March 2025
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2 Reads
Langmuir
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March 2025
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2 Reads
Langmuir
March 2025
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3 Reads
ACS Applied Materials & Interfaces
March 2025
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25 Reads
Natural communication methods have influenced the creation of sophisticated artificial materials capable of coherent and abundant responses to stimuli, a crucial necessity for developing applications such as dynamic encryption systems and high‐density information storage. However, existing materials for encryption and information storage are limited by predictable, single‐stimulus responses and lack the capacity for dynamic, continuous, and programmable changes. To address this gap, a bioinspired multicolor fluorescent polyurethane actuator is developed that combines dynamic color and shape adaptability within a single material platform. This smart actuator mimics the turgor‐driven movements of Oxalis corniculata through a hydrophilic/hydrophobic network that enables water diffusion, hydrogen bonding, and dynamic bond exchange. It responds to multiple stimuli, including temperature, pH, and excitation wavelength, exhibiting reversible multi‐state deformations and programmable fluorescence across red, green, blue, and even white light. The deformation behavior is supported by finite element simulations, ensuring precise control and predictability. Additionally, the tunable trichromatic fluorescence of the actuator underpins a 3D and 4D information encoding system, demonstrating increased information storage capacity and encryption security. The employment of micro‐processing technology in the fabrication of micro‐hidden optical encryption chips has been demonstrated, thus paving the way for underwater communication encryption technologies and adaptive materials.
March 2025
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2 Reads
Dalton Transactions
A novel carboxyl functionalized Co-MOF (–COOH) which can be used to prepare Co-MOF- g -CTS by a one-pot method with CTS was designed. (Co-MOF- g -CTS)-900 derived from Co-MOF- g -CTS exhibited the best 4-NP catalytic reduction activity.
March 2025
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1 Read
Journal of Molecular Structure
March 2025
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1 Read
Journal of Alloys and Compounds
March 2025
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8 Reads
International Journal of Hydrogen Energy
March 2025
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1 Read
Journal of Catalysis
March 2025
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3 Reads
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1 Citation
Polyoxometalates
February 2025
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7 Reads
Constructing a metal‐free adsorbent for one‐step separation of C2H4 from mixture gas of C2, is of great significance and challenging. Here, a porous aromatic cage (PAC‐1) based on aldehyde‐amine condensation is reported with diamond‐like interconnected aromatic cavity‐channel pores for one‐step purification of ethylene. PAC‐1 exhibits superior C2H2 (52.6 cm³ g⁻¹) and C2H6 (46.7 cm³ g⁻¹) uptakes as well as impressive C2H2/C2H4 selectivity (1.5) and C2H6/C2H4 selectivity (1.4), remaining at the forefront of the advanced C2H4‐selective adsorbents of porous non‐metallic materials. The C2H4 adsorption enthalpy (Qst) of PAC‐1 is of 23.6 kJ mol⁻¹, which requires less energy to regenerate than conventional MOF materials. Breakthrough experiments demonstrate that PAC‐1 can reduce the penetration rate of C2H6 or C2H2 through the adsorbent, and present quite valuable one‐step separation of C2H4 from C2H2/C2H6/C2H4 mixture gas. Molecular simulations and DFT studies have shown that oxygen sites and C─H sites in the channels are more favorable for C2H2 anchor with interaction energy over C2H4 by 1.48 kcal mol⁻¹, and the C─H…π interaction point in cage cavity is preferred to C2H6 with the interaction energy over C2H4 by 1.16 kcal mol⁻¹, which in turn results in the separation of C2H4 from C2H2 and C2H6.
... Currently, energy production and environmental pollution pose severe challenges that constrain the sustainable development of human society. The overexploitation and widespread use of fossil fuels lead to resource depletion and environmental degradation, including greenhouse gas emissions and atmospheric pollution [1]. Consequently, there is an urgent need to develop clean and efficient energy conversion technologies [2]. ...
November 2024
... Luminescent coordination polymers and metal-organic frameworks constitute a perspective class of sensors for inorganic cations and anions [19][20][21][22][23][24], small organic molecules [25][26][27][28][29][30][31][32][33] and biomarkers [34][35][36][37][38][39][40][41][42]. However, no MOF-based luminescent probes for SO 4 2− anions were reported so far. ...
September 2024
Talanta
... To further elucidate the exceptional catalytic performance of the prepared catalysts, electrochemical double-layer capacitance (Cdl) measurements were utilized to assess the electrochemically active surface area (ECSA) of several electrocatalysts (Figures 3h and S24). [49] The calculated Cdl values for SUZ-101-H, SUZ-101-Co, SUZ-101-Ni, and CB were 3.84 mF cm −2 , 14.46 mF cm −2 , 7.78 mF cm −2 , and 2.33 mF cm −2 , respectively. This data indicates that SUZ-101-Co exposes a greater number of active sites during the ORR and OER, showcasing superior catalytic activity compared to the other synthesized electrocatalysts. ...
September 2024
Chemical Engineering Journal
... Furthermore, C 60 -encapsulated PAC-2 can be utilized as an electrochemical chiral sensor on glassy carbon electrodes (GCE) for the detection of the chiral compound L-3,4-dihydroxyphenylalanine (DOPA), achieving a detection limit of 2.8 mM. 88 Recently, Khashab et al. reported three cases of POCs with varying hydroxyl substitutions; notably, OC1, a [2 + 3] cage, synthesized from 1,3,5-triformylphloroglucinol and (1R, 2R)-1,2-diaminocyclohexane, featuring a higher number of hydroxyl groups exhibited keto-enol tautomerism and demonstrated increased stability, biocompatibility, photostability, and cell permeability. Consequently, the organic cage (OC1) shows promise as an effective mitochondrial fluorescent probe. ...
June 2024
Chemical Communications
... Indonesian Aquaculture Journal, 19 (2), 2024, 147-156 Table 2 shows that interference materials (salt, lipid/waxes) obtained in the methanol extract of MECp were about 30%. Tian et al. (2024) supported this, who reported the presence of large quantities of inorganic salts in marine invertebrate extracts from sponges and tunicates. ...
May 2024
Separation and Purification Technology
... However, most previously reported MPs exhibit an electrochemical conversion reaction mechanism near the Na/Na + reduction potential, with one exception to the topotactic insertion/extraction reaction mechanism observed in the V 4 P 7 phase [70]. In addition, the electrochemically active composition of MnP, VP 2 , and FeP 2 , etc., in LIBs indicates less activity in SIB applications [71]. In the case of P-rich MPs, their electrochemical performances exhibit highly promising anode materials for SIBs due to their exceptionally high specific capacity and low operating potentials (ranging from 0.3 to 0.7 V vs. Na/Na + ), such as in the case of NiP 3 , MnP 4 , and CrP 4 [72][73][74]. ...
May 2024
Journal of Alloys and Compounds
... By comparing the excitation spectra of Zn-BDPT with the UV-vis absorption spectrum of 3-NT (Figure 9a), it can be observed that the spectra had a large overlap, indicating that the internal filtration effect was the considerable factor leading to the quenching of luminescence [44]. However, there is a partial overlap between the emission spectra and the UV-vis spectra of 3-NT (Figure 9b), demonstrating that Förster resonance energy transfer (FRET) is another reason for the luminescence quenching effect [45]. ...
March 2024
Crystal Growth & Design
... The predetermined, recognizable, and practical nature of the technique has led to its wide application in many fields (e.g., chromatographic separation [30], bionic sensing [31], clinical drug analysis [32], etc.). Methods exist to combine MIT with SERS for selective SERS detection [33]. Among them, the molecularly imprinted polymers prepared by precipitation polymerization were characterized by good dispersion and high yield [34,35]. Preparation of a layer of molecularly imprinted polymer on the surface of the SERS membrane can significantly enhance the selectivity and sensitivity of the assay. ...
April 2024
Analytical Chemistry
... Extensive exploration has been conducted in the application of electrocatalysis, photocatalysis, gas storage/separation, and host-guest recognition due to its tunable porous structures and interesting surface chemistry advantages [13][14][15][16][17][18][19]. The specific response of MOFs toward different targets, such as metal ions [20][21][22], anions [23][24][25][26], amino acids [27,28], toxic organic pollutant molecules [29], pesticides [30,31], antibiotics [32][33][34], and bio-molecules [35][36][37][38], may be related to interactions including π-π interaction, hydrogen bonding, or coordination bonding. At present, many luminescent MOFs have excellent properties and can detect special substances through emission changes. ...
April 2024
Dyes and Pigments
... The positive shift of Cu(111) peak, which has been correlated to compression of the corresponding lattice, suggests that the Cu(111) lattice is compressed during synthesis. [18,29] The trend breaks off as the Cu(111) peak for L 90 ─Cu backtracks slightly, indicating strain relaxation. [30] From the UV-Vis absorption spectra of the pre-irradiation Cu sol-gel and L 60 ─Cu, a decrease in absorbance intensity of the band at ≈234 nm after irradiation indicates the decomposition of the Cu chelate ring (Figure 1d). ...
March 2024