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What is the meaning of the AFt phase in cement concrete?
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AFT (Accelerated Carbonation Test): This is a laboratory test used to assess the carbonation resistance of concrete. Carbonation is a chemical reaction where carbon dioxide from the air reacts with the calcium hydroxide in concrete to form calcium carbonate. AFT helps in predicting how well concrete will resist carbonation over time. AFt (Alumina Ferric Tri-sulfate): In the context of cement, AFt is one of the phases that can form in certain cementitious systems. It is a hydrate phase that includes aluminum, iron, and sulfate. AFt is often associated with the hydration of Portland cements containing significant amounts of sulfate.
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How do diverse aggressive media and modifiers interact with magnesia cements under varying conditions, and what advanced methods enable precise engineering for optimal performance in practical applications.
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The reaction takes place at the atomic or molecular level for the hydration reaction, and it works to accelerate the reaction, and this can be detected using a scanning electron microscope.
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Thank you for guiding me. I am preparing samples of isolated planktic Foraminifera from limestone, when some crushed stone samples are placed in acid, instead of being soft and ready to be washed, they become hard and cemented. What is the cause of this issue?
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ِِDear Omidi
In my experience, when adding acid does not help, it is best to crush the sample with pliers (with the striate surface of the mouth) until the mud is removed from the sample. Then place the prepared sample in water for 48 hours, then grind the appropriate sieve sample under water for a few minutes. This method is helpful for separating the sediment on the isolated form in hard samples
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Dear Sir,
We all know that the water cement ration 0.45, which may vary due to the Mix-Design. But during the concrete due to changes of weather & materials SSD condition the slump changed (Generally Dropped) in mid time.
So looking the help from experience person, how many water may use for 1mm/5mm slump gaining. The equations also okay, I can check with our mix-design for getting the value.
Thanks in advance for your assistance.
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Concrete workability, characterized by its slump, can fluctuate due to environmental variables such as temperature and humidity, as well as variations in constituent materials. Despite targeting a nominal water-cement ratio of 0.45, achieving the specified slump may necessitate adjustments. In response, a careful approach to adding water incrementally becomes imperative to restore slump while preserving the intended water-cement ratio. It is essential to exercise caution to avoid excessive water addition, which may compromise concrete strength and durability. Continuous monitoring and precise documentation of these adaptations are critical to ensuring the conformance and consistency of the concrete mixture, ultimately contributing to the successful execution of construction projects.
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Can cement and asphalt be used in a concrete mix at the same time?
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Cement and asphalt function as binding materials but possess distinct properties and mechanisms, making their simultaneous use in a single concrete mix unconventional and impractical. Cement, a hydraulic binder, undergoes a chemical reaction with water to set and harden. In contrast, asphalt, a bituminous binder, requires heating to become pliable and cooling to solidify. These divergent processes result in materials incompatible in a mix, as the water necessary for cement hydration adversely affects asphalt’s integrity and bonding capability. Combining them would likely yield a mixture with compromised strength and durability, unsuitable for most construction applications. For optimal results, these binders are best utilized separately, each in applications that leverage their unique characteristics and benefits.
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Need it.
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Ferro-cement toilets are a type of sanitary facility constructed using a technique of reinforced mortar. These toilets are relatively easy to build, durable, and are often used in situations where more conventional toilets aren't practical, such as in rural or underdeveloped areas. The operation mechanism of a ferro-cement toilet is quite simple and can be categorized into a few stages:
### Construction:
1. **Skeleton Making:** A skeleton structure is built using steel mesh or chicken wire and then shaped as desired. It can be formed into various shapes and sizes.
2. **Cement Work:** The skeleton is then covered with a thin layer of mortar (cement mixed with sand and water). This forms a durable structure once dried.
3. **Finishing:** Once the cement is cured, it is waterproofed and sometimes tiled for aesthetic and hygienic reasons.
### Operation Mechanism:
The operation mechanism of a ferro-cement toilet can be understood in several key stages:
1. **Use of the Toilet:** The toilet is used in a conventional manner.
2. **Waste Collection:** Depending on the design, waste may be directed to a pit, septic tank, or another kind of waste management system.
3. **Waste Treatment:** The waste undergoes natural decomposition, and if a septic system is used, solid waste is broken down in the septic tank.
4. **Waste Disposal/Use:** Liquid waste (effluent) is generally allowed to percolate into the ground. If the system is designed for it, solid waste might eventually be removed and used as compost.
### Maintenance:
- **Cleaning:** Regular cleaning is essential to maintain hygiene.
- **Checking:** Periodic checks for cracks and other damages to ensure that the ferro-cement is holding up.
- **Desludging:** In the case of pit toilets or septic tanks, periodic desludging may be necessary to remove solid waste when the system gets full.
### Advantages:
- **Durability:** Ferro-cement structures are robust and weather-resistant.
- **Cost-Effective:** They are relatively cheap to build and maintain.
- **Sustainability:** Can be implemented in regions with limited resources.
- **Adaptability:** Can be shaped and sized as per requirement.
### Challenges:
- **Manual Scavenging:** In some instances, manual desludging might be required which poses health and social risks.
- **Waste Management:** Safe and hygienic waste disposal/treatment must be assured.
- **Cultural Acceptability:** Sometimes, communities might be reluctant to use them due to socio-cultural beliefs.
Always note that the efficiency and health safety of any toilet system, including a ferro-cement toilet, largely depend on good maintenance practices and appropriate use. This ensures that the waste is managed effectively, and hygiene is maintained. Furthermore, waste should be handled, treated, and disposed of in a way that is safe for both people and the environment.
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Hello
The effect of nanoclay on the strength will mainly depend on the percentage weight of nanoclay added and the type of cement material you are using as well as which type of strength you are measuring (compressive, tensile, flexural, impact, ...).
This is a very interesting review about the effect of nanoclays as fillers on different material properties.
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hi, how can I get mortar material (cement+sand+wtaer) in envi.met program?
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السلام عليكم دكتورة امال العزيزة تكدرين اتروحين لقسم المعمار النهرين اكو دكتورة متخصصة بالبرنامج اجوبك على كل الاستفسارات تقبلي تحياتي@
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I want to run long term temperature cycles e.g. 30 years day and night temp variation cycles, in molecular dynamics. How can I do it? If someone can refer research articles in this regard, it would be really helpful
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MD simulations cannot be done for such a long time scale. If you implement several crude approximations you will not be able to get any useful data(provided you are able to perform it in the first place).
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is the following mixture respect the europeans standards?
cement => 1 part
sand => 3 parts
water => 1/2 part
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No, in EN 196 the water to binder ratio is fixed at 0.5, irrespective of the flow that you get. The proportions given in the original question are correct. You are allowed to use superplasticizers to compensate if you're using, for example, a cement with high water demand.
What is described above is the ASTM (C109/C109m) approach to standard mortar testing, where you aim for a uniform consistency in the flow table rather than a fixed water to cement (or binder) ratio. Which approach is better or worse is a completely different (and sort of endless) discussion that is still ongoing, but those are the two main trends.
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From a physical and mechanical point of view
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Adding brick powder to cement can have a number of benefits, including:
  • Reduced cost: Brick powder is a waste product, so it is relatively inexpensive to obtain. This can help to reduce the cost of concrete.
  • Improved strength: Brick powder can help to improve the strength of concrete. This is because brick powder contains silica, which is a strong mineral.
  • Increased durability: Brick powder can help to increase the durability of concrete. This is because brick powder helps to protect the concrete from the elements.
  • Reduced shrinkage: Brick powder can help to reduce the shrinkage of concrete. This is because brick powder helps to fill in the voids in the concrete.
The optimal addition percentage of brick powder depends on the type of concrete being used and the desired properties of the concrete. However, a typical addition percentage is 10-20%.
Here are some additional benefits of adding brick powder to cement:
  • Improved workability: Brick powder can help to improve the workability of concrete. This means that the concrete will be easier to mix and place.
  • Reduced water demand: Brick powder can help to reduce the water demand of concrete. This means that less water will be needed to mix the concrete, which can improve the strength and durability of the concrete.
  • Increased fire resistance: Brick powder can help to increase the fire resistance of concrete. This is because brick powder is a non-combustible material.
Overall, adding brick powder to cement can have a number of benefits. It can help to reduce the cost, improve the strength, durability, workability, and fire resistance of concrete. The optimal addition percentage of brick powder depends on the type of concrete being used and the desired properties of the concrete. However, a typical addition percentage is 10-20%.
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Topics related to materials, polymers, composites materials, cement materials, sustainability and so on.
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Good question.
I find that some of the most exciting topics I studied were often those into which I stumbled accidentally and not really by prudent planning, hence, I feel that it might be a wise strategy to follow two strands:
1) just follow your gut feeling and your nose and keep your eyes open on unexpected and strange and outlier type of phenomena where real scientific gold nuggets might be hidden, so to say, watch out off the beaten track.
2) looking for large scale societal needs on the other hand may indeed also be a pertinent strategy because I sometimes feel that our materials science community is a bit conservative and not really taking many risks in such areas nowadays, often rather following topics in which the (expected) impact is relatively high. My personal taste in this category are for instance research topics related to materials related questions such as (a) sustainability/ sustainable metallurgy / sustainable cement etc (i.e. real reduction of carbon dioxide emissions, beyond the usual bla bla); (b) materials for future water supply; (c) machine learning in material science and engineering ; (d) large (huge) scale energy storage for buffering abundant sustainable and grid electricity (i.e. Not just lithium based batteries for vehicles; but land based huge storage capacity): (e) electrochenistry and corrosion of materials (i.e. longevity) etc. etc.
I feel that - for getting good ideas in such directions - it is sometimes more helpful to read financial and business newspapers rather than our usual community material science journals, which, as I mentioned before, are sometimes chasing citation-measured impact alone but not real relevance for society and industry and not real curiosity-driven topics that sit between the established chairs. Open your eyes and look around you and think urself what your local, wider, or global society really needs from us materials scientists? Ideas will then come en gros.
Good luck.
One example what I chase at the moment :-)
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If there is overdosing of admixture then there is chance of segregation,shrinkage and other many problems and company also only provides dosages as 0.5-1.5% of cement in their certificate so how can we know the exact dosage of admixture for concrete??
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To determine the precise dosage of admixture for concrete, a variety of factors must be taken into account. These factors include the unique project requirements, the properties of the admixture itself, and the characteristics of the cement being utilized. While the dosage range stated in the company's certificate can offer a general reference, it is crucial to seek advice from experts and conduct thorough testing in order to ascertain the most effective dosage for your particular application.
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For a mix design of Grade 30 or Grade 40 concrete, whether the admixtures (retarder and superplasticizer) will chemically react with the OPC or BHC in a different manner and results changes in initial and final setting time of concrete?
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I would agree with the answers above. Setting time depends on a multitude of factors. Each project should determine how long a set time they need and then design the mix to set within the desired time span. The effect of admixtures is hard to predict. I had a case where we took a regular water reducing agent, dosed it at twice the manufacturer's recommended dose and achieved excellent retarding effects. In that case we delayed the set time for several hours (we had to transport concrete from a batch plant to a loading dock, transfer it by crane and bucket to barges fitted out with agitating hoppers, tow the barge to concrete placement site, and then place it with a crane barge and buckets in the piers), but we had rapid strength development after that.
So the practice to follow is to determine your requirements then design your mix.
One comment about superplasticizers: They typically increase the workability for about 30 minutes, then need to be re-dosed. You can add superplasticizers several times as the effect wanes.
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I am looking for research papers, articles, and relevant information on the utilization of plastic waste in stabilizing loose soils and how plastic waste affects the engineering properties of cement.
Any help will be greatly appreciated.
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I can think of many ways of using plastic waste to stabilize soil particles and improve cement-grade properties. Plastic wastes can include polythene, compound plastics, wrappers, and so on. One can stitch plastic pieces tightly with unconsolidated soil and apply various nominal stresses and shear forces. 1000-1500 Kpa can be tried at first with plastic-strips boundary at 5mm thickness and 1000 mm span. With notice taken to clay with 0.001 mm particle sizes, require the greatest compression to get rid of void pressures and hydrostatic pressures. Gravel has a large particle size of around 0.2-0.5 mm and requires less compaction. It can take a very long time to consolidate clay. One can increase plastic strips' density by wrapping soil particles with a thickness that can be increased for holding stresses. The holding stresses can be increased to 2000-3000 Kpa, with greater interbinds to hold silt or clay particles. The thickness of the plastic strips has to be increased to prevent rupturing and particle leaks. Solid plastic can be crushed and grid with asphalt, silt, and clay to make cement.
Depending on the percentage composition of the mix, compaction tests can prove the strength and yield of the different cement mixes.
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What kind of rock is formed when fragments are pressed and cemented together and how did you form magma where on the landscape did the magma form?
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Sedimentary rock forms when sediments are pressed and cemented together, or when minerals form from solutions. Magma forms when any type of rock is melted, a process driven by energy from Earth's interior. The plate motion that occurred near the Great Plains and Rocky Mountains uplifted igneous rock that formed underground.
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Can cement and liquid sulfur be used in a concrete mix at the same time?
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mixing liquid sulfur into concrete mix would introduce incompatible materials and could negatively impact the performance of the concrete.
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Do you know a book on scanning electron microscopy of concrete/cement?
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It is not a book, but also try:
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Mitigating the effects of climate change through reducing the amount of cement used or using recycled construction wastes in concrete or decarbonized cement. WE can discuss and explore more in this area.
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Using recycled construction wastes in concrete or decarbonized cement could be an ideal intervention provided that the demand side could be adressed and/or realized. Producing cement using renewable energy sources could also compliment the first option with significant mitigation impact.
Thank you.
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What concrete binder is used in your country? (cement, ash, slag ... and what else?)
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Rajden Skhvitaridze, I meant binders not included in the standard.
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Taking the above as a reference sample, I cant distinguish and differntiate between cement and matrix.
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In a thin section slide of a sandstone, cement and matrix are two important components that can be distinguished based on their mineral composition and texture.
  1. Cement: Cement is the mineral material that fills the spaces between the grains of sand in a sandstone. It is usually composed of minerals such as calcite, quartz, feldspar, or clay minerals. The cement can be identified by its distinct mineralogy and texture, which is different from that of the sand grains. For example, calcite cement is usually clear or white and has a crystalline texture that is different from the opaque, rounded grains of sand.
  2. Matrix: Matrix refers to the fine-grained material that fills the spaces between the larger grains of sand in a sandstone. The matrix is usually composed of clay minerals, silt, or fine-grained sand. The matrix can be distinguished from the sand grains by its smaller size and finer texture. In some cases, the matrix may also contain small amounts of cement.
To differentiate between cement and matrix in a thin section slide of a sandstone, you can use a polarizing microscope. Under polarized light, the cement and matrix will exhibit different colors and textures, allowing you to distinguish between them. The cement will appear brighter and more crystalline, while the matrix will appear duller and finer-grained.
Overall, understanding the difference between cement and matrix is important for interpreting the depositional environment and diagenetic history of a sandstone.
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The IPCC has only recently acknowledged that cement and concrete in the built environment constitute a significant carbon sink due to the process of carbonation. Much has been written about the factor determining carbonation, but no universally accepted indices would guide decision-making to build lower carbon structures.
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Thank you, Claude-Alain, I shall review these references with great interest.
Frank
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As we know, 1kg of cement production produces about 0.8–0.9 kg of CO2 and other greenhouse gases. Many studies have been done on the partial replacement of cement with ash from different waste materials, i.e., rice husk ash, fly ash, coconut shell ash, water hyacinth, bamboo leaf ash, sugarcane bagasse ash, and many more. The burning of these materials will also produce CO2. Everyone is mentioning in their paper that it reduced CO2 emissions, but I did not find it in numbers.
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You are correct that the production of Portland cement is responsible for significant CO2 emissions, with approximately 0.8–0.9 kg of CO2 emitted per kg of cement produced. The use of waste materials as partial replacements for cement, such as rice husk ash, fly ash, coconut shell ash, water hyacinth ash, bamboo leaf ash, and sugarcane bagasse ash, has been studied as a means to reduce these emissions. While the burning of these waste materials does produce CO2, the overall emissions tend to be lower than those associated with traditional cement production.
Quantifying the exact reduction in CO2 emissions from using these waste materials as cement replacements can be challenging due to several factors, including:
  1. Variability in waste material composition: The chemical composition of waste materials can vary significantly, affecting the CO2 emissions associated with their combustion.
  2. Combustion efficiency: The efficiency of the combustion process for each waste material can influence the amount of CO2 released.
  3. Proportion of cement replacement: The amount of CO2 reduction depends on the percentage of cement being replaced by the waste material in the mix.
In many cases, the focus of research papers is on the mechanical properties and durability of concrete made with these alternative materials, rather than providing exact numbers for CO2 emissions reductions. However, it is generally accepted that utilizing waste materials as partial cement replacements can lead to a reduction in overall CO2 emissions, as these materials often have lower carbon footprints compared to traditional Portland cement production.
To obtain more specific numbers on CO2 emissions reductions, you may need to look for studies that have conducted life-cycle assessments (LCAs) for concrete made with these waste materials, as these assessments consider all aspects of production, including CO2 emissions.
I hope this helps!
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Let's say that I have a given mortar mixture with the w/c ratio at 0.74. Consumptions are as follows: Cement - 339.8 kg/m3; Sand - 1676.7 kg/m3; Water - 251.8 kg/m3. The sand is siliceous, with a water absorption of 0.1%. Imagine I am preparing 1m3 of the mixture.
Is it possible to design a cement paste with the water content proportional to the amount of water in the mortar mixture (only excluding the water parcel related to the sand)?
From my perspective, I would discount 2.52 g for the absorption. But I would also need to discount the amount of water needed to wet the grains. Maybe a layer of water times the specific surface area? Any ideas or literature recommendations?
I really appreciate your insights. Thanks!
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What do you mean by "cement paste with the water content proportional to the amount of water in the mortar mixture"? Do you need to design the paste of the same consistency or strength? Because each needs other approach to the task.
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How is thermal insulation measured inside rooms built with clay and cement bricks?
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Thank you, my teacher Thank you, my teacher
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28 days cured alkali activated binder samples were immersed in acetone to stop the hydration reaction before characterization. The samples immersed in acetone were stored in oven in a controlled temperature of 22 +/- 2 degree Celsius. That oven has a temperature range of up to 80 degree Celsius.
While my samples were stored , the oven malfunctioned and the temperature raised to its maximum limit (80 degree Celsius). When I went to store few more sample, I saw the temperature was fluctuating between 75 and 80 degree Celsius and the acetone in vails was boiling (as it has low boiling point).
With the acetone wash, the hydration reaction of samples was stopped but I am wondering if the samples stored in that acetone are still suitable for characterization? or I should synthesize the samples again. Kindly comment your opinion.
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Acetone is a highly volatile compound and easily gets evaporated at normal temperature and in your case samples dipped in acetone were kept in an oven that had temperature, fluctuating between 75 and 80 degree Celsius . As per my opinion, acetone efficacy might had reduced because of which hydration might not had stopped. It is advisable to synthesize the samples again
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i am working on research regarding partial replacement of cement. i have seen some research with related topics and most of them used 5%, 10%, 15% and so on. i planning to use those percentage too but i want to know why start at 5% and what's with the 5% increment?
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Cement is an essential material for many construction projects, and its use has increased as population growth and urbanization increased. However, cement production is a significant source of carbon dioxide emissions and energy consumption, significantly contributing to climate change. As such, finding ways to replace cement with other materials partially is essential for sustainable and environmentally friendly construction. Research shows that the partial replacement of cement with other materials can improve the performance, durability, and environmental impact of construction materials and reduce the overall carbon footprint of the construction process. For example, fly ash, a byproduct of coal burning, can reduce the need for cement by up to 35%. In addition, other materials, such as slag, silica fume, and natural pozzolans, can be used to partially replace cement, with percentages ranging from 5% to 30%. When considering partial cement replacement, it is essential to evaluate why to start at 5% and what the 5% increment is. Starting at 5% is important because it allows researchers to gradually increase the replacement percentage while assessing the concrete's performance. Starting at a higher rate may lead to unexpected results, as the performance of the concrete may be better than initially anticipated. The 5% increment is essential as it allows researchers to gradually increase the percentage of replacement in small steps and assess the changes in performance. In conclusion, the partial replacement of cement with other materials is a critical way to reduce the environmental impact of construction. Research has shown that using different materials to replace cement partially can improve the performance, durability, and environmental impact of construction materials while reducing the overall carbon footprint of the construction process. When considering the partial replacement of cement, it is essential to evaluate why to start at 5% and what the 5% increment is to ensure the performance of the concrete is as expected. References: 1. Bhuian, S.N., and Abdalla, M. (2008). Cement replacement materials. Cement and Concrete Composites, 30(10): 667-673. 2. Sivakumar, M., and Murugan, R. (2013). Partial replacement of cement with fly ash. Indian Journal of Science and Technology, 6(10): 4491-4495. 3. Sharma, M., and Sharma, A. (2018). Partial replacement of cement with Silica Fume and Slag in concrete. International Journal of Engineering Research and Technology, 7(7): 1101-1105. 4. Hadi, M.S., and Ammar, M.A. (2010). Partial replacement of cement with natural pozzolan in concrete. International Journal of Engineering Research and Technology, 1(2): 13-18.
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I am starting to work on a project concerning DEF or SEF as a damage mechanism. We are not able to find any standard accelerated tests for DEF. I have read about Duggan, Fu, and Kelham methods etc. They seem to be quite old. Are there any standard accelerated tests that have been developed for this?
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Thanks for your question, leachate testing for the solution concentration may be one of the options of for measurting the potential DEF-expansion. Please find the details in this manuscript.
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Hi all, does anybody know how to calculate the energy savings from replacing light-wave absorbing cement flooring with epoxy light-wave reflecting cement flooring?
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To calculate the energy savings from replacing L-W absorbing cement flooring with epoxy light-wave reflecting cement flooring, you need to consider the following steps:
  1. Determine the current energy consumption for heating/cooling: You need to determine the current energy consumption for heating/cooling of the building. This information can be obtained from utility bills or by using a building energy simulation software.
  2. Determine the solar reflectance of the existing and new flooring materials: The solar reflectance of the flooring materials is a measure of how much of the incident solar radiation is reflected back into the atmosphere. The higher the solar reflectance, the less energy will be absorbed by the flooring and the less energy will be required to cool the building.
  3. Calculate the reduction in cooling energy consumption: Using the above information, you can calculate the reduction in energy consumption due to the decrease in the amount of energy absorbed by the flooring. You can use the following equation:ΔE = A * I * (R_old - R_new)
where:
  • ΔE is the change in energy consumption
  • A is the area of the flooring
  • I is the average daily solar radiation incident on the flooring
  • R_old is the solar reflectance of the existing flooring material
  • R_new is the solar reflectance of the new flooring material
  1. Estimate the cost savings: Once you have determined the reduction in energy consumption, you can estimate the cost savings by multiplying the reduction in energy consumption by the cost of energy.
It's important to note that the results of the calculation will depend on several factors such as the location of the building, the orientation of the flooring, and the climate. It's always a good idea to consult with a professional engineer or energy analyst to get a more accurate estimate.
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Can Ultrasonic pulse velocity test be used to determine parameters for non cement concrete material such as limestone ( used to build in heritage structures) ? if it is possible, how to measure parameters ? What are the guidelines?
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Yes, you can use Ultrasonic Pulse Velocity test to determine the parameters of non-cement concrete materials such as rock or limestone. You can measure the parameters using ASTM standard: Standard Test Method for Laboratory Determination of Pulse Velocities and Ultrasonic Elastic Constants of Rock D 2845 – 00. This test method describes equipment and procedures for laboratory measurements of the pulse velocities of compression waves and shear waves in rock and the determination of ultrasonic elastic constants of an isotropic rock or one exhibiting slight anisotropy.
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I am studying stress transfer during hydraulic fracturing. However, the stress transfer mechanism is out of my research field. For a simple example, when a cement sample is loaded by compressive stress, if the stress value at a point inside the cement sample is lower than the loaded one (?), how do we get to know the detailed stress inside the cement?
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The internal stress of a natural rock may be less than or equal to and higher than loaded stress, this depends on the internal heterogeneity and defect distribution of the rock. The discrete element method can analyze the stress transfer of rock and soil.
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When trying to make concrete containing aerogel, the hydrophobic nature of the aerogel made the actual manufacturing process very difficult (the aerogel floats on the top side of the cement slurry because of its density, and it takes a long time to mix with the cement slurry), so I wanted to ask if there was a dispersion agent that could facilitate the manufacturing process of the samples.
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Dear,
I suggest to use a wetting agent to engage better the aerogel inside the mixture. There are several types on market that work very well, but dosages can change depending on concentration of reactive content.
I think you could check about BASF portfolio.
These products can work at best if supported by polycarboxylates superplasticizer to manage the high amount of mixing water.
Best
Alex Reggiani
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Recently, i have been subjected to many rejection for the reason of novelty which does not making sense at most. I came through the following abstract in the aforementioned journal and although my manuscript is discussing very importnat applicable topic in porous concrete i came through recent published and accepted article with the below abstract.
Calcium sulfoaluminate (CSA) cement can be used as a replacement for Portland cement to reduce CO2 emissions. However, the performance of CSA cement remains unknown with regard to its hydration mechanism, mechanical and long-term performance. Therefore, it would be beneficial to consolidate the literature on CSA cement to facilitate its use in the construction industry. To this end, recent progress and technical challenges of using CSA cement are discussed in this paper. We begin with the introduction of the different types of CSA cement and the manufacturing process. This is followed by a detailed discussion on the hydration mechanisms and phase assemblage, mechanical performance, and long-term durability of CSA cement. Finally, the applications of CSA cement are discussed.
My question does the journal accept or reject papers on the basis of relationship and politics is the research include also some corroupted and bais basis.
Please i would like to be answered for once
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I cannot comment on this specific case, since this is not my domain of expertise, but I can add that some publishers do not care very much about the quality, novelty or whatever we may consider as quality indicator. For some of the open access journals (generalisation is not fair here as in many other situations), what matters is the payment of the processing fee.
I have the experience of reviewing for one publisher that claims to have papers published slightly above one week after reception, which is phantastic. The point is that reviews are mostly a make-believe action.
A few months ago, I was invited to make a review for one of those journals and was asked to do it in 10 days (after I having said that one week time was too short). After one week, the publisher had already two extremely superficial reviews that accepted the paper without major modifications, while discarding mine that added a 30 points list of arguments to reject it. The paper was published, and I never again accepted the many invitations they are continually making.
Therefore, we must read each new article with a critical sense and not accept that everything written can be taken as valid.
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I am really curious to know why we make clinker in oxidizing conditions? of course because of burning the fuel for the kiln but do the environment really affects the clinker quality.
What will happen to the cement quality if the Clinkerization reaction happen in reducing environment?
regards
Saurabh
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If the clinkerization reaction (the process of forming clinker, the main component of cement, from raw materials such as limestone and clay) occurs in a reducing environment, the quality of the cement may be affected. In a reducing environment, the iron in the raw materials may be reduced to metallic iron, which can cause the cement to be less durable and less resistant to sulfates. Additionally, the formation of metallic iron can lead to a decrease in the overall strength of the cement. Therefore, it is important to maintain an appropriate level of oxygen during the clinkerization reaction to ensure optimal cement quality.
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As it is evident, concrete production industry, especially cement has put the environment in a crucial situation via greenhouse gas production, as well as natural resources (e.g., sand) consumption. what could be done in order to make a shotcrete mix design more sustainable in order to achieve a good properties (e.g., mechanical, workability, etc.) product with less environmental footprints?
Many thanks,
Hossein Pouresmaeil.
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'To make a shotcrete mix more environmentally friendly, replace part of the Portland cement with supplementary cementitious materials, such as fly ash or slag cement. Using recycled aggregates and reducing the water-cement ratio can also help shotcrete have less negative impact on the environment. For example, the use of fly ash instead of half the cement can significantly reduce CO2 emissions. It is possible to further reduce the overall environmental impact of shotcrete by taking into account its life cycle, including the amount of maintenance required. The environmental impact of shotcrete can be reduced by curing it with wet burlap or burlap cloth, which requires less energy.'
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#Cement Science #construction material #waste material #Civil engineering
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Silica Fume;
Water to cement ratio influences concrete permeability,
Etc.
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On November 28, 2003, the government of India has banned the free import of kerosene. As a result, kerosene became extremely scarce. As per IS 4031 Part-11 1988, section-5, "Kerosine free of water, or naphtha having a specific gravity not less than 0.7313 shall be used in the density determination". So, what alternatives to kerosene can be used to determine the specific gravity of cement?
Looking forward for the answers from the researchers who are working on cementitious materials.
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Yes, helium pycnometry will work. If you want to stick with the volumetric method, you can substitute for the kerosene with an alcohol. See for example:
  • DOI:10.1520/JTE20150148
  • Corpus ID: 23507184
Comparative study of methods to measure the density of Cementious powders.
  • Michelle A. Helsel, C. Ferraris, D. Bentz
  • Published 1 November 2016
  • Materials Science, Engineering
  • Journal of testing and evaluation
This paper can also be found on ResearchGate.
Good luck,
Dale
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Hello dear researchers!
I found in my results that the increase in the specific surface area of C-S-H (obtained by BET N2 methode) led to an increase in the hydration degree. Any suggestions or articles about this?
Thanks..
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thank you sir Shashikant Kumar for you recommendations
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Gems Selektor software
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The most recent versions of the CEMDATA database contain a subset dedicated to alkali-activated materials. If I'm not wrong, that database uses zeolites as proxies for N-A-S-H phases. Alternatively, you can create your own set of phases that are relevant in AAM. For reference, you can browse my publication:
Here, you'll be able to find a table with thermodynamic parameters for some relevant phases, comprising N-A-S-H (I used a two end-member solid solution), metakaolinite and alkali carbonates (thermonatrite, trona, pirssonite, gaylussite).
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Health effects due to exposure to cement
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Once it enters your lungs there is a potential for numerous short and long-term problems. Particularly if it is un batched, the list is very long, research on this basis.
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I am looking for specific heat capacity of BCSA or CSA cement that is a rapid setting cement. I appreciate it if you know any reference to recommend.
Thanks
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I would suspect that it would not be that different from OPC, whose value can easily be found in the literature. If you want an easy way to estimate its value, assuming you do not have thermoanalytical equipment (such as a Hot Disk) to make the measurement, you can easily construct a simple calorimeter using a beaker of solution of known heat capacity (an alcohol for instance, don't use water as it will react with the cement). Then, weigh the beaker empty, with the solution added (measure its temperature as well), and finally after adding the cement powder that it is first heated to an elevated (known) temperature (below the boiling point of the liquid of interest). Measuring the final temperature of the mixture in the beaker will allow a quick calculation via an energy balance (m1*deltaT1*Cp1=m2*deltaT2*Cp2) of the unknown heat capacity (neglecting any energy that is added if you stir the mixture, for example --- could further estimate this effect by performing experiment on a powder of known heat capacity...).
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I want to know what are the chemicals that help to activate geopolymer in order to quickly take and harden in a short time close to the hardening of cement
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Geopolymers can be synthesized at low temperatures (25–80 °C) using an alkaline solution and an alumino-silicate material. Materials including amorphous silica, alumina, and alkali hydroxide (NaOH/KOH) are commonly used in the synthesis. For the synthesis of the binder, a variety of aluminosilicate materials can be employed. Metakaolin, rice husk ash, fly ash, and volcanic slag are among them.
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In order to strengthen the cement matrix with combined graphene oxide and metakaolin, in order to their interactions as with cement, I want to inquire if anyone here has a suitable mixing method,
Thank you
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From the perspective of cement, graphene oxide is just expensive soot. Soot has been added to cement in studies like this one:
A serious study would therefore compare:
a) no addition of soot
b) generic, chemically non-specific soot
c) fancy and expensive soot (aka graphene oxide)
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  1. Concrete is the heart of civil engineers, as it plays a crucial role in binding materials properly. Nowadays construction costs are very high due to the scarcity or unavailability of natural resources. This problem can be resolved by the replacement of concrete with a different material that is not conventional in terms of required properties. From previous scientists' research, cement, sand, and metal are replaced by using different artificial materials.
  2. I wonder what other new materials can as binding to reduce cement or concrete?
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By the way, In Poland we hardly ever use pure Portland cement in ordinary concrete - we often use the cements with fly ashes or blastfurnace slag.
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Since Hydration Reaction is well established, now Carbonation of non- hydraulic cement is Hot Topic because of its low lime content and CO2 sequestration ability. while onsite construction is not suitable for carbonation a well-established pre-fabrication industry can utilize this technique. there is significantly less structured data available and standard practice is not available.
join me in this discussion panel and way ahead to sustainable future of construction industry
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An interesting topic!
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I am trying to understand the correlation between free ions content (Ca, K, P...) and degradation of cementitious surfaces. Is there a method or calculation to estimate its content?
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Maybe...you can calculating manually the Relative Atomic Mass
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For Cement Powders: I want to use XRD internal method (Spiking with a crystalline material) to calculate the amorphous content in my system. I have added 20% of Al2O3 (99.9% crystallinity) to the cement powder. I want to know, how can I calculate the amorphous content using High score Plus software?
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Thank you very much for the answer. I have already seen overestimated Al2O3 wt. % in the quantitative analysis. But, I was struggling to get the amorphous content from the overestimated values. I will follow your recommended procedure. Thanking you again.
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This is for the determination of fineness in cement, we are using the air permeability (Blaine) method. I was wondering whther we can ise the same manometer liquid for different test samples?
or we need to change the liquid every time we teat a new sample?
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Hi, the liquid does not have to be changed for each test (fortunately because that would be complicated). The european standart EN 196-6 states "The manometer liquid shall be changed (or cleaned) after servicing or before a new calibration".
Note that you should calibrate the apparatus with reference materials (cement of known specific surface area). The apparatus constant shall be recalibrated with the reference material when another type of manometer fluid and/or a new manometer tube have been introduced.
Best wishes.
Maxime
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Is there any guidebook for their heat treatment process?
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Yes it has an annealing affect.it reduces the residual compressive stresses of cemented carbides.It will reduce the fracture toughness and flexural strength.Annealing in contrast will usually counter the strengthening effects of added reinforcements.Please do some review of annealing effects on cermets.
Depending on the annealing temperature and isothermal dwell time results can vary.
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How can we know the flue gas composition from Coal-fired power plants, Refineries, Cement and Steel Industry?
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Buy a gas chromatograph for $250,000 and you'll know everything in no time
LOL....Mikhail
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Please share your knowledge and experience. How to write a review paper related to cement-based materials/concrete technology? What characteristics review paper should have? What should be the purpose of writing a review paper?
Thank you
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Often, a useful review paper can be produced efficiently if the following two conditions are met:
1) The paper does not already exist in the literature, and
2) you are starting a new research area and performing an extensive literature search so that you can get up to speed on the topic.
Defining of the scope of the review paper is still often a challenge, too broad and you won't be able to efficiently and effectively cover the topic(s) and too narrow and it will be of limited interest to the research community at large.
In addition to review papers, online bibliographies and annotated bibliographies for a research area can also be of interest and extreme value to others working in your field.
Happy review paper writing,
Dale
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Hybrid concrete consisting of fly ash (FA), ordinary portland cement (OPC), slag (GGBS) and sodium hydroxide (NaOH) shows deprived results for compressive strength. While alkali activated material cosisting of FA, GGBS and NaOH offers better compressive strength.
Why the partial (20-40%) replacement of aluminosilicate materials (FA and GGBS) with OPC reduces the strength concretes?
Previous researches based on FA, OPC and NaOH offers higher strength.
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Effect of Different NaOH Solution Concentrations on ... - MDPI
PDF
by Z Huang · 2021 · Cited by 1 — According to different ferronickel alloy production methods, ferronickel slag can be classified as electric furnace ferronickel slag (EEFS)
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Hello
what is the relationship between the surface area and the hydration degree of cement? Does the increase in the surface area cause the hydration degree of calcium silicate hydrate C-S-H gel to rise?
Thanks,
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  • The fineness of cement affects hydration rate, and in turn, the strength. Increasing fineness causes an increased rate of hydration, high strength, and high heat generation.
  • Bleeding can be reduced by increasing fineness. However, increased fineness can also lead to the requirement of more water for workability, resulting in a higher possibility of dry shrinkage.
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Hello,
I have data for a BET analysis (surface area) in order to gain information about the surface area and the pore size of my samples (cement, cement with additive). and when I got the results, I get nothing about this size pores, just the surface area (m2/g) of the two samples and the volume of applied pressure, is there a method to extract the pore size of my sample from the information I have acquired (The test is to apply nitrogen pressure to the sample)?
Thanks,
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Brunauer–Emmett–Teller (BET) analysis is only specific surface area determination, that is why you got surface units (m2) over the specimen mass.
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Currently, the acceptance rate of MDPI Materials is about 65%. Normally, this rate is 20-30% for other journals. Is MDPI Materials publishing so many papers for money and compromising on the quality of work?
Thank you
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In my opinion, based on the quality of articles I have accessed in my area, I can say MDPI materials are of good quality.
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What kind of hydraulic binders do you know besides cement?
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low carbon cements
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Hello,
I'm looking for some help about the understanding of adsorption kinetics of composite cement paste (cement+quartz) towards starch.
My experiment like this: the starch dosage is calculated according to the powder mass cement+quartz), and the water-powder ratio is 0.4. For a given starch dosage, that is, the same starch concentration (g/L). In different systems (OPC_pure cement, Qz15_85% cement+15% quartz, Qz30_70% cement+30% quartz) calculated in the adsorption amount (normalization to cement mass) is different (mg/g cement). But the adsorption amount (normalized to powder mass) is consistent.
So I don't know how to interpret them. Or my analysis is wrong.
  • PS: The literature result shows that quartz basically does not adsorb starch.
Yichuan
Best regards
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Yuri Mirgorod I get it. Thank you. Prof. Yuri Mirgorod
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I have SEM images of cement paste samples, references and others doped with graphene oxide. After 28 days of hydration, the ettringite still appeared in all samples, since it is known that after 12 days of hydration, it turns and disappears.
what are the reasons for this appearance at a later age?
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Lounis, yes it all depends on the type of the cement, amount of sulfur and other factors. Primary ettringite can stay in the paste without any harm, worst case scenario is when delayed ettringite formation is happening, then it is a trouble for concrete performance.
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Regarding cement paste, why does the crystal size (CH) come out to be different (a significant difference) if it is calculated by XRD using Scherrer's equation or calculated using SEM images?
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XRD determines crystallite size. SEM measures particle size. Each particle can consist of several crystallites, so usually particle is bigger (or much bigger) than crystallite. Your results are not surprising.
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I am searching for methods measuring the pore saturation level of cement paste...
any suggestion or related papers?
truly appreciate it.
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Mercury intrusion porosimetry (MIP) is a widely used technique for characterizing the distribution of pore sizes in cement-based materials.
Many work and literature related to this methods is available easily.
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Hi all,
I have some x-ray tomography images of cements and I am interested in modelling their permeability using Lattice Boltzmann Modelling.
Does anyone know of any code to simulate flow throughout such a medium?
Cheers,
Jack
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Jack,
If you are simply interested in permeability, Nicos Martys and I have developed a 3-D Stokes solver that works on a 3-D digital image. See:
Unfortunately, the ftp server that used to supply the codes has been taken offline, but if you provide me with your e-mail address (dalebentz49@gmail.com), I can send you a zip file with the codes, documentation, etc., if you are interested.
Best regards,
Dale
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I need to complete a life cycle assessment of mixing graphene and cement to create a composite. I have found the OpenLCA software and tried to use the free databases available.
The elcd database has portland cement available, however no other free database has any values of graphene. Would anyone know a free database that contains graphene values and process, or anyway I could get these values to create my own data?
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A good LCA study will always have a clearly defined scope, phases and indicators and your study related with graphene composites are no exceptions. I would like to recommend you the following paper as a prototype:
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Recently, I have an idea: an innovation in the manufacture of traditional concrete. My idea is to use tailings instead of part of cement and add fly ash, steel slag and other materials as aggregate to reduce the proportion of cement to 0.3. And the use of foaming technology, plus some additives to increase the porosity of concrete. The concrete made in this way is cured in the environment of high temperature and high concentration of CO2, the mechanical strength is improved by CO2 and alkaline metal carbonation, and the CO2 is fixed.
To this end, I did a simple experiment. Here are some data: I made 4*4*4cm3 concrete according to the picture below,:
put them in 100% CO2 boxes, and did a comparative experiment on air curing, but nothing else. After a certain period of time, the removal results are as follows. I want to know in what ways I should improve my experiment. I have looked up a lot of articles, and the only clue at present is to carry out steam pre-curing before maintenance to ensure its water content.
You are welcome to post the discussion. If you need any other information, please let me know in the comments.
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paper‘s link
二氧化碳养护混凝土技术研究 (wanfangdata.com.cn)
二氧化碳养护混凝土技术研究 - 中国知网 (cnki.net)
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Cement has been in human use throughout history, and due to its binding nature, it is regarded as the backbone of the construction industry. A recent edition of the journal Nano Energy published the results from major breakthrough research conducted by engineers from Incheon National University, Kyung Hee University, and Korea University. The researchers have invented a cement-based composite (CBC) that can be used in concrete to develop electrical properties without affecting its structural performance. But what if cement could be used to generate electricity?
Any ideas from researchers?
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I need to know how to modify an agg process, based in an u-so process in GaBi. For example, I modified some flows of the cement BR (u-so) in ecoinvent 3.6 creating a copy, but I need to modify this date in agg process for I can calculate the environmental impacts, how can I vincule the modifications from u-so process with the agg process?
Best Regards,
Lucas
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Dear, Calculating the environmental impact or circularity or carbon footprint is based on 1001 assumptions. What is the accurancy of these numbers??? fe impact is related to the energy source (nuclear power, renewables, ...)
It is impossible to express the complexity in one number. Environmental impact is also always a compromise with other needs of the product. The way we prefer is the evalation with the lifecycle based ecodesign rules of thumb gathered in checklists.
Good luck
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Equipment needed for analyzing cementitious materials
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You can get XRD equipment in AUST, Abuja and FEDERAL UNIVERSITY Lafiya.
Meanwhile, I do XRD data analysis including Rietveld refinement for inorganic materials generally. Contact: umaruahmadu@futminna.edu.ng
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We have many standards and method for determination of water absorption of the cement paste, mortar and concrete. Is there the standard for determination of water absorption the powder such as fly ash?
What is the difference between the amount of moisture content (%) and water absorption (%) of powders such as fly ash or pozzolan materials?
In ASTM C618 &Table 1: Moisture content, max for fly ash class N, F and C is 3%.
Though, we can use ASTM C311-13, procedure No.11 and No.12 for calculation of Moisture content.
Is there any the standard for determination of water absorption of the powder such as fly ash or pozzolan materials?
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How can type 1 cement be anti sulfated using natural minerals? How much is it used ?
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Thanks a lot.
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The subject of my research is jet grout spoil and I want to do various tests on it.
Thank you for answering my questions.
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1- The water to cement ratio is calculated by dividing the water in one cubic yard of the mix (in pounds) by the cement in the mix (in pounds). So if one cubic yard of the mix has 235 pounds of water and 470 pounds of cement– the mix is a. 50 water to cement ratio.The lower the water to cement ratio, the less air pores and the more compact the concrete structure, which translates into higher strength. The high amount of water will reduces the compressive strength of concrete because it will increases the gap between cement and aggregates thus air voids will increases.
2- The water obsorption is affected by the following factors Porosity of concrete, Relative Humidity, Surface area of element, Exposure period of wetting and drying.
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Cement strength dropped at summer period, this problem repeated annually. Any one face this problem before and what is his recommendation?
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The strength of cement dropped in the summer for the concrete and this issue demande to be carefully, because during the hot weather the water evaporates and make porous concrete and this result the decrease of the strength.
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There are a number of scholars studied the blending of agro-waste ashes with cement and mentioned some of reasons to blend them
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Is it possible to convert the Heat power obtained from the calorimeter for a given cement paste into an adiabatic temperature rise curve?
Can anyone guide me in this regard?
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You would really need the isothermal calorimetry data at several temperatures to compute an activation energy. Then you can apply the basic principles of chemical engineering to numerically integrate over time the heat generation due to the reactions. You will need to specify the boundary conditions and geometry of your specimens. This can be done fairly straightforward in COMSOL or other 3-D computational packages. See the publications by Emilio Hernandez-Bautista that are available from his ResearchGate page and were part of his Ph.D. thesis
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I am aware that EN Standards have defined the following types of cement:
CEM I 42.5 N
CEM I 42.5 R
CEM I 52.5 N
CEM I 52.5 R
where N refers to Ordinary Early Strength and R refers to High Early Strength. In addition 42.5 and 52.5 refers to minimum 28-Day Strength.
But my question is how do we produce CEM I 42.5 R and CEM I 52.5 N?
Because in literature it is reported that increasing fineness increase early strength but how do we increase 28-Day strength then?
Kind Regards,
Muhammad Imran
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The class of cement is its compressive strength of 32.5 MPa; 42.5 MPa and 52.5 MPa. The cement class concerns its strength.
The type of cement is classified according to the components it is made of.
N and R are Early Strength Gain: Normal or High Gain. The process of strength growth as a function of time is different in the N and R cemeners.
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Hello all,
We are researchers conducting a market research study on sustainable cement/concrete. This information will serve as input into research on the development of cement/concrete. Your responses are voluntary and will be held in strict confidence. All responses will be compiled and analyzed at an aggregate level. Neither you nor your responses will be identified. If you have any questions, please contact lassi@email.sc.edu. Thank you for your willingness to participate in this survey! Your candid responses are greatly appreciated. This survey should take less than 5 minutes to complete. https://lnkd.in/dUizjzc
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Thank you so much!
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Hello all, We are researchers conducting a market research study on sustainable cement/concrete. This information will serve as input into research on the development of cement/concrete. Your responses are voluntary and will be held in strict confidence. All responses will be compiled and analyzed at an aggregate level. Neither you nor your responses will be identified. If you have any questions, please contact lassi@email.sc.edu. Thank you for your willingness to participate in this survey! Your candid responses are greatly appreciated. This survey should take less than 5 minutes to complete. https://lnkd.in/dUizjzc
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yes
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I am looking to use the pozzolanic properties of slag, but it is impossible due to its crystalline structure. Therefore, the slag structure must be transformed to amorphous. What is your solution for converting slag crystal structure to amorphous?
Thanks for your contribution.
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Hello, I think you can use blast furnace slag because it has a significant amorphous silica content due to cooling and quenching by water, while the amorphous silica content in steel slag is low and often crystalline. Moreover, blast furnace slags are hydraulic materials and you can determine their hydraulic activity of them according to standards.
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Dear All, I would like to know the basic testing of cement plaster for cracking and adhesion . Thank you
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there are many steps to ensure the quality for the plaster morter
  1. make a sieve analysis for the sand used in the morter to ensure that the fine particles not more than needed.
  2. ensure that the cement was stored in right way , and not expired.
  3. make a compression test for the cement cube
  4. ensure that the mix design is designed well and adjusted in site well
  5. use the suitable mix design for the item
  6. add a bonding agent to increase the tension behavior for the morter
  7. don't forget the curing by water
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If possible, then what parameters could I investigate from the test?
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Dear Tadele Yigrem Yes you can conduct a flexural strength test for plain concrete having pozzolanic materials as a partial replacement of cement. I think in this case, you should concern about the percentage of replacement. For different types of pozzolanic materials, the percentage of cement replacement is different. You can get the proper idea if go through some review papers. Here I attach you some experimental paper for your better understanding.
6-with-cover-page-v2.pdf (d1wqtxts1xzle7.cloudfront.net)
Performance of High Volume Fly Ash Concrete (ijirst.org)
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what kind of tests should perform on self consolidated cement paste incorporating suplementary cementious materials such as fly ash, rice husk, etc. i am using differnt kind of materials for the measuring the durablity of the self consolidated cement paste after using other differnt materials. so what kind of test should i perform on such material
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Additionally, an important element is to check the compatibility of the chemical admixture with cement and the filler additive