Science method

I-V - Science method

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Actually, I am interested to check the ferroelectric behavior of my non-conducting polymer composite film. Since the electrical resistance is high, how to study the voltage variation with respect to applied current? The freestanding films are of the thickness 300 micrometer.
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I would like to design a substrate holder with a 2-probe setup for measuring the I-V characteristics of thin films, including photodiodes, photodetectors, and other devices. Commercially available instruments for such measurements are often expensive, making them inefficient for my budget-specific requirements. Therefore, I want to design one myself. Please help me with this.
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Make few pinholes on a metal plate and connect vacuum hose on one side.
Vacuum suction will hold the detector in place. You can put one electrode on the same plate and one isolated probe to connect to the metal on top of the photo detector. Great set for measuring IV characteristics. You can control the temperature of the metal plate for constant temperature measurements.
Simple and cheap
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I am attempting to calculate the vertical carrier mobility through a semiconductor powder sample coated on FTO using Spin Coating method. The I-V results I recorded using SMU 2401, shows current saturation at very low voltage like 0.3V, 0.4V etc. From Literature I found the saturation Value to be more than 2V. What could be the reason of showing this much low current saturation in my sample. I want know the possible reasons behind such result. whether the device is short? or any other reasons? I am attaching the images of (a) the configuration I chose for coating and I-V measurements (b) Corresponding I-V Graph of my sample (c) reference I-V plot taken from literature .
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Cu2O syntheses in three different crystals morphology: octahedron is highly conductive, a cube is moderately conductive, and a rhombic dodecahedron is nonconductive. The conductivity differences are ascribed to the presence of a thin surface layer having different degrees of band bending [1]. In this respect, each type has its syntheses route: Octahedral Cu2O microcrystals obtain in the absence of oleylamine and at the highest sodium oleate concentration. Rhombic dodecahedral Cu2O microcrystals obtain at the highest oleylamine concentration or at the lowest sodium oleate concentration[2].
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what is the S shaped I-V curve of solar cell?
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The problem of so called S-shaped I-V curves occuring in the case of combinig various semiconductor materials in solar cell structure is well explained in the paper in IEEE JOURNAL OF PHOTOVOLTAICS, VOL. 9, NO. 6, NOVEMBER 2019 ( https://ieeexplore.ieee.org/stamp/stamp.jsp?tp=&arnumber=8788619 )
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i'm processing a MIM capacitance with 50nm TiN/20nm HfO2/50nm TiN, but when i apply cv test to the capacitance it won't show a normal curve, only a line about 100fF, which is far below the theoritical capacitance(about 50pF). but the I-V curve shows that the current is always below 1nA before a clearly breakdown at about 9V. After that i apply Cp-D mode and Cs-Rs mode to the capacitance, and the D(dissipation factor) is about 3 and Rs is about 100kohm(huge!). How is this coming? I'm really confused! Is this show the electrode (TiN) has a really high resistance? How can I improve that?
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Srikrishna Sagar Thanks for your explanation. I will do the experiment again, and I will update the result!
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How to calculate Rsh and Rs using the manufacturer's datasheet and if the I-V curves are not provided? I am unable to find the slope as i do not have enough values.
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It cannot be that the inverse of the slope of the J--V curve at J=0 gives the series resistance, because an ideal device with Rs=0 still shows the characteristic of the p--n junction. For such a device, the slope at J=0 gives the effective diode conductance, and the slope is the effective diode resistance.
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I want to take measurements for the I-V characteristic in resistivity calculation of metal oxide thin films. Can I do this using a potentiostat, especially in a solution-free environment, with two electrode connections? If possible, which technique should be used (for example, pulse voltametry, etc.). Thanks in advance.
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Better not try with 2-probe, cause you do not have control over contact resistance between thin film and electrodes. 4-probe is designed to overcome this contact resistance as well as arbitrary geometry of thin film surface
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It is common to get resistance value from the I-V curve generated by two-point probe. However, if the two points are taken on the surface of the thin film layer, how can I get the resistivity? According to the resistivity formula expressed with resistance, the area is required. However, in this case, what is the 'area'?
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Thank you very much
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I have conducted research on impedance-based humidity sensors and utilized electrochemical impedance spectroscopy (EIS) to understand their mechanism. However, I have noticed that various research articles utilize a perturbation voltage amplitude ranging from 0.5 V to 1 V in measurement and EIS. I seek clarification on the rationale behind using high voltage for impedance measurement. Kindly provide guidance on this matter."
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No need to have the i-E curve. You can check the linearity by just varying the amplitude of your perturbation signal; you are in the linear domain if the impedance is independant of the amplitude.
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Extracting the data from the plot and the equation.
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Thanks for your rapid response Aparna Sathya Murthy, I sent it in private.
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I am trying to simulate the PV module model with varying irradiation (after considering the beam, diffuse and reflected). I have modeled the the PV module using the mathematical equations in Simulink and managed to get the P-V & I-V curves for constant values. But I get error when I input a signal. If anyone know how do this to kindly assist.
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I need to do an experiment in which I solder a resistor to the backsides of two series-connected cells of a commercial PV module, to simulate shunt resistance, then measure the I-V curve of the module at various shunt resistance levels for that one cell. Once I open the poly backsheet, how can I remove the encapsulant from an area of the cell backside, large enough to solder a wire? I can probably scrape most of the encapsulant away, but getting down to the clean metallization will be the challenge.
Thanks
Photonpal
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Thanks for pointing out the safety hazard. In this case, I am a researcher studying mismatch effects within modules, so going through the backsheet to add resistance in parallel with a cell will be done very carefully and the module will be recycled after this experiment. As you mentioned, the packaging must be very robust, and that's why I'm asking how best to work my way down through backsheet and encapsulant so I can solder a wire to the back of the cell.
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How to describe the noise rounding in the I-V data or HTS Josephson junction of micron dimensions at a temperature close to its critical temperature? How could we justify the Resistively shunted junction (RSJ) model in the rounding part of the experimental data?
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In the RSJ model, the junction is represented as a resistor (R) and a capacitor (C) in parallel with a Josephson junction, and the I-V characteristic is given by:
$$I = I_c \sin\phi + \frac{V}{R} + C\frac{dV}{dt}$$
where I is the current through the junction, $I_c$ is the critical current, $\phi$ is the phase difference across the junction, V is the voltage across the junction, and t is time.
At low voltages and currents, the junction behaves as an ideal Josephson junction, and the I-V characteristic is described by:
$$I = I_c \sin\phi$$
However, as the voltage or current increases, the junction begins to behave more like a resistor, and the I-V curve begins to round off.
The rounding in the I-V data can be described by adding a noise term to the RSJ equation:
$$I = I_c \sin\phi + \frac{V}{R} + C\frac{dV}{dt} + \eta(t)$$
where $\eta(t)$ is the noise term.
The Resistively Shunted Junction model is justified in the rounding part of the experimental data because it takes into account the effects of thermal noise and resistance in the junction. The noise term in the RSJ model represents the effect of thermal fluctuations in the junction, which cause random variations in the current through the junction. The resistor in the RSJ model represents the effects of resistance in the junction, which can cause the I-V curve to round off at high currents or voltages.
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Hello all,
I'm simulating a field-plated-GaN-HEMT device. The IdVd characteristics obtained are fine for lower drain voltages. However, for higher drain voltages, the device doesn't enter breakdown. The I-V characteristic continues linearly for drain voltages till infinity.
I have included all models essential for breakdown analysis such as impact selb, field-dependent mobility model (fldmob), fermi and srh.
Further, I am using gummel method for low voltages(<2V), newton method for medium range voltages (2V-50V) and block method for high voltage analysis (50V-2000V). By doing so, I am not getting any convergence or trap errors- but I am not getting proper voltage breakdown either.
Apart from simple ramp voltage variation, I am also using current boundary conditions and compliance parameters. What can I add or change such that breakdown is analysed properly in my device? (breakdown analysis similar to ganfetex02)
Any help is appreciated.
Cheers.
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Aparna Sathya Murthy Thank you for your answer. Unfortunately, despite clamping and adding DIBL analysis, my device did not enter breakdown. Could please look at my new post?
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Hello,
I want to make STM break junction experiment using Gold. So, my setup is made up by a gold tip and a substrate of Gold/SiO2/Si stack lying on a nanopositioner. The substrate is brought in contact with the tip to form gold atomic contacts that can be monitored using I-V curves. So I have to apply a voltage on the substrate. We do this at room temperature
However, the only way I could come up with was to solder a small wire on the substrate. But this method degrades the substrate as it has to be really pure and clean. Also, we have to use a flame to clean it so it will spread the solder everywhere. I tried with several mechanical ways to contact a wire on the substrate but it is hard to form a good connection. Do you know some ways to create a good contact, that would allows us to easily remove the susbtrate and not contaminate it ?
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In very ancient times, to obtain a reliable electrical contact to the substrate, the method of thermal compression was used. But without knowing all the details of the experiment, I can not say whether it is suitable in your case.
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Using MATLAB I first simulated a solar cell and plotted I-V graph, V-T graph and I-T graph. Then I connected 36 simulated solar cells in series and created a solar module in MATLAB. Then I plotted all the above graphs for each cell. The graphs for each cell is same as for one single solar cell when 'insolation' for each cell is equal like 1000Wm-2 insolation for every cell. But when the insolation varies over one cell to another then the graphs for each cell is showing different pattern. I am now confused whether my graphs are ok or not. I am providing a PDF file to understand my work better. Help me someone please.
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What is used as a model for a solar panel cell?
The classical model consists of a current source and a diode connected in parallel. The current in a series circuit is determined by the current of the weakest cell, and the voltage is the sum of the voltages of all cells.
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I am in search of a low cost, widely used and widely accepted characterization method/test to determine I-V (current-voltage) characteristics of semiconducting thin films. Thank you.
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The behavior of (I-V) curve of some Cds sensors takes Ohmic (linear) behavior and schottky behavior, I need to explain when the Ohmic and schottky behavior of sensors appears?
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Hi Khawla Ahmad Aloueedat,
I totally agree with the explanations given by Tanzila Nurjahan above.
However if you want to obtain ohmic behavir of yor contacts, you may first proceed with a local n-type doping with chlorine of your CdS sample as explained in the reference below before processing metallic contacts.
this local n-type doping of CdS prior to process metallic contacts is usually helping to obtain good ohmic (non Schottky-like) behavior of sample contacts.
Reference :
Synthesis of high quality n -type CdS nanobelts and their applications in nanodevices R. M. Ma, L. Dai, H. B. Huo, W. Q. Yang, G. G. Qin, P. H. Tan, C. H. Huang, and J. Zheng Citation: Applied Physics Letters 89, 203120 (2006); doi: 10.1063/1.2387982 View online: http://dx.doi.org/10.1063/1.2387982
Good luck
Abderrahmane Kadri
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I have fabricated MESFET by depositing GeSe thin film on glass substrate and then deposited silver metal for gate. Now when I record I-V between source and drain at 0 gate voltage it passes from origin, but as I increase of decrease the gate voltage then I-V does not pass from origin, instead I get 0 current when the voltage between source and drain reaches the value of gate voltage. i.e. if I apply gate voltage of 5V then the current value is 0 at drain voltage 5V, if gate voltage is -5V then the current value is 0 at drain voltage -5V.
Can anyone suggest the reason for such behaviour or any literature explaining such behaviour.
Thank you in anticipation.
Regards,
Chaitanya.
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Giuseppe Curro Thank you for your valuable answer. I will get back to you with the IV curves of my device as soon as possible. Although it may take time of few days as we have vacation of 2 weeks here on the occasion of Diwali festival.
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Hello,
I want to get a MATLAB code for External Quantum Efficiency (EQE) for solar cells as well as I-V and P-V electrical characteristics.
This will allow me to make an electrical and optical comparison on the coating of anti-reflective layers with GaSb as a substrate.
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Dear Dr. Fabrice Mbakop,
You may want to look at the video info presented below:
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Hello, I am working with PEMFC, simulation by Ansys Fluent. I simulate a model and it works well, convergence, and gives a good I-V curve. When I change the morphology of flow field only, keep the same boundary conditions, good meshing (I think so), V_cell 0.65, the model was not converged in the simulation. After around 1000 iterations, the current density reached a certain value and then the cell diverged right after that. at this point, I check the H2O contour and temperature contour, images showed that there's no reactions at anode and cathode, although O2 and H2 are plenty in these flow fields. Can anyone explain that and tell me the influence of flow rate (anode and cathode) on current density and the convergence of the cell. (stoichiometry of 1 at all cases).
Thank you so much
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Dear Huynh Nguyen , you may perhaps find this article beneficial and get potential answer...
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# (c) Silvaco Inc., 2015
# CREATE SOLAR CELL IN ATHENA
go atlas simflags="-P 1"
mesh width=1e12
x.mesh loc=0.00 spac=0.5
x.mesh loc=1.00 spac=0.5
y.mesh loc=0.00 spac=0.05
y.mesh loc=12.0 spac=0.05
y.mesh loc=37.0 spac=0.05
#Region
region number=1 x.min=0 x.max=1 y.min=0.1 y.max=18 user.material=TiO2&Dye
region number=2 x.min=0 x.max=1 y.min=18 y.max=36.9 user.material=Electrolyte
#Electrode #1=anode #2=cathode#
electrode name=anode number=1 x.min=0 x.max=1 y.min=0 y.max=0.1
electrode name=cathode number=2 x.min=0 x.max=1 y.min=36.9 y.max=37
#Doping
doping uniform conc=1e+9 p.type x.left=0 x.right=1 y.top=0.1 y.bottom=18 direction=y
#doping uniform conc=1e+12 n.type x.left=0 x.right=1 y.top=18 y.bottom=36.9 direction=y
material material=TiO2&Dye user.default=Silicon user.group=Semiconductor
material material=Electrolyte user.default=Silicon user.group=Semiconductor
material material=TiO2&Dye permi=50 affinity=4.0 eg300=1.5 nc300=2.8e19 nv300=1.9e19
material material=Electrolyte permi=3.5 affinity=3.4 eg300=0.93 nc300=2.8e19 nv300=1.9e19
material material=TiO2&Dye sopra=Tio2.nk
material material=Electrolyte sopra=Lif.nk
material material=Electrolyte qe.exciton=1.0
material material=Electrolyte knrs.exciton=1.82694e6 lds.exciton=0.0 taus.exciton=1.0e20 rst.exciton=1.0
material material=Electrolyte a.singlet=2 s.binding=0.004
material material=TiO2&Dye mun=0.3 mup=3e-4
material material=Electrolyte mun=7.07e-2 mup=7.07e-2
contact name=anode workfunction=4.4
contact name=cathode workfunction=4.4
structure outf=solarex01_0.str
# FIRST ATLAS RUN TO FIND SHORT CIRCUIT CURRENT AND OPEN CIRCUIT VOLTAGE
go atlas
mesh infile=solarex01_0.str
# set contact material to be opaque
material material=Aluminum imag.index=1000
material material=TiO2&Dye user.default=Silicon user.group=Semiconductor
material material=Electrolyte user.default=Silicon user.group=Semiconductor
material material=TiO2&Dye permi=50 affinity=4.0 eg300=1.5 nc300=2.8e19 nv300=1.9e19
material material=Electrolyte permi=3.5 affinity=3.4 eg300=0.93 nc300=2.8e19 nv300=1.9e19
material material=TiO2&Dye sopra=Tio2.nk
material material=Electrolyte sopra=Lif.nk
material material=Electrolyte qe.exciton=1.0
material material=Electrolyte knrs.exciton=1.82694e6 lds.exciton=0.0 taus.exciton=1.0e20 rst.exciton=1.0
material material=Electrolyte a.singlet=2 s.binding=0.004
material material=TiO2&Dye mun=0.3 mup=3e-4
material material=Electrolyte mun=7.07e-2 mup=7.07e-2
material material=TiO2&Dye taun0=1e-6 taup0=1e-6
material material=Electrolyte taun0=1e-6 taup0=1e-6
# set light beam using solar spectrum from external file
beam num=1 x.origin=10.0 y.origin=-2.0 angle=90.0 power.file=solarex01.spec
# saves optical intensity to solution files
output opt.int
models conmob fldmob consrh print
solve init
solve previous
# get short circuit current
log outf=solarex01_0.log
solve b1=1
extract name="short_circuit_current" max(abs(i."cathode"))
save outf=solarex01_1.str
# get open circuit voltage
solve init
solve previous
contact name=cathode current
solve icathode=0 b1=1
extract name="open_circuit_voltage" max(abs(vint."cathode"))
save outf=solarex01_2.str
tonyplot solarex01_2.str -set solarex01_2.set
# SECOND ATLAS RUN FOR SPECTRAL RESPONSE
go atlas
mesh infile=solarex01_0.str
# set contact material to be opaque
material material=Aluminum imag.index=1000
material material=TiO2&Dye user.default=Silicon user.group=Semiconductor
material material=Electrolyte user.default=Silicon user.group=Semiconductor
material material=TiO2&Dye permi=50 affinity=4.0 eg300=1.5 nc300=2.8e19 nv300=1.9e19
material material=Electrolyte permi=3.5 affinity=3.4 eg300=0.93 nc300=2.8e19 nv300=1.9e19
material material=TiO2&Dye sopra=Tio2.nk
material material=Electrolyte sopra=Lif.nk
material material=Electrolyte qe.exciton=1.0
material material=Electrolyte knrs.exciton=1.82694e6 lds.exciton=0.0 taus.exciton=1.0e20 rst.exciton=1.0
material material=Electrolyte a.singlet=2 s.binding=0.004
material material=TiO2&Dye mun=0.3 mup=3e-4
material material=Electrolyte mun=7.07e-2 mup=7.07e-2
material material=TiO2&Dye taun0=1e-6 taup0=1e-6
material material=Electrolyte taun0=1e-6 taup0=1e-6
# set monochromatic light beam for spectral analysis
beam num=1 x.origin=10.0 y.origin=-2.0 angle=90.0
# saves optical intensity to solution files
output opt.int
models conmob fldmob consrh print
# spectral response
solve init
solve previous
solve previous b1=0
log outf=solarex01_2.log
solve b1=1 beam=1 lambda=0.3 wstep=0.025 wfinal=1.0
tonyplot solarex01_2.log -set solarex01_3.set
# The "Available photo current" accounts for absorption in semiconductor regions only.
# Users interested in the overall absorption need to calculate EQE as:
# EQE=I anode / I Source Photo Current * Absorption
extract init inf="solarex01_2.log"
extract name="IQE" curve(elect."optical wavelength", \
-(i."anode")/elect."available photo current") outf="IQE.dat"
extract name="EQE" curve(elect."optical wavelength", \
-(i."anode")/elect."source photo current") outf="EQE.dat"
extract name="EQE2" curve(elect."optical wavelength", \
-(i."anode")/elect."source photo current"*elect."Absorption") outf="EQE2.dat"
tonyplot IQE.dat -overlay EQE2.dat -set solarex01_1.set
# THIRD RUN FOR I-V CHARACTERISTICS
go atlas
mesh infile=solarex01_0.str
# set contact material to be opaque
material material=Aluminum imag.index=1000
material material=TiO2&Dye user.default=Silicon user.group=Semiconductor
material material=Electrolyte user.default=Silicon user.group=Semiconductor
material material=TiO2&Dye permi=50 affinity=4.0 eg300=1.5 nc300=2.8e19 nv300=1.9e19
material material=Electrolyte permi=3.5 affinity=3.4 eg300=0.93 nc300=2.8e19 nv300=1.9e19
material material=TiO2&Dye sopra=Tio2.nk
material material=Electrolyte sopra=Lif.nk
material material=Electrolyte qe.exciton=1.0
material material=Electrolyte knrs.exciton=1.82694e6 lds.exciton=0.0 taus.exciton=1.0e20 rst.exciton=1.0
material material=Electrolyte a.singlet=2 s.binding=0.004
material material=TiO2&Dye mun=0.3 mup=3e-4
material material=Electrolyte mun=7.07e-2 mup=7.07e-2
material material=TiO2&Dye taun0=1e-6 taup0=1e-6
material material=Electrolyte taun0=1e-6 taup0=1e-6
# set light beam using solar spectrum from external file
beam num=1 x.origin=10.0 y.origin=-2.0 angle=90.0 power.file=solarex01.spec
# saves optical intensity to solution files
output opt.int
# saves beam intensity to the log files
probe name=inten beam=1 intensity
models conmob fldmob consrh
solve init
solve previous
log outfile=solarex01_3.log
solve vcathode=-0.01 vstep=-0.01 vfinal=-1*$open_circuit_voltage name=cathode
log off
solve init
solve previous
solve b1=1
log outfile=solarex01_4.log
solve vcathode=-0.01 vstep=-0.01 vfinal=-1*$open_circuit_voltage \
name=cathode b1=1
log off
tonyplot solarex01_3.log -overlay solarex01_4.log -set solarex01_4.set
extract init infile="solarex01_4.log"
extract name="Jsc (mA/cm2)" $short_circuit_current*1e08*1e03/20
extract name="Power" curve(v."cathode", (v."cathode" * i."cathode" *(-1))) \
outf="P.dat"
extract name="Pmax" max(curve(v."cathode", (v."cathode" * i."cathode" *(-1))))
extract name="V_Pmax" x.val from curve(v."cathode", (v."cathode"*i."cathode"))\
where y.val=(-1)*$"Pmax"
extract name="Fill Factor" ($"Pmax"/($"short_circuit_current"*$"open_circuit_voltage"))
extract name="intens" max(probe."inten")
extract name="Eff" ($Pmax/($"intens"*20/1e8))
tonyplot P.dat
quit
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If anyone can help me with TiO2&dye nk values and graphs ?
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I'm searching a few PiN Diode. But the I-V characteristics are quite different. I cannot understand why the photo current's lowest level is not 0V. and the reason of Shift. Thank you for answer
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One may think of photodiode when at 0V external as effectively being reverse biased to about 0.6V (about half bandgap, for higher precision one needs to take into acount ratio of logarithm of doping concentration and doping profile). Reverse biasing means wider depletion region so more of rather penetrating red photons can be captured in depletion region and contribute to photocurrent.
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I used osilla I-V solar cell software system to characterize my sample but the graph is straightline with very large fill factors, though it register the PCE, Rsh, Rs, Voc. The graph is uploaded below.
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Yes i have gotten the answer to it. I have to take the Jsc and Voc and simulate it in matlab to get the curve
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I am simulating the breakdown of a si vdmos, when it reaches the breakdown, the progorm gets Non convergence with the increasing drain voltage, so I try to increase the current of drain useing the following codes, but the progrom gets convergence, but I-V cure goes back with the increasing drain current, I dont know the reason, does anyone have met the similiar issues?
models srh fldmob surfmob auger
impact selb
contact name=gate n.polysilicon
interface qf=3e10
solve init
method newton trap maxtraps=10 climit=1e-4 ir.tol=1e-30 ix.tol=1e-30
log outf=VDMOSFET_BR.log
solve vdrain=0.1
solve vdrain=1
solve vdrain=10
solve name=drain vstep=2 vfinal=52
solve vstep=0.1 vfinal=52.5 name=drain compl=1.e-2 cname=drain
contact name=drain current
solve previous
solve istep=1.2 imult ifinal=1e-03 name=drain previous
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Henri Cloetens Thanks so much for answering. But I didn't quite get your idea. Indeed, the "go back" happens at the point of breakdown voltage, and you describe the process of avalanche breakdown in detail,but for normal sistuations, as the breakdown happens, the I-V cure should just goes up sharply, right? I still don't understand why it goes back. Thanks.
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I am unable to measure the illuminated I-V characteristics of solar cell using kickstart2 with interfacing with Keithley. Dark characteristic is fine. But when the cell is illuminated, there is noise at low voltage region and also some points are not calculated. I am attaching the image file at one illumination level. We are using 4-wire connections. We are not getting this type of noise in dark I-V characteristics. Not able to understand why we are getting these type of characteristics in illuminated conditions. Would be really thankful for valuable guidance.
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What is the solar cell that you are testing?
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I know that at nanoscale conductance is quantized and is determined by transmission probability and number of transmission channels (G value). I know that using uncertainty principle we can derive how I/V becomes 2e^2/h. However, I am a little confused by the zero bias and finite bias conductance. Does zero bias conductance mean that even if we do not apply any voltage, current would still flow?
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I can help as per my limited knowledge. You can post your question here, or start a new thread.
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I am unable to measure the illuminated I-V characteristics of solar cell using kickstart2 with interfacing with Keithley. Dark characteristic is fine. But when the cell is illuminated, there is noise at low voltage region and also some points are not calculated. I am attaching the image file at one illumination level. We are using 4-wire connections. We are not getting this type of noise in dark I-V characteristics. Not able to understand why we are getting these type of characteristics in illuminated conditions. Would be really thankful for valuable guidance.
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Dr. Kumar
I am not sure about the reason for your abnormal results, but I think the following might be helpful for you to understand the results.
This presentation describes the limit of the I-V measurements very well. Unfortunately, some parts are written in Japanese, but you can understand through speculation.
In addition,
"Effects of I–V Measurement Parameters on the Hysteresis Effect and Optimization in High-Capacitance PV Module Testing IEEE J. Photovolt., 8(3), p.710-718 (2018)"
Good luck
I.S.
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I have measured the I-V curve of a solar cell, and I got the this curve. Why the I-V present this weird form? What are the possibilities of being at this? Thanks in advance.
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I would like to pay attention to my previous answer. I would like that you be vet aware that you can operate you solar cells this current peaking near the maximum power point. It will work well. This Curve is accepted.
This may ease the fabrication of the solar cells.
Best wishes
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Dear colleagues,
I am trying to calculate I-V characteristics for typical (Left electrode) - (Device) – (Right electrode) system. Besides the well-known problem of difficult electronic convergence in NEGF, I notice that final atomic forces along transport direction near the electrode-device region increase largely while increasing bias voltage. Please, see dashed ellipses which denote these “problematic atoms” and Trans.fdf file attached.
For instance,
voltage = 0 V: forces ~ 0.005 eV/Ang
voltage = 0.01 V: forces ~ 2.5 eV/Ang
voltage = 0.04 V: forces ~ 10 eV/Ang
voltage = 0.08 V: forces ~ 22 eV/Ang
Other atoms also possess larger forces while increasing bias voltage, but much less than these two “boarder” atomic layers near the device region. Intuitively I can guess that some of my input parameters lead to a wrong seam (inter-connection) of bulk-like electrode and device region.
Maybe some of the following flags (or related to them) are used wrongly:
TS.Elecs.Bulk true
TS.Elecs.DM.Update cross-terms
Or maybe I should modify some TS contours while changing voltage. Now contour definitions are kept constant for each bias.
To be noticed, for each new bias the previous TSDE file is used to accelerate electronic convergence (DM and H criteria) and for each bias it is succesfully converged. But, again, forces become bigger and bigger.
So, would you mind answering two main questions?
1) Do these large forces are really wrong or it’s some methodological artefact and I should simply ignore it?
2) If such force enlargement is a bad symptom, how to fix it?
Thank you in advance for any suggestion or comment.
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Why should they? There could be charge transfer between the surface and graphene.
I will close this discussion here, if you have other questions, please open them here:
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four types of switching behaviours are known (1) Binary Switching behaviour (2)multilevel Switching Behaviour (3)unidirectional analog switching behaviour (4) bidirectional analog switching behaviour
in the following IV which one of the behavour is seen ? bidirectional analog switching behaviour ???? What more is it showing
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welcome!
What you have here are nonlinear I-V curves and no switching. Switching exists when you have an S-type curve. Then in this case you have a bistable state.
I would like that you see the I-V curves of resistive switching in the papers at the link:
Best wishes
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I-V Characterization of thin-film memristor and Interpretation of Pinched Hysteresis Loop
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Hello.
I'm trying to measure the rectification behavior with 2 metals, but when two metals are deposited above the semiconductor, the I_V graph does not show a rectification behavior and acts as a resistor. However, with just one metal deposited, the rectification behavior takes place. I'm using the contact type point.
Why does it happen?
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you can remember what the material is used and if you have experimental with a theoretical model
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Can we learn things from the shape of the IV curve of a diode in order to examine issues and phenomena that exceeds from ideal behavior? Things like the slope of the reverse or forward bias, the knee point s-shape, etc.
What mechanisms, for example, tunneling, SRH, strain in heterojunctions, shunt paths, schottky contacts, too high series resistance, hot carrier effects, panch-throghs, traps, non ideal doping, etc. These are known effects but I'm not sure if and how they reflect in the IV curve or if there are other less known effects that I missing out.
Are there good reviews summarizing different issues and effects in the device (design, process, fabrication) and how they con reflect on the IV curve?
Most material I found talks about these effects but in the context of desired effects on different devices.
Where can I start the learning of issues in PN diodes, or semiconductor structures in general.
Any input on this matter will be highly appreciated.
Thanks
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I treated some anomalous behavior of pn diodes either homo or heterojunction in the context of operation of the solar cells. I could at that time model and fully explain the S- curve of the illuminated solar cell characteristics.
I would like that you follow the paper in the link:
I also could fully explain the large ideality factors in heterojunction diodes and solar cells: I covered this issue in two papers:
Dependence of dark current on zine concentration in Znx Cd1-x S/Zn Te hetero – junctions“M. Abdelnaby, A. Zekry
Solar Energy Materials and Solar Cells 29 (january)
Capacitance and conductance of Zn/sub x/Cd/sub 1-x/S/ZnTe heterojunctions
A Zekry, M Abdel-Naby, HF Ragaie, F El Akkad
IEEE transactions on electron devices 40 (2), 259-266
Best wishes
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...
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thank you, for remeasuring I-V.
Say, please, what your sample (material/device).
Also, send (or message), if possible, a draft photo of your sample, including the (2?, or more) electrical contacts.
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Why is I-V characteristic in 10 nm thin film of HfO2 non ohmic/switching type?
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see iarticle
Photodiode characteristics of HfO2 thin films prepared by magnetron sputtering
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I have the short circuit current density calculated from supposed solar cell thin film system
and I want to calculate the short circuit current for a solar cell to plot the I-V & P-V curves
how can we deal with scale up .
any reference please
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welocme!
If you have the current density and you want to calculate the current then you need only to multiply the current density by the active area of the device. The active area must be free from any opaque layers such as the metallic strips acting as busbar to collect the current to the output terminal of the solar cell, and the cross section must contain all the solar cell layer structures. The thick or thin here do not play any role as the layer thickness appears in the vertical layer structure of the solar cell.
So I agree with
Behnam Farid
.
If you display your solar cell structure one can tell you about the active area of the solar cell.
Best wishes
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How to calculate dI/dV/(I/V) in STM? While i calculate it , it also diverges around Ef. How to solve this problem ? Thanks a lot.
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Around EF, I and V are very small, obviously. Therefore you may get artifacts there when I approaches 0 faster than V does because dI/dV/(I/V) contains a "division by almost zero". Maybe it is sufficient to just smooth your raw I/V data before calculating the derivative and performing the division.
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I am working with semiconductor devices modeling. At an early stage one need to validate the developed model with data extracted from papers. sometime the reported I-V characteristics is normalized with the channel width. For example what will be the actual value for current in the shown figure?
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I think it is better to use the simulation [(FDTD) Lumerical ] and there are many examples on the internet
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Hi, I'm studying the electrical properties of amorphous SiC.
I have plotted the I-V curve using data coming from a 4 probe configuration on a TLM structure: the two probes for voltage measurement are in 2 contact pads distant 70micron and the other 2 probes for current injection are in other two external contact pads.
The current used is: from -0.01pA to 0.01pA.
The graphs are more or less straight lines. The strange thing is that at 0 current the voltage is different from zero (around 300 mV).
The idea is that there aren't ohmic contacts , because for ohmic contacts at 0 current the voltage drop should be zero too.
Anyway I don't understand why there is a voltage drop at 0 current.
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welcome,
As you measure a material with very high resistance then the voltmeter may be of the type electrometer with vey high gain amplifiers. Such voltmeters may have to be zeroed before measurement. Which means that this voltage is generated in your voltmeter and you have to refer to the manual of your voltmeter and how you zero it.
The other cause may be due to interference from any nearby source.
When you measure such very impedances you have to shield your probe station to avoid any interference from surrounding sources.
Best wishes
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Hi , while taking repeatedly IV graph from four probe i m getting graph like this , My film is tin selenide . Why am i not getting contact restivity ?
Main goal was to check sheet resistance of the film
using agilant SMU
What is the reason behind a sudden bump near zero ?
what is the reason behind no constant resistance ?
Can we calculate the thick by knowing sheet resistance ??
I am using agilant b 2901a
and "Jandel four probe "
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The resistance is R = Delta(U)/Delta(I) thus you have constant resistance on the positive and negative currents, the inverse of the slope.
The slope is constant, thus the resistance (in absolute value) is constant.
Your mistake is that you compute R at each step as R= U/I not as
R = Delta(U)/Delta(I)
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I've recently trying to make Schottky diodes using n-type silicon (waveguide shape, ~10um wide). I used silver for my Omni contact and gold for Schottky contact. These metals are both 20nm thick and the distance between two contacts are about 200~300um.
However, I got an I-V curve just like an normal resistance. Where could it possibly go wrong? Is the material? (Maybe my material is contaminated? Mistaking p type Si as n type?) Or maybe the physical scale of my structure? Or some other reasons?
Hope someone give some advices. Thanks.
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Dear Sung Pu Yang,
rectifying (Schottky diode) IV-characteristics are usually obtained for high resistivity / low doped material and appropriate Schottky metal choice,
so what´s the doping level of your n-type silicon.
Another effect of Schottky diode rectifying quality (non-linear behavior) is the
surface preparation before metal deposition and area itself:
A very large Schottky contact can look like a ohmic, if this voltage drop
is not the dominant one in your complete network.
Maybe it helps to reduce Schottky diode area as potential
defect sites enabling ohmic current can be avoided?!
Try to analyze IV-curve in the very close vicinity of 0V (+/-0.5V).
Good luck,
Thomas
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I shall prepare semiconductor to use in solar cells
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Theoretically:
From XRD patterns as follows:
Variations in the height of the specimen in its holder, whether increasing or decreasing, cause XRD peaks to change from their original location.
Important and useful pathways are connected to the XRD Curve:
Scherrer’s equation:
Particle Size, D = (0.9 x λ)/ (d cosθ)
λ = 1.54060 Å (in the case of CuKa1) so, 0.9 x λ = 1.38654
Θ = 2θ/2 (in the example = 20/2)
d = the full width at half maximum intensity of the peak (in Rad) – you can calculate it using Origin software.
To convert from angle to rad
Rad = (22 x angle) / (7 x 180) = angle x 0.01746
Example: if d = 0.5 angle (θ)
= (22 x 0.5)/ (7x 180) = 0.00873 rad
Then
Delta=1/D^2
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Highly nonlinear bistable current-voltage (I–V) characteristics are necessary in order to realize high density resistive random access memory (ReRAM) devices ( resisitive switching device ) . Kindly explain it .
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In order to store either logic one or logic zero in a memory cell the memory cell itself must have two stable states which means that the memory device must have Bastable states or bistable I-V curve curve.
Assuming that the memory cell has bisatble I-V curve then the the I-V curve will have S shape with two positive slope potions at the lower and the higher currents.
These two positive slope portions are connected by a negative differential line piece.
In the negative differential resistance portion the device is not stable.
So the device can be operated in the low stable current branch as logic zero and operated in the high current stable sate as logic one or vice verse.
The transfer between the two sates can be affected by a control on the device.
One of such devices which I developed to a static RAM is microthyristor.
I would like that you get more information about this new memory which is based on the S I-V curve by following the paper:
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  1. See the Figure1, it's my I-V simulation result about PDs, however, the photocurrent remains the same (Figure 2).
  2. According to the literature read in the past, the photocurrent changes under different bias voltages. (Figure3)
  3. Thus, I want to consult friends in the light detection/solar cell device related fields how to solve this problem, or is the result like this?
  4. thank u very much!
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Dear Liang Chen ,
1) Current flowing in photodiode has two components : Dark current + Photocurrent.
Dark current or short circuit current is negligible whereas photocurrent changes with the light intensity.
2) Dark current is a drift current which is bias independent whereas photocurrent is a diffusion current.
3) Photodiode is always biased in RB condition.
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Hello, I am studying Dram via Sentaurus T-CAD program.
I want to run my device file for I-V or others.
But it sometimes works and I saw some answer and suggestions.
I wonder how i know the mesh size for device?
my device is 3D and 180*34*800 nm
mesh size max: 0.005 0.0025 0.0025/ 0.001, 0.001, 0.001
I just want to know where is it in device manual.
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Small mesh size= High accuracy with more calculating time
Large mesh size= Normal accuracy with less calculating time
We just have to use smaller mesh size at the critical junctions, otherwise normal mesh size will be better choice at other places.
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I was studying I-V characteristics of dc plasma and i was confused why voltage decreases after breakdown when current increased. At first i was thinking that till breakdown more electron stuck at the electrode and that increases electric field and that's why voltage increases. When breakdown occurs avalanche of electron pass through electrodes and number of electron around electrode decreases, electric field decreases and that's why voltage should decrease. I don't know whether it is true or not but i assumed it can follow by this.
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I agree with the answers of my colleagues, Gianpiero Colonna and others mentioned above. I also recommend to pay attention to the electrophysical properties of the plasma-forming gas that you used in your gas discharge. And look through the classic books that are available, in particular: Yu. P. Raiser, Gas Discharge Physics, Springer, Berlin, New York, 1991, 1997, as recommended by Yuri Ionich. By the way, Professor Raiser is also still alive and kicking at his 94 years old, despite all the problems with the coronavirus around us. This is what real life-giving plasma means! Best regards.
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Hello
Recently, I tried to measure I-V curve of graphene FET device based on ion-gel
The material of ion-gel is P(VDF-HFP) + [EMI][TFSA]
The thickness of ion-gel is roughly 500-800 nm
When I tried to measure I-V curve (I-V for graphene between source and drain, gate voltage is applied to nearby Au pad), I got this weird result... (file is attached
Is there anyone who knows why this thing happen and how to fix it?
Thanks
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Dear Riaz A. Khan
Thanks for your answer
I will check them carefully
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I have a question. I designed and simulated a tunnel diode using ATLAS with varying the doping concentration of P layer. now, I saved every design with its own .in file and plotted the I-V curve for each then export the data into .dat file (I have 5 .dat file by 5 different doping conc "i.e. 5 different designs"). The question is how to combine these .dat files in one graph to compare among them? (Note: Each design has its own .in file.)
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Dear Omar Saif ,
I would like to second Rajiv Thakur
You can export you data files to matlab and draw them together in one graph.
Best wishes
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The Suns-Voc method can be used to get the pseudo I-V curve and pseudo FF. But why the validation of Superposition principle necessary to construct the pseudo IV curves ?
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Welcome!
By applying the superposition theorem we get that
the solar cell terminal current I= the shortcircuit current Isc - the dark current Id,
If the collected photocurrent is affected by the solar cell bias then one has to substitute Isc by the real collected photocurrent which is affected by the terminal voltage. And so, the superposition principle will be no longer valid.
I= Isc - Is( exp (V+IRs)/nVt) neglecting Rsh the shunt resistance effect.
Under open circuit condition I=0 and it follows that
Isc= Is exp Voc/ nVt, from which one can get Is and n eqn (1)
It is known that Isc is proportional to G the insolation.
If the superposition principle is not valid you can get eqn (1)
For more discussion about the validity of the superposition principle please refer to the paper in the link:
Best wishes
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When measuring dark J-V of solar cells, why is the minimum current voltage measured for the dark I-V characteristics of the OSCs not at zero?
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As a result of the presence of a leakage current, this leads to the emergence of a non-zero deflection voltage and it moves away from zero a lot as the leakage current increases.
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Dear researchers,
I am currently trying to perform I-V measurements for thin films. Could anybody let me know what is the best way to perform I-V measurements using Keithley 2600. How to make good top contacts for good I-V data. Any kind of suggestion or some discussion would be helpful.
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The best metal contact electrode is the one whose work function is as high as platinum, for example, because the higher the work function of the metal contact electrode, the greater the opening voltage of the circuit as well.
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Dear Researchers,
I would like to invent to see film our research group. We present our study and laboratory at University of Rzeszow (Poland).
Our research is focused on the optimization and development of semiconductor devices and especially solar cell structures based on copper oxide and titanium dioxide. TiO2/CuO thin-film heterojunctions have been fabricated by direct current reactive magnetron sputtering using the Modular Platform PREVAC. Initially, the I-V characteristics of our TiO2/CuO solar cells were not shown photosensitive behavior. After 3 years extensive research we successfully obtained TiO2/CuO solar cells.
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Architecture : FTO/Cp-TiO2/MAPbI3/Spiro-meotad
This phenomenon is noticeable when only Cp-TiO2 is used without stacking MP TiO2 layer. Also, like the graph, it is a common I-V graph format at first, but when you measure the light multiple times, the graph suddenly becomes strange at a certain voltage.
I want to know the reason.
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Hope you are well!
This strange behavior may be solved.
However i would like to add a comment.
This behavior is due to the pentation of moisture to your perovskite layer through the pin holes in the Titanium oxide layer.
My expectaion is based on the disappearance of the anomaly when you added an additional layer of TiO2.
Best wishes
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I want to calculate Jsc from EQE and want to match with Light I-V data. Could you please suggests the method?
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Please Check this for direct calculation
Created by Prateek Malhotra
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Dear colleagues,
The current-voltage measurements (I-V) are performed on Zn(1-x)CaxO/p-Si for different x . I extract the different parameters of the p-n junction, such as the threshold voltage, the IF / IR rectification ratio, the diode ideality factor (n), the saturation reverse current, the potential barrier Fb, and the series resistance (Rs) using the standard I-V method, Nords and Cheung method’s.
I obtain practically the same potential barrier Fb by these 3 methods but the diode ideality factor (n) and the series resistance (Rs) calculated by these methods are different. It's normal? If yes, what has caused this great difference.
Thanks for all in advance.
Have a nice day
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I am reading a paper and it mentions that when the applied electric field increases to a threshold value, the screening charges are pulled and begin to move away from the polar surface and as a result band bending occurs. I need some guidance about this screening charges? What are they exactly?
Thanks
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The phenomenon of screening the applied electric field by a surface charge sheet terminating the electric field line is a well known phenomena.
In order to explain this in details assume that we have an nMos capacitor with p-type substage. Assume that the surface of the substrate is charged with a negative sheet charge. Then if we applied positive voltage on the gate it will charge the gate electrode by a positive charge and an electric field lines will be initiated at the positive gate charges and terminated at the the negative charges at the surface of the semicondcutor. Consequently the field line can not penetrate to the underlying semicondcutor. It is called that the negative surface charges screened the semiconductor from the effect of the field in MOS capacitor.
If the gate voltage is increased to a voltage to neutralize the negative charges then the extra field lines can penetrate to the bulk and displace the bulk holes from the surface region causing the depletion and at higher voltage causes inversion at the surface.
In order to understand the screening of the surface charges in the field effect
you can study the topic of the MOS and the MIS capacitor.
If you give the citation of the paper I can look at it.
Best wishes
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I am trying to measure resistance from I-V curve from a chemiresistor/ FET sensor with a keithly sourcemeter. The substrate is soaked/ wet with protein and phosphate buffer only. But the I-V line is not passing through the origin (which probably means it's not showing ohmic characteristics), rather its going through the second quadrant. What could be the possible reason. Picture is attached for reference. Thanks in advance.
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maybe its an offset, check your device on a dummy cell
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I am unable to get a proper I-V characteristic by using silver paste and FTO substrate. As, I do not have any deposition techniques such as sputtering, thermal evaporation for electrode fabrication. Provide some suggestions to have an accurate determination of I-V characteristics of a semiconductor device. The obtained current after light illumination is coming in the range of 10^-11 and 10^-12.
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Welcome!
peace upon you!
Yes you can make a photodetector using any sheet or a film of a semicondcutor material. The material can have p-type , n-type doping or intrinsic. As the doping decreases the photodetector will be more sensitive since its dark current decreases. So, the best material is the intrinsic semicondcutor since it has the smallest dark current as has very few intrinsic carrier concentrations.
Such detectors are called photoconductors or light dependent resistance.
They are commertial devices and you can get them from the electronics market.
Best wishes
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HEK cell is Clamped at different membrane potentials (-100 mV to +90 mV; 10 mv Step with Vh -60 mV) of GluK2 receptor and recorded the current by application of 10 mM L-Glutamate.
Herewith I attached data excel file having individual data points (mV and pA)
Could you please explain how to plot the rectification index curve by using these data points? Just for the example purpose, I have given the N=1 data points.
Thank you.
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Hi Rajesh, take peak current for each clamped potential, then plot these peaks as the function of the clamp potential. Then you will have your current/voltage (I/V) curve.
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Hi all,
I am new to electrophysiology, and I have some inqueries about current-voltage relationship.
Why some authors plot both I-V relationship and I/Imax-V relationship. What is the difference between them?? And why they sometimes show some differences in statistical analysis and/or significance at some potentials when comparing the different treated groups ? For example,.there may be sigificance in I-V plot between gpA and B which disappear in I/Imax-V
2. How can I know that a drug has reached its steady-state of action for example; AICAR.
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When on plots the absolute value of I versus V will be different from one plots the normalized value of I versus V. The normalization expresses the profile of the curve such that one can compare the different cases according to the shape of their profiles. Absolute current values contains more information about the speed of the process. Which may be due to larger area of the electrodes for example.
This is a generic answer for your question. This is process of scaling is called normalization.
Best wishes
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Dear siesta users
I am using transiesta code to get the I-V characteristics of Armchair MoS2 nanoribbon as scattering (with 8 unit cells) and electrode material. All the calculations (electrode, transiesta and tbtrans) run perfectly for the voltage range of 0-2V with good SCF convergence. However, in all voltages I get nearly zero transmission in the bias window and consequently very low current (about 10^-16 A).
Since my armchair MoS2 NR is a semiconductor with the bandgap of about 0.5 eV I expected that current should start to increase exponentially from 0.5 V bias and reach the order of micro Ampere. I have attached .fdf files of my scattering and electrodes.
I would appreciate if someone could help me to find the problem.
Best regards,
Samaneh Soleimani-Amiri
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You can't reliably trust NEGF results for semi-conductors.
The reason is quite simple.
The NEGF method relies on "bulk-like" electrodes. And for semi-conductors the relaxation length is much longer than any typical scattering/device region. I.e. to fully relax the semi-conductor electrostatic potential one would need more than 20 Ang of electrode (and perhaps more!) material to properly screen off the device.
Secondly, if this is a pristine system, i.e. electrode and device being the same material, then I don't think applying a bias makes physical sense.
How would you experimentally apply a bias between two semi-infinite materials in some very small region of exactly the same material? So please don't do bias calculations on pristine systems. :)
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Hi, now I'm graduate student and my research part is perovskite solar cell.
our research teammates started reproducibility experiment at July. and we are still doing it. however, our I-V results have so many noise. and we don't know why.
we use FTO substrate and 4% SnO2 by diluting 15% SnO2. and we use only MAPbI3 and spiro solution without any additives. and we are doing spin coating in glove box, but when we finish coating, there are so many dust on the surface. we also use filter before coating perovskite but not working.
I'll upload our I-V result. please answer it and I hope to find problems.
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Dear Joon,
I think you need to make some post heat treatment in order to achieve good contact between the different layers. The annealing must be made under proper
environment and at the proper temperature. The most suitable atmosphere is using inert gas as N2. Also, the temperature may be in around 100 degree centigrade.
The solar cell itself works properly.
I would like to make a remark: The fill factor is less than one.
In order to get the performance of the cell you have to interpolate you points lying on the curve of the solar cell.
Please report on your further experiments.
Best wishes
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Dear all,
When using tonyplot, I can get the I-V curve without any problems, but when I try to add small signal analysis after gate voltage sweep (ac freq=1e6) in Silvaco Atlas it shows zero Cgd for all gate voltages. I was wondeing if there is a way to plot the C-V curve correctly.
Thank You in advance.
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Maryam
May I give a hint that you may use to solve the problem.
When you want to calculate or measure some physical parameter you must stick to its definition relation. Specifically here, you have
cgd= d QGD/dVGD
In small signal notation
cgd= qgd/ vgd
So accordingly:
You have to set certain DC operating point
apply a small signal voltage vgd in series with the DC bias,
Then measure or calculate qgd.By dividing qgd by vgd you get cgd.
You can also calculate the current igd
Then you you can get igd/vgd= jwcgd which is the susceptance of the cgd.
Best wishes
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For a range of concentrations of protein, I am getting the I-V (Current-voltage) data from a Keithley sourcemeter. Accordingly, I am getting the resistance as the response of protein-protein binding on carbon nanotube on my biosensor. What formula should I use to get normalized response versus concentration gradient? Is there any good textbook on this to show the calculations step by step from scratch? Thanks in advance.
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Dear Touhid,
Prof. Reg Penner's work in Nano Lett. with virus bioresistors for HSA protein detection may be of interest to you. Figure 5 shows the change in resistance as a function of protein concentration (calibration curve). The mathematical fits to the Hill equation are outlined in detail, with more information provided in the Supporting Information. EIS data is also provided to establish an equivalent circuit. This paper may represent a good model for comparison as you put your work together!
Kind Regards,
Matt Glasscott
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I know a rule of thumb is that to avoid any current shielding effects you should not bring the Luggin capillary tip closer to the WE than a diameter length of the capillary. My capillary tip diameter is 1 mm, so I could position the tip 1 mm from my WE. However, my WE is producing hydrogen (I am investigating different cathode materials for an electrolysis cell), and I am wondering if the generated H2 bubbles will start to affect my measurements (I-V curves, etc.), Gas is non-conductive. Thus, I imagine that I should somehow take into account the increased measured resistance that is caused by the bubbles.
Do the requirements for the distance between the capillary tip and WE change when the WE in producing gas?
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The use of a Luggin capillary in an electrochemical cell is only necessary when the current is relatively large, e.g. 10 mA or higher, but its effectiveness is limited by its shielding effect on the electric field distribution near the working electrode surface. However, if the current is controlled to be smaller than 1 mA by for example using a working electrode of small surface area, e.g. a Pt disc of 1 mm in diameter, there is no need to use the Luggin capillary.
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Please specify doping values, if any. I mainly want the I-V to show the effect of recombination at low bias and high injection at high bias
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I can also provide you 3 sets of Ib(Vbe) diodes measurements done on two SiGe bipolar transistors C1 and C2 (S. Chen, D. Prêle et al, Radiation Tolerance of RHBD techniques on a SiGe BiCMOS 350 nm ASIC technology, RADECS 2019). One has been irradiated then measured again. The low injection effect is here clearly visible :
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Dear all,
I am working on mixed cation and mixed halide perovskite solar cells(PSCs). I have found that the steady state output(SSO) always exceeds the efficiency from I-V measurement, usually 1% absolute difference(e.g. 16% from I-V and 17% from SSO of the same cell). I changed the scan rate from ultra-slow to ultra-fast and this difference remain the same. What are the possible reasons for this phenomenon? Which efficiency is more credible and how can I make them in better accordance?
Thanks in advance!
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Dear Deyi,
welcome
You need to show us the forward scan with low scan speed and the reverse scan with the same scan speed. This will show how the hysteresis affects your I-V curves. In fact the solar cell would work without hysteresis in an intermediate line.
As would take the lower curve as a worst case efficiency. In fact such cells have two PCEs. One can argue it has a marginal PCE.
Such hysteresis has been intensively studied to mitigate its formation. And i think you must try to eliminate it.
Best wishes
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In four doped samples the series resistance of the samples was increased with the increasing the dopant percentage, but the I-V results show at a particular voltage the current was increased by these percentages of dopant (it means that the sheet resistance was decreased). How to explain this subject.
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welcome!
I will give a conceptual answer and you review your question and measurements according to my answer.
The doping has two effects:
- increasing the mobile carrier concentration n such that normally n is proportional to N (the doping).
-The other effect is that it decreases the mobility of mobile and remain neural charges
For metallic materials such as silicon the conductivity will mostly increase with the doping as the increase in n over weight the decrease in the mobility.
There are deviations from these rules:
When the dopant atoms are not easy to ionize and remain neutral so they will not increase n but decrease the mobility. In this case the conductivity decreases with the doping.
When one heats up the specimen the neutral impurity atoms and they gets ionized so the conductivity will increase by increasing the temperature.
It can be that as you increase the voltage the power dissipated in the specimen increases and the temperature gets higher ionizing more and producing more mobile charges which can decrease the resistivity,.
This may be some scenario for the behavior pf your material.
please comment!
Best wishes
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Hello, im am currently trying to identify possible current conduction mechanisms for graphene schottky diodes by looking at I-V characteristiscs. From reading book "Physics of semiconductor devices" by Sze I know that depending on the strength of applied electric field, electron drift current is expressed by different equations (for mobility regime, velocity saturation regime and ballistic regime J~V^2, J~V and J~V^1.5 respectively). However, double log plotting I-V characteristics gives lines for all of mentioned mechanisms. Is there any experimental or analytical way to distinguish one from another?
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Welcome.
If you examine the I-V curve, you see that 0.0 point is shifted to the right pointing out a clear forward characteristics with a specific cut in voltage and at the same time a reverse characteristics with lower currents at the the same negative voltages.
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In general, ideality factor ''n'' could be calculated by:
n=(V2-V1)/ln(I2/I1)
where voltage and current are taken from the dark I-V curve.
For simple PN Si diode, it is close to 2.
In my case NPNN Si diode and PNN Si diode, however, the ideality factor is less than 1 (0.05-0.2).
I could not find any explanation or research where the ideality factor could be less than 1.
Any suggestions or comments?
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There is strong evidence that it may be falsely calculated as hinted also by Nicolay.
We have
I=I0 exp V/nVt
Assuming two currents I1 and I2, at V1 and V2, then
V2-V1= nVt ln (I2/I1)
Then
n=(V2-V1)/ Vt ln (I2/I1),
So, you have to divide your values by Vt= 26 mv at room temperature
So dividing your values by Vt, one gets
2 to 8
These values are greater than one.
Best wishes
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Hello!
I am studying temperature- and doping-dependent physical models of semiconductor properties, such as energy gap, intrinsic carrier concentration, carrier mobilities, minority carrier lifetimes. Now I want to understand if I use them correctly. Therefore, I try to apply them to calculate the current-voltage characteristics of p-n junction and compare the calculated curves with published measurements (preferably in a wide range of temperature and doping concentration).
I do not use numerical simulation. I calculate the j(V) using the sequence of equations given in the attached file.
The problem is that the Shockley diode equation requires both Na and Nd values. I studied a lot of experimental work on the I-V characteristics of diodes, but I did not find any suitable paper in which both values of Na and Nd were given. The most interesting semiconductor for me is 3C-SiC, but I also checked many papers on 4H-SiC, 6H-SiC, and even Si (without result). This fact makes me think that I am doing something wrong.
Can you please recommend some suitable papers or point out my mistakes, if any?
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Dear Igor,
welcome,
If you please read carefully the references which i gave in my first comment, you will get a satisfactory answer for sure. The physical and technological parameters
needed to calculate the reverse saturation current are discussed in full details and i measured and calculated them many times.
All waht do you need now is to master the pn junction diode theory.
In case of asymmetrical pn junction we have low doped side which is the n-side with doping Nd and we have the emitter side with high doping which is = Na.
As hinted above Na and Nd are in two different sides og the p-n junction.
So, in the case of unsymmetrical p-n junction the diode reverse saturation current is dominated by the reverse saturation current inth lower doped side.
That is
I0= I0n+I0p with
I0n is the electron current in the p-side and I0p is the hole current in the n-side.
It is so here that
I0p>>I0n
and
I0= I0p to a good degree of approximation.
Also for the width of the depletion region in asymmetrical diode
W= Wn+wp the extension of the scr in the n and p sides respectively.
If Na in the p-side >>> the Nd in the n-side, then
W=Wn
Best wishes
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Hello there,
I just recently started characterizing DSSC solar cells and have purchased a Keithley 2400 SMU, from university project funding. Unfortunately I still cannot figure out how to measure I-V characteristics. The multi meter shows a DC voltage of ~0.2V being generated. The voltage and current measurements should be the same when measured with the help of 2400 SMU, which is not the case. Do I need to alter the settings of the SMU in order to get the (precise) measurements.... is it something related to the compliance settings... please suggest. Am using a two wire arrangement to manually measure current and voltages. Think the same thing is also messing up my automated I-V curve measurements, preformed using SMU and I-V software.
Attaching images of the SMU and Multi-meter readings.
Would be really thankful for the help in this regard. Thanks
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If the compliance is reached, it starts blinking. In your case, the voltage is probably not measured, because you apply AND measure voltage at the same time. It means, if you apply 0V, it is fully correct that you measure 0.0001 V (which is almost zero). I suggest to apply 0V and measure current (which would be the short-circuit current of the solar cell) OR you use Isource and apply 0A and measure the voltage of the cell (which would be the open-circuit voltage). Applying 0A means that the SMU will ramp up to a voltage that suppresses any current flow. Thus: Isource 0A results in using the SMU as voltmeter.
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Evolutionary Algorithms, namely Genetic Algorithm (GA), Particle Swarms Optimization (PSO) and Differential Evolution (DE) are used to solve optimization problems. As in photovoltaics (PV), the I-V characteristic of PV cells is non-linear, which requires a resolution method. So according to the three methods cited (GA, PSO, and DE), what is the best method for solving this non-linear problem according to the strengths and weaknesses of each ?.
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Dear Rachid,
The optimization problem in the pv system where it is required to locate the point of maximum power point is characterized by a relativity broad maximum not a sharp maximum so it will be not very critical for the resolution issue. I think the speed of convergence to the global maximum is important and distinguishing for such a problem. Also the oscillations around the steady sate solution is an other performance parameters of the optimization method.
Best wishes
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Hi all,
I have been working with thin-film semiconductor devices and was subjected to severe hysteresis (occasionally) in the I-V electrical profiles that span across both positive and negative current values.
Is there any way to understand the changes ongoing from the materials perspective or is it purely a measurement artifact that I am facing?
Thanks in advance.
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Hope you are well all!
Dear Poh
It is noticed that your current is very small. It seems me that the hysteresis observed is due to that your film behaves not only a pure resistance but also it has also capacitive effect. Since your resitance is very large , the presence of a capacitive component produces a displacement current in addition the ohmic current.
What do you make to verify this model is to slow down the scanning rate as hinted by the respected colleague professor Ioannis.
Best wishes
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I'm doing research about metal-semiconductor contact properties.
I already know the CTLM and TLM for measuring specific contact resistance ( ρ c)
But these are for the ohmic contact condition(linear I-V curve).
Do you know any other methods which can let me know specific contact resistance at non-ohmic condition?
(Non-ohmic means Schottky or S-shape I-V curve).
Thanks.
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Hope you all to be healthy,
I treated this problem since long time ago where i measured the I-V characteristics of the Metal Semiconductor contacts. At that time the reviewers of my paper told me our metal semicondcutor contacts for the conventional solar cells. At that time, one had no vision that this topic will become important for the advanced solar cell structures. Any how this method is the three electrode method. Details about this method can be found in the paper at the link:
It will help you solving your problem.
Best wishes
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Hello everyone
I want to simulate a 3D-LED. The structure has rectangular shape layers in which one layer of them consists of nanorods. Now, I can simulate a 3D device without nanorods in Silvaco with Mesh three.d. The question is that, how can I plot nanorods or cylindrical Structures together with rectangular shape layers in Silvaco?
BEST REGARDS
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You can use 2D or 3D Silvaco but the runing time in 3D Silvaco becomes greater than 2D. In case of 2D simulation take the first two dimensions in consideration and as a surface the third dimension.
good luck
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we have a double-chambered MFC that produced an OCV that reached 220 mV in 1 h, and was getting higher. after 24 hours the OCV dropped down, and I don't know why.
I want to measure the generated current first to plot the I-V curve, then the power density curve.
  1. Is the OCV drop because we didn't use an external resistance? when should we start applying it to the MFC? can someone explain it in details please.
  2. How to decide whether to use a fixed resistance over time, or to use a range of different resistances to carry out these measurements (I-V Curve, Power density Curve)?
I'm using a digital Multimeter for recording Voltage across either fixed or varied resistors.
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Dear Nedan,
The drop in voltage during the OCV evolution is due to the fact that the substrate is depleting. The substrate, such as organic compounds, has been utilized by the microbes to generate electricity in MFCs. Hence, if you are using a bioelectrochemical system in a batch mode, I strongly recommend you to perform feed (substrate) injection until two sequential equal peaks in voltage are obtained. Depending on the experiment, It is impossible to say the exact time for achieving two consecutive equal peaks in voltage (It may take several days to several months).
Variable external resistances are suggested to obtain polarization and power density curves.
For more information, I suggest the following article.
Best Regards,
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I am currently testing the corrosion behaviour of some metal based materials. The first behaviour was clear for me (as it expected). After polarizing the sample at a high portential for a long time and repating the potentiodynamic polarization measuments afterward, I got a a potentiodyamic polrization curve ( the I-V curve is attached) that has totally different corroison behaviour with three corrosion potential regions . Does anyone have an interprestion for such a behaviour ?
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Dear Dr. Abu Bakr Nassr,
you are looking at an active-passive system that is shifting between these two modes of behavior. After polarizing the sample at a high portential for a long time and repating the potentiodynamic polarization measuments afterward, the surface passive film of your sample probably was in bad conditions and after, during the polarization where you increasing potential scan, you are starting with a surface that is free of a protective passivating film and you get an anodic spike at the potential where the passive film forms. Then, after the surface passivates, you get a "cathodic loop," with two additional zero crossings, due to the fact that the cathodic current is greater on the passivated surface than the anodic current. The 2nd and 3rd zero crossings on increasing potential should correspond to the curvature change and zero crossing on the decreasing potential scan.
Best regards, Pierluigi Traverso
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The Suns-Voc shows a pseudo IV curve without the effect of series resistance. Does this curve show the effect of shunt resistance?
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Dear Nafis,
The relation between the photocurrent Iph versus open circuit for different illumination represents the dark I-V curve of solar cells with RS, the series resistance= 0. The shunt resistance remains included. Since the effect of Rsh is dominant at the lower voltage range near the zero voltage condition, one can get Rsh and then one can subtract its current V/ Rsh from Iph which results in the ideal diode characteristics of the solar cells. From this corrected curve one can get the ideality factro of the diode.
Please such curve in the paper at the link:
Best wishes
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I am trying to do some opto-electronic simulations (I-V, C-V, Bandwidth etc.) of a nano-wire(preferably III-V/ II-VI) based MSM photo-detector using Sentaurus TCAD (Synopsys). I could't find much tutorials or materials on electrical simulation of nano wire based PDs. Along with the general elaboration of opto-electronic simulation, I need some suggestions :
1. For the optical generation part, will the inclusion of 'constant generation model' give adequate accuracy in the I-V plot or is it necessary to use other types like 'ComputeFromMonochromaticSource', 'ComputeFromSpectrum' etc.
2. If the nano-wire dimension is not very small (say R > 20 nm and L>= 300 nm ) then is it necessary to use to the Sentaurus Device QTX Solver to get the I-V or just inclusion of Quantum correction models (eQuantumPotential ) will give adequate accuracy ?
3. I am also thinking of using 'Nonlocal Tunneling Model' for the junctions and interfaces along with the above mentioned models .
Are there any requirements for inclusions of any other modes( Hydrodynamic model, model to incorporate effects of traps and Fixed Charges etc.) ? If yes, then it would be much help if anyone could kindly suggest.
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Thanks you so much Ali Houadef and
Muhammad Hamza El-Saba
for your valuable suggestion. I'll surely check them out and get back to you if I have further issues. I really appreciate your time.
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We use ECOPIA Hall Effect measurement system (Model no. HMS-5300 + AMP55T magnet) in our lab. I am trying to determine the carrier concentration and mobility of PbS thin films. I have made electrodes at the four corners using Gold. I have measured I-V curves of the samples, the shape of the I-V curve is linear (an ohmic contact is formed between PbS and Gold). I did hall measurement of a sample at same condition for three times, it gave me positive hall coefficient for two times and negative hall coefficient for one time. The value is not in the same order and the polarity changes randomly. Even successive measurement runs on the same sample without changing anything at all, is showing completely different results. Why does it show positive and negative Hall Coefficient randomly in different for the same sample at the same temperature? What could possibly be causing this behavior and how can it be overcome?
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Dear Ameni,
I would advice you to observe the hall signal with an oscilloscope. Your signal must be a DC signal if you have clear hall voltage polarity. I expect that you will find strong noise voltage superimposed on you dc signal which may much stronger than the DC Hall voltage. Also , if the sample is high ohmic it can pic up nearby alternating field . Please analyse your signal to get out the cause. I think your specimen is nearly intrinsic and high ohmic.
Best wishes
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Hi there, looking for some help regarding the I-V curve in cell-attached patch clamp (voltage clamp) as I am kinda confused.
Does the current (I) in the I-V curve, represent the highest peak current/amplitude or is it the mean amplitude?
Thank you in advance for your kind answers.
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Thank you Chris
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I have a silicon thin film , and i need to determine the change in electrical properties as changing the concentration of the substrate on its surface
Can this be obtained using potentiostat ?(cyclic voltammetry or Linear sweep voltammetry ) ?
considering that no place for the reference electrode , I used it on the surface but it makes no sense
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Curtis Guild
Thanks professor Curtis
I would like to ask about using sodium sulfate aqueous solution , i didn't get it .
in the sensor i use the substrate will be immobilized on silicon surface , then washed with distilled water , no aqueous solution will be used , in is this case can I use the three electrode as well ?
thanks alot
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Hi
I use axograph. I do current and voltage clamp recordings. I have been trying to create a protocol for an I/V curve, but using current channel input and output produces a plot that displays Current instead of volts in the Y axes. The program doesn't give me the option to indicate current in mV. Any suggestion of what to do?
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Dear Antonieta: You may transfer the data you selected (i.e., text file or Copy-and-Past) to either Excel or other application program to make I/V curve for better illustrations.
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I am observing a different I~V cyclic voltammogram while doing 2 electrode test in electrochemical measurement. I don't understand the reason behind this behavior.
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Yeah. It was an artefact I guess. Changing some parameters in the software omitted these curves. Thank you all.
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I am working on Low temp. schottky diodes. It is the extended work of my recent publication " The influence of antimony doping on I–V, C–V-f and (G/w)-V-f characteristics of indium/ SbXW1-XSe2 (X=0, 0.1, 0.5) alloy Schottky diodes".
Normally, ln(I0/T2)-1000/T have negative slope , but i got positive slope in one case. can it be possible??
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Thank you.
I assume that these data originate from fitting the IV characteristics in Fig. 2b? In that case, what you are probably observing here is an ohmic shunt developing at low temperatures (<200K). See how the current for 180K, 160K and 140K is lower than for the higher temperatures as soon as the voltage is above 0.25V? THIS is your diode current; but below that voltage, you have a shunt, i.e. parallel resistance dominating the characterstics. My guess is that something in your sample broke during measuring. This could have happened during cooling, for example some delamination of your metallization, failure of contacting/bonding etc. There are anumerous possibilities. Checking the behaviour upon heating would therefore be interesting to see (i.e., does it restore to the initial behaviour or does the shunt remain?).
From what I can read in your paper, you considered the series resistance, but not the shunt resistance in your modelling. I suggest you try that and see what it does to your I0 and n values (although the range you do your fit is pretty narrow, might be difficult). The diode parameter values as you have them now -- both in your published paper and in your new data -- are probably not physically meaningful whenever that shunt appears.
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Hello,
I am designing a push-pull converter which source is a PV panel with MPPT algorithm.
I need to have calculation method for the output inductance.
I know the calculation in regular push-pull converter with normal DC source however, PV panel I-V curve changes everythings as i assume.
The output voltage is going to be kept 400V ( for now I am changing the output resistor according to input power).
The rated power is 300W.
The input voltage of the converter is between 25V and 45V.
Finally, I want to keep CCM operation until %10 of the rated power.
I am so confused so far. Amy help would be appreciated a lot.
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Tony Maine thanks for the answer.
I know the behavior of the PV panel and of course not to short circuit the battery :).
But the problem is the Duty cycle values that the MPPT algorithm founds.
Normally and ideally the input-output voltage equation of a push-pull converter is Vout=Vin*2*n*D at CCM operation, where n (let's say n is 16.75) is turn ratio and D is duty cycle.
So if I have a Panel that operates 45V and 6.6 A at the maximum point the required Duty cycle value for having 400V output is 26%. With these conditions, it is easy to calculate required inductance according to given ripple current, etc.
However, when the irradiation reduces so as the panel maximum current value,
the MPPT algorithm reduces the D value in order to get the maximum point.
Then the Vout equation I wrote above is out of order because the output voltage is 400V again (I changed the load resistor in order to keep the voltage constant) and the PV panel voltage is 44V ( a little drop due to irradiation changes)
My goal is, to calculate the required critical inductance( for CCM) for the second situation but I can't estimate the duty cycle that the MPPT algorithm calculates.
I have a detailed Simulink simulation and a real circuit. I am testing these situations in both.
I hope I made it clearer.
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I have a p-type silicon wafer with resistivity of 0-0.0015 .
How to obtain the I-V curve for such a sample?
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Ahmed:
The following website will show you how to pass current between two outer probes and measure voltage between two inner probes of a 4-point probe tool used to measure resistivity of a bulk sample. Gathering a set of I-V values, you should plot them and if it is a linear plot, the slope of this plot can be related to your resistivity value.
You may recommend my answer if it is helpful to your question.
Sincerely,
Dr. Nabil Shovon Ashraf
Associate Professor
SAC 932
Department of ECE
North South University
Dhaka, Bangladesh.
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Hello everyone,
Right now I'm trying to simulate individually a solar subcell of Germanium. My goal is to obtain the I-V and P-V curves from it, and then simulate two more subcells individually before I simulate the tandem cell as a whole.
The problem is I must be doing something very stupid since my potential is negative and therefore my I-V curve starts at zero, descending into negative values as the voltage increases.
Can someone point me out what I'm doing wrong?
Thank you!
Edit: I'm currently using COMSOL Multiphysics version 5.4
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The issue of current being positive or negative depends on your frame of reference. In a circuit without any power sources, it's easy to see which direction the current flows and define that direction to be 'positive'. But that's just a convention. Now try putting power sources in your circuit and you'll find currents flowing in the opposite direction. So you might call them 'negative' - but it's just a convention and it certainly isn't stupid to do so!!
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What parameters of a solar cell can be monitored using Dark I-V Measurement? What is the significance of conducting dark I-V measurement.
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I am curious to know that whether Dark I-V measurements obey very basis ie Ohms Law .
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Attached is an I-V curve I am receiving from a solar cell structure. Would the exponential decay be better explained by a high series resistance or low shunt resistance? Thank you for your time.
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You need to measure the dark I-V characteristics.
The first glimpse shows very high nonlinear series resistance.
You have also poor junction.
Best wishes
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I know short circuit current, open circuit voltage, sunlight intensity and temperature of a solar cell; and I want to see the I-V profile. Is there any method of obtaining I-V curve for aforementioned parameters ? Do I need to measure any other parameter for this analysis? Is there any easy way to see the I-V profile of a solar cell?
I will be very thankful to you if you advise me about this problem.
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Hi Manoj, it depends very much what instrument you are using to measure your solar cell parameters. Using a Keithley 2400 series source meter is a popular choice, and they build very good instruments. They also have quite a bit of information on how to carry out such measurements and have sample software too which is a great stating point. See for example:
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Porin channels are present in epithelium (GIT) and endothelium (blooe vessels) for permeation of hydrophilic substances. Then why highly hydrophilic drugs are given I/V instead of oral route?
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The attached article sheds more light on your question.
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I am measuring the resistance of a CNT thin film deposited on Si substrate with a four probe attachment setup. The setup consist of a nanovoltmeter and current source with copper probes. The I-V curve in a direct DC sweep measurement is in the figure. I was hoping if anyone may have an explanation for such a behavior or guide me into the potential measurement errors from the described setup (Such as effect of substrate, probes, etc) that may have caused this.
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welcome,
You have a very good I-V curve. Normally one has to plot I versus V. But this is irrelevant. Your specimen shows breakdown at voltages at -1.5 to 1.5 V. Then it has an ohmic behavior. The resistance is deltaV/deltaI= 3V/ 100 uA= 30 kohm.
Best wishes. The most important condition to measure the measure the sheet resistance using the 4 point probe is that the substrate must be insulating for staight forward assessment of the sheet resistance as rohs= 4.44 V/I= about 130 kohm per square.
The resistivity of the layer will be rohs x the thickness of the layer= 130 kx 1 nano=.013 ohm.cm which means that it has a very low resistivity or high conductivity.
Best wishes
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I conducted an I-V curve measurement for my SWCNT FET and received a very odd result that I can't understand.
The measurement was done with DI water as gate dielectric under gate voltage between -0.5V to 0.5V (single gate potential for each curve).
the metal connectors are made out of Ti-Au.
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Thank you Rüdiger Mitdank .
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Cyclic voltametry
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You could use the information on the image below.
Best regards,
Marie B.
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In case of Multiferroic Perovskite materials, the Current-voltage curves sometimes don't pass through origin and show diode type characteristics due to polarization. But in illumination condition, i have observed that with the interaction of photons some materials show lower current value than dark condition. What would be the physical significance of giving low current value?
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Dear Subharsi,
welcome!
I believe you. One normally observes that when displaying the illuminated I-V curve inn the first quadrant that the reverse scan of the I-V curve will be under the forward scan. This means that polarization voltage lower the terminal voltage for the same current in the reverse direction of the scan.
In order to share in the discussion of the results one has to examine your I-V curves.
Have a nice day!
Best wishes