December 2024
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3 Reads
Chemical Engineering Journal
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December 2024
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3 Reads
Chemical Engineering Journal
November 2024
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19 Reads
Green Chemistry
Coupling urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) in seawater is desirable to produce sustainable and green hydrogen due to the reduced energy consumption. However, developing high-performance UOR/HER...
November 2024
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6 Reads
Organic molecules with tailorable chemical structures, high stability, and solution processability have great potential in the sensing field. Compared with p‐type organic small molecules (OSMs), the electron‐dominated n‐type analogs show superior conductivity when exposed to reducing gases, which can achieve outstanding sensor signal‐to‐noise ratios. However, inadequate humidity resistance at room temperature hinders the development of such molecules. Herein, an A‐D‐π‐D‐A molecular design strategy is proposed based on electron‐deficient B←N units, which results in effective intramolecular charge transport and sensitive responses by extending the π‐conjugation bridge. As a result, the ST‐2BP with A‐D‐π‐D‐A configuration shows a prominent sensitivity of 787 (Ra/Rg) in 20 ppm NH3 at room temperature and an almost initial and stable response under different relative humidity conditions, which is the highest among currently reported OSM sensors. Supported by theoretical calculations and in situ FTIR spectra, it is revealed that B←N units, which function as the active centers mediate the specific ammonia adsorption. This study provides a new understanding of the design of high‐performance room temperature gas sensing materials by decorating B←N units.
November 2024
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11 Reads
Progress in Natural Science
November 2024
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3 Reads
Journal of Environmental Chemical Engineering
November 2024
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5 Reads
Carbohydrate Polymers
September 2024
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32 Reads
Liquid metal (LM) micro‐nano droplets show the superiority in reducing the high surface tension applicable in conductive inks for flexible electronics. However, the dynamic surface makes LM droplets susceptible to be oxidized, facing challenges in storage and applications. Herein, a bifunctional groups cross‐linking strategy is adopted to encapsulate LM droplets into a robust shell. During sonicating LM in carboxymethyl chitosan (CMCS) solution with bifunctional groups (i.e., carboxyl and amino groups), a robust interface shell is constructed by anchoring effect, thereby providing high chemical stability (>7d). When directionally freezing‐drying LM dispersions, aerogel with Janus architecture is produced driven by the gravity of LM droplets. Due to the unique heterogeneous structure, the resultant aerogel exhibits a selective multifunctional response toward directional bending. In addition, owing to the gradient distribution of CMCS within aerogel, moisture electricity generator can be built with a high output voltage of 460 mV. Thus, this bifunctional groups cross‐linking strategy not only improves the chemical stability of LM micro‐nano droplets, but also renders a new method for producing multifunctional aerogel with energy harvesting and selective directional recognition, and applicable in smart sensors and power supplying devices.
September 2024
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4 Reads
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2 Citations
Journal of Power Sources
September 2024
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10 Reads
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3 Citations
July 2024
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2 Reads
ACS Applied Polymer Materials
... As shown in Figure 2d, the commercial Celgard 2400 separator underwent rapid decomposition at 350-500 • C with a weight loss of 97.4%. The thermal decomposition of the CA separator was divided into four main stages: the dissipation of crystalline water from the fibers (50-190 • C), decarboxylation and glycosidic bond cleavage (190-420 • C), char layer and CaCO 3 formation (420-550 • C), and CaCO 3 decomposition to CaO (550-800 • C) [23,24], with a residue of 28.1%. The thermal decomposition process in the coated separator was essentially the same as in the CA separator, with simultaneous PVDF decomposition at 420-550 • C [25] and no additional decomposition stages. ...
June 2024
Polymer Degradation and Stability
... For example, Yang and their team developed a novel curcumin-loaded lysine-modified alginate film reinforced by lignosulfonic acid that leverages the pH-sensitive color change properties of curcumin to provide an effective and reliable means of monitoring shrimp freshness (M. Yang et al., 2024). By visually indicating shrimp spoilage through a color change, curcumin typically shifts from yellow to red or brown as the pH increases, indicating spoilage. ...
June 2024
Food Packaging and Shelf Life
... For ease of fitting, both sides of the equation are obtained by taking the logarithm of each side [44,45]: ...
February 2024
Journal of Colloid and Interface Science
... The flame retardancy of polymeric materials was characterized by the limiting oxygen index (LOI), the vertical burning (UL94) and the cone calorimeter tests, the results were shown in Table 1 and Fig. 6 (d-f). The LOI value is the minimum concentration of oxygen that maintains the sample burning for a specified time or distance (Wang et al. 2024). As shown in Table 1, the LOI value of the SA aerogel was merely 20.5%. ...
December 2023
International Journal of Biological Macromolecules
... Broadly, the impact of Fcontaining materials on PSCs can be summarized in three aspects: 1) utilizing the coordination ability of F to passivate defects, thereby reducing nonradiative recombination and improving the quality of perovskite films; 2) using the polarization ability of F to induce the formation of interface dipoles, which improves the interface WF and enhances the transport capacity of charge carriers; and 3) employing the strong hydrophobic nature of F to improve the resistance of PSCs to moisture/oxygen, enhancing the long-term stability of devices. [115] While the incorporation of F-containing materials is a promising approach to boost both the photoelectric performance and the durability of perovskites, several challenges remain. This review identifies potential hurdles and avenues for future improvement, including: 1) using molecular engineering to reasonably select and adjust molecular configurations, comprehensively considering the effects of electronegativity and steric hindrance on perovskites; 2) fine-tuning addition of F-containing materials and controlling factors such as annealing temperature to optimize the interaction between F-containing molecules and perovskite, thereby improving the crystallization process; 3) addressing the potential toxicity and environmental unfriendly issues associated with F-containing materials by ensuring proper devices encapsulation to prevent leakage and mitigate environmental impacts. ...
February 2024
International Journal of Biological Macromolecules
... A variety of novel materials was incorporated to enhance the flame retardant properties of cellulose nanofiber composite foams, such as flame retardant polymers and inorganic fillers (Sáez De Guinoa et al. 2017;Chen et al. 2020;Yang et al. 2022;Liu et al. 2024). For instance, Xu et al. (2023) used biodegradable binder PVA and biguanide phosphonate (BGP) to construct CNFs-based aerogel with a threedimensional network of KF tubular structure, which had high flame retardancy. ...
December 2023
Carbohydrate Polymers
... The density states of ZnSe/CoSe, ZnSe, and CoSe were also calculated ( Fig. 7j-l). It is noted the ZnSe/CoSe demonstrates the elimination of the bandgap and the higher density of state with strong electron delocalization around the Fermi level (Fig. 7j), suggesting that the formation of the heterointerface of ZnSe/CoSe enhances electrical conductivity compared with bare ZnSe and CoSe [52][53][54][55][56][57]. Figure 8a, b show charge density difference models to investigate the binding characteristics of the adsorbed Na atoms. Compared with ZnSe and CoSe, there is stronger electronic interaction when Na adsorbed on ZnSe/CoSe heterostructure, revealing the heterostructure is more favorable for trapping sodium, which will contribute to higher redox reaction activity. ...
November 2023
Advanced Composites and Hybrid Materials
... Polymers 2024, 16, 2021 2 of 36 muscles and organs, sensors, wound dressings, soft robotics, food packaging or environmental applications. The properties and functions required for a particular application can be fine-tuned by a careful selection of the crosslinking method, PVA characteristics and of other used components for preparing high-performance composites [2][3][4][5][6][7][8][9][10]. ...
August 2023
... Since the carboxyl groups in the G segment of alginate can chelate with Ga 3+ , a thin layer of gallium alginate gel can uniformly cover the surface of MLM droplets (Figs. S7 and S8) [33][34][35]. The formation mechanism is explained in the supporting information. ...
August 2023
... Chitosan is a deacetylated chitin derivative that is non-toxic, biocompatible, and can be applied as a coating material to create a water-repellent or waterproof [70,71]. Chitosanbased coating materials were applied via dispersion casting directly onto carrageenan/ZnO composite films [71] and pectin films [64]. ...
May 2023
Langmuir