Publications related to Ammonia (10,000)
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Testing detailed combustion mechanisms typically concludes that some mechanisms reproduce the experimental data well at most conditions but are inaccurate at other conditions. However, other mechanisms may perform well under these conditions. A better mechanism ("mosaic mechanism") may be obtained by identifying the overall best-performing mechanis...
This study presents the fabrication and characterization of a fiber optic gas sensor based on Lossy Mode Resonances (LMR). For the first time to our knowledge, a nanosized coating of polyphenylene oxide (PPO) is deposited on a cladding removed multimode silica fiber, serving both as the LMR supporting coating and sensitive overlay. The device exhib...
Dear Colleagues,
Meat and dairy production consumption should increase over the next decades despite the well-known impact of livestock production on ammonia (NH3) and greenhouse gas (GHG) emissions, and consequently on climate change. It is therefore of high relevance to define some accurate and specific strategies of NH3 and GHG abatement in each...
The aim of this study was to simulate the water flow and reactive transport of pollutants in a horizontal flow (HF) wetland to better understand the recovery time of the treatment performance for peak load events. For the simulation, the processes-based model HYDRUS and its Wetland Module is used. The system under investigation is the first stage o...
Modelling transient mass release rates from transmission pipelines is an important part of hazard assessments for safety, environmental protection, and regulatory compliance. An understanding of transient flow dynamics can help regulators, operators and emergency responders better assess potential hazards, optimise mitigation measures and minimize...
A facile wet impregnation method was employed to prepare a bimetallic Ni-Cu catalyst on a mesoporous KIT-5 support, keeping the nickel loading constant (5 wt%) while varying the copper wt.% (xCu, where x = 8, 10, 12, 14). Several physico-chemical techniques, including X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) analysis, scanning electron...
Embracing CO2 mitigation strategies, such as state-of-the-art CO2 capture technologies, is essential for effectively reducing atmospheric carbon levels and advancing global efforts toward a more sustainable future. In this context, adsorption sequestering techniques utilising carbon materials have emerged as promising candidates for CO2 capture. Th...
The combustion of fossil fuels releases substantial amounts of nitric oxide (NO), posing serious environmental and health risks. Addressing NO pollution effectively is, therefore, a pressing need. Conversion of NO into valuable chemicals is an appealing strategy with dual benefits, including waste utilization and sustainable energy transformation....
Electrocatalytic nitrate reduction to ammonia (NO3RR) in a neutral medium is a green and effective strategy for treating nitrate pollution meanwhile producing ammonia. However, the insufficient active hydrogen (H*) on the catalyst surface resulting from the sluggish Volmer step (H2O → H⁺ + OH⁻), and the competitive hydrogen evolution reaction (HER)...
Kidney diseases are a group of conditions related to the functioning of kidneys, which are in turn unable to properly filter waste and excessive fluids from the blood, resulting in the presence of dangerous levels of electrolytes, fluids, and waste substances in the human body, possibly leading to significant health effects. At the same time, the t...
New nitrogen‐doped carbon quantum dots (NCQDs) made from Dioscorea alata (DA) extract as the carbon and nitrogen source using the hydrothermal method provide a straightforward approach for extremely sensitive and selective quantification of Cu (II) ions. In this method, aqueous extract of DA served as the carbon source and aqueous ammonia was used...
This study explores the electrochemical properties of the carbonaceous Allende CV3 meteorite, focusing on its potential as a Fe‐based catalyst derived from Mackinawite iron sulfide for electrocatalytic reactions facilitating nitrogen (N2) fixation into ammonia. Through comprehensive analysis, we not only monitored the evolution of key compounds suc...
The Hunjiang River, a vital water system in northeastern China, has suffered severe ecological damage due to overexploitation. This study analyzes the basin’s environmental conditions from 2016 to 2020, identifies key restoration factors, and examines practical restoration projects. Investigating five major pollutants (permanganate index, chemical...
As a carrier of hydrogen, ammonia has great potential in reducing pollution and carbon. This paper investigates the impact of diesel compression ignition on the combustion and emission performance of a natural gas/ammonia mixture RCCI engine through numerical simulation. The energy fraction of ammonia is set from 0% to 100% in the study to evaluate...
High NH 3 uptake is observed in a series of paddlewheel [Cu 2 (O 2 CR) 4 ] metal–organic frameworks.
This study presents the results of laboratory research of kinetics and mechanisms of heterogeneous catalytic reactions of hydrogenation of carbon dioxide to carbon monoxide and methane through the Sabatier reaction on modifications of the serial Ni/α-Al2O3 catalyst GIAP-3-6N manufactured in Ukraine. The research was carried out on a laboratory benc...
Acharya Charaka has mentioned fifteen koshtanga in the shareera. Koshtanga refers to the viscera. Two koshtanga, Yakrit and Pliha, have been designated as the moola sthana (primary centres of physiological activity) of the Raktavaha srotas (haemopoiesis). The description of Yakrit & Pliha corresponds to the functions of the liver and spleen in cont...
Flexible gas sensors are gaining interest for real‐time volatile gas monitoring. A natural rubber (NR)/MXene nanocomposite sensor is developed. Among the six selected target volatile gases, the composite sensor exhibited a strong response value (82% toward 100 ppm NH3) with the fastest response/recovery time (12.3 s/15.5 s) to NH3. The sensitivity...
The sub‐nanometer is a key feature size in materials science. Unlike single‐atom and nanomaterials, size effects and inter‐component cooperative actions in sub‐nanomaterials will effective on its performance is more significant. Here, 0.95 nm ordered arrangement Cu9S5 sub‐nanowires (Cu9S5 SNWs) are synthesized through the co‐assembly effect of inor...
The Kalina cycle is well-known for its innovative energy conversion optimization, utilizing various working fluids such as butane, freon, isobutane, and pentane to evaluate efficiency and performance. This research explores the interaction of fluids in the Kalina cycle to enhance heat recovery by utilizing heat from road infrastructure. Our researc...
A theoretical line list for $^{15}$NH$_3$ CoYuTe-15 is presented based on the empirical potential energy and ab initio dipole moments surfaces developed and used for the production of the ExoMol line list CoYuTe for $^{14}$NH$_3$. The ro-vibrational energy levels and wavefunctions are computed using the variational program TROVE. The line list rang...
The incidence of neurological diseases in dogs and cats is high, leading to several complications that impair the quality of life of animals. Epilepsy, which is characterized by frequent seizures, herniated discs, which can result in spinal cord compression, and hepatic encephalopathy, commonly linked to severe liver problems, are the most common c...
In recent years, nitrate has emerged as a significant groundwater pollutant due to its potential ecotoxicity. In particular, nitrate contamination of brackish groundwater poses a serious threat to both ecosystems and human health and remains difficult to treat. A promising, sustainable, and environmentally friendly solution when biological treatmen...
To achieve the in situ capacity expansion of the post-denitrification biological aerated filter (BAF-DN), the integration of BAF with the anammox process (BAF/AX) was proposed. With the objective of maximizing retaining ammonia nitrogen, the operational optimization of BAF was achieved by two distinct strategies. The treatment performance of BAF de...
In the urban environment dust particles form a major part of air pollutants and can affect the physiological functions of the plant. Plants proved to be very powerful tools in as-sessing environmental pollution because of their wide distribution. Festuca ovina is a durable plant with specific habitat requirements, but there is no data on physiologi...
The growing interest in low‐temperature direct ammonia fuel cells (DAFCs) arises from the utilization of a carbon‐neutral ammonia source; however, DAFCs encounter significant electrode overpotentials due to the substantial energy barrier of the *NH2 to *NH dehydrogenation, compounded by the facile deactivation by *N on the Pt surface. In this work,...
In this work, partial reductive amination of 5‐hydroxymethylfurfural (HMF) with gaseous ammonia over iridium supported on γ‐Al2O3, TiO2, SiO2 and carbon has been studied. The influence of the support and pressure was investigated in the valorization under mild conditions of HMF to 5‐(aminomethyl)‐2‐furanmethanol (AMFM). The catalysts were character...
The electroreduction of nitrate offers a promising, sustainable, and decentralized route to generate valuable ammonia. However, a key challenge in the nitrate reduction reaction is the energy efficiency of the reaction, which requires both a high ammonia yield rate and a high Faradaic efficiency of ammonia at a low working potential (≥−0.2 V versus...
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The Green Revolution rapidly increased India’s food production since the 1960s, but excessive synthetic fertilizer use caused severe environmental problems. Our spatially explicit analysis for 1970–2020 indicates an uneven distribution of the dramatic increase of surpluses of India’s soil N (4.3 to 21.6 Tg N/year) and P budget (0.4 to 3.3 Tg P/year...
The Water Quality Index (WQI) provides comprehensive assessments in river systems; however, its calculation involves numerous water quality parameters, costly in sample collection and laboratory analysis. The study aimed to determine key water parameters and the most reliable models, considering seasonal variations in the water environment, to maxi...
The application of intelligent process-based crop model parameter optimization algorithms can effectively improve both the model simulation accuracy and applicability. Based on measured values of soil N2O emission flux in wheat fields from 2020 to 2022, and meteorological data from 1971 to 2022, five parameters of the N2O emission flux module in th...
Nitrogen oxides (NOx) play important roles in the nitrogen cycle system and serve as renewable nitrogen sources for the synthesis of value-added chemicals driven by clean electricity. However, it is challenging to achieve selective conversion of NOx to multi-nitrogen products (e.g., N2H4) via precise construction of a single N-N bond. Herein, we pr...
This work reports the synthesized V2O5 nanoparticles (Nps) using a simple combustion method with Cleome gynandra seed extract as fuel. Several analytical tools were used to characterize the synthesized Nps, including X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), transition electron microscopy (TEM), UV–...
Interest is growing in transition metal‐free compounds for small molecule activation and catalysis. We discuss the opportunities arising from synthesizing sodium‐doped amorphous silicon‐boron‐nitride (Na‐doped a‐SiBN). Na⁺ cations and 3‐fold coordinated BIII moieties were incorporated into an amorphous silicon nitride network via chemical modificat...
To further understand the influence of n-heptane on the ignition process of ammonia, an isotope labeling method was applied in the current investigation to decouple the influence of the chemical effect, the thermal effect, and the effect of O radical from the oxidation of n-heptane on the ignition delay times (IDTs) of ammonia. An analysis of the t...
Ammonia is a key component of fertilizer and a potential clean fuel and hydrogen carrier. The Haber-Bosch process for ammonia synthesis consumes more than half of industrial hydrogen and contributes up to ~3% of global greenhouse gas emissions. Light-driven reactions via surface plasmon resonances offer a less energy-intensive pathway for ammonia p...
Electrocatalytic nitrate (NO3⁻)/nitrite (NO2⁻) reduction of ammonia (NH3) provides energy‐saving and sustainable methods for NH3 synthesis. However, both reactions involve multiple electrons and multiple protons, making the reaction process complex with many by‐products. Thus, efficient catalysts are needed to improve the selectivity and yield of a...
Jupiter's Great Red Spot (GRS) was mapped by the James Webb Space Telescope (JWST)/Mid-Infrared Instrument (4.9-27.9 micron) in July and August 2022. These observations took place alongside a suite of visual and infrared observations from; Hubble, JWST/NIRCam, Very Large Telescope/VISIR and amateur observers which provided both spatial and temporal...
Nitrate electroreduction reaction (NO 3 RR) to ammonia (NH 3) still faces fundamental and technological challenges. While Cu-based catalysts have been widely explored, their activity and stability relationship are still not fully understood. Here, we systematically monitored the dynamic alterations in the chemical and morphological characteristics...
Ammonia is a globally transported chemical used for a variety of applications, most notably, the production of fertiliser. Over the past decade, attention has been afforded to the use of ammonia as an energy carrier, coupling global supply of renewable energy to demand regions. Ammonia’s advantages as an energy carrier include its ease of liquefact...
Foraminifera are a group of marine microorganisms that are highly important in paleontology and geology, as their fossil remains can be used to date and interpret geological formations. This study aims to provide a paleoenvironmental interpretation of the Albufera de Valencia through the study of benthic foraminiferal assemblages. For this purpose,...
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Green ammonia is assumed to be an important part of the European hydrogen economy and one of the most important substrates of chemical industry. The future development of its manufacturing processes can be related to the electrocatalytic studies yielding in the development of the catalytic materials that would effectively break the nitrogen-nitroge...
The present experiment was performed to reveal the mechanisms of toxic effects of ammonia nitrogen on Chinese hook snout carp (Opsariichthys bidens) based on the levels of antioxidant enzyme activities and the expression of 70-kDa heat shock protein gene (HSP70) and tumor necrosis factor-α (TNF-α) after 96 h of acute toxic ammonia exposure to inves...
In alkaline calcareous soils, ammonia volatilization is the primary nitrogen (N) loss process, resulting in the reduced N use efciency of crops. Tis study aimed at assessing the impact of diferent N sources for top dressing on ammonia volatilization, as well as their efects on wheat growth and yield over two years. In each year, half of the recomme...
A surfactant-free ammonia and carbamide precursor-modulated engineering of self-assembled flower-like 3D NiO nanostructures based on ordered β-Ni(OH)2 and turbostratic Ni3(OH)4(NO3)2 nanoplate-structured intermediates is reported. Employing complementary structural and spectroscopic techniques,...
Observations and model studies suggest that front dynamics can enhance phytoplankton productivity. This study tested whether frontal systems also increase the abundance of nitrifying microbes and nitrogen recycling during repeat sampling transects across the Mid‐Atlantic Bight shelfbreak in July 2019. We measured ammonium concentrations, nitrate du...
Electrochemical nitrate reduction to ammonia (NRA) is a promising approach for alleviating energy crisis and water pollution. Current NRA catalysts are challenged to simultaneously improve the rate of the adsorption and desorption processes to further increase the total activity due to the Brønsted−Evans−Polanyi (BEP) relationships. Herein, a two‐s...
Although the behavior of the supercritical transition during the evaporation of liquid fuels in engine combustion chambers has been studied by many researchers, the effects of convection on the phase transition of liquid fuel in supercritical environments have been little studied. Previous studies mainly focused on hydrocarbon fuels for supercritic...
Ammonia holds promise as an alternative renewable fuel with significant potential for addressing climate change concerns. Blending ammonia with methane has emerged as a viable strategy to improve the laminar burning velocity of ammonia. In this study, we propose a mechanism for methane/ammonia combustion, comprising 31 species and 131 chemical reac...
Ammonia gas is a colorless gas that is known for its pungent odor. It is commonly used in various industries, such as agriculture, refrigeration, and chemical manufacturing. This paper provides a comprehensive overview of various technologies employed in ammonia gas sensors. The objective is to compare and identify the optimum method to detect ammo...
When platinum-containing diesel oxidation catalysts (DOC) are exposed to high temperatures under lean conditions, the platinum nanoparticles form volatile platinum dioxide on the catalyst surface. The exhaust flow carries the volatile platinum dioxide to the downstream aftertreatment catalyst, such as the selective catalytic reduction (SCR) catalys...
Knowledge of the initial conditions of high-mass star formation is critical for theoretical models, but are not well observed. Built on our previous characterization of a Galaxy-wide sample of 463 candidate high-mass starless clumps (HMSCs), here we investigate the dynamical state of a representative subsample of 44 HMSCs (radii 0.13–1.12 pc) using...
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Nitrogen oxides (NOxs) are some of the most important hazardous air pollutants from industry. In China, the annual NOx emission in the waste gas of industrial sources is about 8.957 million tons, while power plants remain the largest anthropogenic source of NOx emissions, and the precise control of NOx in power plants is crucial. However, due to in...
The present study was aimed to investigate the effects of silo type for laboratory scale on chemical compositions, fermentation characteristics, and microbial counts of silage. Four typical silos use on a laboratory scale, consisting of transparent plastic bags (Silo A), black plastic bags (Silo B), transparent plastic bags covered with a bucket (S...
With the increasing awareness of the hazards associated with ammonia (NH3) contamination and the potential application of NH3 detection in physical health monitoring, the exploration of high‐performance NH3 sensors has attracted significant attention in recent years. In this paper, we prepared copper iodide (CuI) nanomaterials combined with CuI‐iso...
This research aims to create a better cage quality monitoring system in poultry farms, the parameters observed in particular are ammonia gas, where this gas greatly affects the health and productivity of laying hens, the data taken is processed in percentage terms and a comparison of several conditions in the location where the equipment is placed....
Various life forms suffer from the negative effects of nitrate when it accumulates in water bodies, which is a major concern in the present day. The removal of nitrate from water bodies is a critical challenge, and the most effective method to achieve that is to change it into ammonia. Ammonia is a clean energy source and a vital input for the fert...
This paper describes a highly alkaline low-grade copper oxide ore. Copper can be selectively leached out while other metals are retained. A thermodynamic model of the CuO-(NH4)2SO4-NH3-H2O system was established for the leaching of tenorite (CuO) under conditions of mass and charge conservation. MATLAB’s fitting functions, along with the diff and s...
Electrosynthesis, a viable path to decarbonize the chemical industry, has been harnessed to generate valuable chemicals under ambient conditions. Here, we present a membrane-free flow electrolyzer for paired electrocatalytic upcycling of nitrate (NO3⁻) and chloride (Cl⁻) to ammonia (NH3) and chlorine (Cl2) gases by utilizing waste streams as substi...
The emission of odour gases from livestock farms is a significant contributor to global air pollution and the resulting unpleasant odors experienced by communities. However, there is a lack of research on the factors influencing odor emissions and the relationships between different odor properties specifically related to poultry operations. Theref...