Yanzhi Xia’s research while affiliated with Qingdao University and other places

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Publications (330)


Highly efficient solar seawater evaporation by aerogel with vertical channels and hierarchical pores structure based on high-absorbent alginate fibers
  • Article

December 2024

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3 Reads

Chemical Engineering Journal

Zihan Guo

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Chen Hang

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Kai Li

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[...]

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Yanzhi Xia

(B,P,Co,Fe)-Ni Modified on Nanowood for Boosting Seawater Urea Electro-Oxidation
  • Article
  • Full-text available

November 2024

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19 Reads

Green Chemistry

Coupling urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) in seawater is desirable to produce sustainable and green hydrogen due to the reduced energy consumption. However, developing high-performance UOR/HER...

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Various magnification TEM images of a−c) ST‐2BP and e−g) ST‐BP (insets: fast Fourier transform patterns of the corresponding images, the lattice fringe image presented by Fourier transform, and the corresponding lattice spacing profile). d) SEM images and EDS mapping of ST‐2BP.
a−c) UV–vis DRS, cyclic voltammetric curves, and schematic representation of the LUMO/HOMO energy alignments of ST‐2BP, ST‐BP, and ST. d) Optimized molecular structure and the Mulliken charges on main atoms. e) Calculated adsorption energy of ST‐2BP and ST‐BP for NH3. f) Electron localization function (Left) and Orbit weight Fukui function (Right, Blue, and purple represent the positive and negative parts, respectively). The total density of states (TDOSs, purple lines), the partitional density of states (PDOSs) of C (green lines) and O (pink lines) for g) ST‐2BP and h) ST‐BP.
UV–vis spectra of a) ST‐2BP and b) ST‐2BP‐NH3 obtained through theoretical calculation and testing. c) Kohn–Sham molecular orbitals of ST‐2BP and ST‐2BP‐NH3, together with the wavelengths and oscillator strengths for the S0→S1, S0→S2, S0→S3, and S0→S5 transitions, based on the DFT calculations.
a) Normalized response–recovery time curves and b) sensing response values of ST‐2BP, ST‐BP, BP, and ST at room temperature (20 ppm NH3). c) Sensing current of ST‐2BP to 6 types of interfering gases (20 ppm). d) Sensing response curve of ST‐2BP to NH3 (1−40 ppm) (inset: The response value is linearly related to the NH3 concentration). e) Relationships between the sensor responses and NH3 concentrations. f) The cycling stability of the ST‐2BP sensor to 20 ppm NH3. g) The current (I)−voltage (V) curves. h) Response of the sensors to 20 ppm NH3 under different humidity levels (saturated salt solution for regulating relative humidity inset). i) The sensing response and corresponding NH3 concentration of reported OSMs and ST‐2BP (this work). (each experiment was independently tested three times; sample size n = 3; mean ± standard deviation (mean ± SD) was analyzed using Origin software; SD reflects the degree of dispersion among individual samples; a small SD means that the value of the test is close to the average; the P‐value indicates significant differences: ST‐2BP to BP: P < 0.0001; ST‐BP to BP: P < 0.0001; the statistical test was two‐sided testing, the α‐value was 0.05 and related P‐values were analyzed by a Student's two‐side test of GraphPad Prism software; P‐values less than 0.0001 indicate that the differences between ST‐2BP to BP and ST‐BP to BP is particularly significant).
The FTIR spectra of a) ST‐2BP and d) ST‐BP before and after adsorption of NH3 in theoretical calculations. The in situ FTIR spectra of ST‐2BP after b) adsorption and c) desorption of NH3. The in situ FTIR spectra of ST‐BP after e) adsorption and f) desorption of NH3. g) EPR spectra of molecules before and after NH3 adsorption. h) Schematic diagram of NH3 adsorption and desorption process.

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Electron‐Deficient Organic Molecules Based on B←N Unit: A N‐Type Room‐Temperature Chemiresistive Sensors with Moisture Resistance

November 2024

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6 Reads

Organic molecules with tailorable chemical structures, high stability, and solution processability have great potential in the sensing field. Compared with p‐type organic small molecules (OSMs), the electron‐dominated n‐type analogs show superior conductivity when exposed to reducing gases, which can achieve outstanding sensor signal‐to‐noise ratios. However, inadequate humidity resistance at room temperature hinders the development of such molecules. Herein, an A‐D‐π‐D‐A molecular design strategy is proposed based on electron‐deficient B←N units, which results in effective intramolecular charge transport and sensitive responses by extending the π‐conjugation bridge. As a result, the ST‐2BP with A‐D‐π‐D‐A configuration shows a prominent sensitivity of 787 (Ra/Rg) in 20 ppm NH3 at room temperature and an almost initial and stable response under different relative humidity conditions, which is the highest among currently reported OSM sensors. Supported by theoretical calculations and in situ FTIR spectra, it is revealed that B←N units, which function as the active centers mediate the specific ammonia adsorption. This study provides a new understanding of the design of high‐performance room temperature gas sensing materials by decorating B←N units.





Fabrication of LM aerogel and mechanism illustration. a) Schematic illustration of fabrication process of LM micro‐nano droplets in CMCS solution b) TEM image of the LM droplet with shell and formation mechanism. The dispersion composed of LM micro‐nano droplets is given as the inset. c) Fabrication of LM aerogel by directional freezing. d) Optical and SEM images of LM aerogel. e) FTIR spectra of CMCS and LM aerogel. f) Schematic demonstration of bimetallic chelation strategy.
Formation mechanism and performance of LM aerogel with a Janus structure. a) Schematic illustration of the movement of LM micro‐nano droplets during directional freezing‐drying. b) SEM image of top surface of the LM aerogel. c) Partial enlarged SEM image of the aerogel wall, showing LM droplets within CMCS layer. d,e) SEM images of upper surface d) and bottom surface e) and their size distribution histograms. f) Schematic diagram of LM aerogel with Janus structure. g) Water‐resistant property of CMCS aerogel, LM aerogel and Ca²⁺‐cross‐linked LM aerogel.
Sensing performance of LM aerogel. a) Sensing mechanism of Janus aerogel during bending process. b) Resistance changes of Janus aerogel under different bending directions. c) Photograph and resistance changes corresponding to different finger bending angles. d) Dependence of relative resistance on inward and outward bending. e) Sensing test by attaching LM‐rich layer toward wrist.
Photo‐thermal and energy‐harvesting performance of LM aerogel. a) Schematic diagram of photo‐thermal energy conversion for LM aerogel. b) Surface temperature evolution curves of LM aerogel (LM: 50 wt.%) under different power densities. c) Infrared image of LM aerogel under solar irradiation of 200 mW cm‒2. d) Maximum temperatures of LM aerogel with different LM contents. e) Comparison of maximum temperature for LM aerogel with other photo‐thermal materials under solar irradiation of 100 and 200 mW cm⁻². f) Open‐circuit voltage of generator for LM aerogel (LM: 50 wt.%) under different power densities. g) Maximum output voltage of aerogel with different LM contents. h) The cycle stability of energy generator under solar irradiation of 100 mW cm⁻².
Moisture‐electricity generation of LM aerogel. a) Electricity generation mechanism of LM aerogel. b) Voc variation upon exposing LM aerogel to moist environment with different RHs. Thickness: 2 mm. c) Effect of thickness on Voc. RH: 99%. d) Photograph and Voc variation when exposing to respiration (LM aerogel is integrated on a commercial mask). e) Long‐term moisture‐induced electricity generation performance of LM aerogel with a RH of 99%.
Liquid Metal Aerogel With Janus Architecture for Selective Direction Recognition and High‐Efficiency Moisture Energy Harvesting

September 2024

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32 Reads

Liquid metal (LM) micro‐nano droplets show the superiority in reducing the high surface tension applicable in conductive inks for flexible electronics. However, the dynamic surface makes LM droplets susceptible to be oxidized, facing challenges in storage and applications. Herein, a bifunctional groups cross‐linking strategy is adopted to encapsulate LM droplets into a robust shell. During sonicating LM in carboxymethyl chitosan (CMCS) solution with bifunctional groups (i.e., carboxyl and amino groups), a robust interface shell is constructed by anchoring effect, thereby providing high chemical stability (>7d). When directionally freezing‐drying LM dispersions, aerogel with Janus architecture is produced driven by the gravity of LM droplets. Due to the unique heterogeneous structure, the resultant aerogel exhibits a selective multifunctional response toward directional bending. In addition, owing to the gradient distribution of CMCS within aerogel, moisture electricity generator can be built with a high output voltage of 460 mV. Thus, this bifunctional groups cross‐linking strategy not only improves the chemical stability of LM micro‐nano droplets, but also renders a new method for producing multifunctional aerogel with energy harvesting and selective directional recognition, and applicable in smart sensors and power supplying devices.





Citations (56)


... As shown in Figure 2d, the commercial Celgard 2400 separator underwent rapid decomposition at 350-500 • C with a weight loss of 97.4%. The thermal decomposition of the CA separator was divided into four main stages: the dissipation of crystalline water from the fibers (50-190 • C), decarboxylation and glycosidic bond cleavage (190-420 • C), char layer and CaCO 3 formation (420-550 • C), and CaCO 3 decomposition to CaO (550-800 • C) [23,24], with a residue of 28.1%. The thermal decomposition process in the coated separator was essentially the same as in the CA separator, with simultaneous PVDF decomposition at 420-550 • C [25] and no additional decomposition stages. ...

Reference:

Calcium Alginate Fibers/Boron Nitride Composite Lithium-Ion Battery Separators with Excellent Thermal Stability and Cycling Performance
Synergistic Flame Retardancy of Metal-ion/Nitrogen in Composite Fibers Prepared from All-Seaweed Biomass.
  • Citing Article
  • June 2024

Polymer Degradation and Stability

... For example, Yang and their team developed a novel curcumin-loaded lysine-modified alginate film reinforced by lignosulfonic acid that leverages the pH-sensitive color change properties of curcumin to provide an effective and reliable means of monitoring shrimp freshness (M. Yang et al., 2024). By visually indicating shrimp spoilage through a color change, curcumin typically shifts from yellow to red or brown as the pH increases, indicating spoilage. ...

Development of a novel curcumin loaded lysine modified alginate intelligent film reinforced by lignosulfonic acid with high color stability for monitoring shrimp freshness
  • Citing Article
  • June 2024

Food Packaging and Shelf Life

... For ease of fitting, both sides of the equation are obtained by taking the logarithm of each side [44,45]: ...

Core-shell heterostructured Ni(OH)2@activation Zn-Co-Ni layered double hydroxides electrode for flexible all-solid-state coaxial fiber-shaped asymmetric supercapacitors
  • Citing Article
  • February 2024

Journal of Colloid and Interface Science

... The flame retardancy of polymeric materials was characterized by the limiting oxygen index (LOI), the vertical burning (UL94) and the cone calorimeter tests, the results were shown in Table 1 and Fig. 6 (d-f). The LOI value is the minimum concentration of oxygen that maintains the sample burning for a specified time or distance (Wang et al. 2024). As shown in Table 1, the LOI value of the SA aerogel was merely 20.5%. ...

Preparation of high-strength photochromic alginate fibers based on the study flame-retardant properties
  • Citing Article
  • December 2023

International Journal of Biological Macromolecules

... Broadly, the impact of Fcontaining materials on PSCs can be summarized in three aspects: 1) utilizing the coordination ability of F to passivate defects, thereby reducing nonradiative recombination and improving the quality of perovskite films; 2) using the polarization ability of F to induce the formation of interface dipoles, which improves the interface WF and enhances the transport capacity of charge carriers; and 3) employing the strong hydrophobic nature of F to improve the resistance of PSCs to moisture/oxygen, enhancing the long-term stability of devices. [115] While the incorporation of F-containing materials is a promising approach to boost both the photoelectric performance and the durability of perovskites, several challenges remain. This review identifies potential hurdles and avenues for future improvement, including: 1) using molecular engineering to reasonably select and adjust molecular configurations, comprehensively considering the effects of electronegativity and steric hindrance on perovskites; 2) fine-tuning addition of F-containing materials and controlling factors such as annealing temperature to optimize the interaction between F-containing molecules and perovskite, thereby improving the crystallization process; 3) addressing the potential toxicity and environmental unfriendly issues associated with F-containing materials by ensuring proper devices encapsulation to prevent leakage and mitigate environmental impacts. ...

Effect of the pre-crosslinking of Ba2+ ions on wet spinning of agar fibers
  • Citing Article
  • February 2024

International Journal of Biological Macromolecules

... A variety of novel materials was incorporated to enhance the flame retardant properties of cellulose nanofiber composite foams, such as flame retardant polymers and inorganic fillers (Sáez De Guinoa et al. 2017;Chen et al. 2020;Yang et al. 2022;Liu et al. 2024). For instance, Xu et al. (2023) used biodegradable binder PVA and biguanide phosphonate (BGP) to construct CNFs-based aerogel with a threedimensional network of KF tubular structure, which had high flame retardancy. ...

Lightweight, flame retardant Janus carboxymethyl cellulose aerogel with fire-warning properties for smart sensor
  • Citing Article
  • December 2023

Carbohydrate Polymers

... The density states of ZnSe/CoSe, ZnSe, and CoSe were also calculated ( Fig. 7j-l). It is noted the ZnSe/CoSe demonstrates the elimination of the bandgap and the higher density of state with strong electron delocalization around the Fermi level (Fig. 7j), suggesting that the formation of the heterointerface of ZnSe/CoSe enhances electrical conductivity compared with bare ZnSe and CoSe [52][53][54][55][56][57]. Figure 8a, b show charge density difference models to investigate the binding characteristics of the adsorbed Na atoms. Compared with ZnSe and CoSe, there is stronger electronic interaction when Na adsorbed on ZnSe/CoSe heterostructure, revealing the heterostructure is more favorable for trapping sodium, which will contribute to higher redox reaction activity. ...

Surface sulfidation of NiCo-layered double-hydroxide nanosheets for flexible all-solid-state fiber-shaped asymmetric supercapacitors

Advanced Composites and Hybrid Materials

... Polymers 2024, 16, 2021 2 of 36 muscles and organs, sensors, wound dressings, soft robotics, food packaging or environmental applications. The properties and functions required for a particular application can be fine-tuned by a careful selection of the crosslinking method, PVA characteristics and of other used components for preparing high-performance composites [2][3][4][5][6][7][8][9][10]. ...

Skin-like cryogel electronics from suppressed-freezing tuned polymer amorphization

... Since the carboxyl groups in the G segment of alginate can chelate with Ga 3+ , a thin layer of gallium alginate gel can uniformly cover the surface of MLM droplets (Figs. S7 and S8) [33][34][35]. The formation mechanism is explained in the supporting information. ...

Versatile Liquid Metal/Alginate Composite Fibers with Enhanced Flame Retardancy and Triboelectric Performance for Smart Wearable Textiles

... Chitosan is a deacetylated chitin derivative that is non-toxic, biocompatible, and can be applied as a coating material to create a water-repellent or waterproof [70,71]. Chitosanbased coating materials were applied via dispersion casting directly onto carrageenan/ZnO composite films [71] and pectin films [64]. ...

Fabrication and Characterization of Carrageenan/ZnO/Chitosan Composite Films
  • Citing Article
  • May 2023

Langmuir