Sourav Dutta's research while affiliated with University of Calcutta and other places
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Publications (4)
Excited-state intramolecular proton transfer (ESIPT) was studied for two different fluorophores M2N3HF and 2P3HBQ in binary solvent mixtures of n-heptane and methanol. While both fluorophores share a degree of structural resemblance, they exhibit sharply contrasting ESIPT dynamics in the solvent mixtures. For 2P3HBQ, ESIPT is ultra-fast in n-heptan...
The 2-Aryl 3-Hydroxybenzo[g]quinolones (2Ar3HBQ) are a relatively new family of ESIPT fluorophores distinguished by their visible absorption spectra, which makes them potential ratiometric probes for biological media. In the present work, we found that 2Ar3HBQ residing as guest fluorophores inside biomimetic host systems like surfactant supramolecu...
The 2-Phenyl,3-Hydroxybenzo[g]quinolone (2P3HBQ) fluorophore and its derivative, 2-(4’-hydroxyphenyl)-3-hydroxybenzo[g]quinolone (2HP3HBQ),exhibit well-separated dual emission peaks attributable to Excited State Intramolecular Proton Transfer (ESIPT), thus offering promise as useful visible-absorbing ratiometric fluorescence probes. Time-resolved e...
An organic-inorganic nanohybrid system (AMC-CdS QD) comprised of a fluorescent carbazole analog, AMC (3-amino-N-methyl carbazole), and CdS QDs has been synthesized, which shows promise as a sustainable energy harvesting material. FT-IR and ¹H NMR spectroscopy have ascertained the covalent grafting of the carbazole moieties onto the mercaptopropioni...
Citations
... The last step in this sequence of processes is the ground state intramolecular proton transfer (GSIPT) reaction, converting the tautomeric form to the normal one. The ESIPT photoreaction (Scheme 1) is highly sensitive to substituents [15][16][17][18][19][20][21][22][23][24][25][26][27] and coordinated metal ions [28][29][30][31][32][33], protonation/deprotonation [34][35][36][37][38][39][40][41], the state of aggregation [42,43], the polarity of solvent [44][45][46][47][48] and the presence of various analytes [49][50][51][52][53][54][55][56]. If the excited state tautomerization (normal-to-tautomeric) is barrierless, the only form to emit is the tautomeric one, which typically luminesces with rather large Stokes shift [57,58]. ...
... The last step in this sequence of processes is the ground state intramolecular proton transfer (GSIPT) reaction, converting the tautomeric form to the normal one. The ESIPT photoreaction (Scheme 1) is highly sensitive to substituents [15][16][17][18][19][20][21][22][23][24][25][26][27] and coordinated metal ions [28][29][30][31][32][33], protonation/deprotonation [34][35][36][37][38][39][40][41], the state of aggregation [42,43], the polarity of solvent [44][45][46][47][48] and the presence of various analytes [49][50][51][52][53][54][55][56]. If the excited state tautomerization (normal-to-tautomeric) is barrierless, the only form to emit is the tautomeric one, which typically luminesces with rather large Stokes shift [57,58]. ...
... 23 However, semiconductor QDs are highly toxic, and organic dyes are easy to photobleach and have poor light stability. 24 Carbon dots (CDs) have the advantages of low toxicity, low cost, and environmental friendliness. The surfaces of CDs are rich in functional groups, which can be easily modied by biomolecules including aptamers and antibodies. ...