Richard J. Roby's research while affiliated with Combustion Science Engineering, Inc and other places
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Publications (75)
It is estimated that 30% of the over 1 billion cubic feet per day of natural gas produced in the Bakken shale field is lost to flaring. Collected and used in DLE power generation gas turbine engines, this gas represents approximately 1.2 GW of collective power. While the main reason that much of this gas is flared, is that the infrastructure in the...
Nearly all states now have renewable portfolio standards (RPS) requiring electricity suppliers to produce a certain fraction of their electricity using renewable sources. Many renewable energy technologies have been developed to contribute to RPS requirements, but these technologies lack the advantage of being a dispatchable source which would give...
The current investigation examines suitability of the hydraulic analog for analysis of fire-induced dispersion within a complex enclosure. This analog has been implemented using salt-water modeling and planar laser induced fluorescence (PLIF) diagnostics providing quantitative visualization of simulated fire-induced flows. The non-intrusive PLIF di...
Autopsy and injury data from victims of fire may provide the investigator with important, discriminant, scientific evidence to assist in origin and cause determination. Through the combined use of fire testing, fire modeling, and physiological modeling, the fire investigator may be able to test or further validate their origin and cause hypothesis(...
A Lean, Premixed, Prevaporized (LPP) combustion technology has been developed that converts liquid fuels into a substitute for natural gas. This gaseous fuel can then be burned with low emissions in place of natural gas in a wide range of combustion devices. The fuel preparation system overcomes the operational and emissions barriers associated wit...
Assigning a level of significance to cyanide concentrations found in the blood of fire victims is often hampered by the fact that cyanide is inherently unstable in cadavers and in stored blood samples. A few researchers have proposed that sodium fluoride can be used to minimize the instability of cyanide in blood samples; however, controlled studie...
Assigning a level of significance to cyanide concentrations found in the blood of fire victims is often hampered by the fact that cyanide is inherently unstable in cadavers and in stored blood samples. A few researchers have proposed that sodium fluoride can be used to minimize the instability of cyanide in blood samples; however, controlled studie...
Currently there is very little data available for jet fuel oxidation at low pressure, vitiated conditions found in some aircraft combustion systems. Due to the lack of this information, current kinetics models do not have the necessary data for validation within these combustions regimes. A previous screening study [1] by the authors has shown that...
A Lean, Premixed, Prevaporized (LPP) combustion technology has been developed that converts liquid fuels into a substitute for natural gas. This fuel can then be burned with low emissions in virtually any combustion device in place of natural gas. This technology offers the possibility of using unprocessed oil-field Natural Gas Condensate (NGC) for...
A Lean, Premixed, Prevaporized (LPP) combustion technology has been developed that converts liquid biofuels, such as biodiesel or ethanol, into a substitute for natural gas. This fuel can then be burned with low emissions in virtually any combustion device in place of natural gas, providing users substantial fuel flexibility. A gas turbine utilizin...
Emissions test results from operation of a commercial dry, low-emissions
Capstone gas turbine demonstrate the commercial feasibility of using the Lean,
Premixed Prevaporized (LPP) Technology to burn a range of light liquid fuels in a
power generation gas turbine, without water injection, while simultaneously
achieving ultra-low, natural-gas-level e...
Klassen et al. recently published a comprehensive study examining the radiant energy transmission properties and breakage
properties of multi-pane glazing. That work was conducted at the bequest of code officials who wanted to understand the implications
of stipulations in the building and fire codes on safety and weigh these against the need to ma...
Flammable liquid fuel spills on flooring including carpets and other porous materials have long been a subject of interest
to the fire investigation community. Early understanding in this community about the indicators of a liquid fuel fire, such
as holes in flooring material or heavy burning in this area, have been shown to be incomplete. Research...
Autoignition delay experiments in air have been performed in an atmospheric flow reactor using typical natural gas components, namely methane, ethane and propane. Autoignition delay measurements were also made for binary fuel mixtures of methane/ethane and methane/propane and ternary mixtures of methane/ethane/propane. The effect of CO2 addition to...
A Lean, Premixed, Prevaporized (LPP) combustion technology has been developed that converts liquid biofuels, such as biodiesel and ethanol, into a synthetic natural gas. This LPP gas can then be burned with low emissions in virtually any combustion device in place of natural gas, providing users substantial fuel flexibility. A Dry Low Emissions (DL...
The presence of significant amounts of H 2O, CO 2, CO, and NO in vitiated air at reduced O 2 levels is thought to play a role on the chemical kinetics of jet fuel oxidation, specifically on the ignition and extinction phenomenon. Current kinetics models can predict ignition and extinction of hydrocarbon fuels (e.g. JP-8); however considerable uncer...
Large Eddy Simulations (LES) were performed to predict the flame profile of bluff-body stabilized premixed flame at stable and blow-out conditions. Probability density function (PDF) based approach was used to solve the scalar transport by fully resolving the chemical source term with 14 species, 44 step propane reduced chemical kinetic mechanism u...
Large Eddy Simulations (LES) were performed to investigate the effect of turbulence - chemistry interaction on flame instability and flame-vortex interactions in bluff body stabilized premixed flames. A semi-global reduced kinetics mechanism and a skeletal mechanism were developed and implemented with a Laminar Chemistry (LC) model and an Eddy Diss...
The toxicological and postmortem analysis of fire victims' blood and tissue can disclose the type and quantity of toxic species,
such as carbon monoxide or hydrogen cyanide, that they inhaled prior to death. For fire cases, these toxicological data can
reveal objective data about the nature and circumstances of a fire, and thus assist both the Medi...
Dry low emission (DLE) systems employing lean, premixed combustion have been successfully used with natural gas in combustion turbines to meet stringent emission standards. However, the burning of liquid fuels in DLE systems is still a challenging task due to the complexities of fuel vaporization and air premixing. Lean, premixed, and prevaporized...
This study chronicles the development and integration of a smoke detector activation algorithm (known as the SDAA) that describes the response time of a smoke detector into a large eddy simulation (LES) fire model [Roby RJ, Olenick SM, Zhang W, Carpenter DJ, Klassen MS, Torero JL. Smoke detector activation algorithm version 1 technical reference gu...
A statistical study was conducted to compare the performance of different residential smoke detector technologies when exposed
to different fire types. In order to facilitate comparisons between different fire and smoke growth rates, a non-dimensional
smoke detector activation relative time was employed. Data from four major experimental studies wa...
A Lean, Premixed, Prevaporized (LPP) combustion technology has been developed that converts liquid biofuels, such as biodiesel or ethanol, into a substitute for natural gas, called LPP Gas™. This LPP Gas™ can then be burned with low emissions in virtually any combustion device in place of natural gas, providing users substantial fuel flexibility. A...
The majority of victims in building fires are found at locations distant from the burning compartment. Experiments were conducted
in a reduced scale facility to quantify the effects of air entrainment and stoichiometry of gases entering the hallway on
the CO yield at locations remote from a burning compartment. Scaling parameters for the air entrai...
Ignition delay times of a “real” synthetic jet fuel (S8) were measured using an atmospheric pressure flow reactor facility. Experiments were performed between 900 K and 1200 K at equivalence ratios from 0.5 to 1.5. Ignition delay time measurements were also performed with JP8 fuel for comparison. Liquid fuel was prevaporized to gaseous form in a pr...
The Integrated Gasification Combined Cycle (IGCC) technology, as currently
defined, couples a complex coal gasification process plant with a syngas-fired
combustion turbine combined cycle power plant. The IGCC process is a two-stage
combustion operation with cleanup between the stages. The first stage
employs a gasifier where partial oxidation of t...
Atmospheric pressure flow reactor experiments were performed to measure the ignition delay times of JP7, JP8, and S8 fuels between 900 K and 1200 K. The equivalence ratio of fuel/air mixtures was varied between 0.5 and 1.5. Based on the ignition delay time measurements, the overall activation energies for JP7, JP8, and S8 were determined to be 33,3...
Experimental and kinetic modeling of kerosene-type fuels is reported in the present work with special emphasis on the low-temperature oxidation phenomenon relevant to gas turbine premixing conditions. Experiments were performed in an atmospheric pressure, tubular flow reactor to measure ignition delay time of kerosene (fuel-oil No. 1) in order to s...
Analytical techniques, such as gas chromatography/mass spectrometry (GC/MS), can identify the presence of an ignitable liquid residue (ILR) in fire scene debris. However, this technique is not currently used to determine whether the presence of an ILR indicates that an ignitable liquid was used to initiate a fire or was the result of contamination...
successfully used with natural gas in combustion turbines to meet stringent emissions standards. However, the burning of liquid fuels in DLE systems is still a challenging task due to the complexities of fuel vaporization and air premixing. Lean, Premixed, Prevaporized (LPP) combustion has always provided the promise of obtaining low pollutant emis...
Dry low Emissions (DLE) systems employing lean, premixed combustion have been successfully used with natural gas in combustion turbines to meet stringent emissions standards. However, the burning of liquid fuels in DLE systems is still a challenging task due to the complexities of fuel vaporization and air premixing. Lean, Premixed, Prevaporized (L...
Hydrocarbons become viable alternatives to hydrogen at Mach numbers below 10, because of greater fuel densities and endothermic cooling capabilities. However, hydrocarbons show difficulties for flame holding under supersonic conditions due to their long ignition delay times. Thus, developing reduced kinetic models that are capable of predicting ign...
A series of small and large-scale tests were performed to measure the radiant transmission of energy and the window breakage
characteristics of seven different multi-plane glazing samples. The samples tested included both double and triple-pane glazing
specimens with a laminate interlayer between panes for additional strength. These test series wer...
The reduced kinetic mechanism for syngas/methane developed in the present work consists of a global reaction step for fuel decomposition in which the fuel molecule breaks down into CH2 O and H2 . A detailed CH2 O/H2 /O2 elementary reaction sub-set is included as the formation of intermediate combustion radicals such as OH, H, O, HO2 , and H2 O2 is...
A study was performed to determine the use of an equivalence ratio to predict gas levels (CO, CO2, O2, and unburned hydrocarbons) transported to locations remote from a post-flashover compartment fire. A series of tests were
conducted in a reduced-scale facility to measure the evolution of post-flashover compartment fire gases flowing down a hallwa...
The objective of this work is to develop a detailed kinetic mechanism for low temperature kerosene oxidation, which is essential to predict premature auto-ignition of liquid fuels in gas turbines and cool flame behavior in hydrocarbon reformers for fuel cells. Kerosene, a fractional distillate of petroleum known by its generic term, is comprised of...
This study integrates a time lag dynamic response algorithm that describes the response time of a smoke detector and a smoke aerosol tracking procedure into a Large Eddy Simulation (LES) fire model. The LES fire model predicts the smoke concentration adjacent to the detector while a time lag dynamic response algorithm and describes the transport of...
The occurrence of a liquid fuel burning on carpet has been involved in many incendiary and accidental fires. While the research on a liquid fuel fire on carpet is still limited, much work on porous media has been performed using sand or glass beads soaked with liquid fuel. In this study, a heat and mass transfer theory was first developed to analyz...
A need exists for advanced kinetics-based modeling tools to assist engine builders in the design and development of high FAR engines. Combustion Science & Engineering, Inc. (CSE) has successfully developed a flexible computational tool based on chemical reactor modeling (CRM) for the initial stages of gas turbine combustor design. Subroutines have...
A series of UL/EN based test fires was conducted in a two room/corridor enclosure to investigate the viability of methods for determining whether a smoke detector sounded under a variety of smoke conditions and to see if this methodology could be applied to a detector with a different horn configuration. The presence of enhanced deposition in the f...
This is a study into the ability of the Fire Dynamics Simulator - Version 1.0 (FDS 1.0) to predict smoke detector activation. FDS is a field computer model that has shown promise in the modeling of fire phenomena. Two methods were used to create a first order approximation of the ability of FDS to predict smoke detector activation. First, the fluid...
Fire and smoke movement in a room is influenced by the turbulence characteristics (such as Reynolds stress, turbulent heat flux, etc.) of the flow and temperature fields. In order to accurately predict fire and smoke movement by computational fluid dynamics (CFD), it is necessary to verify these turbulence quantities. The purpose of this study is t...
The objective of this work was to assess the feasibility of reducing false alarms while increasing sensitivity through the use of combined conventional smoke detectors with carbon monoxide (CO) sensors. This was accomplished through an experimental program using both real (fire) and nuisance alarm sources. A broad selection of sources was used rang...
A full-scale house fire test was conducted to investigate the accuracy of two proposed methods for determining whether a smoke or carbon monoxide (CO) alarm sounded during a smoke exposure. One method involves examining the plastic case of the alarm's piezoelectric horn for locally enhanced soot deposition and agglomerated soot particles. The other...
Nitrogen oxide emission requirements for gas turbines are becoming tighter and tighter and control options differ widely in terms of cost, retrofitability and performance. For gas turbines used less than 500 hours per year, the use of hydrogen-enriched natura gas may represent a favorable economic alternative. An analysis of laboratory data and a s...
A screening level study has been carried out to examine the potential of using H2-enriched natural gas to improve the combustion performance of gas turbines. H2 has wider flammability limits and a higher flame speed than methane. Many previous studies have shown that when H2 is added to fuel, more efficient combustion and lower emissions will resul...
A screening level study has been carried out to examine the
potential of using H2-enriched natural gas to improve the combustion
performance of gas turbines. H2 has wider flammability limits and a
higher flame speed than methane. Many previous studies have shown
that when H2 is added to fuel, more efficient combustion and lower
emissions will resul...
It is known that many of the previously published global methane oxidation mechanisms used in conjunction with computational fluid dynamics (CFD) codes do not accurately predict CHâ and CO concentrations under typical lean-premixed combustion turbine operating conditions. In an effort to improve the accuracy of the global oxidation mechanism under...
This experimental study was performed to determine the effects of wood pyrolyzing in a high-temperature, vitiated compartment upper layer on the environment inside the compartment and an adjacent hallway. This was done by comparing species concentrations and temperature measurements from tests with and without wood in the compartment upper layer. E...
A non-intrusive, fast-response method for the determination of temperature and equivalence ratio has been developed for laminar and turbulent premixed methane/air flames. This method utilizes chemiluminescent flame emissions to make correlations with flame temperature and equivalence ratio. Emissions from two radical groups were used for the correl...
Predicted flow, temperature, and emissions (CO and NO) concentration fields are presented for an axi-symmetric, swirl-stabilized gas turbine combustor operating at approximately 10 atmospheres. Flow field and emissions predictions were obtained by incorporating four different global kinetics mechanisms into the commercially available STAR*CD CFD co...
This report provides technical information for making baseline hydrocarbon measurements in a Class B fire scenario. The automotive industry along with the Environmental Protection Agency has expended a great deal of effort trying to measure reliably hydrocarbon emission from engines. These studies show a 20% error at concentrations less than 1000 p...
An experimental study was conducted to investigate the transport of high concentrations of carbon monoxide (CO) from a burning compartment located on the side of a hallway. Opening sizes of 0.04 and 0.12 m 2 were used to vary the ability of the jet of fire products entering the hallway to entrain surrounding gases. By controlling the depth of the u...
Unexpectedly high concentrations of NOâ have been noted in stack emissions from industrial combustors. NOâ formation has been reported to occur through the so-called HOâ mechanism in which NO combines with HOâ to produce NOâ and OH. In this study, the formation of NOâ was investigated at superatmospheric pressures through experiments and computer m...
The objective of this study was to assess the effect of temperature on carbon monoxide production in compartment fires in order to resolve the difference between global equivalence ratio-yield correlations obtained in simplified upper layer environments and more realistic compartment fires. The chemical reactivity of upper layer gases was studied u...
A band brake is often used as a braking device in an automatic transmission because it fits around the clutch drum and does not require additional space. Its friction characteristics vary depending on the oil film between the brake band and the drum. Less friction force occurs under lower pressure and greater lubrication. In this study, the relatio...
A fast response chemiluminescent flame detection approach is presented along with field test results from a fiber optic based flame detector device. Chemiluminescence, the light given off by molecules formed in their excited states, has long been recognized as a diagnostics method for use in combustion. The recent advent of higher quality optical f...
The overall scope of this research is to investigate the phenomena that control the generation and oxidation of compartment fire exhaust gases, specifically carbon monoxide (CO), total unburned hydrocarbons (THC) and soot, which are transported down an adjacent corridor. The first year of the investigation concentrated on the formation of exhaust g...
The oxidation of underventilated compartment fire exhaust gases during their transport down a corridor adjacent to the compartment was experimentally investigated. External burning from a compartment has been reported to decrease the toxic exhaust gas levels downstream of the compartment. The focus of the investigation was to identify the phenomena...
Turbine blade surface temperatures were studied during transient operation in a turbofan engine test rig. A single fiber radiation pyrometer was used to view the suction side of the blades from approximately 60% axial chord to the trailing edge at an average radial location of 70% blade height. A single ceramic-coated blade produced a once-per-revo...
A Dual-Frequency microwave burn-rate measurement system for solid rocket motors has been developed. The system operates in the X-band (8.2-12.4 GHz) and uses two independent frequencies operating simultaneously to measure the instantaneous burn rate in a solid rocket motor. Computer simulation and limited laboratory testing of the system were perfo...
The development of empirical correlations for major species yields in compartment fires has become an important priority due to the inability to calculate these quantities from first principles. Studies of simplified upper layer environments have shown that major species production rates can be correlated with the equivalence ratio in what is known...
An experimental investigation has been completed which examined the breaking of window glass by fire. The experiments were carried out in a compartment designed to achieve a two-layer fire environment characteristic of normal building fires. The experi mental data was collected from two test groups: the first for windows with their edges insulated...
BACKGROUND A fire occurred in a residential structure in the early morning hours one day in September. At the time of the fire, three people were in the residence, two parents (age 81, male and age 57, female) and their son (age 31). The two-story house was composed of typical wood frame construction, and was built in approximately 1971. The downst...
Citations
... The addition of 1% sodium fluoride may inhibit this phenomenon. This latter point appears to be confirmed by McAllister et al. [90], who showed that the post mortem blood cyanide concentrations of subjects who had died in a fire increased by 35% between the 25 th and the 30 th day, compared with subjects who had died in the same conditions and in whom sodium fluoride had been added to the blood specimens. The specimens were stored at 4°C for the entire duration of the experiments. ...
... Literature studies focused on boilers mention potentialities for CO and NO x reduction [9] [16] [28]. Regarding CO production, it is reasonable to expect a decrease with the H 2 percentage increase -at least until a certain threshold level -because of several aspects: faster chemistry, reduction of flame quenching distance, extension of flammability range, increase in OH radicals (promoting the oxidation of CO to CO 2 [30]) and, naturally, decrease of total carbon in the reactants. A cornerstone about CO production with hydrogen enrichment is the fact that current gas fired devices, nominally working with methane, are already required to safely work with limit gases containing H 2 (see Table 2): this is an indication that a safe operation in terms of CO emission can be achieved with H 2 content up to 23%, even in today's boilers. ...
... NG can be mixed with other more reactive fuels to improve its combustibility. In fact, given that even the world is far from an economy of hydrogen, in which thermal systems only work with said fuel in its entirety [10], international studies on the rate of combustion of hydrogen mixtures have generally been carried out with natural gas or methane, the main component of natural gas [16,17]. ...
... Indeed, optical measurements, given adequate equipment and deconvolution algorithms may provide spatially resolved results [73,52,54]. In this context, Kojima et al. [54], Roby et al. [82], Morrell et al. [72] found that C 2 *, OH* and CH* are the most suitable chemiluminescent species to correlate with the equivalence ratio as their ratios exhibit a nearly linear trend with " in the ranges 0.6 † " † 1.2 and 0.9 † " † 1.5. Note that, while these ranges also covers rich flames, they are still outside of the range of interest for the experiments covered in this work, namely, 0.25 † ⁄ † 0.5. ...
... There is a great opportunity for GMT to transform the biogas to electricity and heat source for the evaporation unit to reduce the amount of liquid in digestate produced by the plant. Progressive method is introduced by Holton et al. [62]. Their paper introduces technology to vaporize liquid ethanol and blend with natural gas to create combustion mixture that could replace natural gas in combustion devices. ...
... 9 With the development of computational technique, high spatial/temporal accuracy numerical accuracy simulation has provided researchers with powerful tools in flames dynamic analysis close to LBO. In the study of flame dynamics near LBO, LES-CMC (Large Eddy Simulation-Conditional Moment Closure) model was employed by Tyliszczak et al. 10 LES-PDF (Probability Density Function) model by Black and Smith 11 and Gokulakrishnan et al. 12 LES-EBU (Eddy Break-Up) model by Kim et al. 13 LES-EDC (Eddy Dissipation Concept) model by Gokulakrishnan et al. 14 LES-LEM (Linear Eddy Mixing) model by Menon et al. 15 and LES-LTEM (Lagrangian Transport Element Method) model 16 by Erickson et al. When the combustion was close to LBO, similar flame behavior was detected in these simulation works. ...
... The presence of NO x (NO and NO 2 ) in the oxidizer stream occurs in various practical devices where combustor design includes exhaust (or flue) gas recirculation (e.g., internal combustion engines and furnaces), vitiated air (e.g., gas turbine exit streams, and high-speed propulsion test rigs), and internal recirculation zones (e.g., gas turbines). Previous works by the authors [3][4][5] showed that NO x plays a significant role in promoting ignition of jet fuels and its surrogate components. Experimental and direct numerical simulation studies of Lee et al. [6] have demonstrated the importance of NO on the reignition process of a vortex-perturbed counter flow flame. ...
... Numerical methods, especially Large Eddy Simulations (LES), have made it possible to model combustion transients' phenomena with high temporal and spatial resolution. During the past decade, LES has developed in a variety of directions: a linear eddy model (LEM) (14)(15)(16)(17) , an Eddy Break-up Model (EBM) (18) , an eddy dissipation 240 February 2017 The Aeronautical Journal concept (EDC) (19) , and probability density functions (PDF) (20) . Menon, based on LES-LEM (16,17,21) , attained the flame distortion and variation in flame spread velocity but did not succeed in capturing eddies that mostly effect the local extinction. ...
... The internal recirculation can be achieved through an internal air distribution system coupled with unique curvature of the combustor's liner, [9][10][11][12] or using high speed jets at the entrance to the combustor, [13][14][15][16]. The effect of air vitiation on the combustion characteristics was described in several studies; see for example, [17][18][19] and it was consistently shown that vitiation (lower oxygen content) increases ignition delay. ...
... The Taxibot is in operation at Schiphol [518], Delhi and Bangalore airports [519], and serves Lufthansa [517]. Currently, it is powered whether by electric or diesel engines [518], but the vision is to power them with 100% batteries or hydrogen in the future [21,520]. ...