March 2025
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12 Reads
Sensors and Actuators Reports
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March 2025
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12 Reads
Sensors and Actuators Reports
February 2025
February 2025
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60 Reads
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1 Citation
This article reports a high‐performance rechargeable battery enabled by an electrospun quasi‐solid‐state electrolyte (E‐QSSE). The E‐QSSE, composed of Poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP), Mg(NO3)2 salt, and Pyr14TFSI ionic liquid (IL), exhibits high Mg²⁺ ion transport and interfacial stability. A unique sandwich structure coupling the E‐QSSE with a Ruthenium nanoparticles decorated multi‐walled carbon nanotubes (Ru/CNT) cathode catalyst on carbon paper significantly augments electrochemical reversibility. The optimized E‐QSSE with a 1:1 molar ratio of salt and IL achieves a high room temperature ionic conductivity of 6.39 mS cm⁻¹. The E‐QSSE's electrochemical stability window extends up to 3.95 V, showcasing its potential for high‐energy‐density applications. The Mg‐O2 cell, with the optimized E‐QSSE, delivers 115 discharge/charge cycles at 100 mA g⁻¹, one of the longest reported cycle‐lives for secondary Mg‐O2 batteries. The battery exhibits a maximum discharge capacity of 9305 mAh g⁻¹ with 100% Coulombic efficiency. X‐ray photoelectron spectroscopy and absorption near‐edge structure analyses reveal MgO as the primary discharge product, with MgF2 contributing to stable solid electrolyte interphase. This E‐QSSE design promotes efficient Mg²⁺ ion migration and stable electrochemical reactions. This work advances the development of stable, high‐capacity Mg‐O2 batteries and can open up avenues for quasi‐solid‐state electrolytes in post‐lithium metal‐air battery technologies.
February 2025
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25 Reads
January 2025
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16 Reads
Journal of Materials Chemistry A
Elastomers are indispensable in wearable electronics due to their elasticity and flexibility. Among them, poly(dimethylsiloxane) (PDMS) is particularly valued for its nontoxicity and chemical stability. However, conventional PDMS materials lack...
January 2025
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14 Reads
IEEE Transactions on Control Systems Technology
Chance constrained stochastic model predictive controllers (CC-SMPCs) tradeoff full constraint satisfaction for economical plant performance under uncertainty. Previous CC-SMPC works are over-conservative in constraint violations leading to worse economic performance. Other past works require a priori information about the uncertainty set, limiting their application. This article considers a discrete linear time-invariant (LTI) system with hard constraints on inputs and chance constraints on states, with unknown uncertainty distribution, statistics, or samples. This work proposes a novel adaptive online update rule to relax the state constraints based on the time average of past constraint violations, to achieve reduced conservativeness in closed-loop. Under an ideal control policy assumption, it is proven that the time average of constraint violations asymptotically converges to the maximum allowed violation probability. The method is applied for optimal battery energy storage system (BESS) dispatch in a grid-connected microgrid (MG) with photovoltaic (PV) generation and load demand, with chance constraints on BESS state of charge (SOC). Realistic simulations show the superior electricity cost-saving potential of the proposed method as compared with the traditional economic model predictive control (EMPC) without chance constraints, and a state-of-the-art approach with chance constraints. We satisfy the chance constraints nonconservatively in closed-loop, effectively trading off increased cost savings with minimal adverse effects on BESS lifetime.
December 2024
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5 Reads
Innovation in Aging
Music-based therapy (MBT) has been shown to be effective in improving upper extremity (UE) functions for older adults with stroke in clinical settings. To expand the MBT benefits to home, we designed a client-centered, stroke-specific MBT app and examined the app feasibility with stroke survivors in this study. During the 2-week pilot home testing, the participants (n=5, mild to moderate UE motor impairments) actively used the app for rehab exercises around 71% of the time, which equals 26.6 ± 16.7 min per day, 5 days per week, over 2 weeks. Motor outcomes portrayed a positive trend from pre- to post-intervention. Participants’ average Fugl-Meyer Assessment scores increased from 53 to 57, and Nine-Hole Pegboard Test time decreased from 38 seconds to 32 seconds. Additionally, participants provided generally positive feedback, commenting on the app user-friendliness (e.g., easy to navigate, clear exercise instructions, convenience) and motivational music feature (e.g., engaging and a new way to experience therapy). They also enjoyed the flexibility of training scheduling – participants could do rehab exercises at any time they wanted. Based on the positive findings, we anticipate that the app will serve as a feasible tool for older adults with stroke to engage in a personalized program to improve UE functions at home. This will minimize the burden of travel and wait times to healthcare clinics and increase rehab access for older adults. We are currently continuing the data collection and app refinement to optimize the app to support stroke recovery in older adults.
December 2024
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27 Reads
Monthly demand charges form a significant portion of the electric bill for microgrids with variable renewable energy generation. A battery energy storage system (BESS) is commonly used to manage these demand charges. Economic model predictive control (EMPC) with a reference trajectory can be used to dispatch the BESS to optimize the microgrid operating cost. Since demand charges are incurred monthly, EMPC requires a full-month reference trajectory for asymptotic stability guarantees that result in optimal operating costs. However, a full-month reference trajectory is unrealistic from a renewable generation forecast perspective. Therefore, to construct a practical EMPC with a reference trajectory, an EMPC formulation considering both non-coincident demand and on-peak demand charges is designed in this work for 24 to 48 h prediction horizons. The corresponding reference trajectory is computed at each EMPC step by solving an optimal control problem over 24 to 48 h reference (trajectory) horizon. Furthermore, BESS state of charge regulation constraints are incorporated to guarantee the BESS energy level in the long term. Multiple reference and prediction horizon lengths are compared for both shrinking and rolling horizons with real-world data. The proposed EMPC with 48 h rolling reference and prediction horizons outperforms the traditional EMPC benchmark with a 2% reduction in the annual cost, proving its economic benefits.
November 2024
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28 Reads
November 2024
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9 Reads
... This QSSE was prepared by combining PVDF-HFP copolymer to achieve good electrochemical and mechanical stability, hydrophobicity, reduced crystallinity, and resilience against nucleophilic superoxide anions; 5 SN as a high-dielectric (ε r ≈ 55) plasticizer; Mg(OTf) 2 as a stable, noncorrosive to Mg, and cost-effective electrolyte salt; 17 and Pyr 14 TFSI IL for good chemical and electrochemical stability, hydrophobicity, low vapor pressure, nonflammability, enhanced ionic conductivity, and faster Mg 2+ flow. 22 Besides, the Pyr 14 + cation in Pyr 14 TFSI protects the Mg anode by electrostatic shielding to make a stable interphase for Mg 2+ transfer. 23,24 The optimized QSSE (with PVDF-HFP:SN:Mg(OTf) 2 = 4:1:1 and 15 wt% IL; see the SI) achieved a room-temperature conductivity of 2.6 mS cm −1 , and the QSSE-based rechargeable Mg−O 2 battery has remarkable cyclability, reaching 94 stable cycles at a current density of 100 mA g −1 and curtailing capacity of 500 mAh g −1 . ...
February 2025
... WaveNet and Tacotron are particularly effective in creating context-aware voice responses, which improve user interaction with AI-driven traffic control centers [54]. Additionally, models like VALL-E enable customized voice synthesis, ensuring a consistent and human-like experience in interactive transportation systems [55]. These advancements contribute to safer and more efficient ITS environments, where real-time, AIgenerated voice communication reduces cognitive load and enhances user engagement. ...
July 2024
... The introduction of certain foreign elements is found to properly modulate the band structure of the planner g-C 3 N 4 resulting in tunable electronic alternation [45]. The new energy levels brought by the doped elements above the VB and below the CB significantly reduce charge recombination and extend light absorption by reducing the band gap [46,47]. The alternation in electronic energy levels caused by the introduced dopants depends on their nature (metal or non-metals) as well as their concentration. ...
September 2024
Applied Surface Science
... We recently reported poly(ethylene oxide)-based semisolid-state Mg−O 2 batteries, where a liquid catholyte alleviated the cathodeelectrolyte interphase issue. 17 In this letter, we report a freestanding QSSE with improved room-temperature ionic conductivity, holistically addressing all these issues in Mg− O 2 batteries. This QSSE was prepared by combining PVDF-HFP copolymer to achieve good electrochemical and mechanical stability, hydrophobicity, reduced crystallinity, and resilience against nucleophilic superoxide anions; 5 SN as a high-dielectric (ε r ≈ 55) plasticizer; Mg(OTf) 2 as a stable, noncorrosive to Mg, and cost-effective electrolyte salt; 17 and Pyr 14 TFSI IL for good chemical and electrochemical stability, hydrophobicity, low vapor pressure, nonflammability, enhanced ionic conductivity, and faster Mg 2+ flow. ...
August 2024
Journal of Materials Chemistry A
... By embedding Au-nanochains within Zn 0.67 Cd 0.33 S semiconductors, the photoconversion efficiency was found to increase 3.5 times compared to conventional surface attached isolated Au nanoparticles (Fig. 17B). Recently, Chen et al. have fabricated very sophisticated double-hollow yolk@shell nanostructures composed of a permeable, hollow CdS shell with an embedded hollow Au nanosphere, for solar H 2 production [128]. An exceptionally large photoactivity with 4.4% apparent yield of H 2 could be obtained with 660 nm irradiation due to generation of long-lived hot electrons and efficient creation of charge separation state at the Au nanosphere/CdS heterojunctions in the yolk@shell structures. ...
June 2024
... This progression is associated with an increased risk of metabolic disorders in adulthood, including type 2 diabetes, hypertension, and cardiovascular diseases [5]. Furthermore, experiencing stigma and social bias due to obesity in adolescence often results in severe psychological repercussions, including low self-esteem, distorted body perception, and exacerbate obesity, as evidenced by decreased athletic performance during adolescence, which may significantly influence mental health outcomes, including psychological distress, anxiety, depression, and the emergence of personality disorders throughout one's life [16]. The findings from the studies reviewed thus far underscore the critical importance of addressing obesity among developing adolescents. ...
April 2024
... With the adoption of VRE sources, such as wind, solar, and electric vehicle (EV) charging stations, net loads have generally become more variable, and DCM with BESS has received much interest in the literature. BESS assisted DCM is applied in commercial and industrial buildings in [9], [10], residential buildings in [11]- [13], utility-scale sites in [14], [15], and at EV charging sites [16]- [19] and are often combined with PV generation [9]- [11]. ...
April 2024
... Semiconductors like TiO 2 , WO 3 , and g-C 3 N 4 , along with their modified structural hybridized materials, and donor-acceptor polymers have been used previously for photocatalytically reducing nitrates to ammonia. [23,[61][62][63] In this work, a BiOI semiconductor hybridized with H 3 [PW 12 O 40 ] polyoxometalate, Cu, and Fe 3 O 4 forms the AmmoGen microrobot. Upon visible light irradiation, BiOI absorbs photons which excites the electrons to the conduction band and holes are simultaneously generated in the valence band (Figure 6a). ...
February 2024
Chemical Engineering Journal
... To demonstrate the comprehensive capabilities of Al ac-0.25 -3N2AP-PTD films and to broaden their application scope in electronic devices, we developed a flexible, stretchable, and self-healing polypyrrole (PPy)-coated composite that emulates human skin's sensing functions. 52,53 As depicted in Figure 7a, the device is constructed using a standalone Al ac-0.25 -3N2AP-PTD film with an overlying PPy layer. Postcoating, the PPycoated Al ac-0.25 -3N2AP-PTD assumes a deep purple color ( Figure S14) and has a surface characterized by noticeable cauliflower-like agglomerations ( Figure S15a). ...
January 2024
Journal of Materials Chemistry A
... Based on previous studies on the interaction between Hsp40 and Hsp70, researchers usually focus only on the interaction between the JD domain of Hsp40 and Hsp70 [38][39][40][41][42][43][44][45][46][47][48]. However, through molecular docking analysis, we have also discovered that the CTD of Dnajb1b can bind to Hspa1a and even interact with three domains of Hspa1a. ...
December 2023