Tsuyoshi Masumoto’s research while affiliated with Tohoku University and other places

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Publications (851)


Structural Study of a Decagonal Al75Fe15Ni10 Alloy by Anomalous X-ray Scattering (AXS) Method
  • Article
  • Full-text available

June 2014

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14 Reads

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1 Citation

Zeitschrift fur Naturforschung A

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A. P. Tsai

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T. Masumoto

A structural study of an as-quenched decagonal Al75Fe15Ni10 alloy has been carried out by anomalous x-ray scattering (AXS) as well as ordinary x-ray diffraction. The environmental radial distribution functions (RDFs) for Fe and Ni determined by the AXS measurements turned out to resemble each other and to be similar to the ordinary RDF obtained by ordinary x-ray diffraction. These results clearly show that the Ni and Fe atoms are homogeneously distributed and occupy the same sites in the decagonal structure of Al75Fe15Ni10.

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On the Structural Evolution of the Amorphous AI75Cu, 5V10 Alloy to the Icosahedral Phase

June 2014

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16 Reads

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16 Citations

Zeitschrift fur Naturforschung A

The transformations occurring on annealing an as-spun amorphous Al75Cu15V10 alloy are studied by X-ray diffraction and transmission electron microscopy (TEM). A continuous growth of icosahedral clusters, which are present already in the as-spun sample, is revealed. The size of the clusters estimated from the diffuse X-ray peak widths is consistent with the size of the modulation observed in the bright field TEM images.


Observed and calculated d-spacings of the super­ conductor. Pseudo-tetragonal cell with a -0.5369(l)nm and c = 2.4627 (5) nm.
Structural Study for a New Superconducting Phase in the Bi-Sr-Cu -O System

June 2014

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30 Reads

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7 Citations

Zeitschrift fur Naturforschung A

A structural identification of the superconducting phase in the Bi-Sr-Cu-O system has been carried out by X-ray and electron diffraction. A lamellar oxide structure expressed by the formula Bi


The Thermal Diffusivity of Quasicrystalline Al72 Pd20Mn8 Alloy

June 2014

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27 Reads

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4 Citations

Zeitschrift fur Naturforschung A

A new cell has been developed for measuring the thermal diffusivity of small samples [about (5x2x0.5) mm3], using the laser flash method. The thermal diffusivities of small samples of titanium, SUS304 and Pyrex 7740 glass measured with this cell agree well with those obtained from samples of 10 mm in diameter and 0.4 mm in thickness. Then, the thermal diffusivity between 300 K and 950 K of quasicrystalline Al72Pd20Mn8 with a single domain size of 5 mm, and that of crystalline Al60Pd25Mn15 were measured. The thermal diffusivity of quasicrystalline Al72Pd20Mn8 was found to be 4 to 7 times smaller than that of crystalline Al60Pd25Mn15.


TMR of Metal-insulator Nano-granular Thin Films and Power-saving Magnetic Sensor GIGS^|^reg;

October 2012

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39 Reads

IEEJ Transactions on Fundamentals and Materials

The structure and tunnel magneto-resistance of (Fe-Ni or Fe-Co)-(Mg-F) nano-granular thin films were investigated. The films were prepared by a tandem deposition method, using Fe-Ni or Fe-Co alloy and MgF 2 insulator targets. A granular structure was found to be consisted of Fe-Ni or Fe-Co based nano-granules surrounded by thin intergranules of Mg based fluoride which were crystallized with a MgF 2 structure. These films show tunnel-type magnetoresistance which is caused by the film structure. The GIGS. (Granular-in-Gap-Sensor) consisting of the (Fe-Co)-(Mg-F) nano-granular thin film filled into a narrow gap of soft magnetic a-CoFeSiB thin film was prepared. GIGS. has large electrical resistance (10 kΩ -10 MΩ) because of high electrical resistivity of metal-nonmetal nano-granular film. The large electric resistivity causes the reduction of the electricity consumption.


TMR and Thermal Stability Improvement of FeCo-AlF Nano-Granular Thin Films

June 2012

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24 Reads

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7 Citations

Journal of the Japan Institute of Metals and Materials

We investigated tunnel magnetoresistance (TMR) properties to improve their thermal stability using FeCo-AlF, a new metal-insulator nano-granular thin film for IGS® (granular in gap sensor), a highly efficient power-saving magnetic sensor. These system films exhibit granular type TMR properties, and Fe 25Co 19Al 17F 39 film has a 12% TMR ratio. The thermal stability of the TMR properties is greatly improved by adding of small amounts of Si to FeCo-AlF. Although the TMR ratio of Fe 23Co 17Al 13F 47 film deteriorates from 550K, Fe 22Co 18Si 3Al 16F 41 film retains its TMR ratio up to 600 K.



Structural Analysis of Nano-Granular Metal-Fluoride TMR Films

August 2011

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9 Reads

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2 Citations

Journal of the Japan Institute of Metals and Materials

We have investigated the structure of (Fe, Co)-Mg-F nano-granular TMR films by HRTEM. These films have nano-granular structure which consists of Co or Fe nano-granules with diameter of 2-3 nm surrounded by thin intergranules of MgF2 with crystal structure. The structure of Co granules is crystalline, whereas the one of Fe is an amorphous state, which may be attributed to small MR ratio of 42 vol%Fe-(Mg0.32F0.68) film compared with the theoretical one calculated from spin polarization (P) of Fe crystal.


Ferromagnetic Glasses with Stable Supercooled Liquid in Gd-Al-(Cu,Ni,Co) Alloys

May 2011

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7 Reads

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1 Citation

Metallic glasses with ferromagnetism and stable supercooled liquid formed in melt-quenched Gd55Al25TM20 (TM = Cu, Ni, and Co) alloys have been studied by means of vibrating-sample magnetometer (VSM) and differential scanning calorimeter (DSC) These glasses show a large temperature interval between glass transition temperature (Tg) and crystallization temperature (Tx) of about 60K which is comparable with typical metallic glasses. The glasses aer predominantly ferromagnetic with curie temperature (Tc) from 90 K to 120 K and saturation magnetization (σs) between 160 cmu/g and 200 cmu/g.


ChemInform Abstract: Tunnel-MR and Spin Electronics in Metal-Nonmetal Granular Systems

June 2010

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12 Reads

ChemInform

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.


Citations (61)


... As demonstrated by metallurgical data, the solubility of N in liquid Fe at 1 atm is as low as~0.045 wt% and sharply decreases with increased temperatures and concentrations of solute Ni [46,47]. Early estimates of the chemical composition of bulk silicate Earth largely presumed that N was only abundant on the surface but depleted in the deep interior [48,49]. ...

Reference:

Electrical Resistivity and Phase Evolution of Fe–N Binary System at High Pressure and High Temperature
Solubility of Nitrogen in Austenitic Iron under High Pressure of Nitrogen Gas and Thermodynamical Properties of Austenitic Interstitial Solid Solution of the Fe-N System
  • Citing Article
  • April 2008

Journal of the Japan Institute of Metals and Materials

... These studies mainly focus on the microstructural evolution and magnetic properties of as-atomized powders. Further studies exclusively report on powder consolidation such as Layer Additive Manufacturing [181], Warm Hydrostatic Extrusion [182], Warm Rolling [183], Spark Plasma Sintering [184], Severe Plastic Deformation [185], Cold Spraying [186], and Thermoplastic Forming [187,188]. The study by Zheng et al. is an exception [26,31], as the authors reported the gas atomization of amorphous aluminum powders in detail. ...

Fabrication of bulk amorphous alloys by powder consolidation
  • Citing Article
  • March 1997

... Based on the main component elements, the Tibased MGs ever-developed could be classified into 4 categories, i.e., TiZrBe-based MGs [6][7][8][9], TiCuNibased MGs [10][11][12][13], TiZrCu-based MGs [14][15][16][17][18], and TiZrSi-based MGs [19][20][21][22], which show distinct glass forming abilities (GFAs). The GFA of MGs is usually indicated with the critical diameter of the maximum MG rod that could be fabricated by casting. ...

Ti-based amorphous alloys with a wide supercooled liquid region
  • Citing Article
  • June 2007

Materials Letters

... The noncrystalline structure also improves wear and corrosion resistance and lowers friction in BMGs [26][27][28][29][30][31]. Several BMGs are tailored for specific functional properties such as biocompatibility [32][33][34][35][36], biodegradability [37][38][39], catalytic activity [40][41][42][43][44][45], and ferromagnetism [46][47][48][49]. ...

Ferromagnetic Glasses with Stable Supercooled Liquid in Gd-Al-(Cu,Ni,Co) Alloys

... 10,11 In the (Fe-Co)-(Mg-F) system, the high temperature environment makes the granules larger, and hence the electrical resistivity becomes larger and the MR ratio becomes smaller. 12,13 It is thought that the increasing the size of the Fe-Co granules changes the magnetic state and the structure of magnetic tunnel junctions, and thereby the electric properties of the film. For practical use for the magnetic sensors, it is important to improve the film's thermal stability. ...

Thermal change of the structure of FeCo-MgF nano-granular TMR films
  • Citing Article
  • January 2012

Journal of the Magnetics Society of Japan

... While these approaches can effectively describe specific viscoelastic responses, they often involve many fitting parameters, increasing the risk of overfitting and reducing the reliability of the predictive power of theoretical models. Newtonian flow is typically observed at low strain rate or elevated temperature, while plastic deformation transforms to non-Newtonian behavior at high rate or lower temperature, particularly below the glass transition temperature [8,9]. Non-Newtonian behavior has been attributed to stress overshoot, which induces structural disordering through the rapid increase of stress-induced free volume [10,11]. ...

High-Strain-Rate Superplasticity due to Newtonian Viscous Flow in La55Al25Ni20 Metallic Glass

Materials Transactions JIM

... It should be noted that the nanogranular film, which has a small amount of magnetic metal, becomes a transparent magnetic material with a large Faraday effect [12][13][14]. Furthermore, nanogranular films have practical advantages such as ease of production, good reproducibility, and good heat resistance [15,16]. On the other hand, existing magneto-optical materials (thin films with high figure of merit [17]) do not have a large coercive force and require an external magnetic field to stabilize their magnetization state. ...

Effects of Substrate Temperature and Heat Treatment on GMR Properties of Co^|^ndash;RE^|^ndash;O Nano-granular Films
  • Citing Article
  • June 1998

Materials Transactions JIM

... 2) The application of this type of alloy to precision mechanical equipment is progressing, and the importance of strength and other mechanical characteristics is also increasing. 3) As "additional processing," additive manufacturing technology of alloy materials has been called the third pro-cessing method after "cutting technology" by machining and related techniques and "forming technology," such as casting, forging, and press forming. Additive manufacturing is now applied in an increasing number of cases, firstly because it is possible to produce parts with shapes that cannot be obtained by conventional processes, and also because shortening of the delivery times when manufacturing products with complex shapes are also expected accompanying progress in process digitalization. ...

New Advances in Invar Alloys. Applications of Invar-type Alloys to Various Precision Instruments.
  • Citing Article
  • January 1997

Materia Japan

... One of the most characteristic properties of the prepercolated ferromagnetic metal -insulator composites is a tunnel magnetoresistance (TMR). The relatively high values of TMR are usually observed in the cobalt-based composites [1][2][3][4][5][6][7][8]. For example, the TMR value is 7 -8 % in composites with mono-element ferromagnetic phase (Co-Al-O [2,7]). ...

TMR and Thermal Stability Improvement of FeCo-AlF Nano-Granular Thin Films
  • Citing Article
  • June 2012

Journal of the Japan Institute of Metals and Materials

... Therefore, amorphous/nanocrystalline Fe-based alloys are considered in various applications such as magnetic cores and magnetic screens. [64][65][66] The aim of this paper was to manufacture novel, low-cost [9,67] nanocrystalline Fe 79 B 20Àx M x Cu 1 (where x = 0 or 4; M = Ti, Mo, Mn) bulk alloys directly in the casting process without performing additional heat treatment. Comprehensive studies of the relationship of microstructure to mechanical and magnetic properties were performed in a wide range of mechanical loads, temperature, and magnetic fields. ...

Applications of nanocrystalline soft magnetic Fe-M-B (M = Zr, Nb) alloys
  • Citing Article
  • December 1997

Nanostructured Materials