Zhanghai Chen’s research while affiliated with Xiamen University and other places

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Publications (33)


Room Temperature Coherently Coupled Exciton Polaritons in Two-Dimensional Organic-Inorganic Perovskite
  • Article

August 2018

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179 Reads

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139 Citations

ACS Nano

Jun Wang

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Rui Su

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Two-dimensional (2D) organic-inorganic perovskite semiconductors with natural multi-quantum well structures and confined 2D excitons are intriguing for the study of strong exciton-photon coupling, due to their large exciton binding energy and oscillation strength. This strong coupling leads to a formation of the half-light half-matter bosonic quasiparticle called exciton-polariton, consisting of a linear superposition state between photonic and excitonic states. Here, we demonstrate room temperature strong coupling in exfoliated wavelength-tunable 2D organic-inorganic perovskite semiconductors embedded into a planar microcavity, exhibiting large energetic splitting-to-linewidth ratios (>34.2). Angular dependent spectroscopy measurements reveal that hybridized polariton states act as an ultrafast and reversible energy oscillation, involving 2D perovskite exciton, cavity modes (CM) and Bragg modes (BM) of the distributed Bragg reflector (DBR). Meanwhile, sizeable hybrid particles dominantly couple to the measured optical field through the CMs. Our findings advocate a considerable promise of 2D organic-inorganic perovskite to explore fundamental quantum phenomena such as Bose-Einstein condensation, superfluidity and exciton-polariton networks.


Room Temperature Polariton Lasing in All-Inorganic Perovskites

April 2017

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5 Reads

Polariton lasing is the coherent emission arising from a macroscopic polariton condensate first proposed in 1996. Over the past two decades, polariton lasing has been demonstrated in a few inorganic and organic semiconductors in both low and room temperatures. Polariton lasing in inorganic materials significantly relies on sophisticated epitaxial growth of crystalline gain medium layers sandwiched by two distributed Bragg reflectors in which combating the built-in strain and mismatched thermal properties is nontrivial. On the other hand, organic active media usually suffer from large threshold density and weak nonlinearity due to the Frenkel exciton nature. Further development of polariton lasing towards technologically significant applications demand more accessible materials, ease of device fabrication and broadly tunable emission at room temperature. Herein, we report the experimental realization of room-temperature polariton lasing based on an epitaxy-free all-inorganic cesium lead chloride perovskite microcavity. Polariton lasing is unambiguously evidenced by a superlinear power dependence, macroscopic ground state occupation, blueshift of ground state emission, narrowing of the linewidth and the build-up of long-range spatial coherence. Our work suggests considerable promise of lead halide perovskites towards large-area, low-cost, high performance room temperature polariton devices and coherent light sources extending from the ultraviolet to near infrared range.


Figure 2 Angle-resolved reflectivity and photoluminescence of CsPbCl3 perovskite microcavity. a, Angle-resolved reflectivity spectrum measured using a white light lamp. The dashed white lines show the theoretical fitting dispersion of the upper (UP) and lower (LP) polariton dispersions. The solid white lines display the dispersions of uncoupled CsPbCl3 perovskite exciton (X) and cavity photon mode (C) obtained from a coupled harmonic oscillator model fitting. The parabolic-like dispersion is caused by the bare microcavity, without any embedded perovskite, as a result of the smaller sample size compared with the white light beam diameter. b, Angle-resolved photoluminescence spectrum of perovskite microcavity. The detuning Δ, obtained from a coupled harmonic oscillator model fitting to the measured dispersion (dashed white lines), is indicated on the figure. Note the slight energy differences between reflectivity and photoluminescence spectrum due to slightly different spot positions.
Figure 3 Power dependent angle resolved photoluminescence spectrum. a, Angle-resolved photoluminescence spectrum measured at 0.75 Pth. Polaritons show a broad emission distribution at all angles. b, Angle-resolved photoluminescence spectrum measured at 1.0 Pth. The ground state near || 0 k  exhibits a much stronger emission than other angles, indicating the onset of polariton lasing. c, Angle-resolved photoluminescence spectrum measured at 1.3 Pth. The ground state near || 0 k  is massively occupied, experiencing a sharp increase of intensity along with a blueshift of peak energy. 
Figures and Captions 
Room Temperature Polariton Lasing in All-Inorganic Perovskites
  • Article
  • Full-text available

April 2017

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1,092 Reads

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431 Citations

Nano Letters

Polariton lasing is the coherent emission arising from a macroscopic polariton condensate first proposed in 1996. Over the past two decades, polariton lasing has been demonstrated in a few inorganic and organic semiconductors in both low and room temperatures. Polariton lasing in inorganic materials significantly relies on sophisticated epitaxial growth of crystalline gain medium layers sandwiched by two distributed Bragg reflectors in which combating the built-in strain and mismatched thermal properties is nontrivial. On the other hand, organic active media usually suffer from large threshold density and weak nonlinearity due to the Frenkel exciton nature. Further development of polariton lasing towards technologically significant applications demand more accessible materials, ease of device fabrication and broadly tunable emission at room temperature. Herein, we report the experimental realization of room-temperature polariton lasing based on an epitaxy-free all-inorganic cesium lead chloride perovskite microcavity. Polariton lasing is unambiguously evidenced by a superlinear power dependence, macroscopic ground state occupation, blueshift of ground state emission, narrowing of the linewidth and the build-up of long-range spatial coherence. Our work suggests considerable promise of lead halide perovskites towards large-area, low-cost, high performance room temperature polariton devices and coherent light sources extending from the ultraviolet to near infrared range.

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Citations (26)


... E xciton-polaritons, bosonic quasi-particles resulting from the strong coupling between excitons and cavity-confined photons, have continuously drawn lots of attention in recent decades. [1][2][3][4][5][6] As hybrid states of light and matter, exciton-polaritons show unique properties that are significantly different from those of pure photons and excitons. Due to their photonic component, exciton-polaritons exhibit impressive coherence in both time and spatial domains. ...

Reference:

Room temperature ballistic transport of exciton-polaritons in a one-dimensional whispering gallery microcavity
Ex Situ Production and Storage of Exciton-Polariton Vortices in Higher-Order Topological Corner Modes
  • Citing Article
  • August 2024

Physical Review Letters

... This research uncovers new physical phenomena, such as quantum entanglement and chiral quantum light fields [11], while also offering practical implications for the advancement of cuttingedge optoelectronic devices and quantum information technologies. Chiral exciton-polaritons, for instance, hold potential for realizing all-optical switches [12]- [14], optical logic gates [15], novel quantum light sources [16], [17], and optical isolators [18], furthering advancements in quantum computing and communication. ...

All-optical temporal logic gates in localized exciton polaritons

Nature Photonics

... Among TMD-based bilayer systems, MoSe 2 /WSe 2 vdW heterostructures exhibit excellent structural stability and minimal lattice mismatches, thus have been extensively addressed in the past decade [25][26][27][28][29]. For example, they can be prepared through the 'tear and stack' method, and the relative energy and coupling strength of dipole excitons can be regulated by small twist angle and an electric field [26]. ...

Stacking order dependence of interlayer excitons in MoSe 2 / WSe 2 heterobilayers
  • Citing Article
  • July 2024

... Particularly for open microcavities, aligning both the cavity length and the relative orientation of the two mirrors can present a significant * Contact author: c.u.mattschas@utwente.nl challenge [22][23][24][25][26]. Useful methods for tackling this problem include deflection measurements (autocollimation) and interferometry. ...

Analogue of Charge Conjugation in the Optical Spin Hall Effect
  • Citing Article
  • August 2023

Physical Review Applied

... This review not only aims to offer a broad overview of the current state of the TMD-based strong coupling but also attempts to inspire further investigations and developments of new polaritonic devices and technologies within van der Waals materials. For a detailed description of microcavity exciton-polariton physics and strong coupling with alternative promising materials, we refer the readers to some excellent reviews 5,23,50,51 . Here, we start with a brief introduction to TMD polaritons in various optical structures. ...

Nanophotonics of microcavity exciton–polaritons
  • Citing Article
  • March 2023

... Indeed, nonlinearities of polaritons governed by polaritonic interactions have become one of the most studied topics in the field of polariton physics. A variety of nonlinear phenomena, such as inter-and intra-band parametric scattering, 2,[8][9][10][11] polariton blockade, [12][13][14] topological edge mode, [15][16][17] and evaporative cooling 18) have been reported in recent years. Understanding and controlling the nonlinearities of polaritons is critical for both fundamental polariton physics and their potential optoelectronic applications. ...

Ultrafast intermode parametric scattering dynamics in room-temperature polariton condensates
  • Citing Article
  • February 2023

... Indeed, nonlinearities of polaritons governed by polaritonic interactions have become one of the most studied topics in the field of polariton physics. A variety of nonlinear phenomena, such as inter-and intra-band parametric scattering, 2,[8][9][10][11] polariton blockade, [12][13][14] topological edge mode, [15][16][17] and evaporative cooling 18) have been reported in recent years. Understanding and controlling the nonlinearities of polaritons is critical for both fundamental polariton physics and their potential optoelectronic applications. ...

Controllable topological edge mode in an optically excited exciton-polariton lattice
  • Citing Article
  • December 2022

... However, there are some property differences even in the same type of material because of differences in the preparation method, sample treatment, etc. For instance, the two-photon absorption (TPA) coefficient of monolayer MoS 2 obtained by the mechanical exfoliation (ME) and chemical vapor deposition (CVD) method may differ by nearly two times, which can be ascribed to the large difference in the defect concentration between them [16]. The two-photon fluorescence of MoS 2 improved after treatment with bis-(trifluoromethane) sulfonimide as the defect density decreased during the defect repair process [17]. ...

Two-photon absorption towards pulse modulation in mechanically exfoliated and CVD monolayer cascaded MoS2 structures
  • Citing Article
  • January 2019

Chinese Optics Letters

... All these AlGaN based LEDs are using standing NW or NW arrays to improve the LEE, here we use surface plasmon resonance with plasmonic aluminum bowtie antenna array to enhance the LEE of AlGaN based LEDs with laid down NW structures. And our previous experimental work have demonstrated that the local surface plasmon resonance of Al bowtie antenna array can enhance the absorption, the emission and the second harmonic generation efficiency of ZnTe nanowire at the visible wavelength range [27][28][29]. ...

A hybrid plasmonic-dielectric metal-Nanowire coupler for high-efficient broadband nonlinear frequency conversion
  • Citing Article
  • August 2022

Photonics Research