S. Sengupta’s research while affiliated with Jadavpur University and other places

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Publications (73)


The Deformable Shell Model Calculation of Infrared Absorption Frequencies of Ionic Crystals
  • Article

January 1969

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5 Reads

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22 Citations

physica status solidi (b)

D. Roy

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A. N. Basu

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S. Sengupta

The deformable shell model which includes many-body effects and accounts for the breakdown of Cauchy relation is extended to the case of the CsCl structure. The TO mode frequencies for q = 0 are calculated for eight ionic crystals of both NaCl and CsCl structures. For comparison, the shell model values are also calculated. The results are compared with the infrared absorption frequencies. It is found that the deformable shell model gives better agreement than the shell model. The result is particularly striking for crystals showing a large Cauchy relation breakdown. Das deformierbare Schalenmodell, das Vielteilcheneffekte einschließt und für das Versagen der Cauchy-Beziehung verantwortlich ist, wird auf den Fall der CsCl-Struktur ausgedehnt. Die Frequenzen der TO-Schwingungsmode für q = 0 werden für acht Ionenkristalle sowohl der NaCl- als auch der CsCl-Struktur berechnet. Zum Vergleich werden auch die Werte des Schalenmodells berechnet. Die Ergebnisse werden mit den Infrarotabsorptionsfrequenzen verglichen. Es wird gefunden, daß das deformierbare Schalenmodell bessere Übereinstimmung als das Schalenmodell gibt. Die Ergebnisse sind besonders gut für Kristalle, die ein starkes Versagen der Cauchy-Beziehung zeigen.



A Deformable Shell Model for the Alkali Halides

January 1968

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12 Reads

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79 Citations

physica status solidi (b)

The simple shell model which takes account of the polarizability of the ions is improved by including the effect of deformations of the electron shell during the vibrations of the ions. The deformability is introduced in a phenomenological way and it is shown that this ultimately leads to three body interactions between like particles. Because of the inclusion of many body effects the elastic constants do not satisfy in general the Cauchy relation C12 = C44. The theory is applied to the calculation of the dispersion curves for NaI and the result is compared with the simple shell model curves and with the curves obtained by neutron diffraction experiments. Definite improvement of the agreement for the deformable shell model is noticed. Das einfache Schalenmodell, das die Polarisierbarkeit der Ionen berücksichtigt, wird durch Einbeziehung der Verformungen der Elektronenschalen während der Schwingungen der Ionen verbessert. Die Deformierbarkeit wird phänomenologisch eingeführt und es wird gezeigt, daß dies zu einer Dreikörperwechselwirkung zwischen gleichen Teilchen führt. Wegen der Einbeziehung der Vielkörpereffekte erfüllen die elastischen Konstanten im allgemeinen nicht die Cauchy-Relation C12 = C44. Die Theorie wird angewendet zur Berechnung der Dispersionskurven für NaJ und das Ergebnis wird mit Kurven nach dem einfachen Schalenmodell und mit Kurven, die durch Neutronenbeugungsexperimente erhalten werden, verglichen. Das Modell mit deformierbaren Schalen zeigt deutlich bessere Übereinstimmung.


Citations (26)


... Quantum Brownian motion (QBM, Caldeira and Leggett 1983) is paradigmatic for the field of open quantum systems theory (Breuer and Petruccione 2002). Description of quantum decoherence (Giulini et al 1996, Dugić 2004 as well as modeling of -quantum dissipation‖ is directly provided for QBM as a realistic physical situation with the well-defined classical counterpart. The usefulness of the QBM model places the model at the heart of applications regarding the nano-and mesoscopic systems and some artificial setups as well as regarding the related emerging technologies, e.g. ...

Reference:

The first and second moments for the quantum Brownian planar rotator in external harmonic classical field
Classical limit of quantum mechanics
  • Citing Article
  • March 1983

American Journal of Physics

... Venkataraman and Sahni, [124] and corrected by others in subsequent work. [212,213] The necessary molecular derivatives (both rotational and translational) are expressed as appropriate sums involving the corresponding derivatives applied to the interaction sites, which can be evaluated analytically. ...

Correct formulation of lattice dynamics of molecular crystals
  • Citing Article
  • April 1987

... However, a note on a comparison of these results to classical results may be worthwhile. Despite previous reports [33][34][35] on the difference between the classical and quantum mechanical definitions of scattering cross sections and the problem of classical limit, the general derivation of classical results from the quantum mechanics, i.e., the reduction theory, is still afar. While such calculations are outside of the current work, to compare the classical and quantum results, one may consider the more tangible case of a finite nanostructure. ...

Classical limit of scattering in quantum mechanics—A general approach
  • Citing Article
  • March 1997

Pramana

... Das Modell wurde in der Literatur genutzt, um die Eigenschaften von nanogefüllten teilkristallinen Thermoplasten nachzuvollziehen [155,156]. Unter Annahme des klassischen 2-Phasenmodells wurde das Modell zudem so modifiziert, dass das anisotrope elastische Verhalten nach starker Verstreckung beschrieben werden kann [157]. Weiterhin wurde das Modell erfolgreich angepasst, um das elastische Verhalten teilkristalliner Thermoplaste unter Berücksichtigung des 3-Phasenmodells zu beschreiben. ...

Mechanical properties of semicrystalline polymer-polypropylene
  • Citing Article
  • September 1982

Pramana

... In particular, one can try to directly evaluate the world-sheet integrals in closed-string genusone amplitudes thus obtaining lattice-sum representations of MGFs [1][2][3][4]18]. Although it is possible to extract the asymptotic expansion at the cusp τ → i∞ from some of these lattice-sum representations [39,48], this is nonetheless a hard task suggesting that a different approach might in general be necessary. ...

Evaluation of a new lattice sum
  • Citing Article
  • January 1985

Journal of Physics C Solid State Physics

... The Aharonov-Bohm (AB) effect is an authentic quantum phenomenon and was first considered in [19,18,1]. There are many discussions about the justification of the famous Aharonov-Bohm Hamiltonian and interpretations (see, for instance, [2,7,8,9,11,15,20,22,26,28,30] and references therein); the questions are particularly interesting for the more realistic case of solenoids S of radii greater than zero. Sometimes it involves the quantization in multiply connected regions, and the main points to be clarified are the presence of the vector potential A in the operator action (occasionally in regions with no magnetic field), and the (natural) choice of Dirichlet boundary conditions at the solenoid border. ...

A critical re-examination of the Aharonov-Bohm effect
  • Citing Article
  • October 1983

American Journal of Physics

... (6) have also been used in the literature to simulate pressure effects on atoms with the extreme pressure polarized continuum model (XP-PCM). 62,[90][91][92][93][94][95][96][97] Again, from the Schrödinger equation, while the first derivative is now continuous as long as V 0 is finite, 98,99 it appears that the discontinuity in the potential of eq. (6) is reflected by a finite jump in the second derivative of the resulting orbital. ...

Discontinuity in the first derivative of the Schrödinger wave function
  • Citing Article
  • June 1982

American Journal of Physics

... With the rotational invariance and equilibrium conditions correctly applied, the phonon dispersions of 158 materials become real and display a quadratic ZA branch in the longwavelength limit. The remaining 87 materials are either dynamically unstable (54) or require tighter numerical convergence (33). ...

On born-huang invariance conditions
  • Citing Article
  • September 1977

physica status solidi (b)

... This phase space describes semiclassical electron dynamics in a magnetic Bloch band, with periodic potential in an external magnetic field and Berry curvature [7]. This fluid dynamics is relevant in electron hydrodynamics in condensed matter, where electron flow obeys hydrodynamic laws instead of Ohmic [8]. Generically electrons in metals act as nearly-free Fermi gas with a large mean free path for electron-electron collision. ...

An electron fluid model for the lattice dynamics of metals
  • Citing Article
  • February 1977

Pramana