Yu. V. Titova’s research while affiliated with Ivanovo State University and other places

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Publications (17)


The influence of elementarization on flax fiber properties and on the composition of additives
  • Article

January 2016

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11 Reads

V.G. Stokozenko

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I.Yu. Larin

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E.R. Voronina

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[...]

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A.P. Moryganov

The composition of additives and properties offlax fiber were analyzed after mechanical modification by different methods. The possibility was shown that the method of complex fiber destruction by the action of cyclic deform loads may provide the obtaining of high quality flax materials.


Effect of the cathode material on the accumulation of hydrogen peroxide in a plasma-solution system
  • Article
  • Full-text available

November 2013

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86 Reads

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3 Citations

Surface Engineering and Applied Electrochemistry

The accumulation of hydrogen peroxide in a plasma-solution system with an electrolyte cathode under glow discharge action in relation to the cathode material has been studied, as well as the kinetics of the accumulation of Cu2+, Ni2+, and Ag+ ions passing from the cathode into the solution at the discharge combustion. It is shown that the Cu2+ concentration is comparable with that of the H2O2, and the use of a silver cathode results in a considerable decrease of the initial formation rate and the highest concentration of hydrogen peroxide in the plasma-solution system under study.

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Yields of hydroxyl radicals and hydrogen peroxide in a glow discharge system with a liquid cathode

December 2012

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16 Reads

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4 Citations

Surface Engineering and Applied Electrochemistry

A model of the hydroxyl radical yield estimation in a glow discharge-water system is presented. The hydroxyl radical yield has been found. The initial yield of hydrogen peroxide and its effective lifetime have been calculated. The yield of hydroxyl radicals obtained by the suggested model is shown to be in good agreement with the experimental data of other investigators.


Chemical interactions of a model lignin compound under plasma-solution treatment

July 2012

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20 Reads

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7 Citations

Surface Engineering and Applied Electrochemistry

Chemical transformations of isoeugenol (a model lignin compound) have been investigated under the combined action of an atmospheric pressure discharge initiated in the volume of an electrolyte and alkali treatment using UV spectrophotometric analysis. Plasma-solution activation has been shown to be an initiator of the oxidative breakdown of the aromatic structure of the compound during alkali treatment.


Accumulation of Hydrogen Peroxide at the Long-Term Effect of an Atmosphere Pressure Glow Discharge on Electrolyte Solutions

February 2012

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10 Reads

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3 Citations

Surface Engineering and Applied Electrochemistry

The kinetic characteristics of the hydrogen peroxide accumulation at the long-term effect of an atmospheric pressure glow discharge on aqueous solutions of electrolytes have been obtained. The initial rates of the H2O2 generation and the primary yields are calculated using the straight line portions of the kinetic characteristics. It is found that the times of reaching a steady hydrogen peroxide concentration (or its maximum) are rather long (about several hours). The OH· yield has been estimated, and the initial yield of hydrogen peroxide and its effective lifetime have been calculated using the kinetic relationship obtained for a glow discharge-water system.


The influence of plasma-solution treatment on the properties of hemp fiber lignin

April 2010

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20 Reads

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6 Citations

Surface Engineering and Applied Electrochemistry

The effect of an atmospheric pressure gas discharge generated inside an electrolyte solution on hemp lignin has been investigated by the methods of IR spectroscopy. It is shown that the gas-discharge activation causes a threefold increase of the lignin solubility with the further chemical treatment. The feasible processes of the interaction of the active particles generated in the electrolyte solution under the discharge action with the lignin macromolecules are considered.


Effect of a Gas Discharge in the Bulk of an Electrolyte Solution on Its Physical and Chemical Properties

August 2009

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4 Reads

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1 Citation

Surface Engineering and Applied Electrochemistry

The effect of a gas discharge at atmospheric pressure in dielectric tubes filled with an electrolyte solution on the acidity and electroconductivity of solutions of sulfuric acid, sodium hydroxide, and sodium sulfate at various concentrations has been studied. The dynamic current-voltage characteristics of the volume discharge have been obtained for a wide number of electrolytes. It is shown that such discharge action on the investigated solutions causes the growth of their pH and the decrease of their electroconductivity. The process under study is found to be periodic with the electrophysical parameters being dependent not only on the solution electroconductivity but also on its chemical composition.


Application of plasma-solution treatment for modification of bast fibers

February 2009

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8 Reads

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4 Citations

Surface Engineering and Applied Electrochemistry

Delignification processes of rough bast fibers under the action of face discharge were studied. The residual lignin content in the fiber and the fiber mass loss were determined after the plasma-solution and subsequent short chemical treatment with reduced alkalinity. This two-stage treatment was shown to be an effective delignification method for bast fibers, since the delignification degree amounts to 68% for flax, 64% for hemp, and 39% for jute fibers.


Investigation of the Opportunity for Increasing the Yield of Hydrogen Peroxide in Plasma-Solution Systems

August 2008

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31 Reads

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11 Citations

Surface Engineering and Applied Electrochemistry

The influence of the addition of alcohol (ethanol and propanol-2) to an electrolyte solution on hydrogen peroxide formation under the action of glow and gliding discharges of atmospheric pressure was studied. The addition of alcohol up to 0.1 mol/l was found to increase the yield of H2O2 significantly.



Citations (13)


... Sergeeva et al. (2002) compared the effect of the glow and diaphragm discharge on the MB water solution. It was found that diaphragm discharge was more efficient. ...

Reference:

Kinetic regularities of methylene blue destruction processes in different media under the impact of the diaphragm discharge plasma
The action of glow discharge and diaphragm discharge of atmospheric pressure at methylene blue solution
  • Citing Article
  • January 2002

... According to a previous work [38], PVP is effectively depolymerized in the presence of H 2 O 2 . Numerous studies of the kinetics of hydrogen peroxide accumulation in plasma systems in contact with liquids have shown that the electrode material can be both a catalyst and an inhibitor of the decomposition reaction of hydrogen peroxide [39][40][41][42]. The results of measuring the concentration of hydrogen peroxide under conditions of a diaphragm discharge action in distilled water with Mo, Nb, and W electrodes are also presented in Table 1. ...

Effect of the cathode material on the accumulation of hydrogen peroxide in a plasma-solution system

Surface Engineering and Applied Electrochemistry

... Recently, nonthermal atmospheric-pressure plasma (NTAPP), which is an external energy source, has attracted attention as a method for generating reactive oxygen species (ROS) under mild conditions [1]. NTAPP can generate ROS in an energy saving and sustainable manner [2][3][4][5] because of its operation under ambient conditions, low input energy less than several hundred watts, and the utilization of gases with high abundance, such as air and argon, as the plasma source gas [1]. It has been reported that NTAPP-irradiated liquids (i.e., plasma-activated liquids) appear various functions due to ROS generated in the liquid phase [6]. ...

Accumulation of Hydrogen Peroxide at the Long-Term Effect of an Atmosphere Pressure Glow Discharge on Electrolyte Solutions
  • Citing Article
  • February 2012

Surface Engineering and Applied Electrochemistry

... In this case however, the light emission would not be directly related to the Faradaic charge transfer which governs the electrochemical behaviour of the system as pointed out in Section 4.1. One of possible (but not definitive) mechanisms underlying high-field electroluminescence also relies upon water decomposition and ionisation due to bombardment of the gas-electrolyte interface by energetic cations [80]: ...

Yields of hydroxyl radicals and hydrogen peroxide in a glow discharge system with a liquid cathode
  • Citing Article
  • December 2012

Surface Engineering and Applied Electrochemistry

... The dominant reaction pathway of lignin degradation is the cleavage of the C β -O covalent bond followed by the cleavage of the C β -C α bond. Titova et al. 150 investigated the chemical transformations of isoeugenol (2-methoxy-4-ppropenylphenol, a model lignin compound) under the combined action of an atmospheric pressure discharge initiated in the volume of an electrolyte and alkali treatment using UV spectrophotometric analysis. They found that plasma-solution activation was an initiator of the oxidative breakdown of the aromatic structure of the compound during alkali treatment. ...

Chemical interactions of a model lignin compound under plasma-solution treatment
  • Citing Article
  • July 2012

Surface Engineering and Applied Electrochemistry

... plasma zone initiating the formation of chemically active particles with excessive reactivity [6,7]. The formed active particles, namely, radicals and hydrogen peroxide, are capable of penetrating deep into a cell membrane thus activating the cell processes and affecting the initial stages of the plant development. ...

Effect of a Gas Discharge in the Bulk of an Electrolyte Solution on Its Physical and Chemical Properties
  • Citing Article
  • August 2009

Surface Engineering and Applied Electrochemistry

... According to a previous work [38], PVP is effectively depolymerized in the presence of H 2 O 2 . Numerous studies of the kinetics of hydrogen peroxide accumulation in plasma systems in contact with liquids have shown that the electrode material can be both a catalyst and an inhibitor of the decomposition reaction of hydrogen peroxide [39][40][41][42]. The results of measuring the concentration of hydrogen peroxide under conditions of a diaphragm discharge action in distilled water with Mo, Nb, and W electrodes are also presented in Table 1. ...

Generation of chemically active oxidative particles in electrolyte solutions under the action of glow and diaphragm discharges
  • Citing Article
  • April 2007

Surface Engineering and Applied Electrochemistry

... Liu et al. [10] used a glow-like discharge plasma device to treat a sodium lactate solution, and the yield of hydrogen peroxide in activated sodium lactate is eight times higher than that of the PAW, reaching 325 μmol/L. Kuz'micheva et al. [11] found that the yield of H 2 O 2 increased from 5:2 � 10 −4 mol=L to 1:4 � 10 −3 mol=L when glow discharge plasma was used to treat 0.01 mol/L Na 2 SO 4 and 0.1 mol/L ethanol mixed solution compared with only 0.01 mol/L Na 2 SO 4 . In our previous study [12], a DC-driven air plasma device has been used to treat solution containing H+, NO − 2 and NO − 3 species and achieved a better decontamination effect than PAW. ...

Investigation of the Opportunity for Increasing the Yield of Hydrogen Peroxide in Plasma-Solution Systems
  • Citing Article
  • August 2008

Surface Engineering and Applied Electrochemistry

... These reactive oxygen species (ROS) have strong oxidative activity, which can damage fungal membrane, resulting in spore inactivation (Sen Gupta, 2015). It has been reported that the increase of voltage and the decrease of electrode gap leads to the increase of electric field intensity between electrodes, the average energy of high-energy electrons becomes stronger, and more ROS is generated (Kuz'micheva, et al., 2007). Due to the presence of antioxidant substances such as polyphenols, flavonoids, carotenoids and vitamins in fruit juices, part of ROS produced by CGDE can be removed, resulting in reduced inactivation efficiency (Surowsky et al., 2015). ...

Effect of the discharge-gap distance on the formation of hydrogen peroxide in a plasma-solution system with atmospheric-pressure glow discharge
  • Citing Article
  • December 2007

Surface Engineering and Applied Electrochemistry

... Solution plasma processing (SPP) or plasma in the liquid phase is regarded as an advanced oxidation method because of its potential to generate highly active species, particularly hydroxyl radicals (Surov et al., 2018;Zakharov et al., 2007). In a study, Surov et al. (2018) reported a novel oxidation-hydrolysis method involving atmospheric pressure glow discharge SPP system for production of CNCs from MCC and filter paper (FP). ...

Physicochemical Properties of Plasma — Solution Systems and Prospects for Their Use in Technology
  • Citing Article
  • October 2007

Russian Chemical Reviews