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Dear Sirs,
the paper:
Use of negative contrast computed tomography for diagnosis of a colonic duplication in a dogArticleJune 2013 · Journal of Small Animal Practice📷 A. De Battisti · N Harran · 📷 Guillaume Chanoit · Chris Warren-Smith
About which you sent me a question on authorship, is not a paper of mine. The "A. De Battisti" there mentioned is not me. My research area is Physical Chemistry and Electrochemistry, not medical science.
With Best Regards
Achille De Battisti
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This is the Q&A forum, not the RG service helpdesk.
However, if a wrong publication is appearing on your profile, you can open the "Research" tab there, search for the incorrect publication, click the small blue arrow and choose "Remove".
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Dear Researchers, I would like to bring your attention to Nano Research, a highly respected journal in the field of nanoscience and related disciplines. With an impact factor of 9.6 in 2023, this journal is known for publishing innovative and high-quality research that significantly contributes to the advancement of the field. Here are some key details about Nano Research: Ranked in the Q1 quartile for several SCIE categories: Chemistry, Physical: Rank 30/178, Q1 Materials Science, Multidisciplinary: Rank 56/439, Q1 Nanoscience & Nanotechnology: Rank 24/141, Q1 Physics, Applied: Rank 18/179, Q1 Starting from Volume 18 (2025), Nano Research will transition to an Open Access model through the SciOpen platform. This shift will make all published articles freely accessible, thus enhancing their visibility and allowing for wider dissemination of cutting-edge research. This journal could be an excellent platform for your own research, and I believe it offers great potential for staying updated with the latest developments in the nanoscience field. For more information, check out these links: Journal Homepage: https://www.sciopen.com/journal/1998-0124 Editorial Board: https://www.sciopen.com/journal/join_journal/editorial_board?id=1400285564990251009&issn=1998-0124 Editorial Office: https://www.sciopen.com/journal/join_journal/editorial_office?id=1400285564990251009&issn=1998-0124 I encourage you to explore the journal, consider submitting your work, or simply follow its developments if they align with your research interests. Let’s continue to support open access and the growth of our academic community.
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I agree the APC info is well hidden but according to the following link https://mc03.manuscriptcentral.com/nanores and I quote "Nano Research is now adopting an Open Access publishing mode for all articles submitted after 3 September 2024. No Article Processing Charge (APC) is required currently"
When it comes to your remark about the qualifications of the editorial team I see qualified members
Best regards.
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#physical chemistry
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If you just need "stable dispersion of SiO2 in H2O", just buy Ludox (R). Otherwise, more details are needed (see Alans answer)
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hello every body
Does anyone have the article(s) and the book i mentioned bellow?
someone asked me to find for but i can not even find them anywhere
please help me
Schlegel, H. B. (1990). "Geometric Phase in the Intrinsic Reaction Coordinate." Journal of Physical Chemistry*, 94(18), 6829-6835.  Gao, J., & Truhlar, D. G. (2002). "Theory and Applications of the Intrinsic Reaction Coordinate." *Chemical Reviews*, 102(7), 2301-2322.  Frenking, G., & Froese Fischer, C. (2014). "Theoretical Methods in the Study of Organic Chemistry." *Wiley-VCH*.
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Dear Fatemeh Razavi As indicated by Madelaine Lawrence the references are incorrect. Even stronger: I think the references are fake and non-existing. I suspect that they are AI generated. See for example https://teche.mq.edu.au/2023/02/why-does-chatgpt-generate-fake-references/
Best regards.
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what are the main points
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These are suggested references, hope they will be helpful:
- Principles of Physical Chemistry, 2nd Edition, Hans Kuhn, David H. Waldeck, Horst-Dieter Försterling
- Principles of Physical Chemistry
Book by B.R. Puri, L.R. Sharma, and M.S. Pathania
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The question seems to be whether mathematics is necessary or not, but the question mark is that if mathematics is essential for physics, chemistry and almost all other subjects, then they should change their methods and language to something understandable for teachers of these subjects.
Which makes sense.
Classical mathematical language and formations are redundant, in many cases illogical and contradictory, and they furthermore have the structural appearance of a heroglipic language.
Personally, I and too many of my mathematician and physicist friends find ourselves paralyzed when faced with the simplest mathematical situation.
So what !?
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Normally we do not comment on the answers of our fellow contributors but when the answer ("nature can only be described in a unitary four-dimensional x-t space"
There is no basis for this claim.)
comes from our friend Professor John Francis Miller, this should be different.
You can't ask Mother Nature if she lives and performs her functions in 3D+t space or in 4D unitary space?
But when you model nature in a 4D unit space and the numerical results in solving problems in all areas of mathematics and physics are precise and breathtaking, we consider that a respectable baseline.
We remind you that the real proof of the Schrödinger equation only comes from its exact and diverse applications.
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Well, all of it also refers to the Proposed Education of Physics, Chemistry, Biology and Math with Cymatics in High Schools with Hypothesis and Research of Philselfology as discussed in the following Research Proposal:
Now, it simply seems to raise a question of "Is it possible to have a Single or Common Subject of Education with Research for Physics, Chemistry, Biology and Math with Cymatics in High Schools?", and thus it is requested here as a question, where Name of Philselfology is also proposed for all of it as a Single, Common and Unified Subject as well.
All of it can go with sharing one's own or others' Research Publication and Other Related Published Research Works for Two or More Subjects as Single with Common and Unified Approach especially in the Schools, where Science goes into Physics, Chemistry, Biology and Other Subjects at High Schools, but Single, Common and Unified Approach still seems to be required especially in the developing nations.
It is also to be remarked here that Science, which goes into Physics, Chemistry, Biology and Other Subjects at High Schools keeps into Single Subject Specialization at College and University Levels, where it is question on High School Education, which also seems to lack the World Languages as Bilingual Language Streams, while it seems a separate question as well.
Well, all of it also has another Post for Discussion on Yes, No and Both with even Not Sure Answers to the above Question:
Is it possible to have a Single or Common Subject of Education with Research for Physics, Chemistry, Biology and Math with Cymatics in High Schools? (https://www.researchgate.net/post/Is_it_possible_to_have_a_Single_or_Common_Subject_of_Education_with_Research_for_Physics_Chemistry_Biology_and_Math_with_Cymatics_in_High_Schools2)
Additional Research Publication References for the Discussion as added on 24th of April, 2024 as well:
While, all of it also links to Wonderful Research Question for Future Research about School Education, which deals with questions about curriculum to integrate physics, chemistry, biology, and geology (PCBG integration) as well.
Research Question by Relevancy: [1] Any curriculum to integrate physics, chemistry, biology, and geology (PCBG integration)? (https://www.researchgate.net/post/Any_curriculum_to_integrate_physics_chemistry_biology_and_geology_PCBG_integration)
Thanks for your answer and the input in advance with also thanks for your precious time!
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In the United States many schools have a course called General Science, which discusses the development of our understanding of the natural world through experiments and attempting to explain the results through hypotheses of cause and effect that can be applied to predict the results of future experiments. Issues such as as the effect of experimental error on the results, precision versus accuracy, and bias are discussed. The development of a few concepts, such as the shape of the earth, gravity, and the inheritance of some physical characteristics in plants and humans may be included. While there is not time to include the details of specific subjects such a biology, chemistry, and physics in such a course, these foundations of experimental science are important for all the sciences.
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Currently, in Japan, physics, chemistry, biology, and geology are taught independently in science education context. So I would like to know, has any country developed a curriculum that emphasizes the relationship or overlaps between these four fields? I know that similar movement is occurring under the name of "STEM integration." But how about the case of physics, chemistry, biology, and geology? (Or I should say "PCBG integration") I would appreciate it if you could let me know anything.
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Well, thanks for sharing a Wonderful Research Question for Future Research about School Education, which deals with questions about curriculum to integrate physics, chemistry, biology, and geology (PCBG integration) as well.
While, it seems that all of it also refers to the Proposed Education of Physics, Chemistry, Biology and Math with Cymatics in High Schools with Hypothesis and Research of Philselfology as discussed in the following Research Proposal:
Now, it simply seems to raise a question of "Is it possible to have a Single or Common Subject of Education with Research for Physics, Chemistry, Biology and Math with Cymatics in High Schools?", and thus it is requested here as a question, where Name of Philselfology is also proposed for all of it as a Single, Common and Unified Subject as well.
It is also discussed more here as well:
ResearchGate Question and Discussion Reference: [1] Is it possible to have a Single or Common Subject of Education with Research for Physics, Chemistry, Biology and Math with Cymatics in High Schools? (https://www.researchgate.net/post/Is_it_possible_to_have_a_Single_or_Common_Subject_of_Education_with_Research_for_Physics_Chemistry_Biology_and_Math_with_Cymatics_in_High_Schools)
Thanks for your precious time!
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I think there is a big confusion between qualities / universals and physical properties. We speak of properties of things in physics, chemistry, biology, etc. In my opinion, properties are sets of general qualities. But are these qualities in physical science and the qualities in philosophy the same? Are there essential differences between them in science and in philosophy?
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I synthesized a molecule. I want to know what are the self-assembled structures possible for it through hydrogen bonding.
If possible, please suggest me some free software available (installation-based or online)
Any relevant suggestions are highly appreciated. Thanks.
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For a high level discussion see Dr. Werner Gitt, In the Beginning Was Information: A Scientist Explains the Incredible Design in Nature
He details 5 levels of information including the atomic scale.
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I'm from Ukrane and while teaching students I realize that our handbooks differences in this topic.
I want to be more qualified in this area.
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Here are a few books on physical chemistry that cover the topic of extraction and include problems and solutions:
1. "Physical Chemistry: Principles and Applications in Biological Sciences" by Ignacio Tinoco Jr., Kenneth Sauer, James C. Wang, and Joseph D. Puglisi
2. "Physical Chemistry: A Molecular Approach" by Donald A. McQuarrie and John D. Simon
3. "Experiments in Physical Chemistry" by Carl W. Garland, Joseph W. Nibler, and David P. Shoemaker
4. "Physical Chemistry: Thermodynamics, Statistical Mechanics, and Kinetics" by Andrew Cooksy
Good luck
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I am looking for any publicly available data sets for open ended questions in Science subjects like Physics/Chemistry/Biology.
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Ajit, there is no shortage of "unsolved" problems or quandaries in sciences, especially in Physics (my background), however finding open data sets that will help students of science and technology address these problems is as well an "unsolved" problem. During the last decade of my career (2006-2017), I had the opportunity to visit with leading global research universities and labs (US and Europe); many held on to datasets developed (or acquired) that could help researchers address such problems but I am not sure now if any made it to the public domain.
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Hellow.
I would Like to suggest an Economical idea, of Replacing the Entire Swedish Royal Academy of Sciences by an international Group of Pure and Applied Mathematicians which will make a decision on the Physics/Chemistry/Biology parts. for several reasons:
1. Mathematics is not included within the Domain and the entire Scientific body is build upon and by the Mathematics. Its the most important of all sciences. It would be only fair to somehow include mathematicians in the process for the disgrace of not including the field.
2. The Integrity of mathematicians when facing a proof or a principle as well as their ability to hold and take into account the small details and pitfalls of an idea, is second to none.
3. The International group would be less biased than a national group coming from a single country. There are regions in which no scientific nominations were made, for reasons which are highly likely, national or racial.
Thank you.
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With theoretical physics, mathematicians might have some judging skills, but when it comes to judging experimental work, I don't see where they should be getting an advantage from. They wouldn't be able to make a judgement of their own and would have to rely on other experimental scientists to tell them what is actually a breakthrough and what's just overhyped publicly.
This would get worse in chemistry and even more so in biology because the fraction of experimentalists getting Mr. Nobel on a medal is rightfully higher than in physics.
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If had not been read & noticed the importance of Williard Gibbs' (Gibbs' Free Energy which started the science of "Physical Chemistry") article by James Clerk Maxwell, therefore most probably that utmost important scientific article would have been fully forgotten forever in Yale Unv archives !?
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You know, RG is interesting and fun, but it is certainly not a replacement for actual databases and libraries. Therefore RG metrics like its score and also other common social media denominators like the number of comments are definitely no meaningful indices of actual relevance. For that reason, a historic paper missing in RG is not a measure of lack of quality.
Having said that, for being a good physicochemist you should know what the Gibbs Free Energy is and how to use it which you can both learn from modern day textbook which is probably more accessible to most people. What part of the whole thing was derived by Gibbs and how he formulated it may be interesting [and helpful for the next science pub quiz], but not having read the original does not reduce your general qualification as a scientist.
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Question: The measured decomposition voltage of HBr is less than the reversible voltage, and the prediction of the second law of thermodynamics is exactly the opposite. Do you have any other examples that do not comply with the second law of thermodynamics (prompt: in Physical Chemistry)?
The following is the answer from ChatGPT:
I apologize for my previous response which might have been incorrect. The relationship between experimentally measured decomposition potential and reversible potential does not necessarily always conform simultaneously to the predictions of the Second Law of Thermodynamics, Faraday's laws and the Nernst equation. Thus, decomposition reactions with lower measured potentials do not necessarily indicate that some decomposition reactions do not conform to the Second Law of Thermodynamics.
In addition to the example of HBr, other anti-thermodynamic reversible reactions like the electrochemical deposition of thallium, where the reaction enthalpy is negative, also violate the prediction of the Second Law of Thermodynamics. Moreover, in cases involving biochemical reactions, some enzymes drive high entropy reactions (i.e. different types of molecules are combined to form larger, more complex molecules) by consuming energy molecules such as ATP, which is also an example of a violation of the Second Law of Thermodynamics.
However, it is important to note that these examples do not mean that the Second Law of Thermodynamics is incorrect, but rather that it is not applicable to all chemical reactions in the real world.
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Carnot efficiency=1-T1/T2<==>dE/dV=(dP/dT) * T-P. The accuracy of the second law of thermodynamics requires accurate E=E (V, T), P=P (V, T). Now, as long as you know that E is a function of volume, you can verify the correctness of the second law of thermodynamics.
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Hellow.
Anybody familiar with the History of Nobel prizes, I am interested to know what is the shortest interval between a discovery to the win in Exact sciences ? Physics, chemistry/Physiology ?
Thanks.
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In 2004 Novoselov, Geim, and colleagues succeeded in isolating graphene, awarded the 2010 Nobel Prize for Physics. Novoselov was 36 years old.
Hartmut Michel, The Nobel Prize in Chemistry 1988, “for the determination of the three-dimensional structure of a photosynthetic reaction centre” In 1982 Michel succeeded in crystallizing these types of proteins. The follow year he, along with Johann Deisenhofer and Robert Huber, determined the structure for the photosynthetic reaction center.
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Which formulae are best used for calculating q, w, ∆U and ∆H for a nitrogen gas with a mass of 1.12 g that has been compressed adiabatically in the temperature range of 100 to 400 K from 400 torr and 1000 cm3 to final volume of 250 cm3 with Cp,m = 29.1 J/K/mol?
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Use the formulas provided in our Student Dictionary
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I am following the procedure as:
Pal, M., Garcia Serrano, J., Santiago, P., & Pal, U. (2007). Size-controlled synthesis of spherical TiO2 nanoparticles: morphology, crystallization, and phase transition. The Journal of Physical Chemistry C, 111(1), 96-102.
2ml of TBT, 20 ml of Ethylene glycol and then this glycolated precursor was added into acetone (100 ml) and water (3-6 ml) solution.
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After Optimization of certain conditions involved, stochiometric approach application.
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The kinetic theory of gas is based on five postulates, all of which relate to the free movement of
molecules in the gas phase. While the general properties of gases match extremely well with this theory, its application into the photoelectric effect results into the interpretation that light is a massless particle.
use the thought experiment, or an alternative postulate, that molecules in gases are not free, but form linear aggregates that can close into loops and derive a concept of a supramolecular orbital with a quantized size. This orbital can absorb energy in the form of a ring of particles, each of Planck length and moving at the speed of light.
When the energy of this true quantum of light is shared equally with each molecule in the orbital, the energy of taken up by a molecule can follow the Planck relation. We explore the postulates resulting from this alternative postulate and observe that self-consistent new kinetic theory of gases emerges that produced a new interpretation of the photoelectric effect, where the true quantum of light is the photon multiplied with the number of molecules within the supramolecular orbital.
Thus, based on this alternative postulate light can have mass and the theory becomes self-consistent. If the findings of this paper are verified, this will inevitably lead to the reinterpretation of numerous other phenomena in physic, chemistry and physiology.
The supplementary information shows that the new theory predicts the generation of protons than the current kinetic theory of gases.
What I do not show in the preprint is that our company LignoSphere (https://www.lignosphere.fi/) already applies the finding of quantized water for the aqueous self-assembly of lignin spheres, as I could not be explicit enough without revealing corporate secrets.
However, some of the thought behind the theory can be found on my blog: https://lintinen.wixsite.com/the-string/blog
As my background is in supramolecular/physical chemistry, I do not take a standard quantum mechanical approach in the proof.
I would welcome the hopefully lively discussion on the topic, and would be happy to answer any questions.
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Why don't you admit your mistakes? You didn't write my name and that's why I always looked for you for a long time. Now they wrote and the robot informed me about it. I can't send my article. She is preparing for publication. Read the modern review I sent and comment on it. I am participating in the discussion because I want to help you. I expressed my opinion about your theory. It does not correspond to the modern achievement of science. Write review errors about the Nuclear quantum effect. This is roughly what you are asking me to do after reading your theory.
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From some literature review I have found that the Seebeck coefficient is directly proportional to the slope of Density of States ( or Derivative of DOS). But, I couldn't understand how these two are related. Can someone please explain the physical meaning of this?
Reference paper:
Strain Effects To Optimize Thermoelectric Properties of Doped Bi2O2Se via Tran-Blaha Modified Becke-Johnson Density Functional Theory
Guo, Donglin, Chenguo Hu, Yi Xi, and Kaiyou Zhang. "Strain effects to optimize thermoelectric properties of doped Bi2O2Se via Tran–Blaha modified Becke–Johnson density functional theory." The Journal of Physical Chemistry C 117, no. 41 (2013): 21597-21602.
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The Seebeck coefficient depends on an imbalance between the density of electrons above the Fermi level and electrons below it. If the Density of States is rather flat (slope is small) the imbalance is small and the Seebeck is small. If the Density of States changes sharply near the Fermi level (large slope), the imbalance is large and so is the Seebeck. Note that the sign of the slope (positive or negative) near the Fermi level also determines if the Seebeck is "n-type or p-type". That is why some metals have a "p-type" Seebeck coefficient.
Look for the Boltzmann formulation of the Seebeck coefficient and the interpretation of the Fermi window (df/dE). I have attached my dissertation, read section 2.1.4.2, hopefully that will clear it up a little.
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I'm working on the thesis in the field of physics particularly physical chemistry in electrolyzer cell technology (related to fuel cell technology). but i'm confused which contents should I include in the introduction? If you help
thanks and regards.
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In principle the structure given by Ali A. Al-Allaq is correct. About the degree of detail you should discuss with your referee because that's a question of the standards within your department/faculty:
Some want a "closed" document in which you find everything so that the thesis is self-explanatory and does not require actually checking out the references while others have the attitude that they don't want to read too much so they want you to just briefly summarize your method and then reference more detailed introductions.
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Can it be published in Physical Chemistry Chemical Physics completely free of charge?
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If you don't want to make it open access, are there any indicators why that shouldn't be possible?
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Six Nobel Prizes are awarded each year, one in each of the following categories: literature, physics, chemistry, peace, economics, and physiology & medicine. However Mathematics a subject mankind cannot do without is a strange omission and has remained excluded until today. Same with accounting. From 1901 doyens such as Albert Einstein, Marie Curie, Earnest Hemingway were honored with the prestigious Nobel. Do you think it’s time to rethink ?
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The Abel prize is a new mathematics prize of the Norwegian Academy of Science and Letters, dedicated to the memory of Niels Henrik Abel (1802-1829) on the occasion of the bicentenary of his birth. It is modeled after the Nobel Prize, and developed from a proposal by the mathematics department at the University of Oslo in fulfillment of a request formulated by the Norwegian mathematician Sophus Lie towards the end of the 19th century.
From MathWorld--A Wolfram Web Resource. https://mathworld.wolfram.com/AbelPrize.html
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Example:
1. You use Material 1 in Biology and after using it, you recycle it in Chemistry to come up with Material 2.
2. You use Material 1 in Biology and then its product is used in Chemistry, Physics, Earth Science.
3. Or any related activities that make use of similar or related ideas.
If you can share also your related studies, I highly appreciate it. Thanks!
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I used 1 material in biology lab and recycle it that's used it in Field work
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I measured the particles size (<1000 nm) in aqueous solutions by DLS, but I found these particles can aggregate spontaneously, and it seems that smaller particles aggregate more.
I sincerely hope you can help me explain this phenomena.
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Dear all, Ostwald ripening may be behind such aggregation, this mostly happen when surface free energy in too high, i.e. fine nanoparticles with high specific surface area, so coarsening of nanoparticles is the mean by which size is increased and specific surface area is reduced. Small nanoparticles are more prone to aggregation because of their high surface free energy which for stability reason should be reduced, and for this purpose protective colloids techniques have been developped to prolonge stability time. My Regards
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Dear fellow scientists, here's sth that puzzles me at present: In virtually all research repositories that I know, PDF documents dominate, even though they are a 1990s format targeted at bringing classical paper documents to screen, without being resonsive not linked. Back in the 90ies, though, Tim Berners-Lee proposed another format with hypertext capabilities for scientific exchange. Why do paper-page-style PDF still dominate so much? Do you have ideas? Or do you know about other formats that may exist out there in communities beyond mine (chemistry/physics/materials science)?
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Kindly see also the following RG link:
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Electrochemistry
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All branches of Science overlaps, all branches of chemistry overlaps. There is no borderlines between them. The breakthroughs are commonly happened in the areas, where several branches of science/chemistry overlap. The classification of different branches of science is very important for librarians, who have to assign codes to books, journals, etc. I don't think that this question deserves any discussion.
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Hi guys,
I'm a Ph.D. Scholar in Physical Chemistry in Turkey and I'm becoming a Ph.D. soon.
I'm working on the adsorption of metal ions using various types of nanoparticles/nanocomposites.
I want to ask this question;
For instance we used the initial metal concentration C0 = 100 ppm,
We got the result of ICP-MS analysis Ce = 30 ppm and before we sent our sample to ICP analysis we diluted it 2 folds and our V/m value is 0,5, for instance.
I know Qe = (C0 - Ce)x V/m and we should consider Ce = 30 x 2 = 60 ppm, since it is diluted 2 folds. BUT, do I have to use Ce value as 30 ppm or 60 ppm when I'm building my adsorption isotherms? Qe = (100 - 60) x 0,5 = 20 mg/g but which Ce should I use for building my isotherms? 30 ppm or 60 ppm? If I remember correctly we were using Ce with dilution factor, I suppose I have to use 60 ppm as my Ce value here, but I wanted to make sure, so I require help now.
If you help me with this issue, I would be most grateful.
Best Regards.
H. Arkut Akalın
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Thank you all for your answers.
I have been working as a researcher in academy world since 2008 and becoming a Dr. in this academic term. Even though I'm a teacher in Physical/Nuclear Chemistry and very experienced, we all know even the most experienced may forget the fundamental terms because of hard working conditions.
Good luck with your scientific studies and sincere regards.
Hilmi Arkut Akalın
Ph.D. Scholar in Physical/Nuclear Chemistry
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MSc III sem physical chemistry practicle .
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Généralement les réactions d'oxydation sont lente
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Hi all,
for some quick tests I am looking for nanoscopic sources of circularly or elliptically polarized light, ideally single photon sources. I am aware of publications about specially synthesized twisted fluoresence molecules which emit elliptical polarized light after optical pumping (e.g. Kumar, J.; Nakashima, T.; Kawai, T., Circularly Polarized Luminescence in Chiral Molecules and Supramolecular Assemblies. The Journal of Physical Chemistry Letters 2015, 6, 3445-3452.)
In contrast to time-consuming fabrication, are there also circular/elliptical light sources, which are commercially available (e.g. fluorescent organic molecules, colloidal quantum dots, 2Dmaterials, defects in 2Dmaterials)?
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Recently, single photon emitter (or Quantum emitter) is actively researching in many labs, which means intensity of quantum emitter is very weak. That could be why the quantum emitter is not commercially available.
The circular polarized light can be easily formed with a linear-polarizer and a quarter-wave plate.
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Hi all,
To the best of my knowledge, electron transfer (ET) is a critical process in almost system of mechanisms related to Physics, Chemistry, and Biology.
I want to compile the most relevant and useful articles on ET. I have been doing this for a long time. However, I would love to receive the articles on the ET mechanisms that you are most interested in. I really appreciate that.
Thanks to all.
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Hello everyone,
I want to know during PLD, where from bound charges come at the surface of ferroelectric materials? I want to know their origin, their charge either positive or negative, and their screening process (i.e. how to screen) and their effect on polarization of material. Moreover I also want to know what is depolarizing filed and what is its origin and how it could effect ferroelectric materials? A good ferroelectric material should have high depolarization field or low and why?
The last thing I want to know that these bound charges/depolarization field could exist only in PLD film preparation or also can be in hydrothermal/solgel film synthesis ?
Kindly anyone who is expert explain it.
Thank you
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Hello,
First of all, the bound charges are inherently generated by the ferroelectrics, by its definition, so I guess what you ask is the origin of screening charges. Screening charges comes from band bending, surface reconstruction, and absorption, etc, their characteristic dynamics are diverse.
If the bound charges are not fully screened, then comes the depolarisation field. Usually this leads to domain reconfiguration. The ferroelectrics will reduce its depolarisation field to reach minimum energy. So it should be not large if the system is stable, but it is not a criteria of whether it is good or bad.
Screening process do exist in all the preparation techniques.
Please refer this review for details.
Kalinin, Sergei V, Yunseok Kim, Dillon D Fong, and Anna N Morozovska. “Surface-Screening Mechanisms in Ferroelectric Thin Films and Their Effect on Polarization Dynamics and Domain Structures.” Reports on Progress in Physics 81, no. 3 (March 1, 2018): 036502. https://doi.org/10.1088/1361-6633/aa915a.
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Specialists are trained according to the programs of special sections of physics, chemistry, etc. What other disciplines do they need to study? What is your experience in this area?
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Nanoprocedes+nanomateriaux+technique de caractérisation
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Which field is better for master's program?
1) Interfacial and surface chemistry: biosensing, electrochemistry, electronics
2) Materials and polymer chemistry: clean energy
3) Physical chemistry: superresolution microscopy, laser spectroscopy, biophysics
4) Catalytic processes: green chemistry
Actually I am keen on all 4 options and do not know which one to choose.( I have to choose one of them.)
Please share with me if you have information about these fields. I will be happy to know your point of view.
Comparison in terms of: the demand and needs of the community, the application, the novelty of the field and other factors that you think are important to consider.
Thanks.
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I would choose materials with unique properties.
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Hi,
Now I would like to model a simple system that a benzene on a Au(111) surface.
However, as I know the reaxFF parameter from the paper:
Jarvi, T.T., van Duin, A.C.T., Nordlund, K. and Goddard, W.A. (2011) Development of interatomic ReaxFF potentials for Au-S-C-H systems. Journal of Physical Chemistry C 115, 10315-10322
The force field was parameterized for sp3 carbon system. Does anyone have any experience to model the case for sp2?
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maybe this could work?
Susanna Monti, Vincenzo Carravetta, and Hans Ågren Simulation of Gold Functionalization with Cysteine by Reactive Molecular Dynamics J. Phys. Chem. Lett., 2016, 7 (2), pp 272-276
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If someone conducts a PhD research in natural science such as Physics, Chemistry etc, but meanwhile grows interest on social-science related research such as in anthropology, sociology etc and can provide evidences of relevant self-learnt skills, is he/she likely to get a post-doc position in social science? Can anybody share his/her personal experiences on anything similar?
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Yes and no! There's a number of fields which welcome researchers into projects from what might be a non-linear point of view, and there are even some programmes to encourage cross-pollination. However, it doesn't sound like you want to do an anthology of physics project or similar (science and technology studies etc).
Activism studies is also an underfunded but tightknit area, which means you will be competing with people who have developed strong connections and a network through their masters and PhD. It is also now increasingly common to have published during your PhD.
However, there are quite a few opportunities to volunteer on research projects, esp with monitoring and evaluation with charities/third sector organisations. This would help you build up your connects in relation to the area you want to work in, and learn from experts.
It also depends on your long term goals -if you want to work in a uni long term, you are better getting a PhD in the subject you want to work within. If you want to go into international or charity work, then I don't think there would be a value in that. Instead, it is more important to build up a coherent narrative of your background and showing that you have connects.
Good luck!
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Hello everyone,
i need help with the following questions to Physical Chemistry of Nanostructured and Soft Material. You can find the questions in the pictures.
I would be very happy if you could show me the answer and how you got to that answer. I am completely clueless and I don't know where to start.
Greetings
Jan
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Dear Jan Gries, you have to search for the answers by yourself by reading documents such as the attached one, no one can do your 'homework' at your place. My Regards
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Dear all,
We are looking for people interested in a postdoctoral position on ab initio and / or classical modeling of graphene-based systems.
I kindly ask you to pass this information on to all potential interested persons and to contact me. Location Pisa, Italy.
Thank you.
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Hi,
Computational chemistry about graphene, fullerene, puyuelènes is a good research subject.
It seems to me that the priority, in order not to waste time, is to obtain new carbon macromolecules for new treatments for COVID-19, bipolar disorder and special alloys to reduce gravity useful in the automotive and aerospace industry.
In short: little time in R&D and more responsiveness in B2B and industrialization of new solutions.
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I was offered to become a part of this journal editorial board - and encouraged to publish in it
I am suspicions.... you have to pay a substantial fee for publishing , the journal does not appear in SCIFINDER
If you can help me to asses this journal - I will be grateful
thanks
best
Yosef Scolnik
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In addition to the good points made above, any journal that charges a "substantial fee for publishing" is a predatory journal. Nice trick, " We'll put your name on the editorial board and take your money for each article you publish."
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Gas Dynamics, Physical Chemistry, Heat and Mass Transfer
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For Gas:
The pressure and volume change in temperature and the amount of heat required to raise the temperature for 1(gmol) of gas through 1°C depends on the way gas is heated.
Specific heat possesses infinite values. The specific heat of the gas is not constant. If you supply heat at constant pressure, you must have Cp. If you supply heat at constant volume, you must have Cv. For an ideal gas:
Cp – Cv = nR, where n is amount of substance, R:8.314 J /(mol K ).
Therefore, Cp is greater than Cv for gases.
For Solids and liquids:
The volume and the pressure of solid remains constant when heated through a small range of temperature. So, Cp=Cv.
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Are existing virtual laboratories efficient? How do you see the realization of practical works for other disciplines during emergency situations (architecture, agriculture, electronics, civil engineering, art, informatics, physics, chemistry, etc.). Are online practical works beneficial? Finally, is using simulation software a good solution for some fields?
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As part of my PhD project, which is developing a platform for teaching and practical works in robotics, I've conducted a study on how remote and virtual laboratories can be effective in a pedagogical activity. A questionnaire was given to a number of our teachers (who were 10 teachers) and the results showed that simulation and even practical activities on remote laboratories can be as effective as usual activities IF we can provide a platform in which interactions between students and teachers are possible. Student must have the possibility of asking their teachers any question at any time, they should work together and do their practical activity with their classmate even if they are apart. Teachers have to follow their students progress during the activity and ask questions, conduct tests and rectify their mistake. The list is long, but the main idea is that if we want to develop a full practical activity using simulated or remote labs their are pedagogical aspects and criteria we have to take into consideration. My results are sill primary, to validate those results I need more time to test the platform I put together on real pedagogical activities, in teaching a robotic course and to check the effectiveness of the platform on students. I hope I'll find support from my department!
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Book title : The Physical Chemistry of Natural Waters
Author: Frank J. Millero
this chapter....??The Kinetics of Oxidation and Reduction of Metals in Natural Waters.
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Agree with Frank T. Edelmann this article may help you
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Physics, Chemistry, Biology, Engineering - In the next month many professors are being challenged to move all classes online, including classes with Laboratory components. How do you teach someone to perform a titration experiment to determine solution pH over the internet? How do you have someone perform a 1-D collision experiment online? What about petri dish experiments on bacteria growth, or a Drosophila trait propagation breeding experiment?
An open forum such as this provides an opportunity for academics to share best practices for such a shift. It would be a terrible waste of resources for every professor, even every school, to try to develop a path forward in isolation. So what are some of the best ideas out there for distance learning with different laboratory classes? Are there resources readily available? Have there been case studies of this from which we all can learn?
(as a linear Q&A, this may not be the best format to capture and disseminate the information either, so pointers to better resources are also appreciated.)
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The development of OLabs includes the study and use of mathematical techniques to demonstrate the various complex functions in diverse areas of science The OLabs are hosted at www.olabs.edu.in. Access to OLabs is free for Schools upon registration.
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One remembers, first, that all matter used in anything is constructed of atoms, where atoms are made of particles, where quantum mechanics (QM) physically works.
Any physics, chemistry, engineering, computer science, even mathematics -- where the electrons, light, wave, and number behaviors are determining these fields by Nature -- will obey quantum rules, such as NO "law of the excluded middle" and NO "axiom of choice", and where QM principles play main roles.
One reads, for example, at Stanford U. that: the concepts and techniques of quantum mechanics are essential in many areas of engineering and science such as materials science, nanotechnology, electronic devices, and photonics.
Nominations by participants here (in order of appearance) include:
Superfluidity, superconductivity, HVDC with QM rectification by a thyristor (semiconductor), incandescence, laser, quantum decoherence, entanglement, P-type or N-type semiconductors, transistor radio, and the entire known universe for 13.8 billion years so far.
What is your reasoned opinion? What is your best example of QM having visible effects on microscopic and macroscopic scales?
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One thing that comes to mind in regards to your primary question is hydrodynamic quantum analogs. These experiments were done at MIT in July of 2013 published in Physical Review Letters E. Dr. Daniel M. Harris displayed that "a coherent wavelike statistical behavior emerges from the complex underlying dynamics and that the probability distribution is prescribed by the Faraday wave mode of the corral." I hope this helps!
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What is the "Biomechanics" of "heliotropism" as exhibited by Sunflowers? Can any one technically explain the physics and chemistry responsible behind?
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More informative and interesting responses are welcome
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There is a paper that was published in Atmospheric Chemistry and Physics by Wang et al. in which they have plotted the mass absorption coefficient (MAC) of brown carbon (BrC) with -log(NOx/NOy). They say that they have used -log(NOx/NOy) as a photochemical clock. Could anyone explain as to why they have done that?
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If the paper doesn't justify their reasoning, you may contact the authors.
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The molar volume of slag was calculated according to the molar volume of pure components and the excess molar volume of the slag:
Vm=XiVi(T)+VEX
where Vi(T) is the temperature-dependent partial molar volume of component i, and VEX is the excess molar volume of the slag.
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Thank you for your help!
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Counting all Sciences (including Physics, Chemistry, Life and Environmental Sciences, and similar), Technologists of all kinds (including IT), Electrical and Electronic Enginees, and pure and applied Mathematicians.
What is it in absolute terms and in percentage of the population?
And how fast do those numbers evolve?
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It would take a LOT of work to answer that question, but there is some useful information pertaining to recent rates of change of STEM graduates across the globe:
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What are the major reasons for the blue shift in absorption bands on complex formation( transition metal used) from the absorption bands of ligand?
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Do not mistake every blue- or red-shift as being due to changes in the bonding strength / energy. An absorbance spectrum is prone to many optical influences based on orientation, interference, particle shape and matrix effects etc. See e.g.
Furthermore, the peak maximum of absorbance usually blue-shifts the stronger the oscillator is (peak maximum and oscillator frequency do generally not coincide!).
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we know that Nonlinear Partial Differential Equations have a remarkable ability to predict the world around us. They are used in a wide variety of disciplines, from biology, economics, physics, chemistry and engineering. They can describe exponential growth and decay, the population growth of species or the change in investment return over time. Therefore we want some references in this field . Thanks
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let's express our thanks for your answers.
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We should not only study: morphology, chemistry, physics of nanoparticles. One of the most important factors for NPs to be suspended or resuspended is density. How to measure the amount of suspended NPs then considering the density?
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Stokes law.
By definition of nanoparticles as smaller or equal to 100 nm in at least one dimension most nanoparticles will not or only slowly settle at gravity.
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Dear fellow researchers,
I want to ask whether it is possible to cap the silver ions in a complec form, without converting them into AgNPs or breaking the complex structure?
Please don't mind my basic question. My area of expertise is not chemistry or physics.
Thank you in advance for your guidance.
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Well, "the" classical cheap silver complex is Diammine silver [Ag(NH3)2]+. Just add ammonia to water-dispersed AgCl and you've got a solution. If you want your complex to be soluble in different solvent, check out the catalogue of special chemical providers. Aldrich actually has a "Silver Complexes" segment.
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I have heard that rich mixtures produce more power and lean mixtures less power. I am not able to understand this concept as for me, rich mixtures mean that the entire fuel is not burned and hence peak power obtainable is lost. But lean fuel mixtures allow for the entirety of the fuel to be burnt and hence more chances of peak power. Please explain this to me
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Comparison of New and Old Thermodynamics
1. Logic of the Second Law of Thermodynamics: Subjectivism, Logical Jump, Interdisciplinary Argumentation.
2. New thermodynamics pursues universality, two theoretical cornerstones:
2.1 Boltzmann formula: ro=A*exp(-Mgh/RT) - Isotope centrifugal separation experiments show that it is suitable for gases and liquids.
2.2. Hydrostatic equilibrium: applicable to gases and liquids.
3. The second and third sonic virial coefficients of R143a derived from the new thermodynamics are in agreement with the experimental results.
3.1. The third velocity Virial coefficient derived is in agreement with the experimental data, which shows that the theory is still correct when the critical density is reached.
4. See Appendix Pictures and Documents for details.
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I wonder if there is a simple methodology (apart from the Gibbs Phases Rule or visual inspection) to determine the number of liquid phases in a given mixture. Any suggestion will be very appreciatted and helpful.
All the best,
Carlos
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hello,
you can separate the mixture to enhance the phase rule is F= C-P+2 or F=C-P+1 or F= C-P......
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Pierre Telihard de Chardin speaks about deep conection between human being and nature.Processes into living organism do not depend only on physics, chemistry or biochemic. Discussions about forces which governed into living being have been living yet... Do supernatural forces govern life phenomena as well?
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Yes, supernatural forces definitely govern life on Earth. How else you can explain statistical data that Earth population became dumber and less educated?
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I did a computational chemistry research regarding molecular docking and molecular dynamics. I scored well in that research. However, I am desired to be a physical chemist, majoring the field of chemical thermodynamics. Due to lack of facilities and experts in my college I could not do a research on this area. I am willing to go abroad and do a PhD in physical chemistry. Will my undergraduate research be a problem in that case? What is your advise about publishing my undergraduate research?
Thanks in advance.
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Moving from computational chemistry back to experimentes is precisely what I did proceeding from undergraduate to Dipl./PhD works without losing any time; several other people did the same so it is definitely not an unusual path. However, classical chemical thermodynamics are often no longer performed by physical chemistry institutes but can rather be found in engineering faculties/departments. So if you want to move your location for your PhD, I would recommend you to check out those facilities; many of them also offer chemical PhD degrees, if you prefer that.
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The universal/molar/ideal gas constant R is given by
R=PV/nT; this however, on an average, is considered true for gases (H2, O2, N2 are excluded). Involving R in chemical expressions dealing with gases is understandable; but could it's inclusion in the chemical equations, primarily evolved for the gases and later being used for liquids as well be justified? To be more specific, I am talking about the Dubinin isotherms which are also being used for modelling the adsorption of adsorbates present in a liquid, uses the term RT for determining the adsorption energy. Is it justified? Please enlighten me; I am eager to hear from you.
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Following
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Could someone please suggest me a book that details Thermophoresis/Soret effect and Its applications or implications in physics, chemistry, biochemistry and geology?
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please list out the sci journals in physics and chemistry paid journals with fast publications
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Dear search the website of the journal using the abstract and title of the work.
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Can anyone suggest online site for downloading chemistry text book and presentations for free? now a days most of the site ask money for getting e book. If possible please give the link for those site...
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@sci-hub.tw/
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Are there singularities in the equations of Physical Chemistry, similar to those that appear in Classical Electromagnetism, General Relativity, Cosmology and Aerodynamics? What would be their physical implication, interpretation and consequences?
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Of course, yes. To give an example, from quantum chemistry, let z be a perturbation parameter and suppose that we computed E(z) function by using Rayleigh-Schrödinger perturbation series (n>3 order). This function involves singularity points in the complex z plane which are responsible for the convergence of the perturbation series. In terms of Schrödinger equation (and conformal mapping) these singularities manifests some changes in molecular geometry or in basis set. Such points may connect the ground state to an excited state of the molecule (generally to a low lying excited state or the one as its lowest symmetry). Some other points behave as critical points upon dissociation. MP4 and CCSD(T) type computations reveal such phenomena.
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Dear friends,
I would like to receive suggestions for 1 or 2 textbooks for "Physical Chemistry" or "States of Matter" courses. I have some titles in mind, but I would like to have a feedback from the community, including novel editions that maybe I am not familiar with.
Thank you!
CS
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Atkins' Physical Chemistry, Eleventh Edition, Oxford University press, Peter Atkins, Julio de Paula, and James Keeler.(ISBN: 9780198769866)
I quote: "Atkins' Physical Chemistry epitomises the benchmark of achievement for a chemistry degree throughout the world. Its broad coverage, concise explanations, and robust mathematical support are clearly presented in an engaging style to furnish students with a solid foundation in the subject."
In other words: as a student (long time ago...) it was already an excellent book. Nowadays it is supported with all sorts of additional features.
Good luck and enjoy!
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Soil infertility, soil chemistry, physical chemistry, Soil physics
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Mr. Phogat,
Via MS.