Yakun Guo’s research while affiliated with China Academy of Engineering Physics and other places

What is this page?


This page lists works of an author who doesn't have a ResearchGate profile or hasn't added the works to their profile yet. It is automatically generated from public (personal) data to further our legitimate goal of comprehensive and accurate scientific recordkeeping. If you are this author and want this page removed, please let us know.

Publications (19)


Fabrication of a novel Pd/h-BN/Nb composite membrane and investigation on the impact of h-BN on the hydrogen permeation character and stability
  • Article

June 2025

·

4 Reads

International Journal of Hydrogen Energy

Na Lin

·

Qi Dan

·

WenSheng Ren

·

[...]

·

Changan Chen


Selective hydrogenation of nitroaromatics catalyzed by surface Pt-rich high-entropy alloy catalysts at room temperature

January 2025

·

12 Reads

Catalysis Science & Technology

A high-entropy alloy with a surface Pt-rich structure for efficient selective hydrogenation of p -chloronitrobenzene at room temperature.


Hydrogenation of aromatics by PdPtRuCuNi HEA catalyst at room temperature
a The hydrogenation schematic of solid DEB molecules catalyzed by Pd (left) and PdPtRuCuNi HEA (right) catalysts at 25 °C under ≤1 bar H2. b The conversion of different liquid and solid aromatics at 25 °C under 10 bar H2 in a solvent-free state. Liquid reaction condition: 40 mg PdPtRuCuNi HEA/CNFs, 3 mL toluene, styrene, or phenylacetylene, 10 h. Solid reaction condition: 10 mg PdPtRuCuNi HEA/CNFs, 30 mg biphenyl or diphenylacetylene, 36 h.
Characterization of PdPtRuCuNi/CNFs
a,b The morphologies. c HRTEM images. d EDS mapping. e XRD pattern. f-j The high-resolution XPS spectra of PdPtRuCuNi HEA and monometal catalyst. f Pd 3d, g Pt 4 f, h Ru 3p, i Cu 2p, and j Ni 2p.
The hydrogenation performances of DEB catalyzed by PdPtRuCuNi/CNFs and Pd/CNFs at 25 °C under ≤ 1 bar H2
a The final hydrogen uptake capacities of PdPtRuCuNi/CNFs-DEB and Pd/CNFs-DEB composites compared with catalysts themselves. b The final hydrogen uptake capacities of commercial Pd/C-DEB, Ru/C-DEB compared with PdPtRuCuNi/CNFs-DEB. c The hydrogen uptake curves with time at different temperature. d The curves of hydrogen uptake and reaction time of PdPtRuCuNi/CNFs-DEB and Pd/CNFs-DEB. e¹³C NMR spectra of DEB before and after hydrogenation. f The conversion of C-C unsaturated bonds (alkynyl and phenyl groups) in the hydrogenated DEB molecules.
The synergistic catalytic effect of PdPtRuCuNi HEA
a The reaction rates of the DEB-contained composites catalyzed by quaternary and quinary catalysts. b The overall conversion of C-C unsaturated bonds in DEB and the relative conversion of alkynyl (pink) and phenyl (blue) groups. c¹³C NMR spectra of DEB before and after hydrogenation. d The yields of different hydrogenated DEB products.
DFT calculation of H2 and phenylacetylene over the PdPtRuCuNi (111) surface
a Binding energies of dissociated H species at the hollow and bridge sites of a representative PdPtRuCuNi slab (upper panel) and at the hollow (with subscript “h”) and bridge (with subscript “b”) sites of Pd, Pt, Ru, Cu, Ni slabs (lower panel). b The absorption energy of PhA over the (111) surface of PdPtRuCuNi (above) and Pd, Pt, Ru, Cu, Ni (below) catalysts. c The first-step hydrogenation reaction barriers of the alkynyl and phenyl groups in PhA over PdPtRuCuNi (111). d The first-step hydrogenation reaction barriers of the phenyl groups in phenylethane over PdPtRuCuNi (111), Pd (111), and Ru (111). e Reaction pathways for the hydrogenation of DEB over PdPtRuCuNi HEA nanocatalysts.

+1

Ambient hydrogenation of solid aromatics enabled by a high entropy alloy nanocatalyst
  • Article
  • Full-text available

July 2024

·

103 Reads

·

14 Citations

Hydrogenation is a versatile chemical process with significant applications in various industries, including food production, petrochemical refining, pharmaceuticals, and hydrogen carriers/safety. Traditional hydrogenation of aromatics, hindered by the stable π-conjugated phenyl ring structures, typically requires high temperatures and pressures, making ambient hydrogenation a grand challenge. Herein, we introduce a PdPtRuCuNi high entropy alloy (HEA) nanocatalyst, achieving an exceptional 100% hydrogenation of carbon-carbon unsaturated bonds, including alkynyl and phenyl groups, in solid 1,4-bis(phenylethynyl)benzene (DEB) at 25 °C under ≤1 bar H2 and solventless condition. This results in a threefold higher hydrogen uptake for DEB-contained composites compared to conventional Pd catalysts, which can only hydrogenate the alkynyl groups with a ~ 27% conversion of DEB. Our experimental results, complemented by theoretical calculations, reveal that PdPtRu alloy is highly active and crucial in enabling the hydrogenation of phenyl groups, while all five elements work synergistically to regulate the reaction rate. Remarkably, this newly developed catalyst also achieves nearly 100% reactivity for ambient hydrogenation of a broad range of aromatics, suggesting its universal effectiveness. Our research uncovers a novel material platform and catalyst design principle for efficient and general hydrogenation. The multi-element synergy in HEA also promises unique catalytic behaviors beyond hydrogenation applications.

Download





Nitrogen-doped carbon foams with high Pd dispersion for efficient solid phase catalytic hydrogenation of 1,4-bis(phenylethynyl)benzene

December 2022

·

7 Reads

Materials Today Communications

To solve the problems of hydrogen embrittlement and explosion risk generated by the use of hydrogen energy in large-scale applications, organic hydrogen getters have been used to eliminate hydrogen in sealed systems and related fields. However, the hydrogen absorption rate of existing hydrogen getters needs to be further improved. Herein, a three-dimensional (3D) N-doped carbon with interconnected hierarchical pores loaded with a uniform dispersion of palladium particles (6.8 nm) was successfully developed. This material was used as a catalyst for 1,4-bis(phenylethynyl)benzene (DEB) hydrogenation under mild conditions, exhibiting good catalytic performance. The hydrogen uptake performance of this Pd/MFC/DEB getter for the reduction of hydrogen gas was examined at 0 – 1 bar and 25 ℃ with hydrogen consumption evaluated with time. The prepared Pd/MFC/DEB getter demonstrated a hydrogen uptake of 212.2 cm³/g after about 20 h, which was significantly higher than that of a typical Pd/AC/DEB pallet getter (162.0 cm³/g). This was due to the interactions between the Pd and MFC support, which enhanced the dispersion of Pd, increased the area available for the reaction with DEB, promoted the hydrogen dissociation process, and improved the hydrogen spillover effect. This research offers a highly promising approach for the use of MFC as a catalyst support material in hydrogen getters.


Effects of preparation temperature on alkynyl-functionalized graphene oxide

May 2022

·

14 Reads

·

2 Citations

Fullerenes Nanotubes and Carbon Nanostructures

Alkynyl-functionalized graphene oxide (GO) is an attractive nanomaterial for many applications. Controlling the functionalization of GO is essential for the design of GO derivatives with novel properties. Here, we reported a new strategy to conveniently control the degree of alkynyl-functionalization of GO by manipulating the reaction temperature. The alkynyl-functionalized GO was characterized via Zeta potential, Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray diffraction, and Thermogravimetric analysis, confirming the covalent modification of the GO surface with propargylamine. The results showed that GO was successfully functionalized by propargylamine. And the degree of alkynyl-functionalization of GO increases with the increase in reaction temperature. The effects of the temperature on the mechanism of alkynyl-functionalized GO were also revealed. This method could be exploited to prepare functional GO with potential applications in many fields.


Citations (10)


... Figure 6c and Supplementary Table 8 compare the hydrogen uptake capacity of DEB-containing composites using Pd and Pd-based multifunctional catalysts. Our PdPtRu-contained nanocatalysts exhibit the highest catalytic activity for DEB than other Pd catalysts [22][23][24]47,48 . ...

Reference:

Ambient hydrogenation of solid aromatics enabled by a high entropy alloy nanocatalyst
Ultrathin flexible hydrogen getter films with excellent hydrogen uptake and mechanical properties

International Journal of Hydrogen Energy

... After high doses radiation exposure polymeric chains could undergo destruction, with further-as a consequence of the polymer chains breaking-free radicals creation [61]. While natural rubber (NR) constitute unique compound in the flexible nanocomposite development, it is susceptible to degradation-for instance, in Ref. [62] the natural rubber latex (NRL) film was analyzed in terms of degradation after radiation exposure, where the changes in physical properties with the greater dose occured (the reduction in tensile strength and elongation at break). The mechanical properties due to gamma and UV irradiation of epoxy resin with ZnO particles addition have also deteriorated, where it was stated, that the strength has decreased by at least 45% [63]. ...

Post-irradiation degradation of radio-oxidized natural rubber latex films induced by 60Co gamma rays
  • Citing Article
  • May 2023

Radiation Physics and Chemistry

... In an experimental study, Shi and Maimaitiyiming reported that a three-dimensional porous structure including nitrogen, phosphorus and sulfur dopants for as efficient bifunctional electrocatalysts for direct methanol fuel cell [39]. Another experimental study reported by Zhao et al. that consisted of Pd doped three-dimensional graphene aerogel for hydrogen adsorption [40]. ...

Three-dimensional layered porous graphene aerogel hydrogen getters
  • Citing Article
  • April 2022

International Journal of Hydrogen Energy

... The SEM micrographs of SAT-based coatings displayed a relatively smooth surface topography, before and after UV irradiation, except for SAT50-5EG where the surface was covered with some relatively wide microcracks ( Figure S7). We observed that UV irradiation slightly reorganized the surface morphology of the films, in agreement with the previous literature, 50,51 particularly for the amphiphilic SACbased coatings. ...

Improving mechanical and water vapor barrier properties of the parylene C film by UV-curable polyurethane acrylate coating

... A quadrupole mass spectrometer (QMS) was used to track the ion current of D 2 (mass 4) at the downstream. Before the measurement was taken, the D 2 signal was calibrated using a D 2 standard leak to determine the relationship between leakage and ion current [38]. The steady-state deuterium permeation fluence that passes through the samples was calculated as follows [39]: ...

Deuterium Gas-Driven Permeation and Retention Through Tungsten-Coated CLAM Steel
  • Citing Article
  • February 2020

Fusion Science & Technology

Zhanlei Wang

·

Kaigui Zhu

·

Wei Wang

·

[...]

·

Chang An Chen

... Small-angle X-ray Scattering (SAXS) was used to evaluate the microphase separation structure of SEBS. Preparation of DEB-Pd/C DEB-Pd/C was produced by ball milling DEB and Pd/C [25]. The methods of preparation are shown in Supporting Information. ...

Fabrication of highly dispersed Pd nanoparticles supported on reduced graphene oxide for solid phase catalytic hydrogenation of 1,4-bis(phenylethynyl) benzene
  • Citing Article
  • February 2020

International Journal of Hydrogen Energy

... To verify the reliability of the existing data, the niobium film diffusivity (Figure c) and permeability (Figure d) obtained in this study were compared with the existing literature. The deuterium permeability results we observed are roughly in agreement with Steward and Guo's work [21,22], lower than Liu's by about 1 orders of magnitude [17]. While the diffusivity is roughly consistent with Guo's results, it is significantly lower than Steward's and Liu's by about 3 orders of magnitude. ...

The effect of surface oxides and grain sizes on the deuterium permeation behavior of niobium membranes
  • Citing Article
  • October 2019

Fusion Engineering and Design

... Because tritium is The Journal of Chemical Physics ARTICLE pubs.aip.org/aip/jcp one of the main transmutation products in RAFM, 19,[29][30][31] various experiments have been conducted to measure its permeability and investigate the trapping of hydrogen isotopes in RAFM. 18,19,30 Recently, Nakamura et al. 32 and Shimada and Pawelko 33 directly measured the permeability of tritium in tungsten. ...

Diffusion of hydrogen in China Reduced Activation Ferritic-martensitic steels at low temperatures
  • Citing Article
  • June 2019

Fusion Engineering and Design

... The strategy to increase the efficiency and rate of DA-based self-healing processes through the photothermal effect of graphene has also been employed in epoxy/ graphene and polyacrylonitrile/graphene nanocomposites [104][105][106][107]. In a very interesting and innovative study, Jiang et al. demonstrated the efficacy of this strategy to design functional devices with highly sophisticated 3D structures in DA-epoxy networks. ...

Infrared induced repeatable self-healing and removability of mechanically enhanced graphene–epoxy flexible materials

... This is mainly due to the conditions at which the polymer will heal. Healing of the most applicable agent glycidyl methacrylate (GMA) with a modified aliphatic polyamine latent curing agent (EH-4360S) in an epoxy matrix, would require the 20 pole to be heated to 120 o C for 48 hours to return to 90% material integrity [21][22][23]. While this is not feasible today, self-healing polymers could be on the horizon for pole vault. ...

Damage indication of 2′, 7′-dichlorofluorescein for epoxy polymer and the effect of water on its damage indicating ability