Xiwu Li’s research while affiliated with General Research Institute for Nonferrous Metals (GRINM) and other places

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Publications (114)


Effect of grain characteristics on stress corrosion resistance of a novel Al-Mg-Zn-Si alloy with high Mg content
  • Article

April 2025

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8 Reads

Materials Today Communications

Xiang Cheng

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Baiqing Xiong

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Mingyang Yu

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[...]

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Yongan Zhang


The effect of different preparation methods on the microstructure and mechanical properties of Al-Zn-Mg-Cu alloy wire

February 2025

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2 Reads

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1 Citation

Journal of Physics Conference Series

The number of fasteners used in aircraft is vast, reaching millions. Aluminum alloy wire for fasteners has become a focus of research. In this study, the Al-Zn-Mg-Cu alloy wire was prepared by hot rolling and extruding methods. A comparative analysis of microstructure and mechanical properties was examined. Results indicated that the hot rolling technique yields a more homogeneous microstructure and enhances the stability of mechanical properties. Following solution treatment and aging, a significant quantity of nano-sized strengthening η′ phases developed within the alloy. This led to improvements in both strength and elongation relative to the cold-deformed state. Consequently, the hot rolling method emerges as the most effective approach for the industrial production of alloy wire for fasteners.


Effect of aging regime on the microstructure, mechanical properties, and impact toughness of Al-Zn-Mg alloys

February 2025

Journal of Physics Conference Series

This article investigates the effects of different aging regimes on the microstructure, mechanical properties, and impact toughness of Al-Zn-Mg alloys. The mechanisms by which microstructural changes influence mechanical properties and impact toughness are discussed. In an overaged condition, as aging temperature is elevated and aging time extends, intragranular precipitates become coarser, and the density of precipitates decreases, leading to a decline in yield and tensile strength properties. However, it narrows the strength gap between intragranular and intergranular regions, enhancing the impact toughness. The appearance of the equilibrium η phase and the expansion of PFZ are also reasons for the improved impact toughness of the alloy.


Schematic diagram of C[T] specimen.
In‐situ tensile sample schematic diagram.
The GAM images of the aged alloy. a) Sample I, b) Sample II, and c) quantitative statistical data of recrystallization characteristics.
The SEM images of the aged alloys. a) Sample I, b) Sample II, c) EDS result for marked phase of Sample I, and d) EDS result for marked phase of Sample II.
The size distribution statistical results of the iron‐rich phases in the two samples.

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Enhancing Stress Corrosion Cracking Resistance in a High Alloying Al–Zn–Mg–Cu Alloy by Controlling Recrystallization Morphology
  • Article
  • Publisher preview available

January 2025

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19 Reads

Al–Zn–Mg–Cu alloys are widely used in aerospace, with recrystallization significantly influencing their stress corrosion resistance. This study examines the impact of recrystallization morphology on corrosion resistance in a high‐alloying Al–Zn–Mg–Cu alloy, focusing on lath‐shaped and equiaxed recrystallized grains. The findings reveal that, at the same recrystallization fraction, the equiaxed sample has a 2.83 times higher corrosion current density and a 1.15 times higher stress corrosion cracking susceptibility index than the lath sample. However, its critical stress intensity factor is only 89.3% of the lath alloy's. Lath recrystallization demonstrates superior stress corrosion resistance due to larger grain sizes, wider grain boundary precipitate spacing, lower Zn and Mg content, and higher Cu content. Finite element simulations and in‐situ tensile tests show that the equiaxed sample experiences more stress concentration and cracking at grain boundaries under the same applied stress. These results provide insights into optimizing the stress corrosion resistance of Al–Zn–Mg–Cu alloys.

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A Review of Solid-State Additive Manufacturing: Method, Microstructural Evolution, Mechanical Properties, Applications and Challenges

December 2024

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57 Reads

Solid-state additive manufacturing (SSAM) is an emerging technology that offers a unique approach by avoiding the melting and solidification of metals during the fabricating process. As a result, it eliminates common solidification related defects like porosity and cracking. This method is characterized by low residual stress, low distortion, and the formation of fine equiaxed grain structures, making it particularly advantageous for fabricating large-scale components in sectors like aerospace, aviation, and rail transportation. This review explores the fundamental principle and recent development of solid-state additive techniques, namely, friction stir additive manufacturing (FSAM), additive friction stir deposition (AFSD), friction and rolling-based additive manufacturing (FRAM), and wire-based friction stir additive manufacturing (W-FSAM). Furthermore, the advantages, challenges, and future trends of these SSAM techniques are reviewed. A comprehensive review of the characteristics and current research trends in solid-state additive manufacturing methods is crucial for driving further advancements in this technology.


Figure 5. SSRT engineering stress-strain curves of samples after different aging treatments tested in silicone oil and 3.5% NaCl conditions.
Figure 7. STEM images and EDS analysis of the samples in different aging treatments: (a,c) aging at 120 °C × 6 h + 152 °C × 18 h; (b,d) aging at 120 °C × 6 h + 162 °C × 8 h + 120 °C × 24 h.
Aging conditions used for 7085 aluminum alloy samples.
Enhancing Stress Corrosion Cracking Resistance of Low Cu-Containing Al-Zn-Mg-Cu Alloys by Aging Treatment Control

November 2024

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12 Reads

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1 Citation

The 7085 aluminum alloy with a low Cu content is an important lightweight structural material in the aerospace field due to its advantages of low density, high specific strength, and high hardenability. However, like other high-strength Al-Zn-Mg-Cu alloys, this alloy is susceptible to stress corrosion cracking (SCC). Additionally, the lower Cu content may increase its tendency toward SCC, potentially impacting the safe use of this alloy. Therefore, this study investigated the effects of aging treatment processes on the mechanical properties and SCC resistance of 7085 aluminum alloy. And the factors affecting the properties of the alloy were analyzed by optical microscope (OM), scanning transmission electron microscope (STEM), and energy-dispersive X-ray spectroscopy (EDS) analyses. The results indicated that increasing the secondary aging temperature and adding a tertiary aging step can significantly reduce the alloy’s susceptibility to SCC while meeting the mechanical performance requirements. The reduced SCC sensitivity was mainly attributed to the increased spacing of grain boundary precipitates, a wider precipitate-free zone at the grain boundaries, and a higher Cu content in the grain boundary precipitates.


Effect of Extrusion and Annealing Treatment on Peripheral Coarse Grain Structure and Mechanical Property of an Al-Cu-Li-Mg Alloy Extrusion Profile

October 2024

In the current study, the effects of extrusion and annealing treatment on the peripheral coarse grain (PCG) structure were investigated. The results showed that the edge of profiles recrystallized during the extrusion process, the grain size was in the range of 2-5 m and the degree of recrystallization had obvious heterogeneity along the extrusion direction, showing two kinds of recrystallization microstructure. The thickness of recrystallized microstructure at the head of the profile was 2 mm and there were obvious boundaries. The thickness of recrystallized microstructure at the tail reached 13 mm and there was no obvious boundary. The recrystallized grains grew abnormally to form PCG structure during the solution process. The PCG structure was significantly reduced when the extrusion ratio decreased from 20 to 14. The higher the extrusion temperature reached, the more serious the PCG structure was. The suitable annealing regime is 350°C/5h.


Citations (44)


... However, with the rapid advancements in national economic and defense industry construction, traditional 2A12 Al alloy materials are increasingly unable to meet the demands posed by use in severely corrosive environments due to susceptibility to pitting [2,5]. Certain second phases, particularly Cu-containing phases such as θ phase (Al 2 Cu) and S phase (Al 2 CuMg), which commonly manifest as larger particles, impede the formation of passivation coatings on the surface of Al alloys, resulting in a discontinuous and defective passivation coating [6][7][8][9][10]. ...

Reference:

Effect of Deposition Parameters for Ni-Au Coatings on Corrosion Protection Properties of 2A12 Aluminum Alloy
Enhancing Stress Corrosion Cracking Resistance of Low Cu-Containing Al-Zn-Mg-Cu Alloys by Aging Treatment Control

... This work investigates an age-strengthened Al-Mg-Zn alloy (Beijing, China, Al-7.02Mg-1.98Zn) [22]. The alloy underwent an artificial aging treatment of 90 • C for 24 h followed by 140 • C for 24 h to achieve the peak aging state, during which the alloy exhibits the highest strength. ...

Effect of grain orientation distribution on the mechanical properties of Al-7.02Mg- 1.78Zn alloys
  • Citing Article
  • June 2024

Multidiscipline Modeling in Materials and Structures

... Therefore, through a comparison of solid solution properties, it can be recognized that the solid solution of specific atoms is advantageous in enhancing the modulus and specific modulus of Al alloys, especially Al-Li alloys, which exhibit significant advantages in lightweighting and achieving high strength-to-weight ratios. Based on previous experimental studies [7,52], it has been established that the elastic modulus of Al-Li solid solutions is directly proportional to the concentration of Li atoms. As the Li concentration increases from 0.91 to 3.98 wt.%, the elastic modulus increases correspondingly from 72.8 to 80.3 GPa. ...

The Influence of Aging Precipitates on the Mechanical Properties of Al–Li Alloys and Microstructural Analysis

... This involves achieving a distinct range of phases such as singlephase Solid Solutions (SS), Intermetallic (IM) and mixed phases (SS+IM) [6]. Evaluation of microstructural information requires high-resolution imaging techniques, which are tedious and costly due to the vast compositional space and complex microstructure of HEAs, and also require costly equipment [7], [8]. To overcome these challenges, computational techniques, molecular dynamics and empirical relations are used to lessen trial-and-error experiments. ...

Machine Learning Phase Prediction of Light-Weight High-Entropy Alloys Containing Aluminum, Magnesium, and Lithium

... On samples, they used solid-solution treatment and direct aging to investigate the aging process. The solid-solution treatment was reported to exhibit greater hardness and also showed accelerated aging [27]. ...

Effect of Processing Parameters and Heat Treatment on Selective Laser Melted Al-Cu-Mg-Ag Alloy

Journal of Physics Conference Series

... The high CR resulted in increased strength and decreased ductility. In aluminum alloy 7050, a high CR features fine grains and small precipitates with a high density [105]. Also, a high CR results in increased strength and decreased ductility. ...

Effects of Different Heating and Cooling Rates during Solution Treatment on Microstructure and Properties of AA7050 Alloy Wires

... Age-strengthened aluminum alloys typically undergo deformation processes, such as extrusion and rolling, prior to solid solution aging. During the deformation of polycrystalline materials, grains are internally rotated homogeneously to maintain geometrical compatibility, influenced by the constraints imposed by neighboring grains [25][26][27]. ...

Effect of Zn/Mg ratio on aging precipitates and mechanical property of high Mg content Al-Mg-Zn alloys with Sc and Zr additions
  • Citing Article
  • December 2023

Journal of Alloys and Compounds

... Одним из основных легирующих элементов сплавов данной системы является литий, который обеспечивает одновременно низкую плотность и высокую жесткость [4]. Другой важной добавкой является медь. ...

Influence of enhanced Li content on the as-cast eutectic phase features and the evolution during homogenization of Al-Cu-Li alloys
  • Citing Article
  • September 2023

Journal of Materials Research and Technology

... The typical microstructures of the Al alloy after this step are shown in Figure 2. Three distinct precipitate morphologies can be observed in this state, characterized along different crystallographic orientations of [110] Al and [001] Al (Figure 2(a-e)). Based on diffraction patterns, plate-like precipitates aligned with the 111 Al habit plane were identified as η phases [29,36,37], while near-spherical precipitates were identified as T phases [38][39][40]. Additionally, high-density fine precipitates with coherent rectangular cross-sections emerged, exhibiting a specific hexagonal diffraction pattern, resembling the precursors of Si-rich phases reported in the literature [41]. ...

Comprehensive investigation on the structural, electronic and mechanical properties of T-Mg32(Al,Zn)49 phases in Al-Mg-Zn alloys
  • Citing Article
  • February 2024

Journal of Material Science and Technology

... Al-Mg-Zn-Cu alloys are extensively utilized in the aerospace and automotive industries due to their high specific strength and superior overall properties [1][2][3]. The conventional Al-Mg-Zn-Cu alloy is a typical wrought Al alloy with excellent mechanical properties, but the lengthy and complicated deformation process raises the production cost and limits its application fields [4][5][6]. ...

Effect of Zn/Mg ratio on the microstructure and mechanical properties of as-cast Al–Zn–Mg–Cu alloys and the phase transformation during homogenization
  • Citing Article
  • August 2023

Journal of Materials Research and Technology