February 2025
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24 Reads
Journal of the Indian Chemical Society
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February 2025
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24 Reads
Journal of the Indian Chemical Society
February 2025
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9 Reads
Defence Technology
December 2024
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26 Reads
Dyes and Pigments
November 2024
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16 Reads
September 2024
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80 Reads
The overwhelming emergence of nanotechnology, encompassing nanoparticles, nanofibers, nanotubes, and more, is evident. Nanotechnology revolves around materials with dimensions ranging from 1 to 100 nm. The transformation of materials into their nanoform yields distinct properties, offering added functionalities and increased benefits. Among the most ancient and essential industries in society lies the textile sector. While this industry continually advances, integrating nanotechnology into its realm can yield significant advantages. This chapter dives into the incorporation of nanotechnology pertaining to coating and finishing sectors of the textile industry. It subsequently expands to cover synthesis methods like electrospinning, chemical vapor deposition, and various characterization techniques, providing a comprehensive overview. Nanotechnology has already propelled textiles to the forefront commercially, manifesting as finishes with antimicrobial, anticorrosion, flame-retardant properties, and more. However, the research and commercial adoption of these materials still lack the necessary momentum. The discussion further explores diverse application areas where nanomaterial coating and finishing play a central role. Ultimately, the chapter concludes by outlining anticipated future trends and overarching considerations.
August 2024
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33 Reads
Fibers and Polymers
Over the generations, the textile industry has built a reputation as one of the world’s biggest water consumers and polluters. Today, the shift in environmental and social awareness impacts textile markets and production techniques. This paper describes a unique way to reduce the intake of freshwater for the dyeing process in the textile industry. Efforts have been made to utilize reactive, basic, and direct dye-bath effluents directly as liquor in polyester dyeing for 0.5, 2, and 4% shade of primary colors. The obtained result shows that the fabric dyed in effluents has acceptable color strength and color difference as that of the conventional dyeing process with freshwater. The fastness properties of all the dyed fabrics were good to excellent. Thus, this process can effectively reduce the intake of freshwater by about 30,000 L/ton. Also, it has an economic benefit and can save 450 Rs/ton. Thus, the findings prove that effluents generated from the cotton dyeing unit can be used directly for polyester dyeing.
April 2024
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335 Reads
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3 Citations
Composite Interfaces
April 2024
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65 Reads
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2 Citations
This study attempts a successful synthesis of a cellulose‐based adsorbent using orthophosphoric acid as a chemical activating agent followed by pyrolysis. A detailed characterization of synthesized adsorbent in terms of its morphology, material crystallinity, and surface area was studied. Batch studies were performed to remove reactive blue 19 dye from its simulated wastewater. The impact of various adsorption parameters such as adsorbent dosage (A: 0.1 to 0.5 g), initial dye concentration (B: 100 to 500 mg/L), contact time (C: 10 to 180 min), pH (D: 2 to 10), temperature (E: 35 to 60 °C) were examined and optimized using on Box‐Behnken method with Response Surface Methodology. The experimentally obtained adsorption data were fitted to different isotherms and kinetic models. The findings prove that more than 96 % of 400 mg/L of RB19 dye removal is possible with 4 g/L dosage in 18.5 min at 50 °C with its original pH of 6.8. Also, three cycles of regenerability and reusability of CBA gives 51.88 % of RB19 dye removal. Moreover, the possibility of using spent adsorbent in the boiler as a fuel was explored. Consequently, this research will contribute to SDG6 by maintaining circularity and sustainability in the entire process.
March 2024
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114 Reads
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1 Citation
This study focuses on the development of an advanced chemical protective filter material to be used in Nuclear, Biological and Chemical (NBC) protective gears. The NBC protective clothing mainly consists of three layers- outer, middle, and inner layers. Specific features like flame retardancy, oil repellency, water repellency, and antistaticity are imparted in the outer layer, while the innermost layer, which remains close to the body consists of features providing comfort and safety. The middle layer is a filter layer made of adsorbent material. Activated Carbon Fabric (ACF) is a versatile textile material owing to its high surface area, meso and microporosity, flexibility, and ease of lamination onto various substrates. However, due to its fragility, lamination of ACF onto a substrate is recommended to provide strength to it. In the present work, a coating of poly (diallyl dimethyl ammonium chloride) (PDDA) was developed onto the ACF surface using the dip coating method to improve the tensile strength of the fabric without sacrificing its comfort and chemical properties. Polymer-coated ACF (PDDA@ACF) samples were characterized by scanning electron microscope (SEM), Fourier transform infrared (FTIR) spectroscopy, Thermogravimetric analysis (TGA) and Brunauer–Emmett–Teller (BET) surface area analyser. Samples were tested for tensile strength and air permeability. The performance evaluation of the developed coated fabric was determined as per IS 17377 against Sulphur Mustard (HD), a chemical warfare agent. The analysis confirmed the successful introduction of PDDA onto the surface of ACF. Tensile and air-permeability test results revealed improvements in mechanical and comfort properties, respectively. A marginal reduction in BET surface area was observed which may be attributed to the presence of polymer over the structure of ACF. The chemical protection performance was found as per the requirement of NBC protective clothing (BTT > 24h).
February 2024
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186 Reads
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4 Citations
Iranian Polymer Journal
The present research work deals with the preparation of semi-synthetic leather using fruit vegetable waste, acrylic polymer resin, and additives. Glycerol and polyvinyl acetate were used as additives to improve the flexibility and crack resistance properties. The leather film was prepared by pouring a mixed solution containing fruit vegetable waste powder, acrylic resin, and additives into the aluminium mold and drying in the oven at 120 °C for 4 h. Optimization of the concentration of acrylic resin, polyvinyl acetate, glycerol, as well as the powdered fruit vegetable waste, was studied. The characterization was performed to analyze mechanical properties and structural analysis using standard testing methods and instruments. The findings disclose that the optimized specimen with a recipe of 40% acrylic resin, 5% fruit vegetable waste powder, 5% polyvinyl acetate, 5% glycerol, and 45% water exhibits tensile strength of 112.1 N, elongation of 91%, tear strength of 15.06 N, and flexural rigidity of 62.44 mg.cm. It was also observed that the concentration of the acrylic resin, powdered fruit vegetable waste, and additives have a significant correlation with the mechanical properties. The abrasion resistance of the film was excellent for 20,000 abrasion cycles. FTIR analysis confirmed no alteration in the chemical structure after film preparation.
... However, rather than relying solely on mathematical models for comparative studies of dye removal from binary and ternary mixtures, the research could pivot towards practical experimentation using real textile effluent samples. This approach allows for a more accurate assessment of treatment methods under realistic conditions where controlling specific dye concentrations may be challenging [12]. ...
April 2024
... Patil et al. [115] introduced 5% fruit vegetable waste powder into a composition based on acrylic polymer resin, glycerol, and polyvinyl acetate for the purpose of fabricating a semi-synthetic leather, which exhibited an abrasion resistance of 20,000 abrasion cycles. ...
February 2024
Iranian Polymer Journal
... Additionally, high production costs remain a challenge to the industrial application of nanocellulose in agricultural products. Therefore, the development of agricultural waste biomass-based nanocellulose with high quality for application in high value-added fields, such as biomedicine or pharmacy, could be one solution to make up for the high production cost (Liu et al. 2016;Yu et al. 2021;Biranje et al. 2022Biranje et al. , 2023. Using low-cost agricultural waste biomass as raw materials to prepare full-component nanofibers that meet agricultural production applications is expected to be another solution to this challenge. ...
April 2023
... However, high cost and low production are some of the obstacles faced by this technique. New advancements are being carried on increasing the production opening scope for commercialization, among which multi-needle electrospinning is one of them, where instead of single needle multiple needles simultaneously work to produce the nanofibers [43,83]. ...
March 2023
... This effect occurs because CS disrupts the cell wall of bacteria, infiltrating and disturbing their normal physiological functions owing to the positive charge of -NH 3 + in chitosan. 147,148 Research by Patankar et al. 149 supported the flame-retardant potential of chitosan chemically modified with melamine and sodium pyrophosphate, which serve as nitrogen and phosphorus sources, respectively. The modified chitosan-treated cotton fabrics exhibited not only fire-retardant properties, but also UV protection and antibacterial effects, although the mechanical properties of the fabrics were slightly compromised, remaining within acceptable textile standards. ...
October 2022
Materials Today Communications
... Superhydrophobicity requires a specific surface roughness and low surface energy combination. To develop such surfaces, researchers and industries are increasingly drawing inspiration from nature, mimicking biological systems and structures to create innovative hydrophobic materials [14,15]. Superhydrophobic surfaces are highly sought after because of their potential for numerous advanced applications. ...
June 2022
Materials Today Chemistry
... HBT architecture (4), in general, has been constructed from the condensation of salicylaldehyde (1) or salicylic acid (2) and their derivatives with 2-aminothiophenol (3) in the presence of various reagents such as H 2 O 2 /HCl [29,30,38,52,73], I 2 [31] and methanol, PCl 3 [32,34,37,74,78], dimethylsulfoxide (DMSO) [33], PPA [39,43,44,59,75,76], Na 2 S 2 O 5 [51,53,57,66,67,69], NH 2 SO 3 H [65], indion-190 resin [77], etc. Further, conjugation on the fluorophore is achieved by substitutions on the phenolic and benzothiazole parts of the fluorophore by coupling through Pd/C [74,78], Suzuki [30,32,34,35,37,38], Heck [29], and Sonagshira [29,36] methods which afford target compound (5) (Scheme 1). The synthesis of fluorophores which is not covered in the general Scheme 1, have been mentioned separately in the preceding section. ...
April 2022
Polycyclic Aromatic Compounds
... In conventional textile dyeing, 1 tonne of fabric could result in the pollution of up to 200 tonnes of water. The wastewater produced in textile processes is highly colored and contains complex concentrations of chemicals, such as salt, dye, detergents, peroxides, and heavy metals [3][4][5]. In addition to water pollution, other environmental issues emerge from the burning of fossil fuels, which result in atmospheric emissions and contribute to climate change and greenhouse gases. ...
January 2022
... Another research study describes a chemical method of modifying keratin with melamine (a nitrogen-rich compound) and sodium pyrophosphate (a phosphorus-rich compound) for use as a flame-retardant additive for cotton fabrics. The limiting oxygen index (LOI) of cotton after the application of modified keratin increased by ~ 66.7% compared to that obtained on untreated cotton (Patankar et al., 2021). The use of keratin and tannin derived from renewable biomass (rich in polyphenols) as a reinforcing agent in the polyamide 66 (PA66) matrix was studied, in order to improve the fire-retardant and anti-drip performance. ...
November 2021
Cleaner Engineering and Technology
... HBT architecture (4), in general, has been constructed from the condensation of salicylaldehyde (1) or salicylic acid (2) and their derivatives with 2-aminothiophenol (3) in the presence of various reagents such as H 2 O 2 /HCl [29,30,38,52,73], I 2 [31] and methanol, PCl 3 [32,34,37,74,78], dimethylsulfoxide (DMSO) [33], PPA [39,43,44,59,75,76], Na 2 S 2 O 5 [51,53,57,66,67,69], NH 2 SO 3 H [65], indion-190 resin [77], etc. Further, conjugation on the fluorophore is achieved by substitutions on the phenolic and benzothiazole parts of the fluorophore by coupling through Pd/C [74,78], Suzuki [30,32,34,35,37,38], Heck [29], and Sonagshira [29,36] methods which afford target compound (5) (Scheme 1). The synthesis of fluorophores which is not covered in the general Scheme 1, have been mentioned separately in the preceding section. ...
November 2021
Journal of the Indian Chemical Society