May 2025
·
1 Read
Journal of Water Process Engineering
Manganese is abundant in the Earth's crust as a mineral and commonly enters mining and metallurgical wastewater (MMW) through extraction and smelting activities. However, comprehensive reviews on manganese removal technologies for MMW remain limited. This paper begins by introducing the basic properties and hazards of manganese and then details the formation processes, characteristics, and hazards of two representative types of manganese-containing MMW, namely, acid mine drainage (AMD) and electrolytic metal manganese residue leachate (EMMRL). This study then categorizes the current manganese removal technologies into chemical, physicochemical, and biological methods, and special attention is given to the widely used techniques, such as chemical precipitation, chemical oxidation, adsorption, and emerging electrochemical methods, along with their typical cases, removal mechanisms, and advantages and disadvantages. The key factors that influence the effectiveness of these technologies are also summarized. Resource recovery from manganese-containing wastewater is currently achieved through carbonate precipitation, phosphate precipitation, and electrochemical methods. This paper also discusses some prospects for the future removal and recovery of manganese from MMW.