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We have carried out chemical analyses on springs and underground waters collected from 31 localities on and around the Volcano Asama. Their characteristic chemical features are as follows: (A) generally rich in ΣCO2; (B) mostly poor in Cl-; (C) generally poor in SO4-- with an exception of those from Zigokudani; (D) comparatively rich in H2SiO3; (E) a little rich in Ca++: (F) show a remarkable difference between RoH and pH; and (G) give the ratios K(K+Na)=5~15% and Ca(Ca+Mg)=60~70%. They are classified according to their chemical contents into three groups: type (1) containing SO4--, ΣCO2, Al+++ and Fe++; type (2) ΣCO2 and Fe++ and type (3) chiefly ΣCO2.