Zhong Lin Wang’s research while affiliated with Beijing Jiaotong University and other places

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Publications (587)


a) Schematic diagram of the process of preparing the porous PTFE layer by plasma treatment and scraping coating. b) The concept and interface diagram of the flexible porous PTFE/LMs layer array, the structural diagram of LMs‐TENG and the equivalent circuit. c) SEM image and EDS energy spectrum of the LMs/porous PTFE cross‐section. d) The Voc of the device with/without a series GDT switch. e) The Isc of non‐polar/polar output mode. f) The load power curve of the generator. g) The recently reported voltage records based on liquid metal flexible generators.
a) The DC output circuit diagram. b) The corresponding resistance curve under different pressure conditions. c) Mechanism diagram of the electric field at the interface of the layered LMs embedded in the porous PTFE. d) Current in different output modes. e) The solid‐liquid double electric layer model of the multiphase interfaces. f) Charge transfer curves under the contact‐separation mode and ultrasonic mode. g) The output current of injecting positive charges into the LMs layer. h) The output current of injecting negative charges into the negative electrode.
a) Porous PTFE layer and LMs embedded layer with solid‐liquid‐gas multiphase interface structure. b) Dynamic test of LMs droplets and c) the wetting mechanism at the solid‐liquid interface. d) The amplified Voc, Isc signals and e) continuous Voc, f) Qsc signals when LMs droplets contact and separate from the porous PTFE surface. g–i) SEM images and j–l) pore size distribution obtained from mercury intrusion tests for the porous PTFE membranes with different parameters. m) The output current of devices constructed with different porous PTFE membranes. n) The output current of devices with different PTFE encapsulation layers. o) The current and amplified signal of the device in a hybrid output of ultrasonic excitation and p) contact‐separation mode. q) The electrical output performance of the device in series with the discharge switch.
a) A schematic diagram of the device for controlling the solid‐liquid phase transition of LMs. b) The impact of temperature on Qsc. c) The effect of temperature on output current Isc. d) Thermal imaging pictures of the LMs droplets/PTFE layer during continuous temperature variations. e) Continuous thermal imaging distribution of the device when heated from room temperature to high temperature. f) Thermal imaging distribution of writing with direct finger touch. g) Current output at different temperatures. h) Charge curves under ultrasonic excitation at 0 °C and 25 °C. i) Charge curves for contact‐separation mode at 0 °C and 25 °C. j) Charge curves for contact‐separation mode at different temperatures.
a) Equivalent circuit diagram of the room‐temperature LMs generator. b) Power curve in ultrasonic mode. c) The output current and d) amplified signal when the 1 GΩ resistance load is coupled with the contact‐separation mode and ultrasonic mode. e) Transfer of charge by ultrasound and contact‐separation mode. f) Physical photos of ultrasonic generators and transducers. g) Photos before/after triggering the device by hand. h) Thermal imaging images when the device is wearable on the human body. i) Thermal imaging images of writing consecutive numbers with a finger. j–m) Thermal imaging distributions of the device triggered by different parts of the hand and n–q) Corresponding electrical signals.
Flexible Triboelectric Nanogenerator Arrays for Energy Harvesting and Direct Current Output via Solid‐Liquid‐Gas Interfaces Involving Liquid Metals
  • Article
  • Publisher preview available

June 2025

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3 Reads

Jiangtao Guo

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Liangfei Duan

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Wen Yang

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Peizhi Yang

Triboelectric nanogenerators (TENGs) efficiently convert mechanical energy into electricity, offering unique advantages for powering wearable electronics. Key objectives for wearable TENGs include flexibility, and high power density output. Liquid metals (LMs) are emerging as a category of functional materials with both metallic and liquid properties at room temperature, which opens up broader opportunities for TENG applications. Herein, a concept is proposed for constructing a fully flexible triboelectric nanogenerator array for mechanical energy harvesting by using LMs. The LMs layers are embedded in a porous polytetrafluoroethylene (p‐PTFE) film, resulting in a series of parallel friction interface arrays. The strong electronegativity of PTFE and the high electronic activity of liquid metals are explored, and the interface at the solid‐liquid‐gas three‐phase junction is constructed to facilitate the energy conversion. Using mechanical triggering, the direct current pulse is generated and amplified at the solid‐liquid interface, resulting in an open‐circuit voltage (Voc) of 1080 V and a power density (Pmax) of 12.44 W m⁻². Furthermore, Voc generated by the device in the contact‐separation mode amounted to 1690 V under ultrasonic (40 kHz) excitation. Consequently, this finding is anticipated to offer new opportunities in applications such as flexible electronics, mechanical energy conversion, and human‐machine interaction interfaces.

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Roadbed tribological energy harvester

June 2025

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5 Reads

Science Advances

Roadbed tribological energy (RTE) is a promising recoverable resource with an estimated potential on the terawatt scale, generated annually by the interaction between tires and road surfaces. However, RTE remains underutilized due to the lack of effective energy harvesting technologies that can address its high-entropy characteristics. Here, we present a revolutionary harvester formed by a freestanding layer triboelectric nanogenerator array embedded in the road. The harvester effectively converts low-grade vibratory RTE into electrical energy. It demonstrates the potential to achieve a peak power of 16.409 milliwatts and an average power of 2.2 milliwatts from a compact 78–square centimeter road area under a single tire impact, with a triboelectric conversion efficiency of 11.723%. In addition, we developed a self-powered intelligent and connected transportation system (SP-ICTS), integrating a five-in-one harvesting array. Experimental findings show that the system can meet the SP-ICTS’s electricity requirements along a 1-kilometer segment with a 50-meter harvester.


Evaluation and Rehabilitation System for Ulnar‐Innervated Muscles Facilitated by Rare Earth Oxide‐Enhanced Triboelectric Sensor

Ulnar nerve injuries often lead to muscle atrophy and reduced hand function, necessitating precise monitoring and effective rehabilitation strategies. Current grip strength measurement tools rely on rigid mechanical equipment, which is inconvenient and requires frequent calibration. To address this, a muscle atrophy evaluation and rehabilitation system (MUERS) is presented, featuring a highly sensitive rare earth oxide‐enhanced triboelectric sensor (RETS). Utilizing the unique electrochemical properties of rare earth oxides, RETS demonstrates a linear voltage‐force response in the range of 8–80 kPa, with a maximum linear error of 1.5%. Integrated with a multi‐channel STM32 signal collector, RETS enables real‐time grip strength monitoring across all five fingers. Combining sensor output with an SVM algorithm, the system achieves 98.61% accuracy in identifying finger grip strength injuries and classifies damage into three levels with an average accuracy of 96.67%. MUERS evaluates rehabilitation progress by scoring grip strength and providing feedback to clinicians. Over a four‐week cycle, it consistently captures improvements in muscle recovery, aiding individualized rehabilitation plans. This system offers fine‐grained assessment capabilities for diagnosing and monitoring nerve injury‐induced muscle atrophy, paving the way for advanced biomedical sensing and personalized rehabilitation.


Ionic rectification via electrical double layer modulation at hydrogel interfaces

June 2025

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10 Reads

Hydrogel-based iontronics have emerged as key enablers for sustainable energy harvesting and bio-inspired sensing, with applications spanning human–machine interfaces, brain–computer interfaces, and neuromorphic computing. Central to their operation is precise modulation of the electrical double layer (EDL) at hydrogel interfaces, which governs ionic rectification, a critical function for efficient iontronic performance. This review systematically examines EDL modulation strategies for achieving ionic rectification in hydrogel systems, classifying them into four fundamental mechanisms: (1) EDL formation on charged polymer chains in polyelectrolyte hydrogels; (2) nanopore-confined EDL enhanced by hydrogel modification; (3) EDL at hydrogel-based p–n junctions; and (4) asymmetric EDL at hydrogel/electrode interfaces. Representative studies highlighting breakthrough applications of these mechanisms are discussed, alongside an outlook on the future of EDL engineering in hydrogel-based iontronics, emphasizing both opportunities and challenges in optimizing performance.


Concept of a static Schottky MSM‐based TVNG. a) Schematics of a static M‐S junction driven by light and water and a dynamic M‐S junction driven by sliding friction. b) I‐V curve of a static Schottky MSM structure, the top M‐S junction is Schottky contact, while the bottom junction is featured as an ohmic‐like contact. c) Band diagram of the p‐Si‐based static Schottky MSM structure, the built‐in electric field is formed in depletion region and causes the band bending. d) Electron‐cloud‐potential model of the electron transfer process from the sliding state to the separate state. e) The band diagram of the p‐Si‐based dynamic Schottky M‐S junction shows how the built‐in electric field competes with the interfacial electric field generated by contact electrification, illustrating carrier transport when the friction‐induced interfacial electric field becomes dominant. f) Carrier transport behavior in static MSM structure, which is based on the photovoltaic effect. g) The negative current signal of MSM structure driven by ultraviolet light. h) Carrier transport behavior in dynamic M‐S junction, which is based on the tribovoltaic effect and dominated by ECE‐induced. i) The positive current signal generated by sliding friction. j) Carrier transport behavior in static MSM structure, which is controlled by triboelectric potential. k) The positive current signal of MSM structure driven by impinging water droplet. l,m) Comparison of the transferred charge and charge density with the reported droplet‐based generators.
State density modulation in Schottky MSM structures. a) Schematic energy band of p‐Si and Pt and their theoretical work functions. b) Schematics of the state density in Si‐SiO2 system, with the character of M‐S contact shifting from an ohmic contact to a Schottky contact and MOS structure. c) I–V curves of MSM structure inserted different thickness SiO2 layer between p‐Si and top Pt. d–f) The comparison of short‐circuit current, open‐circuit voltage, and transferred charge when single droplet impinges MSM structures with different SiO2 thickness.
Carrier transport mechanism in the p‐Si Schottky MSM structure under water excitation. a) Working mechanism. b) Corresponding energy band diagrams. c) The current generated by the water droplet‐driven MSM structure under 0 bias voltage. d) Quantitative analysis of the bias voltage applied by droplet water. e) Comparison between the bias voltage applied by water droplet and the threshold on‐state voltage of the Schottky junction. f) Carriers transport behaviors of Schottky MSM‐based TVNG, mainly including thermoelectric emission and diffusion.
Investigation on the system parameters and output energy. a) I–V curves of Schottky MSM structures with various surface electrodes, such as Pt, Cu, and Ag (with a standard deviation across three tests). b) The quantified triboelectric potential of water droplets versus transferred charge. c) The correlation between water droplet, p‐Si, and the top electrode involved in the electricity generation process. d,e) Comparison of Isc and Voc of MSMs based on high and low resistance p‐Si with various thickness SiO2 layer. f) Impedance matching test. g) Comparison of Isc and Qtc of MSM structure under various pH water droplet excitation. h) Details of the current within a single cycle of a Schottky MSM structure and its corresponding fitted curve. i) Details of the current within a single cycle of a transistor‐like generator and its corresponding fitted curve.
Application demonstration. a) Schematic diagram of a TVNG module based on Schottky structure, consisting of 60 unit cells in parallel. b) I‐V curve of the TVNG module, displaying Schottky character. c) Isc of the TVNG module under single water droplet excitation. d) Schematic of single water droplet moving on a Schottky diodes array. e) Isc of the TVNG module under multiple water droplets excitation, showing non‐pulsed current character. f) Application demonstration of fast charging for capacitors.
Schottky MSM‐Structured Tribovoltaic Nanogenerator Enabling Over 25,000 nC Charge Transfer via Single Droplet Impact

Using water droplets to generate electricity is an attractive approach for addressing the energy crisis. However, achieving high charge transfer and power output in such systems remains a major challenge. Here, a tribovoltaic nanogenerator (TVNG) is developed based on a specially designed Schottky metal‐semiconductor‐metal (MSM) structure. This device is capable of efficiently converting the kinetic energy of water droplets into electricity. To improve performance, a patterned interface layer between the metal and semiconductor is introduced, which helps guide charge flow and control surface conductivity. Upon droplet impact, the mechanical friction between the liquid and the surface generates a potential that activates charge transport across the Schottky barrier. This breaks the equilibrium state and enhances carrier movement. As a result, the device achieves a record‐high charge output of 25500 nC from a single droplet, along with an output energy of 5.8 × 10⁻⁶ J. To showcase scalability, a TVNG module with 60 cells on a 3‐inch wafer delivers milliamp‐level current and charges a 220 µF capacitor to 0.6 V within 2 s. The effects of processing, materials, structure, and droplet properties are studied to guide the future design of high‐efficiency Schottky MSM‐based TVNG.


Achieving Dual‐Function In Situ Monitoring of Water Level and Flow Velocity via a Flapping‐Wing Triboelectric Nanogenerator

Real‐time monitoring of water level and flow velocity is essential for reflecting hydrodynamic properties, serving as a core component of intelligent hydrological monitoring systems. However, the measurement accuracy and anti‐interference capabilities of existing sensing methods limit their practical applications. Here, a flapping‐wing water level‐velocity method (FWVM)is proposed, which combines the flapping‐wing motion with the triboelectric nanogenerator (TENG). Through the decoupling analysis of the TENG characteristic signal reflected by the flapping wing motion, the information of water level and flow velocity is extracted. Based on this method, a self‐sustaining flapping wing TENG (FW‐TENG) with a water level resolution of 1 mm is established. The accuracy and stability of FW‐TENG are improved through optimization of the wing shape and the magnetic drive design. Furthermore, a dual‐function monitoring system has been developed for real‐time in situ monitoring and early warning of water level and flow velocity. Compared with a commercial sensor, the error rates of maximum water level and flow velocity are below 0.45% and 2%, respectively. This research provides an approach for the development of underwater sensors and holds great potential for widespread application in hydrological monitoring.


FIG. 2. The two-particle piezoelectric system consisting of two point charges q and −q connected by a spring.
FIG. 11. Piezoelectric constants˜dconstants˜ constants˜d i = L i /L i E computed for different eigenstates of Auld's piezoelectric system shown in Fig. 8.
Quantization of the piezoelectric constant

June 2025

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2 Reads

Physical Review Research

The well-known and celebrated first-primer classical analysis of a one-dimensional inversion-asymmetric assembly of electric point charges interconnected by mechanical springs shows that the system is piezoelectric and characterized by a parameter-dependent but constant piezoelectric coefficient d defined as the ratio between the change in system length and the change in electric field. The former system is the simplest system displaying the phenomenon of piezoelectricity. We demonstrate that a quantum-mechanical analysis of the Hamiltonian for the same system of electric point charges and mechanical springs leads to a piezoelectric constant that depends not only on the system parameters but also on the eigenstate. Hence, the piezoelectric constant, determined as the ratio between the change in the expectation value of the system length and the change in the applied electric field, is quantized. It is demonstrated analytically and numerically, which is a necessary condition, that the quantized piezoelectric constant vanishes if the system Hamiltonian is inversion symmetric. Published by the American Physical Society 2025





Citations (10)


... Despite their promise, all these techniques face fundamental limitations in low charge output and high internal impedance, which hinder their ability to achieve high power density and restrict their applications. [19][20][21] To address the issue of low charge output, previous studies utilized strategies such as material optimization, [22] surface modification, [23] and environmental idealization. [24] Remarkably, the charge shuttling method enhances charge density to 1.85 mC m −2 . ...

Reference:

Achieving Ultra‐High‐Power Output in Triboelectric Energy Harvesters by Torrent‐Like Charge Regulation
Symmetrically pumped charges with high confinement stiffness for boosted performance in wave energy harvesting
  • Citing Article
  • January 2025

Energy & Environmental Science

... The core mechanism behind this effect arises from the disruption of the material's lattice symmetry by the strain gradient, leading to the separation of positive and negative charge centers, thereby generating spontaneous polarization on a macroscopic scale [20]. Unlike piezoelectric polarization [21,22], flexoelectric polarization is not constrained by the crystal symmetry of the material and is observed in a wide range of materials, including ceramics , dielectric polymers, and liquid crystals [23][24][25]. As a dielectric effect commonly found in nature, flexoelectricity is not typically apparent in bulk materials. ...

Progress in Flexoelectric Effect Research and Related Applications

... However, the average physical distance from generation to consumption remains far, causing higher loss during the transmission [2,3]. As a supplementary, small wind turbines (SWTs) could be installed within the built environment and act as a part of an urban-scale distributed energy system [4]. Such distributed wind energy systems are more flexible to adjust according to real-time consumption compared to centralized wind farms, and could be locally operated and maintained on demand, bringing unique advantages to end users. ...

A tightly coupled electromagnetic-triboelectric hybrid generator for wind energy harvesting and environmental monitoring
  • Citing Article
  • April 2025

Nano Today

... After the performance tests of four solid-liquid triboelectric nanogenerators (L-S TENGs) with SAS-TENG@CIP, SAS-TENG@CIP (spinulose arrays), SAS-TENG@CIP (Tshaped arrays), and commercial PDMS as dielectric materials were conducted based on the design model of a single-electrode L-S TENG and the combined method of material doping and surface modification, a series of interesting experimental results as shown in Figures 8-12 were obtained. Referring to the theoretical research on composite dielectric materials by Dang, Zhi-Min, et al. [73], Nan Zhang [74], Kikuo Wakino [75], Yu BaoSheng, and Xiangyuan Wang, et al. [76], and strongly inspired by the research on the surface electro-static breakdown (EB) effect of L-S TENGs published by Zhonglin Wang's team in February of this year [77], theoretical analyses were respectively conducted on Figures 8,9,11 and 12. Finally, some conclusions were drawn based on all the experimental data. ...

Electrostatic breakdown at liquid-solid-gas triple-phase interfaces owing to contact electrification
  • Citing Article
  • February 2025

Matter

... This mixing approach achieved an accuracy of 82.0%, demonstrating its capability for high-precision recognition. In addition, the distinct ability of memristors to simultaneously store and process data minimizes data transmission requirements and enhances computational efficiency [38] . As shown in Figure 4(f), when the same accuracy is achieved, the power consumption of the memristor-based convolutional neural network is only 3.8×10 −2 W [39] , while the power consumption of the traditional CPU architecture is approximately 49 W. Thus, it can be seen that the power consumption of the memristor-based convolutional neural network is about 0.1% of the traditional CPU architecture. ...

Neuromorphic devices assisted by machine learning algorithms

... The application of superhydrophobic treatment enhances the microstructure of the sensor's surface, resulting in substantial improvements in output voltage, sensitivity, and response time. The constructed underwater material identification system (UMIS), based on the OI-TENG (Octopus-Inspired Triboelectric Nanogenerator), is illustrated in Figure 3b [46]. octopus sucker. ...

Octopus-inspired multichannel tactile sensor for enhanced underwater material identification
  • Citing Article
  • February 2025

Chemical Engineering Journal

... The phenomenon of CE, characterized by the generation of triboelectric charge at the interface between contacting materials, has been observed for over 2600 years since its initial discovery [12,35,36]. However, its crucial role in interfacial chemical reactions has often been overlooked. ...

Recent Progress of Chemical Reactions Induced by Contact Electrification

... Another future direction lies in the realm of human-machine interaction: TENG-based sensors integrated with AI could provide the robots with nuanced feedback regarding touch, pressure, and motion, thereby enabling more natural and efficient interactions with humans [30,31,129,140,141]. In the field of aerospace technology, TENG-based self-powered sensors can be integrated into the external operational and mobility systems of aircraft or spacecraft [32,142,143], while also serving to monitor the health status of various components of space vehicles [33,144]. However, TENG-based sensors face rigorous environmental challenges in this domain, including vacuum conditions in space and extreme temperature fluctuations, icing, gusts, thunderstorms, and low visibility within the atmosphere. ...

Conformal self-powered high signal-to-noise ratio biomimetic in-situ aircraft surface turbulence mapping system
  • Citing Article
  • April 2025

Nano Energy

... Cationic polymers combined with polysaccharides have attracted increasing interest due to their intrinsic antibacterial properties, environmental friendliness, and high biocompatibility. [25][26][27] Among these, the combination of chitosan and PHMG has been widely employed in the development of antibacterial coatings and membranes. 28,29 In addition to their antimicrobial activity, both chitosan and PHMG exhibited strong positive triboelectric properties. ...

Fabrication of alginate-based bio-tribopositive films via amine modification and metal ion coordination for high surface charge density
  • Citing Article
  • April 2025

Nano Energy

... Recently, a flexible, self-powered TENG wound patch (epatch) was developed to promote wound healing through combined electrostimulation and photothermal effects. The e-patch was fabricated using a polyacrylamide/polydopamine (PAM/PDA) dual-network hydrogel doped with multi-walled CNTs, offering high conductivity, stretchability, and biocompatibility, while enabling real-time detection of mechanical and electrical signals during human motion (Figure 3b) [61]. While the solvent-casting method used here is compatible with roll-to-roll production, the incorporation of CNTs via sonication limits throughput. ...

Flexible Triboelectric Nanogenerator Patch for Accelerated Wound Healing Through the Synergy of Electrostimulation and Photothermal Effect