Stephen A. Morin's research while affiliated with University of Nebraska at Lincoln and other places

Publications (59)

Article
A general approach to increase the adhesion of metal films to commodity plastic substrates using a metal-chelating polymer, polyethyleneimine, in conjunction with patterned electroless deposition is described. This general fabrication...
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The effect of anisotropic surface roughness on the spontaneous transport of droplets on chemical wettability gradients has not been investigated. Understanding the details of this process has the potential to unlock new fluid handling functionality critical to the development of next-generation surfaces with intelligent control capabilities. Herein...
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Natural particles possess varying degrees of surface heterogeneities. Although the impact of collector surface heterogeneity on particle deposition is more or less established, the impact of particle surface heterogeneity on the deposition of colloids in porous media is not well studied. In this work, Janus SiO2 microparticles (Janus SiO2 MPs) were...
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Adaptive materials with tunable superhydrophobic surfaces promise to impact a range of fluid handling technologies; however, adaptive superhydrophobic materials remain difficult to fabricate, control, and switch rapidly. Here, a versatile method for generating hierarchically structured and adaptive superhydrophobic silicone films for the rational c...
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Materials and strategies applicable to the dynamic transport of microdroplets are relevant to surface fluidics, self-cleaning materials, thermal management systems, and analytical devices. Techniques based on electrowetting, topographic micropatterns, and thermal/chemical gradients have advanced considerably, but dynamic microdroplet transport rema...
Article
The fabrication of soft hydrogel actuators that rapidly respond to multiple stimuli in ambient environments is a challenge. This article describes a method—based on surface molding—to generate multi-stimuli-responsive soft actuators consisting of arrays of geometrically patterned hydrogels on elastomeric supports. The stimuli-responsive properties...
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Techniques that enable the spatial arrangement of living cells into defined patterns are broadly applicable to tissue engineering, drug screening, and cell–cell investigations. Achieving large‐scale patterning with single‐cell resolution while minimizing cell stress/damage is, however, technically challenging using existing methods. Here, a facile...
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Biological systems generate crystalline material with properties and morphologies that cannot be duplicated using synthetic procedures. Developing strategies that mimic the control mechanisms found in nature would enhance the range of functional materials available for numerous technological applications. Herein, a biomimetic approach based on the...
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Biological systems demonstrate exquisite three dimensional (3D) control over crystal nucleation and growth using soft micro/nanoenvironments, such as vesicles, for reagent transport and confinement. It remains challenging to mimic such biomineralization processes using synthetic systems. A sythetic mineralization strategy applicable to the sythesis...
Article
Silicone elastomers are used in a variety of “stretchable” technologies (e.g., wearable electronics and soft robotics) that require the elastomeric components to accommodate varying magnitudes of mechanical stress during operation; however, there is limited understanding of how mechanical stress influences the surface chemistry of these elastomeric...
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Microfluidics has enabled numerous applications in, for example, analytical chemistry, medical diagnostics, microelectronics, and soft robotics. In most of these applications, the geometries of the microchannels are of fixed dimensions that (ideally) remain invariant during operation. In soft robotics, however, the geometries of the microchannels c...
Article
The Front Cover shows an artistic rendering of emergent soft lithographic methods where each new technique is represented by an additional “card” in the expanding “deck” of soft lithography. More information can be found in the Review by M. A. Rose et al. on page 909 in Issue 7, 2019 (DOI: 10.1002/cphc.201801140).
Article
The front cover artwork is provided by the Morin Group, University of Nebraska ‐ Lincoln. The image shows an artistic rendering of emergent soft lithographic methods where each new technique is represented by an additional “card” in the expanding “deck” of soft lithography. Read the full text of the Review at 10.1002/cphc.201801140. “Recent efforts...
Article
Polymeric microstructures (PMs) are useful to a broad range of technologies applicable to, for example, sensing, energy storage, and soft robotics. Due to the diverse application space of PMs, many techniques (e.g., photolithography, 3D printing, micromilling, etc.) have been developed to fabricate these structures. Stemming from their generality a...
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Advanced manufacturing strategies have enabled large‐scale, economical, and efficient production of electronic components that are an integral part of various consumer products ranging from simple toys to intricate computing systems; however, the circuitry for these components is (by and large) produced via top‐down lithography and is thus limited...
Article
There are a limited number of methods applicable to the large-scale fabrication of arrays of discrete microparticles; however, such methods can be applied to the fabrication of structures applicable to photonics, barcoding, and optoelectronics. This manuscript describes a universal method, “microparticle screen printing” (µSP), for the rational pat...
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Synthetic approaches based on the patterned deposition of volatile molecules from the vapor phase are used extensively in the creation of surface-chemical gradients; however, the ability to generate diffusion-controlled 1D and 2D gradients from multiple sources remains a challenge. The current work reports a one-step approach to the synthesis of co...
Article
The lamination of mechanically stiff structures to elastic materials is prevalent in biological systems and popular in many emerging synthetic systems, such as soft robotics, microfluidics, stretchable electronics, and pop-up assemblies. The disparate mechanical and chemical properties of these materials have made it challenging to develop universa...
Article
Some embodiments of the disclosed subject matter includes a laminated robotic actuator. The laminated robotic actuator includes a strain-limiting layer comprising a flexible, non extensible material in the form of a sheet or thin film, a flexible inflatable layer in the form of a thin film or sheet in facing relationship with the strain-limiting la...
Article
Systems and methods for providing a soft robot is provided. In one system , a robotic device includes a flexible body having a fluid chamber, where a portion of the flexible body includes an elastically extensible material and a portion of the flexible body is strain limiting relative to the elastically extensible material. The robotic device can f...
Article
Systems and methods for providing flexible robotic actuators are disclosed. Some embodiments of the disclosed subject matter include a soft robot capable of providing a radial deflection motions; a soft tentacle actuator capable of providing a variety of motions and providing transportation means for various types of materials; and a hybrid robotic...
Article
This work describes the fabrication of numerous hydrogel microstructures, μ-gels, via a process called "surface molding"—chemically patterned elastomeric assembly substrates were used to organize and manipulate the geometry of liquid prepolymer microdroplets, which, following photo-initiated crosslinking, maintained the desired morphology. By adjus...
Article
This work describes the fabrication of numerous hydrogel microstructures, μ-gels, via a process called "surface molding"—chemically patterned elastomeric assembly substrates were used to organize and manipulate the geometry of liquid prepolymer microdroplets, which, following photo-initiated crosslinking, maintained the desired morphology. By adjus...
Article
The use of fluid flow to control crystal morphology during the liquid-phase synthesis of inorganic nanomaterials is a relatively under explored approach. Synthetic strategies that take advantage of flow effects present the opportunity to tune several parameters (e.g., flow velocity and direction) in addition to conventional growth parameters (e.g.,...
Article
The emerging field of soft robotics makes use of many classes of materials including metals, low glass transition temperature (Tg) plastics, and high Tg elastomers. Dependent on the specific design, all of these materials may result in extrinsically soft robots. Organic elastomers, however, have elastic moduli ranging from tens of megapascals down...
Article
A soft robotic device includes a flexible body having a width, a length and a thickness, wherein the thickness is at least 1 mm, the flexible body having at least one channel disposed within the flexible body, the channel defined by upper, lower and side walls, wherein at least one wall is strain limiting; and a pressurizing inlet in fluid communic...
Article
The directed assembly of micro-/nanoscale objects relies on physical or chemical processes to generate structures that are not possible via self-assembly alone. A relatively unexplored strategy in directed assembly is the “active” manipulation of building blocks through deformations of elastomeric substrates. This manuscript reports a method which...
Article
This manuscript describes the adhesion characteristics of micron-scale crystals to chemically-functionalized, soft elastomeric supports throughout repeated cycles of tensile stress. The ability to tune the characteristics of hard/soft interfaces (e.g., those formed between silicones, such as polydimethylsiloxane, and semiconductors, such as ZnO) is...
Article
A micromechano optical material is rapidly and reversibly switched between distinct states of reflectance by simply stretching and relaxing the hybrid structure. The material is fabricated and controlled by leveraging the ability of soft elastic substrates to regulate the growth and morphological evolution of a chemically deposited polycrystalline...
Article
Some embodiments of the disclosed subject matter includes a laminated robotic actuator. The laminated robotic actuator includes a strain-limiting layer comprising a flexible, non extensible material in the form of a sheet or thin film, a flexible inflatable layer in the form of a thin film or sheet in facing relationship with the Strain-limiting la...
Article
Microfluidic channels are typically fabricated in polydimethylsiloxane (PDMS) using a combination of photolithography and soft lithography. Photolithography, while ubiquitous in the fabrication of microfluidic devices, generally requires skilled technicians, expensive chemicals, and specialized equipment. This manuscript describes a simple method f...
Article
The chemical properties of a surface are readily controlled using a layer (or layers) of surface-functional groups that can be generated with, for example, self-assembled monolayers (SAMs) or polymer brushes. These methods have enabled rational control over surface chemistry, which directly impacts surface properties, such as wettability, but gener...
Article
Microfluidic channels are typically fabricated in polydimethylsiloxane (PDMS) using soft lithography and sealed against a support substrate using various irreversible/reversible techniques—the most widely used method is the irreversible bonding of PDMS to glass using oxygen plasma. These techniques are limited in their ability to seal channels agai...
Article
Soft devices can be bent, stretched, and compressed reversibly, but conventional wires are rigid. This work describes stretchable composites that are easily fabricated with simple tools and commodity materials, and that can provide a strategy for electrical wiring that meets certain needs of soft devices. These composites are made by combining meta...
Article
Apparatus, Systems, and methods for providing modular soft robots are disclosed. In particular, the disclosed modular soft robot can include a flexible actuator having a plurality of molded flexible units. Each molded flexible unit can include a mechanical connector configured to provide a physical coupling to another molded flexible unit, and the...
Article
An elastically-deformable, conductive composite using elastomers and conductive fibers and simple fabrication procedures is provided. Conductive elastomeric composites offer low resistance to electrical current and are elastic over large (>25%) extensional strains. They can be easily interfaced/built into structures fabricated from elastomeric poly...
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This paper describes the fabrication of 3D soft, inflatable structures from thin, 2D tiles fabricated from elastomeric polymers. The tiles are connected using soft joints that increase the surface area available for gluing them together, and mechanically reinforce the structures to withstand the tensile forces associated with pneumatic actuation. T...
Article
Soft three dimensional, elastomeric structures and composite structures are easy to fabricate using click-e-bricks, and the internal architecture of these structures together with the capabilities built into the bricks themselves provide mechanical, optical, electrical, and fluidic functions.
Article
This paper demonstrates that the gas-filled compartments in the packing material commonly called "bubble wrap" can be re-purposed in resource-limited regions as containers to store liquid samples, and to perform in-field bioanalyses. The bubbles of bubble wrap are easily filled by injecting the samples into them using a syringe with a needle or a p...
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This paper describes the modular magnetic assembly of reconfigurable, pneumatically actuated robots composed of soft and hard components and materials. The soft components of these hybrid robots are actuators fabricated from silicone elastomers using soft lithography, and the hard components are acrylonitrile–butadiene–styrene (ABS) structures made...
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This article describes a hybrid robotic system combining hard and soft subsystems. This hybrid comprises a wheeled robot (an iRobot Create; hard) and a four-legged quadruped (soft). It is capable (using a simple, wireless control system) of rapid locomotion over flat terrain (using the wheeled hard robot) and of gripping and retrieving an object (u...
Article
Stacking faults are an important class of crystal defects commonly observed in nanostructures of close packed crystal structures. They can bridge the transition between hexagonal wurtzite (WZ) and cubic zinc blende (ZB) phases, with the most known example represented by the "nanowire (NW) twinning superlattice". Understanding the formation mechanis...
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Full-text available
One strategy for actuating soft machines (e.g., tentacles, grippers, and simple walkers) uses pneumatic inflation of networks of small channels in an elastomeric material. Although the management of a few pneumatic inputs and valves to control pressurized gas is straightforward, the fabrication and operation of manifolds containing many (>50) indep...
Article
Nanoscience and nanotechnology impact our lives in many ways, from electronic and photonic devices to biosensors. They also hold the promise of tackling the renewable energy challenges facing us. However, one limiting scientific challenge is the effective and efficient bottom-up synthesis of nanomaterials. We can approach this core challenge in nan...
Article
Soft robots have emerged as a new set of machines capable of manipulation [1–4] and locomotion. [5–8] Pneumatic expansion of a network of microchannels (pneu-nets) fabricated in organic elastomers, using low-pressure air (< 10 psi; 0.7 atm; 71 kPa), provides a simple method of achieving complex move-ments: [1, 5] grasping and walking. Despite their...
Article
Reaping the promise of human embryonic stem (hES) cells hinges on effective defined culture conditions. Efforts to identify chemically defined environments for hES cell propagation would benefit from understanding the relevant functional properties of the substratum. Biological materials are often employed as substrata, but their complexity obscure...
Article
Mechanical Chameleon A wide range of animals can adapt their color patterns as a means of camouflage or otherwise changing their appearance. This is accomplished through changes in coloration, contrast, patterning, or shape. Morin et al. (p. 828 ) show at a basic level that some of these features can be added as microfluidic layers attached to mobi...
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Material innovation will be a key feature in the next generation of robots. A simple, pneumatically powered actuator composed of only soft-elastomers can perform the function of a complex arrangement of mechanical components and electric motors. This talk will focus on soft-lithography as a simple method to fabricate robots--composed of exclusively...
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Full-text available
This manuscript describes a unique class of locomotive robot: A soft robot, composed exclusively of soft materials (elastomeric polymers), which is inspired by animals (e.g., squid, starfish, worms) that do not have hard internal skeletons. Soft lithography was used to fabricate a pneumatically actuated robot capable of sophisticated locomotion (e....
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We report the dislocation-driven growth of two-dimensional (2D) nanoplates. They are another type of dislocation-driven nanostructure and could find application in energy storage, catalysis, and nanoelectronics. We first focus on nanoplates of zinc hydroxy sulfate (3Zn(OH)(2)·ZnSO(4)·0.5H(2)O) synthesized from aqueous solutions. Both powder X-ray a...
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We report the rational synthesis of α-FeOOH (goethite) nanowires following a dislocation-driven mechanism by utilizing a continuous-flow reactor and chemical equilibria to maintain constant low supersaturations. The existence of axial screw dislocations and the associated Eshelby twist in the nanowire product were confirmed using bright-/dark-field...
Article
In the current examples of dislocation-driven nanowire growth, the screw dislocations that propagate one-dimensional growth originate from spontaneously formed highly defective "seed" crystals. Here we intentionally utilize screw dislocations from defect-rich gallium nitride (GaN) thin films to propagate dislocation-driven growth, demonstrating epi...
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We discuss a nanowire and nanotube formation mechanism in which axial screw dislocations provide self-perpetuating steps to enable one-dimensional (1D) crystal growth, unlike previously understood vapor−liquid−solid (VLS) or analogous metal-catalyzed growth. We initially found this mechanism in hierarchical pine tree PbS nanowires with helically ro...
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Nanosynthesis Without a Twist The synthesis of many nanoscale materials occurs under conditions of changing saturation because generation of product decreases the concentration of reactants. Morin et al. (p. 476 ) used a flow reactor to maintain conditions of low supersaturation during the growth of zinc oxide nanotubes and nanowires. Under these c...
Article
Growing in line: The surface chemistry of self-assembled nanostructured block copolymers is used to control the sites at which semiconducting metal sulfide nanocrystals nucleate and grow on a surface directly from aqueous solutions. This process is a new and general strategy for the bottom-up assembly of functional nanocrystalline materials for a v...
Article
Inspired by nature's ability to fabricate supramolecular nanostructures from the bottom-up, materials scientist have become increasingly interested in the use of biomolecules like DNA, peptides, or proteins as templates for the creation of novel nanostructures and nanomaterials. Although the advantages of self-assembling biomolecular structures cle...
Article
We report a simple and inexpensive approach to directly assemble arrays of cadmium sulfide (CdS) semiconductors onto transparent flexible poly(ethylene terephthalate) (PET) sheets via a polymer-mediated selective nucleation and growth process from an aqueous solution. This strategy of assembling functional materials onto plastics utilizes the surfa...
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We employ principles derived from biomineralization to assemble functional nanoscale inorganic materials onto flexible polymer substrates under low-temperature, benign chemical conditions. Our biomimetic approach involves the selective functionalization of polymer surfaces to create regions of differing surface energy which can promote heterogeneou...

Citations

... Their anisotropic nature has permitted diverse applications ranging from stimuli-responsive drug delivery carriers [3,4] to active swimmers with controlled movement [5,6]. Among the various types of Janus particles [7,8], zwitterionic particles with oppositely charged surface regions, also termed inverse patchy colloids, represent an important class [4,[9][10][11][12][13][14][15][16][17]. For example, by coating the hemispheres with weak polymeric acid and base groups, pH-driven aggregation and disaggregation can be efficiently achieved [11,12]. ...
... where θ is the measured WCA for PDMS nanocomposites; r is the surface roughness of PDMS nanocomposites; θ e is the equilibrium WCA on the smooth PDMS surface; and f s is the solid fraction of the solid-air compound surface [18]. Due to the inherent hydrophobicity of PDMS, superhydrophobicity can be achieved simply by roughening the surface of pure PDMS or its nanocomposites to increase the r value and/or decrease the f s value, using various techniques: spin coating [108], electrospinning [109], dropcasting or spray-coating [110][111][112][113], replication [17,[114][115][116][117][118][119], laser engraving [120][121][122][123][124][125], introducing a sacrificial template [126], wrinkling [127], 3D printing [20,128], and other methods [129][130][131][132][133][134][135][136][137][138][139][140][141][142][143][144][145][146][147]. Although the exact method or resultant morphology may differ, they have the same goal of introducing micro-and nanoscale or hierarchical roughness (higher r and/or lower f s values) into the hydrophobic PDMS-based material to achieve superhydrophobicity. ...
... By introducing chemical/structure wetting gradients, the lateral adhesion force along the droplet contact line can be modulated, and its effect is switched from resisting to driving. [19][20][21] Thus, droplets can be spontaneously steered without external energy consumption. ...
... Soft actuators represent an exciting new technology with the capacity to transform multiple industries, ranging from healthcare to robotics. One of the most notable breakthroughs in the field of SSAs is the creation of multiresponsive versions, which present numerous benefits compared to mono-responsive types [176][177][178]. The improved functionality of multi-responsive soft actuators is a crucial advantage. ...
... Many researchers are trying to elucidate the mechanistic pathway underlying the synthesis of these tiny magnetic structures as they can be exploited for biotechnology and nanotechnology purposes. However, they are limited owing to the fact that these bacteria are difficult to isolate from the deep ocean samples and also difficult to handle under laboratory conditions due to their fastidious nature (Stoller et al., 2020). Furthermore, the synthesis of magnetosomes is a very tidy process controlled by a complex set of genetic components (Jogler and Schuler, 2009). ...
... Enormous efforts have been spent on inhibiting dewetting during film processing. For example, attempts have been made in hydrophilizing the PDMS surface through surface grafting, 15,16 O 2 plasma 17,18 and UV/ozone 19,20 treatment, and addition of small amounts of nanoparticles. 21,22 Meanwhile, progressive understandings on the nonequilibrium behavior of pre-prepared thin films 23−25 promote greatly in achieving more stable films without dewetting after processing. ...
... Before controlling the robot ' s action, the first key problem to be solved is to obtain accurate and reliable information. Sensing can greatly reduce the risk of damage to external objects through better displacement accuracy, pressure accuracy and temperature accuracy [88][89][90][91][92]. Soft robots often require connections with rigid machine sensing, control systems and energy sources. ...
... However, standard photolithography creates patterns that have fixed height in Z-direction, where the height of the micromold (and thus the resulting microfluidic structure depth) is determined by the thickness of the spincoated photoresist. This is why standard photolithography is being referred to as a 2.5-dimensional microfabrication technique, as it lacks the spatial Z-direction patterning capability that true 3-dimenstional fabrication methods such as 3D printing are capable of producing (Rose et al. 2019;Derkus 2016). Thus, for example in the microfluidic applications mentioned above, where two or more different heights are desired within the same microfluidic device, a two-step photolithography has to be employed by patterning the first layer, followed by spincoating the next photoresist layer on top of the first patterned layer, and then creating the second pattern on this second photoresist layer. ...
... The original technique was "borrowed" from the MEMS community. The earliest work of microfluidic performed using soft lithography [171,172] can be traced back to the Whiteside group [173,174]. The term "soft lithography" was first introduced back then, referring to a technique based on printing and replica molding using elastomeric soft materials and photomasks with the patterns of interest. ...
... 26 Finally, in some cases, the substrate may also contain surface heterogeneities, such as metal traces on flex circuits. 63 Having established the necessary parameters to bond PDMS, we next sought to demonstrate two approaches to use the properties of the liquid metal to make electrical connections. We demonstrate two strategies, although there are likely many ways to integrate stretchable conductors into PDMS. ...