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Dear experts, authors, professionals and professors, I cordially invite interested professionals to contribute in the next issue. Important Dates: Submission Deadline: June, 1, 2024 Reviewers Feedback to Authors: 10th June 2024 Revised Submission Deadline: 15 th June 2024 Final Decision: 20th June 2024 Publication Date: July 2024 Important Notes: 1- Before submitting your content, please check the Author Guidelines ,Ethics,.... from the webpage of QOR Newsletter Here is the link: https://organizationalexcellencespecialists.ca/newsletter/ 2- Communication related to the newsletter should be directed to the Editor, Mohammad Hossein Zavvar Sabegh, Email: mohammad@organizationalexcellencespecialists.ca / quality20zavvar@gmail.com 3- The scope of QOR Newsletter includes: Leadership and Management, Operational Research, Excellence Models and Challenges in Digital Era, Industry 4.0 and Quality 4.0, The Future of Quality and Organizational Excellence, Continuous Improvement, Quality Management and Innovation, Quality and Risk Management, Customer Satisfaction, Quality Standards, Quality Systems, Supply Chain Quality Management, AI and Quality, Lean Six Sigma, Operational Research and Smart Cities, Project Management, Smart Optimization, Machine Learning, Big Data Analytics, Digital Process Operation, Robotic Process Automation, Supply Chain Management, Optimization Theory and Applications, Climate Change, Cleaner Production, Circular Economy. 4- The content of QOR Newsletter includes: Papers and opinion articles on quality, excellence and operational research; insightful reviews about publications; important events such as conferences, workshops and webinars; success stories about projects; calls for a chapter or paper; book announcement, introductions to new technology; career opportunities with potential employers and resumes from prospective employees.
5- Author-guidelines attached. Kind regards, Mohammad Hossein Zavvar Sabegh, Editor at QOR Newsletter https://organizationalexcellencespecialists.ca/newsletter/
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Is there any cost for this?
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Dear Colleagues, It is our greatest pleasure to announce the launch of a Special Issue of Cleaner and Circular Bioeconomy (CLCB) from Elsevier, entitled "Towards Carbon Neutrality in the Bioeconomy." The submission period is from 15 February 2024 to 15 September 2024. This special issue aims to explore both theoretical and practical solutions that can effectively lower the carbon intensity of the bioeconomy. Potential approaches include introducing sustainable agricultural practices; optimizing biomass production; minimizing waste in agricultural and forestry operations; promoting recycling and reuse of biomass; enhancing energy efficiency in processing and converting biomass into biofuels, bioenergy, and other bioproducts; utilizing renewable energy sources like solar, wind, and hydroelectric power; implementing Carbon Capture and Storage (CCS) technologies in bioenergy production; and conducting Life Cycle Assessments (LCA) to fully understand the environmental impact of bio-based products and processes. Additionally, implementing public policies that encourage greenhouse gas (GHG) emission reductions in the bioeconomy, such as carbon pricing, subsidies for sustainable practices, and regulations promoting low-carbon technologies, can also be effective. For more information, please refer to: https://www.sciencedirect.com/journal/cleaner-and-circular-bioeconomy/about/call-for-papers#towards-carbon-neutrality-in-the-bioeconomy CLCB (ISSN: 2772-8013) is an international, cross-disciplinary companion journal to the prestigious Journal of Cleaner Production. It publishes original full-length research articles, perspectives, and reviews aimed at fostering a cleaner and more circular bioeconomy. Additionally, it is free to publish since CLCB is currently waiving all publishing costs for articles published in this special issue. We thank you for your attention and look forward to hearing from you. Please spread the word around you. Arnaud Z. Dragicevic, Chulalongkorn University, CIRANO Florent Allais, FRSC, AgroParisTech, URD ABI - AgroParisTech Guest Editors
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Thanks for sharing. Wishing you every success in your task.
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Hello,
Can someone kindly help me to download the supplementary data file from the paper published in Journal of Cleaner Production.
I could not find the position where the supplementary file is actually located in the website.
There is a note in the article which is "Supported information associated with this article are available free of cost at website"
Thank you for your time
With regards,
Waheeba
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Find attached the document!
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Sugarcane filter cake is one of the sugar industry waste which produce in a large quantities and has a potency to process as a biomass. What is the future idea for the utilization of sugarcane filter cake in industry?
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The composition of press mud generated is influenced by locality, cane variety, milling process and the clarification process chosen for sugar purification. Main components of press mud are moisture (50–65%), fibre (15–30%), crude wax (5–14%), sugar (5–15%), crude protein (5–15%) and nitrogen (2–2.5%). It is a potential source of hydrocarbons and valuable chemicals through thermochemical conversion processes.
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Is it possible to download the "Appendix A. Supplementary data" of the article "A multi-objective optimization model for decision support in water reclamation system planning" from the "Journal of Cleaner Production" and from where?
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I can simply download the Supplementary Materials from the website? Can you confirm that you can get the full text from the website? If that's the case, scroll all the way down to and press download. If it's an access issue (i.e. your institute does not have the required access to the Journal), it's always worth asking the authors here on RG.
and 'request full-text' speficiying you're interested in the the Spp Materials.
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The editor of Journal of Cleaner production referred my paper to Journal of Cleaner Waste System which is a partner Journal. It is a new Journal with only one issue published and no information regarding IF, H-factor etc. The email says the article will be indexed by SCOPUS. Is it worth publishing there?
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If it is one of your first publications I think it is worthwhile. It is a trustworthy journal https://www.journals.elsevier.com/cleaner-waste-systems (publisher behind it is Elsevier) and a so-called companion journal of a high impact journal. It is to be expected that the journal will be indexed in Scopus (in the next three-four years) and will receive an impact factor by Clarivate (like basically all Elsevier journals on the long run). Furthermore before September this year it is free of costs.
However, if you need papers in Scopus indexed journals for your PhD or for promotional purposes for your institute, then it depends when this will become relevant.
Best regards.
PS. The links provided by Prem Baboo are not safe, see for example:
For example:
-The journal “International Journal of Mechanical Engineering” is no longer indexed in Scopus https://www.scopus.com/sourceid/21101016918
-The journal “Universal Journal of Accounting and Finance” is no longer indexed in Scopus https://www.scopus.com/sourceid/21101023074
This tells you how reliable these types of anonymous sites are.
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Research within the environmental science is pretty interesting and practical in nature. The journals focusing on environmental studies often have very high impact factor compared to other journals in social sciences. What is the secret?
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You are most welcome dear Mohammad Razib Hossain
Wish you the best always.
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I have just seen two media treatments at the Nobel speech of O. Tokarczuk (Nobel Prize in Literature 2018):
1. Reprinted speech with underlined fragments
2. Article entitled: three words to remember from speech: "I am", "myth" and "tenderness"
I consider such media practices as an example of generating modern intellectual slavery because: (1) the media suggest learning selected content by heart instead of initiating a discussion of these fragments, (2) the media skip other fragments and the context of all speech (3) the media put themselves in the position of hierarchs of ready-made unquestionable values ​​and the auditorium in the position of someone ... (4) the media does not give the auditorium any benchmark or tool for independent analysis.
I think the role of an intellectual or leader is to give the auditorium (auditoriums) tools for independent analysis/use.
For example, if we use the metaphor 'art is a tool' (Ernst et al 2016) for analysis of the speech, we will obtain our independent result.
Consequently, the scientists' task is not only to do empirical research and suggest theorie, but also to identify and suggest methodological metaphors to immunize/empower the auditoriums against the above-mentioned practices.
 What do you think about this?
Literature:
Ernst D, Esche Ch, Erbslöh U (2016) The art museum as lab to re-calibrate values ​​towards sustainable development. Journal of Cleaner Production 135: 1446-1460
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I have just submitted a paper on the sci-art cooperation. Here is the abstract. What do you think? From reformers to living labs: radical changes (transformations) of practices in art and science. Abstract Living labs is a formula of cooperation between scientists and artists that combines new methods of project implementation, new research methods (action research and design-based research). The results of these projects represent radical changes in current practices. I begin by presenting what a radical change in art and science is all about. Next, I present interdisciplinary stakeholder workshops as a working method of living labs and social phenomenology as an interpretative and methodological basis for researching artistic practices in the humanities. In the last part, I present what and how scientists of humanities and artists can study in the living lab formula. The originality / value of the research presented in the article lies in the indication of how artists and scientists can implement joint Sci-Art projects, based on the above-mentioned methods and the model of transformation of artistic practices. Keywords: radical change (transformation), social practices, living lab, humanities, art, social phenomenology
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The European Parliament has approved a ban on single-use plastics by 2021. Currently there is a growing concern about the environmental and health issues caused by plastic and micro (nano) plastics wastes. This ban approved by the European Parliament means a scientific and economical challenge for both plastic industry and society in general, so I would like to discuss some points about it with the RG community.
Which could be the best replacement materials / products or perspective to adopt on the single-use plastics issue, which nowadays are everywhere in the daily life? Are we scientifically / technically prepared for these changes? I also would like to know if there are new proposals to deal with this challenges, and of course, deal with the existing contamination of plastics and micro (nano) plastics.
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A ban on single use plastics came in to effect in Kenya. Though a big reduction was observed, there are still clothes, bread and other items which are still in use.
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How to perform a power analysis to calculate the sample size for a change between two periods between control and treatment group (Dif-in-Dif)?
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I completely agree with your opinion
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Butt, U. M., Letchmunan, S., Hassan, F. H., Ali, M., Baqir, A., & Sherazi, H. H. R. (2020). Spatio-Temporal Crime HotSpot Detection and Prediction: A Systematic Literature Review. IEEE Access, 8, 166553-166574.
This paper was published on the 8th of September 2020. The authors state in the abstract:
The authors were unable to find a comprehensive study on crime hotspot detection and prediction while conducting this SLR. Therefore, to the best of author’s knowledge, this study is the premier attempt to critically analyze the existing literature along with presenting potential challenges faced by current crime hotspot detection and prediction systems.
Below I enlist relevant papers omitted by the authors, including our SLR paper of the same scope:
1. Kounadi, O., Ristea, A., Araujo, A., & Leitner, M. (2020). A systematic review on spatial crime forecasting. Crime Science, 9(1), 1-22. https://doi.org/10.1186/s40163-020-00116-7
2. Hardyns, W., & Rummens, A. (2018). Predictive policing as a new tool for law enforcement? Recent developments and challenges. European Journal on Criminal Policy and Research, 24(3), 201–218. https://doi.org/10.1007/ s10610-017-9361-2.
3. Seele, P. (2017). Predictive Sustainability Control: A review assessing the potential to transfer big data-driven ‘predictive policing’ to corporate sustainability management. Journal of Cleaner Production, 153, 673-686. https://doi.org/10.1016/j.jclepro.2016.10.175
I wonder whether you can do a thorough review circle from submission to acceptance in 7 days and if incorrect information should be corrected.
Finally, what is the opinion of the authors and the Editor-in-Chief on this matter? We asked for it but received none.
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Dear Ourania,
I guess I have a bit more nuanced view on this. In case of a non-review article, I encourage my co-authors always to add 'to the best of our knowledge', as there is an enormous amount of material out there and it is almost impossible nowadays to have a complete overview of all publications that appeared in a particular field. It is also a bit rethoric I guess, as you want to show the added value of your work.
In case of a systematic literature review it might be different. Normally a methods section is included in which the choices of keys and databases is explained and legitimized. For instance, if the authors argue to do a systematic literature review based on web of science from 2010-2020, it might explain why other reports and articles are not adopted/considered. On the one hand, one can argue that especially in established fields of research it is good to limit the review to the database with the highest quality journals only (this is different in case of emerging fields of course, as many material may be published as grey literature and in non-ranked journals as well). On the other hand, if the articles you refer to are in fact meeting the selection criteria but are not adopted in the review article, this provides indications that the review is very weak . But even in that case I am not completely sure whether an erratum is necessary, as we as scientists always build on each others work and always show weaknesses in previous research in order to legitimize our additional research. So maybe you have to see this article as a (weak) stepping stone that should encourage you to do a better job.
hope this helps, vincent Blok
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Have you ever wondered about time-loops? How is it possible to publish a paper today that is published in December 2020? Have a look at the Journal of Cleaner Production. The issue in progress is the issue of December 2020. https://www.sciencedirect.com/journal/journal-of-cleaner-production/vol/277/suppl/C
It is announced that "This issue is in progress but contains articles that are final and fully citable". The Journal of Cleaner Production is not an exemption. Have a look at the Total Science of the Environment. https://www.sciencedirect.com/journal/science-of-the-total-environment/vol/747/suppl/C
Always the same pattern.
How does this practice potentially affect the Impact Factor and why might this be considered as manipulation? Already in 2012 there was a paper published raising the issue of time loops as a way to manipulate IF. See https://www.researchgate.net/publication/266618323_Academic_publishers'_time-loop_Another_mechanism_to_manipulate_impact_factors
Sure, if you know how IF are calculated (https://en.m.wikipedia.org/wiki/Impact_factor) a possible manipulation is quite likely.
According to my knowledge most publishers stopped the practice of time-loops, except some major Elsevier journals. Due to modern publication technology time-loops can’t be justified on any kind of technological or workflow argument!
What is your opinion on this issue? Does it deserve further investigation?
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Two months after asking the question of this forum and one month after starting my small investigation, I would like to take the opportunity to draw some preliminary conclusions:
(1) Time-loops can be considered as a serious and continuous problem in academic publishing. They potentially distort citation metrics and make it potentially difficult to appropriately cite papers.
(2) Time-loops are not a specific problem of Elsevier. Many other publishers that use “first-online” have significant time lags between the first online publication and the final assignment to a journal issue. Partly, the problem is related to print versions of the respective journals.
(3) Currently, no other publisher than Elsevier uses time-loops in such a systematic way and assigns papers published at a certain point in time to a journal issue far in the future “final and fully citable”.
(4) Time-loops create particular problems for citations and journal metrics when first-online and final issue publications are shifted between years.
(5) Using the year of the first-online publication is the most promising way to fix the problems with regard to publication metrics. This solution was already suggested by Tort et al. (2012). It’s not so sure how it should be handled in scientific referencing.
(6) Clarivate Analytics is aware of the problem and wants to change the calculation to the “early access” principle, i.e. the date of the first publication.
Overall, I think there might be progress and an increasing awareness. I also like to inform you about the extent and results my investigations and the responses so far:
- Clarivate Analytics: very prompt, kind and serious response, informative and to the point
- Elsevier: no response after more than a month
- Journal of Cleaner Production: no response after more than a month
- Science of the Total Environment: no response after more than a month
- Ecological Economics: prompt, kind and serious response
- Land Use Policy: very prompt, kind and serious response
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Social innovation is a concept associated with changes that organizations develop and implement to primarily address pressing social needs (Silvestre & Tirca, 2019). Social innovation is a key driver for social change (Cajaiba-Santana, 2014) that derive from the intrinsic desire to resolve/attenuate existing social problems, instead of a marketing mechanism to make firms to sell more (Morais & Silvestre, 2018).
With this in mind, we are willing to enhance the debate on how we can advance the social innovation field from the theoretical, practical and policy stand-points. That is, what are the key issues/challenges on SOCIAL INNOVATION that research still needs to address?
REFERENCES:
Cajaiba-Santana, G. (2014). Social innovation: Moving the field forward. A conceptual framework. Technological Forecasting and Social Change, 82, 42-51.
Morais, D. O., & Silvestre, B. S. (2018). Advancing social sustainability in supply chain management: Lessons from multiple case studies in an emerging economy. Journal of Cleaner Production, 199, 222-235.
Silvestre, B. S., & Ţîrcă, D. M. (2019). Innovations for sustainable development: Moving toward a sustainable future. Journal of Cleaner Production, 208, 325-332.
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Thank you, Stephen! I had the chance to read the document, and it will be very useful! Best, Bruno Silvestre.
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In the 21st century, various solutions based on ecological innovations, renewable energy technologies, green economy, clean economy, reclamation of secondary raw materials, etc. should be developed. This way, added value can be generated based on the synergy achieved in parallel, mutually supporting processes. In this way, this kind of ecological added value can help to create a new economy in the future based on more sustainable development.
In view of the above, I am asking you: How can you describe, explore and measure the ecological added value resulting from the synergy of pro-ecological activities ...?
Please, answer, comments. I invite you to the discussion.
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Before any problems coming from ourselves can be addressed the mantra of denial needs to be accepted. When it comes to current climate change is measured and demonstrated we can only address it when we accept it. I will not deny but accept it and act accordingly..
Authorities not crack pots point to reducing fossil fuel emissions not denying there part and increasing sequestration as the solution to the issues this from experts with training and capacity in the subject matter not chimps, old farters or whatever derisive inappropriate term you are presently trying to concoct.
Reducing of emission has been demonstrated over and over the Montreal Protocol a good example proven by science and the cap and trade for sulfur emission another good example. But if we cannot even get out of the river in Africa of denial none of these can be support publicly because of campaign of vilification. This is way I believe the polemic of derision is a conscious decision of propaganda not scientific discussion.
Take a good example the value of solar energy competitive available and effective growing recognized around the world for its utility and usefulness. Lengths some are willing to go. A good way to deride the whole issue is crucify that tree on a cross of ignorance. Deny deny and deny.
Trees recognized for ecological environmental and economic value huge natural wonders which have shrunk with planetary mis management they too a subject of denial and ridicule.
Now my devotion to our mother earth the soil. While the amount of carbon in the air in its wildly enriched state yes the one that is engaging a observable and accelerating global warming is 3 to 4 times that of atmosphere pool. If the idea is that where can we put the excess baggage of Carbon dioxide we have a massive field to deal with. Taking a look at the global carbon budget there is almost carbon in the planetary biomass as in our atmosphere and lo and behold the budge and pool can transfer from the air to green mass. It is called carboncycle.
Lets start with no till agriculture completely accepted by conventional farmers in Brazil who are pioneers which has reach over 7 million acres for zero in just a courple of decades. Dr. Rattan Lal, the world foremost Carbon sequestration agriculture expert estimate when this technology is applied on all tillable global land it will sequester 10% of the actual current greenhouse emission.
Puget and Lat from a 4 decade controlled field in Ohio show that no till alone can sequester over 300 kg/ha per acre while simultaneously reducing fossil fuel use foe land tillage.
But wait the long term experimentation on cover crops from the Rodale Institute and now USDA and land grant universities show cover crop can sequester easily 2 to 3 times the no till sequestration while reducing needs for ammoniated fertilizer use which is the biggest carbon foot print in our current system. That very useful concept which actually allow things to be measured no wonder that would be under attack.
Now 10% no till and 30% cover crops that sounds like 40% of the issue can be dealt in proven economical ways with reduce energy costs and improve the environment. These things are zero end games as they depict chose energy or chose environment. We can grow both with a sacrifice this is part of the idea of synergy. You know another idea to deny.
Lets look at compost modest applications of this organic amendment can lower our costs related to waste procession and the sequestration at that rate both avoids issues in comtaminating a widely fouled water system and works to regenerate it but also can give the types of sequestration at level of no till and cover crops together. Math 40% plus 40% that is 80% of the presentday carbon emissions.
Lets keep growing compared to our tillable lands globally the pastures of our world are twice as extensive indeed the highest most fertile soils come for grassland than naturally sequester massive amounts of greenhouse gases. Now the potential sequestration of these system using intensive rotation grazins is found to over double the combined no till, cover crop, and compost field system. Now let double the acreage and double the potential 80 plus 80 there 160 much more than all the current emission presently.
But wait we have not looked biochar this technology applied at Pre Colombian Indian level can sequester a 1,000,000 kg/ha of carbon dioxide and has been demonstrated on lands greater than the size of modern day France and it has been shown to produce carbon which has thousands of year of half life.
The experts in the field has shown that through pyrolysis we can produce renewable energy and char with provide a clean renewable energy system superior to fossil fuel. Oh yes fossil fuels are not renewable and are declining. In this system half of the carbon becomes fuel and the other have builds the soil carbon and reduces the content in the soil.
This system could completely over ride all the others and address the very real issue of soil acidity particularly plaguing the tropics but prevalent through the zones of the world.
In terms of the emission we need to start with our energy system. For instance coal represents our worst case scenario just converting to natural gas would reduce emission from the electrical sector in one half. In addition natural gas is abundant cheap the plants are faster to construct and the health issue related to them are much less than coal.
Secondly wind energy is completely competitive in price to natural gas and can be used responsively. Solar is becoming more the real option every day. But also micro hydro electric is not exploited fully and yes when new approaches of nuclear which are both reliable and resolve waste nuclear material issues they certainly can be on the table.
Just a while back my friend Kenneth Towe quipped that carbon dioxide levels have been much higher than currently and no problem.. It was not even warm then. Wow. You may want to read Dr. Peter Ward who is paleogeologist at University of Washington.
He takes all the massive extinction events in geological record and points to level of carbon dioxide. In the last 200,00 years when it is considered at the human area arrived and in the 100,000 years when populations started growing or in the last 10,000 years when we experienced the agricultural and industrial revolution the Carbon dioxide fluctuated between 180 to 290 ppm.
Yet tn the prehistoric age we have 10 massive extinction even with the following CO2 concentration 4,000, 3,800, 3,900, 3,000, 1,200, 1,800 1,600 1,200 and 600 ppm with recorded by Dr. Ward. .
At 410 ppm Carbon dioxide and climbing the deniers are not worried Kenneth says we seen this before was not even warm. Yet there is an undisputable geological record that show when carbon dioxide as risen the temperature of our earth has followed suite. Also in 10 known massive every single one of them are associated with greatly enriched greenhouse house environment 600 to 4,000 ppm.
Our civilization and are advanced as all come in levels which are much inferior to the current and certainly. Now if geological record shows how temperature rise naturally with increasing carbon dioxide and it the 10 events of massive extinction are occurring under the high carbon and heat events are we willing to ignore all evidence and say lets just roll the dice.
Lets just deny say there is no evidence and say there is no solution.
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To minimize the pollution impacts of the old dirty economy only model on the environment is the goal of green markets to ensure environmental sustainability and addressing the economy polluting problem of the dominant non-renewable energy based economy.
But what would be really best for environmental sustainability would be a dominant, if not fully, renewable energy based economy.
Therefore, clean economies would be better than green economies in environmental sustainability terms. But the need to transition to the clean economy is not mention in millennium development goal # 7; it only has goals to reduce pollution, to increase renewable energy sources apparently as complements, but not goals for planning for as transition from green economies, still a partially dirty economy, to clean economies and have clean energy as permanent substitue for dirty energy..
Why neither of the 17 sustainable development goals including SDG #7 are capturing the need, which we know it will come, to transition to clean economies?
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Dear Dariusz, thank you for your comment...
I asked the question to bring attention to what main stream thinkers in the development agenda may have missed or are missing....
When the bruntland commission/1987 told us to go beyond business as usual I thought about a two step long term approach:
a) to move from full dirty economies to partially clean economies(green markets
b) to transition from green markets or partially clean economy to fully clean markets
While the original millenium development goals, the 2012 shift to green market thinking, the new UN development goals, and the paris agreements all talk about green markets/green economies, they do not talk about the need in the end to transition to a fully clean economy.
As you may know, the history of what happened after the 2012 shift from perfect tradtional market theory to perfect green market theory to achieve a perfect shift to green market or green economies shows that the theory does not match the current practice....in practice since 2012 we have moved towards a world of DWARF GREEN MARKETS...markets under eternal government intervention....
Have a nice day!
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Hello to everyone.
I am working on the adsorption of Cu2+ from aqueous solution onto the biochar.
I found a strange result in thermodynamic analysis. At low temperature (15C), ∆G is 2 kJ/mol (∆G is positive). it means that the process is not spontaneous, and in fact, it shouldn't happen. But, adsorption happens in reality based on the experimental results.
At higher temperature, ∆G is negative.
I found ∆G > 0 results in a few papers but there is no explanations except that: adsorption is not easy if ∆G > 0.
{Yargic et. al., Assessment of toxic copper(II) biosorption from aqueous solution by chemically-treated tomato waste, Journal of Cleaner Production 88 (2015) 152-159
Hajjaji et. al., Adsorption of blue copper on a natural and electrochemically treated bentonite, Appl Water Sci (2016) 6:11–23}
I have used following equations found in literature:
∆G = ∆H - T∆S (equation 1)
∆G = -RTln(Keq) (equation 2)
Keq = (Qeq) / (Ceq) (equation 3)
Qeq is the amount of copper adsorbed divided by the mass of adsorbent (mg / g)
Ceq is the concentration of copper in the solution at equilibrium (mg/L)
Combining equations and the linearization will give:
lnKeq = ∆S / R - ∆H / (RT)
This equation was used for linear regression to estimate the values of ∆S and ∆H. ∆G was calculated by the definition.
I tried to find a reason. I really appreciate it if you could help me.
Explanation 1) Regression error
R2 is 0.96 in linear regression. There is an error in estimation of ∆S and ∆H, and therefore ∆G. Especially the value of ∆G is small.
Explanation 2) Physical adsorption
The equation (2) is defined for a reversible chemical reaction (Gibbs free energy isotherm equation). But, what if the adsorption is physisorption?
Is it necessary for ∆G to be negative even in case of physical adsorption? Especially, the formula used is defined for a reversible chemical reaction.
The value of ∆H is 30.2 kJ/mol. Based on literature, if the ∆H is less that 40 kJ/mol, the dominant mechanism is physical adsorption. It means that, in my experiment, adsorption is physical.
Explanation 3) Definition of Keq
if ∆G > 0, based on equation 2, Keq < 1 which means that:
Qeq < Ceq.
On the contrary, if ∆G < 0, Qeq > Ceq.
But, there is not any rule or limitation in the adsorption regarding the relationship between Qeq and Ceq. Especially, there quantities have different units and dimensions, and it is not possible to compare them.
It seems that the definition of Keq in adsorption is not appropriate. Based on equation (2), equilibrium constant must be dimensionless. Ln is a natural logarithm and therefore Keq must be a pure number and cannot have a dimension, since logarithms can only be taken of pure numbers. But, in adsorption, Keq is not dimensionless.
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There is another confusing issue for me. If the assumption is equilibrium, ∆G must be zero. But, in all papers that I read, ∆G has a value either negative or positive. So, why?
Thank you very much for your time and patience to read such a long question.
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The results obtained are strange. When the equilibrium is reached delta G has to be zero. If it is positive the adsorption is not possible as such.
What I feel in this case is there could be possibility of physical adsorption or multi layer adsorption.
This can be confirmed by finding linear representation of adsorption isotherm model and check whether it follows BET isotherm.
Each layer adsorbs according to the same Langmuir type model and layers of molecules are adsorbed on top of the previously adsorbed molecules.
We should better consider adsorption isotherm rather than thermodynamic equilibrium system
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In the RE-FUEL POWER projects, we are considering a number of conventional power cycles, such as supercritical reheated steam cycle, and advanced power cycles, such as supercritical CO2, ethane, helium or HAT cycles. Based on your experience, what other cycles can compete with these in terms of techno-economic performance? 
#powercycle #thermodynamic #economic #feasibility #cleanenergy #refuelpower
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The superiority of any power plant from a techno-economic point of view depends on several economic parameters that vary from a country to another namely: fuel cost, C&M cost, electricity selling price... Then, we can not say that a power plant is better than another absolutely. Each case study has its own results. However, I suggest you to add the combined cycle in the set of your power plants since it has shown interesting results in a large range of economic and thermodynamic parameters.
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I cant seem to put my own data in the software openLCA. can anyone walk me through the process?
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Guten Tag Herr Peters!
Thank you very much for your advice! I really appreciate that. I also noticed that ecoinvent data is free for educational users from non OECD countries such as myself.
I sent necessary documents to openLCA and applied for the ecoinvent database few days ago. I should be able to import their database very soon. As you mentioned it was indeed becoming difficult to enter background data for my LCA on rice. 
If all goes to plan, this case study will one day be my first publication. Thank you for wishing me luck!
Best,
Jimmy
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I am currently optimizing PCR for amplification of the ITS2 region for fungi and V4 region for archaea/bacteria from environmental gDNA.  This amplification is being done using degenerate primers appended with Illumina Nextera adapters (as detailed below).  The PCR product from this first round will be submitted to a sequencing facility on campus for a second round of PCR where indices will be added, then sequencing will be carried out on an Illumina MiSeq. 
I have encountered two issues:
1) After running an annealing temperature gradient, I am still uncertain which annealing temperature to use for the V4 primer set.
2) Both ITS2 and V4 primer sets are yielding non-specific product which show up as a faint smear with some diffuse 'bands' in my gel. 
I've attached a gel image of the Ta gradient (annotated in PowerPoint) which depicts both issues. 
For issue (1), my Ta gradient yielded virtually identical bands across more than 20C span of annealing temperatures – from 50C all the way up to 72C.  This makes it difficult to select an annealing temperature based on the gradient results.  Based on these results, I could select a Ta as high as 72C and run a two-step protocol, but I’m worried that I may miss some taxa by selecting a Ta which is so far above the lower Tm.  I am using a popular V4 primer set (515f-Y/806rB, see below) that has a large difference in melt temperatures.  Under the buffer conditions used, the Tm of the forward primer is 74C, whereas the Tm of the reverse primer is only 56.6C. 
Does anyone have experience with this primer set? 
Is it expected to get similar amplification over such a wide range of annealing temperatures?
Why do so many people use a primer set that does not conform to the basic rules of primer design, yet nobody talks about this in the literature or elsewhere?  ;)
For issue (2), both the ITS and V4 product has non-specific smears at higher molecular weights above the expected bands.  For ITS some of this may be due to varying ITS length in the potentially complex community from which the gDNA was derived, but the V4 product is expected to be ‘cleaner.’  I tried titrating the primer and shortening the extension time for the ITS reaction to little affect, but haven’t had time to troubleshoot the V4 reaction yet.  I suppose I would start by titrating the primer concentration.  The cycle count is high, but I would like to optimize at the highest expected cycle count assuming that lower cycle counts will yield cleaner product.
I’m wondering if anyone has experience with these primer sets and whether this amount of non-specific product is common? 
Is this caused by degeneracy in the primers? 
I anticipate that the presence of non-specific product will reduce the number of usable reads in my sequencing results at the very least.  Should I be concerned about this, or proceed with the second round of PCR and sequencing?
PCR Protocol:
Polymerase:  Invitrogen Platinum SuperFi 2X MM
Recipe:
MasterMix (2X)                   5 uL
Forward primer (10 uM)     0.5 uL
Reverse primer (10 uM)     0.5 uL
Tmeplate  (10 ng/uL)         1 uL
PCR Water                         3 uL
Total Reaction volume       10 uL
Thermocycler Program (based on Invitrogen suggested protocol for SuperFi polymerase):
Cyc1 (1X)     98C for 2 min
Cyc2 (35X)   98C for 10 s
                      (50-72C) for 10s
                      72C for 15 s
Cyc3 (1X)     72C for 5 min
Cyc4              4C HOLD
Primers:
All primers have the following Illumina adaptors appended:
Forward – TCGTCGGCAGCGTCAGATGTGTATAAGAGACAG
Reverse – GTCTCGTGGGCTCGGAGATGTGTATAAGAGACAG
Tm listed below for each primer was calculated at www.thermofisher.com/tmcalculator
For ITS,
ITS3mix (forward)
CATCGATGAAGAACGCAG  61.1
CAACGATGAAGAACGCAG  61.2
CACCGATGAAGAACGCAG  63.7
CATCGATGAAGAACGTAG  54.5
CATCGATGAAGAACGTGG  60.8
CATCGATGAAGAACGCTG  61.1
ITS4ngs (reverse)
TCCTSCGCTTATTGATATGC 62.5
Tedersoo, L., Anslan, S., Bahram, M., Põlme, S., Riit, T., Liiv, I., … Abarenkov, K. (2015). Shotgun metagenomes and multiple primer pair-barcode combinations of amplicons reveal biases in metabarcoding analyses of fungi. MycoKeys, 10, 1–43. http://doi.org/10.3897/mycokeys.10.4852
For V4,
515f-Y (forward)
GTGYCAGCMGCCGCGGTAA 74
806rB (reverse)
GGACTACNVGGGTWTCTAAT 56.6
Walters, W., Hyde, E. R., Berg-lyons, D., Ackermann, G., Humphrey, G., Parada, A., … Jansson, J. K. (2015). Transcribed Spacer Marker Gene Primers for Microbial Community Surveys. mSystems, 1(1). http://doi.org/10.1128/mSystems.00009-15.Editor
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Thanks Dirk and Oliver for taking the time to offer some insight.
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Can anyone suggest, how to find cleaner production index?
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Check: LCM - Life Cycle Management - UNEP 2007 & ISO 14040:2006 & 14044:2006.
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They may recommend material on Management of Environmental Sustainability : Cleaner Production
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Excellent contribution , Thanks
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Me and my colleagues recently studied one of the oldest centralized collection programs for waste portable batteries, named also as, single organization model, which is in operation in Belgium since 1996. The collective battery management program is monitored by the Belgian battery organization (BEBAT).
The operation of BEBAT is financed by a government mandated fee or levy, which is set by law and is included in the price of the battery. Consequently, it is paid by consumers.
Although, the BEBAT achieved 84 % of public participation in 2012 and a dense network of collection points (on average one active collection point for 450 residents), the collection ratio of portable waste batteries has remained stagnant at around 50 %. The data showed that the dynamic problems present in the sector: despite increasing public awareness the collection rate is not increasing.
Therefore we developed a system dynamics model to sheds light on the structure of the system and the system’s behavior. The model allows examining how the physical processes and information flows interrelate in the structure of a dynamic system, and how this structure generates dynamic behavior over time.
We found out that important feedbacks are missing in the collection scheme:
  • the level of the levy on the price is not linked to the achieved collection goal.
  • effectiveness of the information campaign and the costs related to these awareness-increasing activities are not linked.
The presented model can be adapted for other types of batteries’ collection models. In the context of the Europe Union the developed model can be used by member states to align with the collection targets set in the Directive 2006/66/EC on batteries and accumulators and waste batteries and accumulators.
Our model and results are presented in Journal of Cleaner Production (Elsevier) under title “Dynamic modelling of a collection scheme of waste portable batteries for ecological and economic sustainability”.
What feedbacks have you found missing in other principal models of collection schemes (state fund models, competing organizations models, and models without organizations (more details about principal models can be found in the supplement))? What are your thoughts and observations?
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Dear all,
I am pleased to inform you that the final version of our article is now available online.
There is free access to our article valid for 50 days, until January 25, 2015 by following link: http://authors.elsevier.com/a/1Q9Rx3QCo9AcRt
No sign up or registration is needed - just click and read!
Best regards, Lelde Timma
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Fate of solid waste:
1) For landfil.
2) For incineration.
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The emissions will depend on a number of factors including the composition of the waste, climate, landfill conditions and methane capture. The IPCC (http://www.ipcc-nggip.iges.or.jp/) provides the methodology and also an Excel tool to calculate emissions, although this is more aimed at total national waste emissions.
For incineration, the main question is whether there is any energy recovery, in which case the emissions are attributed to the energy, rather than the waste.
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I want to explore how to make strategic management to manage solid wastes in an industrial area in a developing country. What is the proper method for this? SWOT analysis and/or any other recent methods?
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Dear Emma, 
In order to be useful for drawing up the strategic plan, as Deshmukh says, I suggest to use Life Cycle Assessment (LCA). There are several studies that deal whit solid wastes and LCA.
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The factors that would cause industry to adopt CP at higher rates (>50% of target population) than currently practiced worldwide. The types of interventions and at what levels (country, network, company).
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That is an extremely broad question and I think the right ideas will be different for every industry in which you are trying to encourage more diffusion and ultimately higher rates of adoption.