possible to detect other heme peroxidases through the method used in pulse oximetry even if they had different peaks?
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It is a novel question no doubt . Please go through -https://www.google.com/url?sa=t&rct=j&q=&esrc=s&source=web&cd=&cad=rja&uact=8&ved=2ahUKEwi65a_Jsv_1AhUfzzgGHQ-YCZkQFnoECAYQAQ&url=https%3A%2F%2Fwww.ncbi.nlm.nih.gov%2Fbooks%2FNBK470348%2F&usg=AOvVaw2_r6r3aQVdi6yRm0mrBW_s in detail . If the condition of pulse oximetry satisfies for the detection of other heme - peroxidases .
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I want to briefly know, how theoretically IR and Raman spectrum of a particular optimised structure is estimated using DFT. Actually I want to know what is the basic theory behind this in a brief way.
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It is indeed hard it is to explain it briefly. Basically, you have to change the displacement of a given atom, this changes the electric field and generates a force (k), which is related to the frequency in the FTIR. I may have oversimplified the process, and I am sure there are other ways to compute the frequency. You might be interested in this paper: https://hal.archives-ouvertes.fr/hal-00906659/document
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After doping a InN nanostructure energy gap reduces and also in Ir spectrum molar extinction coefficient value decrease. What are reasons behind this?
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@Chian Heng Lee ,I have calculated dipole moment it's value also changes after doping.
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This strange waveform appeared today while measuring the IR background. After changing many parameters and testing many times, I still only get this waveform.
Then, sample measurement did not yield the desired waveform, so what is the reason for this waveform? Is there something wrong with the machine?
Thank you very much
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In answer to your question, "Infra Red background of what?" The background, in the case of this instrument, is measured without anything in the optical path except air. In other words, the instrument is measuring the output of the Nernst glowbar (the ceramic light source). When one transforms the interferogram to its spectrum using the Fourier Transform, you get the gray body spectrum of the light source with two pronounced notches (dips) for the absorption of CO2 and H2O in the air. The background spectrum should produce a very large signal.
Regards,
Thomas Cuff
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the thin film shows negative absorption in the IR region while taking UV-Vis -Nir spectra.
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Kamal Bhujel As I said, it is not possible to measure absorbance - your instrument either measure transmittance or reflectance and converts it to absorbance.
Can you tell me what your sample is (what kind of substrate)? Is the light going through your sample? You also had to perform a reference measurement... is the instrument empty for this measurement, or do you insert the pure substrate? Or, by any chance, a mirror?
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I have the NMR and IR of an organic unknown. The percentage of C, H, and O, is 71.1, 5.22, and 23.68, separately. And what are its 2,4-Dinitrophenylhydrazone derivative and Semicarbazone derivatives?
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is that 4,4'-Dimethoxybenzil?
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Two different IR spectroscopy for the same molecule:
Note: The cyano stretching band should disappear upon cyclization of the molecule.
-The first IR spectroscopy (A) represents the cyano absorption observed in the 2190 cm-1 region.
-The second IR spectroscopy (B) represents two different stretching bands observed in the 2194 cm-1 and 2207 cm-1 regions.
Concerning the second spectroscopy (B), if the stretching band 2194 cm-1 represents the cyano group, then what functional group does the stretching band 2194 cm-1 present, or do these two stretching bands illustrate the same functional group.
Thank you for your help.
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The functional groups observed in IR spectroscopy around the region 2190 cm-1 and 2194 cm-1 is unsymetrical C≡C.
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Basically, I have this protein: and I wanted to run an optimization on it and get thermodynamics, IR, NMR in a solvent. I believe due to the protein size, Gaussian crashes. Is there another software I can use? Thank you.
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Gaussian
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Transmission-FTIR spectroscopy can be used to analyze analytes in aqueous solutions e.g. Proteins in a formulation. Critical step: In order to correctly analyze the structure of proteins, the buffer solution's spectrum needs to be subtracted from the spectrum of the sample containing proteins. However, due to differences in the amount of water that is present in each sample, the difference spectrum cannot be simply calculated by: Difference Spectrum=Protein Spectrum-Buffer Spectrum.
What is a correct method to calculate the difference spectrum for e.g. algorithm based on least squares? I have looked into many papers and the most frequent answer is that a factor is used in calculating the difference spectrum to ensure that the resulting spectrum has a 0 baseline between 1750-2000 cm-1. But using a factor results in negative peaks in the difference spectrum.
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Sven Delbeck If you used Beer's approximation for calibration (or chemometrics based on Beer's approximation), then I hope you used molar concentrations.
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I am not familiar with solid state parameters especially in rectification ratio where my background was in biotechnology,.
Currently I want to calculate rectification ratio (RR) of my sample/device and plot some graph for my paper. However, I found it quite confusing with little to no basics. The formula for RR = IF / IR , where I can plot a graph RR versus V based on several papers that i refered. Unfortunately, I do not know how they got the value based on this table
My question is the graph that i plotted is very weird as i refered to other people's work as attached. And some paper mention use RR value above threshold voltage? I need guidance and help in calculation as well as plotting the graph RR versus voltage.
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Hello
Bring the forward biased voltage and current in sequential columns do the same for reverse then divide IF/IR
plot IF/IR versus VF
This is valid if both forward and reverse biased voltage steps are the same
Good luck
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infra red heating become more popular recently because of low cost energy and efficienty , Radiant IR-Heater Tube is the most useful technology to achieve this as i know, I'm interested to collect IR generated by this kind of IR-Heater Tube in a linear fresnel concentrator for Infra red Radiations to obtain a high temperature in a centrale cynlindrical surface. This kind of IR Concentrator Exists ? Some one can advice ?
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We have imidazole ring N and Imine N for coordinating to metal in 2:1 (L:M) ratio. Both are forming coordinate bind with metal. So two covalent bond is from 2 O atom of acetate group. And the complex found be 6 coordinated in this case? Is there any possibility for this. How can we confirm the structure from IR and TGA for this acetate groups?
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Dear Anjali,
As Florian mentioned, it is not easy to state an adequate answer based on limited data. Please can post a chemical structure?
I agree with Matheus, concerning specificity there are only 2 posisbilities: IR or NMR; XRD does not provide any molecular specificity at all. But you might get the periodicity, if (and only if) a somehow periodic structure will be formed.
(1) You might start with IR/NMR measurements using a series of different L:M ratios starting from 0. Then, you can assign which peak belongs to imidazole, which to imine, and which to the rest.
(2) If you increase the L:M ratio, new (IR) peaks will appear due to binding. Most like they will arise at a lower frequencies/wavenumbers than the corresponding peaks from the unbound moieties. However, there might be exceptions. In most cases stretching vibrations undergo a redshift due to binding, whereas deformation vibrations undergo a blue shift.
(3) After you have the peak assignment you can study the ratio of the peak areas in dependence of the L:M ratio. I expect that particular sturture of coordination strongly depends on the L:M ratio.
I compiled some examples of IR measurements focused binding.
It might be that not all publications are exactly dealing with imidazole or imine, but you will definitely find instructions and band assingments. Look also in the reference there. Remember temperature changes affect the binding equilibrium somewhat comparable than changing the L:M ratio.
Best regards
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I need to perform Thermogravimetric Analysis with Infrared Spectroscopy (TG-IR) for my samples I have checked analyticsir.in both CIMFR and NITT instutes TG-IR system not working. other than that I couldn't be able to find any other facility in India. Someone point me in the right direction. Thanks.
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Snehalatha V 5c/min upto 800c. N2 atm.
Thank you for the reply
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Can I get electroluminescence camera and IR camera , PV analyzer on rent for research work in India?
Can I get the access or work permission of solar simulator lab in India for research work in any institute?
and what can I used instead of EL camera?
please share the link.....
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may be
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Help me with the identification of an unknown compound, I have attached the IR spectrum.
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Yes. You are right, if your peaks around strong 1785 cm-1 stretching C=O is acid halide, and medium 2900 cm-1 stretching is alkane, medium 3100 cm-1 C-H stretching is alkene, strong range 1650 cm-1 C=O stretching is lambda - lactam, and gamma-1750-1700 & beta-1760-1730, and strong 1725-1706 C=O stretching is Aliphatic ketone or cyclohexanone or cyclopentenone.
On your spectrum graph you can show the specific wavelength no. of peaks with the help of instrument, then you get a better results in your research
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I have a sample with magnesium, potassium, phosphate and water. I have found a peak around 3750, is it possible to consider magnesium with OH bound in IR for this peak?
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Dear
3600–3750 cm-1 relate to the OH stretching vibration.
Reference: (The structural OH mainly appears as characteristic peaks in four regions, 500–720, 3600–3750, 4000–4600, and 7000–7600 cm−1 , corresponding to the OH bending vibration, the OH stretching vibration, the OH secondary combination vibration, and the OH overtone vibration, respectively, Development of FTIR spectroscopy Methodology for ... - MDPI https://www.mdpi.com › 11 ›)
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I have tried to prepare the Schiff base from tetraphenylcyclopentadienone and p-aminophenol using MeOH, AcOH, 2 drops of HCl, and short bursts of microwave radiation (800W, 3 secs for 1 min).
Although it was small scale, a product formed that was clearly a light violet color. Naturally, tetraphenylcyclopentadienone is black and p-aminophenol is actually a beige/light brown color (due to degradation from light).
The IR looks very messy and I cannot find a reference IR for this compound. Is there a chance that I have failed to actually produce the desired product due to the intense 800W Microwave radiation, or bad solvent system? Maybe the HCl was problematic? Maybe I should have used EtOH?
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Dear Aidan,
that's a very interesting technical question. I did a SciFinder search for the desired product (such compounds are also called tetracyclone anils) and found that it has not yet been reported in the literature. Do you have access to SciFinder? In that case you should run a search using the structural formula of your product and see what literature references could help you. I'm not sure if tetracyclone (= tetraphenylcyclopentadienone) undergoes normal Schiff base formation reactions. In most previous literature references the authors carried out reactions of tetraphenylcyclopentadiene with aromatic nitroso compounds.
Good luck with your work and best wishes, Frank Edelmann
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I am wondering if we make a quantitative measurement of metabolites with an IR spectroscopy such as FTIR?
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Take a look at these.
1. Baker, M.J., et al., Developing and understanding biofluid vibrational spectroscopy: a critical review.Chemical Society Reviews, 2016. 45(7): p. 1803-1818.
2. Durlik-Popińska, K., et al., Correlations between autoantibodies and the ATR-FTIR spectra of sera from rheumatoid arthritis patients. Scientific Reports, 2021. 11(1).
3. Fang, T., et al., Rapid Diagnosis of Type II Diabetes Using Fourier Transform Mid-Infrared Attenuated Total Reflection Spectroscopy Combined with Support Vector Machine. Analytical Letters, 2017: p. null-null.
4. Finlayson, D., C. Rinaldi, and M.J. Baker, Is Infrared Spectroscopy Ready for the Clinic? Analytical Chemistry, 2019. 91(19): p. 12117-12128.
5. Rüther, A., et al., Vibrational Spectroscopic Based Approach for Diagnosing Babesia bovis Infection. Analytical Chemistry, 2020.
6. Sharaha, U., et al., Using Infrared Spectroscopy and Multivariate Analysis to Detect Antibiotics’ Resistant Escherichia coli Bacteria. Analytical Chemistry, 2017.
7. Banerjee, A., et al., Rapid Classification of COVID-19 Severity by ATR-FTIR Spectroscopy of Plasma Samples. Analytical Chemistry, 2021.
8. Nogueira, M.S., et al., Rapid diagnosis of COVID-19 using FT-IR ATR spectroscopy and machine learning. Scientific Reports, 2021. 11(1): p. 15409.
9. Pokhrel, P., C. Hu, and H. Mao, Detecting the Coronavirus (COVID-19).ACS Sensors, 2020. 5(8): p. 2283-2296.
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So I was running an IR on a sample that I had thought (or rather hoped) was phenol (hydroxy benzene), but what came out was either trash and noise, or I simply did not have phenol. My professor and I were quite stunned as it showed no signs of organic peaks at all, especially no -OH peak near 3100. My professor suggested to run my reaction again, but sadly I do not have the reagents on hand at the moment and it will be some time before I get them.
The reaction I ran was one taken from an old book on recycling benzene waste. When I conducted it, I took a mixture of nitrobenzene and benzene waste and I added a random amount of relatively pure Fe2O3 and 13% Hydrogen Peroxide to try and oxidize anything in the waste to phenol or hydroxynitrobenzene. After I treated it with NaOH to make a phenoxide salt and then I did some work up to isolate. What I was left with was a nice white crystalline salt (or so I thought). But the IR says it contains zero organics as far as our IR machine can tell, and our machine is used daily if not hourly, and is kept in great condition.
If someone could help me understand what I have or teach/lead me how to identify inorganics, that would be very appreciated.
Because the attached picture is possibly hard to see small details, I have listed the peaks as well.
Peaks:
-610.07 cm^-1 transmittance: 60%
-635.08 cm^-1 transmittance: 79%
-1091.13 cm^-1 transmittance: 64/65%
Rizal Awaludin Malik After rereading my notes, I have come to realize that I distinctly changed my procedure because I was having trouble with the Iron Oxides previously mentioned. My pseudo-procedure looks more like this:
Fe + 2HCl -> FeCl2 + H2
2FeCl2 + Cl2 -> 2FeCl3
FeCl3 + H2O2 (13% aq) -> Fe(OH)3 + Reactive Species
And my idea was to combine the benzene/nitrobenzene wastes I had with the final reaction in the scheme (combining the reactive species) to try and produce hydroxylated benzene and nitrobenzene.
Some notes from my notebook leave me further puzzled:
"Smell of nitrobenzene and benzene has totally disappeared, and lots of gas evolution. A red precipitate (likely iron oxides) has formed at the bottom of the beaker. There is no longer 2 layers (2 phases) and the yellow color of the solution is very faint, where it was quite deeply colored beforehand."
I'm not sure what exactly happened but I have done a little bit of searching and came across Hexaaqua iron (III) chloride, which may be what I have crystallized out.
To explain further, after the whole reaction was completed, I filtered off the red precipitate and tried to crystallize out whatever product I had formed. When I did so, I was left with a pure white free-flowing powder. The powder seems hygroscopic in nature.
I will likely try this again, with pure benzene to see if the same result occurs.
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Aidan Bradley as we know the range 1085-1050cm-1 is for strong-
C-O stretching. This is a primary alcohol. You have a pick is the 1091.13 cm-1 so it is more likely that is indicating the presence of C-O stretching. The other two picks are 636.06cm-1 and 610.07 cm-1. We know 690-515 cm-1 range indicates the presence of strong C-Br stretching, which is a halo compound. So those two picks are indicating the presence of C-Br stretching.
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Hi All,
I want to use silicon wafers for my mid-IR imaging project. I have some specifications for them from my previous lab colleagues. In our previous lab we used to buy:
3” N TYPE <1-0-0> 1-50 OHM-CM 350±10µm SEMI-Std FLATS DOUBLE SIDE POLISHED.
However, getting exact specification is proving to be an hassle!
I am not sure about some parts of the specifications. Could you please help me with the following questions?
1) If imaging data is collected in transmission mode, does the thickness of the silicon wafer matter? What I mean is change in thickness from 300um to 500 um?
2) If the imaging data is collected in transmission, does it matter if the silicon wafers are single side polished or double side polished?
3) if the imaging data is collected in transflection mode single polished silicon wafer should be fine?
Thanks
Mugdha
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Dear Mugdha,
1) Ideally, silicon is not absorbing. However, yours is doped (“N type”) and has a comparably low resitivity (1-50 OHM-CM). This means that the free electrons will lead to absorption, and the thicker your wafer is the less light you get through. I would recommend > 10.000 Ohm cm.
2) Double side polished means that spectra of layers will show interference effects, but those can be treated properly (see e.g. https://www.researchgate.net/publication/340232874_Removing_interference-based_effects_from_infrared_spectra_-_interference_fringes_re-revisited). Single side polished substrates suppresses the interference effects, but causes scattering effects which lead to spectra that cannot be safely quantitatively evaluated,
3) Same problems like those under 2)
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Especially for Agriculture Field which one is better?
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Surely ultrasonic sensors have definitive edge over IR sensors..
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Can you calculate IR and IRR p-values and CI in SPSS without using a regression model such as Poisson? I have calculated the breast cancer incidence for various groups by hand using the breast cancer incidence rates of the entire population of a country as a reference. I have calculated the p-values and CI also by hand, but I would like to check this using an analysis in SPSS. Thank you in advance.
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Hello Rachel Dassen. Well, you could convert your hand calculations into SPSS syntax. But I'm not sure that's what you're asking.
Which method of adjustment are you using, direct or indirect? Can you share the data (including the standard population info) with us?
Why are you opposed to using a regression model if it gives the correct results? HTH.
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Hi,
I have recently completed my Ph.D. from the Department of Government and IR at the University of Sydney. I am currently looking for a Post-doc position in Europe. My proposed project examines religiosity and support for radicalism among the migrants in Europe.
To begin my journey as an academician/researcher, what scientific and transferable skill should I have? Knowledge or training on which quantitative or qualitative methods or data collection softwares will benefit me in future?
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Hi Saimum, congrats on getting your PhD done! It is a great achievement.
If you want to engage in a project on radicalism, religion, and migrants, I'd suggest looking at qualitative research methods a bit more, as you would most likely be interested in talking to people about their experiences. Some interview/focus groups training or experience could be beneficial. Sometimes you can find community-run projects to acquire those skills. Learning SPSS and Nvivo is always good.
In addition, there is a growing tendency in Political Science to be working on big data. I'd suggest you have a look at the existing projects in your area that you find fascinating and see what approaches and software they used and why, and decide for yourself if you want to study it in your own time.
I'd be happy to answer any questions, and good luck!
Best wishes,
Ana