Xuecai Han’s research while affiliated with Institute of Scientific and Technical Information of China and other places

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Publications (7)


Temperature-controlled DCP Fluorescent Probe Based on Hydrogel-immobilized Quantum Dots Composite
  • Article

July 2024

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2 Reads

Journal of Wuhan University of Technology-Mater Sci Ed

Yilin Tong

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Kun Yang

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Xuecai Han

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[...]

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Jiaqi Bao

A composite was created by incorporating the quantum dot-enhanced SiO2 nanoparticles within this hydrogel. Based on this composite, a temperature-controlled fluorescent probe for DCP was developed. A meticulous examination of this probe revealed its attributes and factors affecting its performance. By using temperature modulation, the probe was adept at detecting DCP concentrations ranging between 1.0×10−6 and 9.0×10−6 mol/L. Such a probe offers remarkable selectivity, repeatability, and robust stability, so that the detection of DCP can be carried out at different temperatures, and a fast, reliable, sensitive and low-cost intelligent detection method is realized.


A Fiber Optic Sensor for the Simultaneous Measurement of Dual-parameter Based on Hydrogel-immobilized Enzyme Complex

November 2023

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23 Reads

Journal of Wuhan University of Technology-Mater Sci Ed

A novel fiber optic sensor based on hydrogel-immobilized enzyme complex was developed for the simultaneous measurement of dual- parameter, the leap from a single parameter detecting fiber optic sensor to a fiber optic sensor that can continuously detect two kinds of parameters was achieved. By controlling the temperature from high to low, the function of fiber sulfide sensor and fiber DCP sensor can be realized, so as to realize the continuous detection of dual-parameter. The different variables affecting the sensor performance were evaluated and optimized. Under the optimal conditions, the response curves, linear detection ranges, detection limits and response times of the dual-parameter sensor for testing sulfide and DCP were obtained, respectively. The sensor displays high selectivity, good repeatability and stability, which have good potentials in analyzing sulfide and DCP concentration of practical water samples.



Figure 2. SEM image of Fe (III) PcTs 3.3. XRD pattern of Iron(III) Tetrasulfophthalocyanine 2 θ XRD pattern of Fe (III) PcTs in the range from 5 o to 30 o was shown inFigure3, which presented the strongest characteristic diffraction peaks corresponding 2 θ are 4.97, 9.75, 12.85, 24. 26. These 2 θ are consistent with corresponding diffraction card (Pdf No. 14-1047) of Fe (II) Pc and literature reported results [11].In Fe (III) PcTs molecule, center metal ion atom and the N atom have different strength and bond length, make some changes have taken place in the lattice constant of crystal, which result in some changes of the the diffraction peaks and relative position in the XRD spectra of Fe(III)PcTs compared with Fe (II) the Pc, and its main crystal phase is phthalocyanine crystal structure. 
Figure 3. XRD pattern of Fe (III) PcTs 
Figure 4. UV-Vis spectrum of Fe (III) PcTs dissolved in DMSO 
Figure 5. Typical chromogenic reaction of 2-chlorophenol 
Figure 5 of 5
Performance Research of Fe (III) Tetrasulfophthalocyanine and Its Catalyzed Application in 2-Chlorophenol Detection
  • Article
  • Full-text available

July 2018

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191 Reads

IOP Conference Series Earth and Environmental Science

Iron (III) tetrasulfophthalocyanine (Fe (III) PcTs) has been used as a biomimetic enzyme to catalyze the oxidation of 2-CP. Fe (III) PcTs has been Prepared and characterized, including FT-IR, SEM, XRD, UV-Vis and element analysis of Fe (III) PcTs. It showed Fe (III) PcTs has high purity. We studied the oxidation of 2-CP catalyzed by Fe (III) PcTs, the intensities of absorption at 510 nm.

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