Serang Park’s research while affiliated with Queens University of Charlotte and other places

Metamaterials, in the form of perfect absorbers, have recently received attention for sensing and light-harvesting applications. The fabrication of such metamaterials involves several process steps and can often lead to nonidealities, which limit the performance of the metamaterial. A novel reciprocal plasmonic metasurface geometry composed of two plasmonic metasurfaces separated by a dielectric spacer was developed and investigated here. This geometry avoids many common fabrication-induced nonidealities by design and is synthesized by a combination of two-photon polymerization and electron-beam-based metallization. Infrared reflection measurements revealed that the reciprocal plasmonic metasurface is very sensitive to ultra-thin, conformal dielectric coatings. This is shown here by using Al2O3 grown by atomic layer deposition. It was observed experimentally that incremental conformal coatings of amorphous Al2O3 result in a spectral red shift of the absorption band of the reciprocal plasmonic metasurface. The experimental observations were corroborated by finite element model calculations, which also demonstrated a strong sensitivity of the reciprocal plasmonic metasurface geometry to conformal dielectric coatings. These coatings therefore offer the possibility for post-fabrication tuning of the reciprocal plasmonic metasurface resonances, thus rendering this novel geometry as an ideal candidate for narrow-band absorbers, which allow for cost-effective fabrication and tuning.

One-dimensional photonic crystals composed of alternating layers with high- and low-density were fabricated using two-photon polymerization from a single photosensitive polymer for the infrared spectral range. By introducing single high-density layers to break the periodicity of the photonic crystals, a narrow-band defect mode is induced. The defect mode is located in the center of the photonic bandgap of the one-dimensional photonic crystal. The fabricated photonic crystals were investigated using infrared reflection measurements. Stratified-layer optical models were employed in the design and characterization of the spectral response of the photonic crystals. A very good agreement was found between the model-calculated and measured reflection spectra. The geometric parameters of the photonic crystals obtained as a result of the optical model analysis were found to be in good agreement with the nominal dimensions of the photonic crystal constituents. This is supported by complimentary scanning electron microscope imaging, which verified the model-calculated, nominal layer thicknesses. Conventionally, the accurate fabrication of such structures would require layer-independent print parameters, which are difficult to obtain with high precision. In this study an alternative approach is employed, using density-dependent scaling factors, introduced here for the first time. Using these scaling factors a fast and true-to-design method for the fabrication of layers with significantly different surface-to-volume ratios. The reported observations furthermore demonstrate that the location and amplitude of defect modes is extremely sensitive to any layer thickness non-uniformities in the photonic crystal structure. Considering these capabilities, one-dimensional photonic crystals engineered with defect modes can be employed as narrow band filters, for instance, while also providing a method to quantify important fabrication parameters.

A new configuration for metasurface construction is presented to exhibit potential multi-functionalities including perfect absorption, bio/chem sensing, and enhancement of light–matter interaction. The reciprocal plasmonic metasurfaces discussed here are composed of two plasmonic surfaces of reciprocal geometries separated by a dielectric spacer. Compared to conventional metasurfaces this simple geometry exhibits an enhanced optical performance due to the hybrid plasmonic–photonic cavity. The discussed reciprocal metasurface design further enables effective structural optimization and allows for a simple and scalable fabrication. The physical principle and potential applications of the reciprocal plasmonic metasurfaces are demonstrated using numerical and analytical approaches.

A polymer-based, one-dimensional photonic crystal exhibiting anisotropic responses was demonstrated in the terahertz frequency range. The photonic crystal was composed of alternating compact and low-density polymethacrylate layers. The low-density layers consisted of sub-wavelength sized columns, which were slanted 45° with respect to the substrate surface normal to achieve form-birefringence. Normal incidence polarized terahertz transmission measurements were carried out for characterization of the fabricated photonic crystals in the range from 82 to 125 GHz. The experimental data revealed a 2 GHz shift in the center frequency of the photonic bandgap as a function of in-plane orientation, well demonstrating the anisotropic behavior of the fabricated crystal. The transmission data were analyzed using stratified optical layer model calculations. A good agreement was found between the relevant model parameters and the corresponding design parameters.

Mechanical tuning of a 3D-printed, polymer-based one-dimensional photonic crystal was demonstrated in the terahertz spectral range. The investigated photonic crystal consists of 13 alternating compact and low-density layers and was fabricated through single-step stereolithography. While the compact layers are entirely polymethacrylate without any intentional internal structures, the low-density layers contain sub-wavelength sized slanted columnar inclusions to allow the mechanical compression in a direction normal to the layer interfaces of the photonic crystal. Terahertz transmission spectroscopy of the photonic crystal was performed in a spectral range from 83 to 124 GHz as a function of the compressive strain. The as-fabricated photonic crystal showed a distinct photonic bandgap centered at 109 GHz, which blue shifted under compressive stress. A maximum shift of 12 GHz in the bandgap center frequency was experimentally demonstrated. Stratified optical models incorporating simple homogeneous and inhomogeneous compression approximations were used to analyze the transmission data. A good agreement between the experimental and model-calculated transmission spectra was found.

Mechanical tuning of a 3D-printed, polymer-based one-dimensional photonic crystal was demonstrated in the terahertz spectral range. The investigated photonic crystal consists of 13 alternating compact and low-density layers and was fabricated through single-step stereolithography. While the compact layers are entirely polymethacrylate without any intentional internal structures, the low-density layers contain sub-wavelength sized slanted columnar inclusions to allow the mechanical compression in a direction normal to the layer interfaces of the photonic crystal. Terahertz transmission spectroscopy of the photonic crystal was performed in a spectral range from 83 to 124 GHz as a function of the compressive strain. The as-fabricated photonic crystal showed a distinct photonic bandgap centered at 109 GHz, which blue shifted under compressive stress. A maximum shift of 12 GHz in the bandgap center frequency was experimentally demonstrated. Stratified optical models incorporating simple homogeneous and inhomogeneous compression approximations were used to analyze the transmission data. A good agreement between the experimental and model-calculated transmission spectra was found.

A polymer-based one-dimensional photonic crystal with a defect mode was demonstrated for the terahertz frequency range. The photonic crystal was designed to achieve a photonic bandgap centered around 100 GHz with a narrow defect mode at the center frequency. The defect mode allowed a narrow band transmission at the center of photonic bandgap, while the transmitted signal was suppressed in the rest of the bandgap. The photonic crystal incorporated two identical sets of alternating compact and low-density layer pairs symmetrically enclosing a defect layer. The compact layers consisted entirely of polymethacrylate with no intentional internal structures, while the low-density layers were composed of sub-wavelength-sized columns. The columnar structures had a volumetric fraction selected to provide a desired index contrast between the adjacent layers. The photonic crystal samples were fabricated in a single-step stereolithography using a commercial system. THz transmission spectroscopy measurements were carried out to determine the optical response of the sample in a range from 82 to 125 GHz. Stratified optical layer model calculations were used to evaluate the transmission data. A distinct photonic bandgap with a defect mode centered at 99 GHz was observed in the experimental transmission spectra. A good agreement between the relevant model parameters and the corresponding design parameters was found.

A new configuration for metasurface construction is presented to achieve multi-functional capabilities including perfect absorption, bio/chem sensing, and surface-mode lasing. The reciprocal plasmonic metasurfaces discussed here are composed of two plasmonic surfaces of reciprocal geometries separated by a dielectric spacer. Compared to conventional metasurfaces this simple geometry exhibits an enhanced optical performance. The discussed reciprocal metasurface design further enables effective structural optimization and allows for a simple and scalable fabrication. The physical principle and potential applications of the reciprocal plasmonic metasurfaces are demonstrated using numerical and analytical approaches.