Yasumasa Ogawa's research while affiliated with Akita University and other places

Publications (50)

Article
Full-text available
In the use of coal fly ash (FA) mixed cement, the assessment of the leachabilities of toxic elements in FA is crucial. This study evaluated the leaching behavior of arsenic and selenium in 40 types of raw FA (R-FA), aging-treated FA (A-FA), and cement-mixed FA (C-FA). The mean leaching concentrations from R-FAs were 0.03 mg/L for arsenic and 0.09 m...
Article
Long-term mining activities in the Bor and Majdanpek porphyry copper mining areas located in Eastern Serbia have led to serious environmental problems, the most notable being surface water pollution by heavy metals downstream of the mining sites. However, the geochemical characteristics and environmental impact on groundwater in the mining areas ar...
Conference Paper
Full-text available
This paper presents the results of the monitoring of pH value and concentrations of the dissolved and particulate forms of copper in the period from 2015 to 2021 in wastewaters that form Bor River, and in the water of Bor River, Krivelj River, Bela River, and Timok River which are under the influence of mining and metallurgical activities in Bor. C...
Article
Acidic thermal water originating from the Kusatsu geothermal area of Gunma Prefecture, Japan is introduced into rivers, where there are many anthropogenicobjects such as a neutralization plant, a dam and water channels for hydroelectric power plants. We have investigated changes in the physico-chemical nature and fractionation mechanisms of rare ea...
Article
Full-text available
Coal fly ash (CFA) is a useful recycled resource for uses such as cement raw material. To manage and evaluate safety for effective utilization of CFA, the leaching concentration and amounts of toxic elements in CFA need to be determined. In this study, 38 types of CFA and aged CFA generated in Japan were used to measure the occurrence and leaching...
Article
Full-text available
Mining activities in the Bor and Majdanpek mining areas in Eastern Serbia started in 1903 and 1961, respectively. Environmental problems in the Bor mining area began after the opening of the Bor mine. Long‐term pollution of river water in the Bor and Majdanpek mining areas has an environmental impact on East Europe because all of the river water fr...
Article
Full-text available
Coal fly ash (CFA), a by-product generated from coal-burning power plants, readily leaches toxic elements into aquatic environments. The present study describes a classification system for CFA based on the chemical composition of CFA and leachability of toxic elements, which can promote the safe and effective utilization of CFA for uses such as fly...
Article
In the Tamagawa geothermal area of Akita Prefecture, northern Japan, Obuki spring discharges a large amount of thermal water (∼9000 L/min), which is chloride-rich and acidic (pH 1.2). We have investigated changes in the physico-chemical nature and fractionation mechanisms of rare earth elements (REEs) including Y and actinides (Th and U) in the Shi...
Article
Full-text available
We previously reported that a simple treatment—addition of only small amounts of water to coal fly ash (CFA) to form CFA paste followed by aging for 1–4 weeks—is advantageous for the immobilization of highly soluble B, F, Cr, and As. In this study, we investigated the leachability of Ca, SO4, B, and As over time from non-aged and aged CFA samples t...
Conference Paper
Full-text available
Release of flotation tailings containing Fe-bearing minerals and acidic wastewater containing dissolved metals caused the pollution of rivers downstream from Bor copper mines and metallurgical plants. Dissolved metals from acidic wastewater may change to particulate form by chemical precipitation during the neutralization with natural river water....
Article
Full-text available
Bor, Krivelj, and Bela Rivers belong to the watershed of Timok River, which is a tributary of transboundary Danube River. These rivers receive metal-rich acidic wastewater from metallurgical facilities and acid mine drainage (AMD) from mine wastes around Bor copper mines. The aim of this study was to determine the mobility and natural attenuation o...
Poster
Full-text available
The aim of this study was to determine spatial distribution and mobility of elements in river water and river bed sediments (<180 µm) that were affected by mining and metallurgical activities in Bor and Majdanpek mining areas in eastern Serbia. Geochemical survey was conducted in 2015 and 2016. Total number of sampling points was ~200, with average...
Article
Alternation layered lake sediment that had accumulated over a period of 22 years, from 1990 to 2012, was collected from the Tamagawa Dam Lake, which is located in the northeastern part of Akita Prefecture. The lake water is acidified (pH = 4.1) by the inflow of high-acidic thermal water (pH = 1.2) from the Obuki Hot Spring, the main hot spring in t...
Article
Full-text available
This work assessed both the fractionation and the seasonal mobility variations of Ga and In in systems impacted by acidic thermal waters. This was accomplished by performing thermodynamic calculations using the PHREEQC algorithm and by assessing the activity of acidophilic iron-oxidizing bacteria. The pH of the Kusatsu thermal waters in Gunma Prefe...
Article
Full-text available
The extraction method from soils by water is authorized in the Soil Contamination Law in Japan for heavy metal dissolution risk assessment. However, the applications to rocks are not accepted, although there are several kinds of rocks from which toxic heavy metals are possibly eluted. For examinations, differently from soils, rocks need to be crush...
Article
Full-text available
In hydrothermal alteration area, arsenic and metals included in rocks can be expected to leach out from the outcrops. In order to perform risk assessments of leaching arsenic and metals, it is important to systematically understand the leaching behavior of arsenic and metals from rocks and soils. In this study, the geochemical behavior of arsenic a...
Article
Full-text available
Geochemical discrimination has recently been recognised as a potentially useful proxy for identifying tsunami deposits in addition to classical proxies such as sedimentological and micropalaeontological evidence. However, difficulties remain because it is unclear which elements best discriminate between tsunami and non-tsunami deposits. Herein, we...
Article
Fourteen different alkaline coal fly ashes (CFAs) were used for the experiment, in which each sample was mixed with water to be 28.6 % of water content (wt/wt) and aged for 1-4 weeks at 10-30 °C. This simple treatment is advantageous for decreases in water-soluble B, F, Cr, and As. Compared to non-aged CFAs, their water-soluble fractions remained 0...
Article
Full-text available
The Shozu-gawa River, located in Aomori Prefecture, northern Japan, is affected by volcanic activities and acid thermal waters. The river is unique because both solid arsenic (As; as orpiment, As2S3) and dissolved As are supplied to the river from the uppermost caldera lake (Usori-ko Lake) and thermal ponds. The watershed is an excellent site for i...
Article
During Li recovery from salar brines, Li concentration is typically increased to about 60,000 mg L−1 by evaporation. We investigated the concentration changes of Li, Na, K, Mg, Cl, SO4, and B during evaporation of both natural Uyuni and artificial Atacama brines. The Uyuni brine exhibited a maximum Li concentration of 6810 mg L−1 at 31 days of evap...
Article
Full-text available
Understanding the geochemical characteristics of tsunami deposits assists in revealing the mechanisms of tsunami inundation, assessing environmental risks, and using tsunami deposits industrially. Understanding geochemical characteristics is complex because geochemical compositions result from an accumulation of various known and unknown processes,...
Article
Full-text available
Long-term dissolution experiments from waste dumps that includes marine sediment under both anoxic and aerobic conditions were performed to elucidate the As dissolution mechanism and assess As dissolution risk. Core samples drilled at a waste disposal site in Sendai were collected for the experiment. Almost completely oxidized and partially oxidize...
Article
The Kusatsu and Tamagawa hot springs contain both toxic elements and rare metals used in high-technology industries. High acidity and significant discharge of these springs have led to the construction of dams and neutralization of spring waters by lime addition. However, the same neutralization process causes differing effects in the Kusatsu and T...
Article
Major minerals (sulfates, sulfides, quartz) are distributed in different parts of submarine hydrothermal ore deposits. For instance, the abundance of barite increases stratigraphically upwards in the massive orebodies of the Kuroko deposits (black and yellow ores), while quartz is abundant in the lower parts (siliceous ore). The different distribut...
Article
The Pacific coast of Tohoku District in Northeast Japan (Iwate, Miyagi, and Fukushima Prefectures) was seriously damaged by a violent tsunami resulting from the 2011 off the Pacific coast of Tohoku Earthquake on March 11 2011. The disaster area was covered by tsunami sediments, which are mainly marine sediments. We collected 137 tsunami sediments f...
Article
The Obuki spring is the largest and most acidic of the Tamagawa hot springs (Akita Prefecture, northern Japan), and it discharges ca. 9000 L/min of chloride-rich acidic water (pH 1.2) that contains high concentrations of both As and rare metals such as Ga and In. This paper aims to quantify seasonal variations in the mobility of these elements in t...
Article
We conducted hydrothermal experiments in olivine (Ol; Fo91)–H2O and orthopyroxenite (Opx; composed of 95% of orthopyroxene, En66)–H2O systems under conditions of 250 °C and vapor-saturated pressure (Psat) to examine the temporal evolution of the solution chemistry and products in runs of up to 1008 h in duration. The maximal degree of hydration (i....
Article
Possibilities of polarizing energy dispersive X-ray fluorescence (EDXRF) spectrometry were fully explored to materialize rapid trace element determinations of soil and sediment samples. The pressed powder pellet technique was adopted for sample preparation because of its simplicity. The trace elements examined were V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y,...
Article
Full-text available
The Tsurumi, a class-one Japanese river, has a significant metal loading originating from urban environment. Water and sediment samples were collected from 20 sites in winter and summer, 2009 and were analyzed to determine and compare the extent of different trace element enrichment. A widely used five-step sequential extraction procedure was also...
Article
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As one type of the CCS (Carbon Capture and Storage), “distributed CCS” (DCCS), conducted by injection facilities situated dispersively near CO2 emission sources, has recently attracted attention. This study estimates the storage potential of CO2 of the DCCS into the aquifer in Japan. This study assumes three cases of the storage depth of 50m∼400m,...
Article
Despite environmental and geochemical interests, Cr and Fe have been left beyond the reach of determinations by ICP-MS due to severe interferences originating from Ar. The applicability of a dynamic reaction cell (DRC)-ICP-MS has been examined for determinations in environmental and geochemical samples. The reaction with NH(3) in the DRC system pro...
Article
A rapid simultaneous multi-element analysis method for soils and environmental samples has been established using polarizing energy dispersive X-ray fluorescence (EDXRF) spectrometry. The pressed powder pellet technique was adopted because it is simple and requires no specialized skills for sample preparation. The analytes examined were: Na2O, MgO,...
Article
Full-text available
High-indium ore deposits are associated within the rise tectonic zones of progressive rift-rise structures resulted from the late Cenozoic back-arc spreading of the northern Honshu arc. We examined the indium concentration mechanism around the Hokuroku district, which constitutes one of the typical rift-rise settings. The Tatsumata mine area in the...
Article
In this study, effect of weathering on changes of leaching properties and chemical forms of heavy metals was investigated through a laboratory scale weathering experiment using several geological samples obtained from some outcrop Tatsunokuchi formation which was distributed widely in Tohoku area of Japan as a marine sedimentary layer. At the case...
Article
A total of 122 farmyard manure samples (75 cattle manure, 23 poultry manure and 24 swine manure) collected in Fukushima Prefecture were analyzed for trace elements. The results obtained are summarized as follows: 1) The trace element concentrations were in the order of Na, Fe and Al (the median in all farmyard manure: 4194-4985mg kg^<-1>)>Ti, Mn an...
Article
The global carbon cycle controls the climate change in the Earth's environment on a geological timescale and is mainly associated with greenhouse effects produced by atmospheric carbon dioxide (CO2) and methane (CH4). This paper reviews the relationship between the global carbon cycle and presumed climate events during the Cenozoic. The global carb...
Article
A global carbon–strontium coupled model over the Cenozoic is presented. The carbon cycle includes improvements on the uplift parameter in the Himalayan and Tibetan regions and the hydrothermal flux at back-arc basins from the carbon cycle model of Kashiwagi and Shikazono [Kashiwagi, H., Shikazono, N., 2003. Climate change during the Cenozoic inferr...
Article
The elements existing as "water soluble form" and "ion exchangeable and surface complexed forms" were extracted from weathered slates with different weathering level by water and diluted HNO3 (ca 3%), respectively. The sample (Spl) is almost non-weathered black slate sample. On the contrary, the sample (Sp3) is intensely weathered and oxidized frag...
Article
The Sr, Ba, and rare earth elements (REEs) concentrations and Sr isotopic composition of anhydrite and gypsum have been determined for samples from the Matsumine, Shakanai, and Hanaoka Kuroko-type massive sulfide–sulfate deposits of northern Japan to evaluate the mechanisms of sekko (anhydrite and gypsum) ore formation. The Sr isotopic compositions...
Article
We have developed a GIS-based geosphere integration information system named Geosphere Environmental Informatics for evaluating heavy metal distribution on a national-scale. Geosphere Environmental Informatics includes various geosphere environmental information such as geological map, soil map, vegetation topography, locations of mineral deposits,...
Article
The Sr and rare earth elements (REEs) concentrations and Sr isotopic composition (87Sr/86Sr) of anhydrite and gypsum have been determined for samples from the Matsumine, Shakanai and Hanaoka Kuroko-type massive sulfide-sulfate deposits in the Hokuroku District in Akita Pref. in northern Japan. The anhydrite samples exhibit two styles of chondrite-n...
Article
Full-text available
In this study we investigated the geological and biogeochemical processes that influence groundwater chemistry in the Boso Peninsula, Chiba, central Japan. We also discuss the factors that control groundwater chemistry within a sedimen- tary basin. Saline groundwater is found throughout the study area, while fresh groundwater is distributed unevenl...
Article
Experimental studies on the interactions between artificial seawater (ASW) and fresh rhyolite, perlite and weakly altered dacitic tuff containing a small amount of smectite suggest changing cation transfer during smectite-forming processes. Initially, dissolution of K from the rocks accompanies incorporation of Mg and Ca from ASW during both earlie...

Citations

... The arsenic concentrations in the studied sediment samples vary between 0.02 and 875 mg/kg. Most of the concentrations are below or around the Bulgarian soil normal (10 mg/kg) and Romanian alert (15 mg/kg) values (Figure 2 (Nikolic et al., 2011;Adamovic et al., 2022). The pollution is confined to the Danube right bank in bottom and suspended sediments, while arsenic concentrations are low in the Pristol floodplain sediments (Figure 2). ...
... While the mobility of U in the ecosystem depends on redox conditions (IRNS, 2012) and complexation by organic matter (Bone et al., 2020), with the most stable and mobile form being U(VI), the mobility of Th in soil is very limited due to strong sorption to soil particles (Torstenfelt, 1986). In contrast, the content of REEs in soil is related to redox potential and pH as well as to the presence of clay, carbonate, organic matter, and Al, Fe, and Mn oxides and oxyhydroxides (Aide and Aide, 2012;Felipe-Sotelo et al., 2017;Mihajlovic and Rinklebe, 2018;Aide, 2019;Tang et al., 2020;Ogawa et al., 2021). Their content generally decreases with the decrease of pH, redox potentials, and Al-Mn-Fe contents (Aide and Aide, 2012;Mihajlovic and Rinklebe, 2018;Aide, 2019). ...
... Ogawa et al. also reported that an extremely low-cost process in which FA is mixed with approximately 30 wt% of water and aged for a week is effective in inhibiting the leaching of boron, arsenic, chromium, and fluorine [29,30]. In contrast, Seki et al. reported that the aging treatment reported by Ogawa et al. promoted the leaching of toxic elements for some types of FA samples [31]. Furthermore, in the leachabilities of elements from concrete or cement containing coal ash, Mahedi et al. reported the leaching characteristics of calcium, magnesium, sulfur, manganese, barium, and chromium from cement activated soil-fly ash [32]. ...
... Nieto et al. [22] and Adamovic et.al. [23] noted pollutant transport over significant distances from AMD [22,23]. The total amount of pollutants from mine outflow from the Kizel Coal Basin (for the catchment areas of the Yaiva, Kosva, and Chusovaya Rivers) is 21,455 tons per year of iron, 1128 tons per year of aluminum, and 217 tons per year of manganese [24]. ...
... The leaching behavior of arsenic and selenium over time was examined using three representative R-FAs (R-FA1, R-FA2, and R-FA3) and their C-FAs (C-FA1, Table 2, and their densities, BET-specific surface areas, and particle size distributions are shown in Table 3 and Figure 3. According to the chemical compositions shown in Table 2, the pH of FA samples depends on the content of CaO [41]. The density changed minimally with or without cement mixing. ...
... Several comprehensive reviews of surficial weathering of iron sulfide ore-derived mine tailings in a semi-arid environment have been published over the past decades (Blowes and Jambor, 1990;Jambor, 1994;Jambor and Blowes, 1998;Lindsay et al., 2015). Previous studies have also investigated the geochemical mobility of metals, aqueous rare earth elements, and actinides (i.e., U and Th) in the natural aquatic system (Ogawa et al., 2021;Ogawa et al., 2019). The REEs patterns in groundwater result from complex solid-water interactions and can be applied as process indicators of a post-mining area (Grawunder et al., 2018). ...
... Kashiwakura et al. revealed the removal of boron and arsenic from FA by washing with acid [26,27], and Bhattacharyya et al. demonstrated their stabilization for arsenic, boron, chromium, molybdenum, selenium, and vanadium by adding ferrous sulfate [28]. Ogawa et al. also reported that an extremely low-cost process in which FA is mixed with approximately 30 wt% of water and aged for a week is effective in inhibiting the leaching of boron, arsenic, chromium, and fluorine [29,30]. In contrast, Seki et al. reported that the aging treatment reported by Ogawa et al. promoted the leaching of toxic elements for some types of FA samples [31]. ...
... We hypothesize that the LMCT process plays a role in As(III) oxidation under neutral pH conditions, but with a different contribution and mechanism from that under alkaline pH conditions because of the inadequate formation of Cu(OH) 2 colloid. Since acidic water or wastewater co-contaminated with arsenic and copper is often discharged downstream of copper smelters (Matschullat, 2000), copper mines, and gold mines (Camm et al., 2004;Đorđievski et al., 2018;Milu et al., 2002), the environmental significance of Cu(II) photochemistry may increase with a decrease in the acidity of the medium in natural or engineering systems. ...
... Sorption onto hydrous Al or Fe oxy-hydroxides (HAO or HFO) is an important process for natural attenuation of many elements in acidified aquatic systems (e.g., Gammons et al., 2005aGammons et al., , 2005bGammons et al., , 2005cWood et al., 2006;Schemel et al., 2007;McCleskey et al., 2009;Ogawa et al., 2014;Carrero et al., 2015;Ayora et al., 2016). Sorption onto HAO and HFO is largely dependent on pH and thus aqueous speciation of target metals and their fractionation (Ogawa et al., 2018(Ogawa et al., , 2019. It is also reported that REE fractionation are also caused by differences in the stability of aqueous REE complex with various anions (e.g., Grawunder et al., 2014;Olías et al., 2018;Lozano et al., 2019Lozano et al., , 2020aMunemoto et al., 2020). ...
... After the tsunami disaster of the Great East Japan Earthquake 2011, As contaminated marine sediment that came from the tailing of the abandoned gold mine was brought back to the coast of Kesennuma City, Miyagi Prefecture, located in the subarctic area of Japan. Risk assessments of As in tsunami sediments was conducted, and it was revealed that the water-soluble As concentration in the sediment was higher than Japan Environmental Quality Standard of As as 10 μg/L restricted by Japan Soil Contamination Countermeasures Law (Tsuchiya et al., 2012). ...