Ranko M. Simonović's research while affiliated with University of Mitrovica and other places
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Publications (16)
The efficiency of the application of electrochemically generated Na2FeO4, for the purpose of the elimination of Th(IV) ions from water samples as coagulating agent was investigated. Th is a radioactive element often used as a fuel for nuclear reactors. The continuous exposure to Th(IV) may cause cancer of the pancreas, bone or lung. Analyzed natura...
The present work describes a rapid and sensitive method for the determination of ultramicro amounts of tungsten (VI) based on its inhibitory effect on the oxidation of 4-hidroxycoumarine by potassium permanganate in the presence of hydrochloric acid. The sensitivity of the method is 20 ng/cm³. The probable relative error is -4.8-13 % for the W(VI)...
Development and application of a simple, fast, green analytical kinetic method for the determination of micro-amounts of gold(III ) ions, were presented in this paper. The method was based on the inhibitory effect of traces of Au(III) ions on the redox reaction between disodium-6- hydroxy-5-[(4-sulfophenyl)azo]-2-naphtalenesulfonate (artificial azo...
A new kinetic method has been developed for simple, fast and selective determination of trace amounts of vanadium (V) (0.5–5 μg/cm3) based on its inhibiting effect on the oxidizing reaction of 4-hydroxicumarine by means of KMnO4 in acid media. The proposed kinetic method was used for determination of vanadium (VP) in different samples of water with...
The simple PVC-based membrane containing N,N′,N″,N′′′-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) as an ionophore and dibutyl phthalate as a plasticizer, directly coated on a glassy carbon electrode was examined as a new sensor for Cu2+ ions. The potential response was linear within the concentration range of 1.0×10−1–1.0×10−...
A sensitive and rapid kinetic method for trace determination of Cu(II) was developed and validated, based on its catalytic effect on the oxidation of disodium-6-hydroxy-5-[(4-sulphophenyl)azo]-2-naphtalenesulphonic acid (wide used, food colour “Sunset Yellow FCF”, E110, in text selected as SY) by hydrogen peroxide in borate buffer at pH 10.5. The r...
A new kinetic method for determination of traces of Mn(II) has been developed. The method is based on tfie catalytic effect of Mn(II) on the oxidation of trimethylenediarnine-N,N,N',N'--tetra acetic acid (TDTA) by KMnO4 in acid media. Under optimal conditions the limit of determination of Mn(II) was 0.5 ng mL-1. The probable relative error was 4.0-...
A simple and fast kinetic method is based on the oxidation of 4-OH coumarone using KMnO4 and the determination of ultramicroamounts of Au(III) by its catalytic effect on this reaction. The sensitivity of the method
is 25 ng/mL. The relative error ranges between 9.20–3.90% for the concentration interval 5 × 10−8–2 × 10−7 g/mL. The selectivity of the...
This study covers the results of research on the chromium concentration in plant samples grown on soil contaminated by the waste water generated from the leather industry. The concentration of Cr was measured in the roots, leaves and fruits of tomatoes (Lycopersicon esculentum) and green beans (Phaseolus coccineus) as well as in the roots and leave...
The present paper describes a simple, selective and sensitive kinetic method for the determination of trace amounts of molybdenum(VI) based on its inhibitory effect on the reaction oxidation of 4-hydroxycoumarine by KMnO(4) in the presence of hydrochloric acid, at pH 1.75 at 25 degrees C. The rate of the indicator reaction was followed spectrophoto...
A new inhibitory reaction is proposed and a kinteic method developed for the determination of ultra-micro amounts of Mo(VI) on the basis of its inhibitory activity in oxidation of trimethylenediamine – N,N,N¢,N¢-tetraacetic acid (TDTA) by KMnO 4 in the presence of hydrochloric acid. Under optimal condi-tions the sensitivity of the method is 0.5 ng/...
A new kinetic method for determination of traces of manganese(II) based on its catalytic effect on the oxidation of 4‐hydroxycoumarine with KMnO4 at pH=1.35 and at a temperature of 25°C was proposed. The reaction was followed spectrophotometrically by measuring the decrease in the absorbance of the dye at 525 nm. The calibration graph is linear in...
Oxidation of 4-hydroxycoumarin by potassium permanganate in acid media of acetate buffer is catalyzed by Al(III) ions, which is the basis of the proposed new homogenocatalytic method for determination of Al(III) in solutions. Under the optimum conditions, Al(III) has been determined at 525 nm in solutions containing analyte at 50-1000 ng/ml with pr...
A new inhibitory reaction is proposed and a kinetic method is developed for the determination of ultramicro amounts of V(V) on the basis of its inhibitory activity in oxidation of ethylenediamine -N,N'-diacetate-N,N'-dipropionic acid (EAP) by KMnO4 in the presence of hydrochloric acid. Under optimal conditions the sensitivity of the method is 15 ng...
A new catalytic reaction is proposed and a kinetic method developed for the determination of ultramicro amounts of As(III) on the basis of its catalytic activity in the oxidation of ethylenediamine-N,N-diacetic-N,N dipropionic acid (EAP) by KMnO4 in the presence of hydrochloric acid. Under optimal conditions, the sensivity of the method is 20 ng/...
Citations
... The main iron species that act as coagulants is nanocrystal Fe(III) oxide/hydroxide, produced through Fe(VI) reduction. The use of ferrate as a coagulant in water treatment and polluted water containing inorganic chemicals, such as thorium, cyanide, and thiocyanate [11][12][13][14]. ...
... mgL À1 ). The analytical features of the proposed preconcentration system were compared with several of the previously published methods [41][42][43][44][45][46][47][48]. As shown in Table.5, our method is characterized by low cost, reproducibility, high sensitivity and selectivity. ...
... The kinetic spectrophotometric methods are known as sensitive methods for element quantification (Muller et al., 1980). By studding red-ox reactions of permanganate with organic compounds (Petković et al., 2007), (Micić et al., 2006), it is noticed that tungsten has performed inhibitory effect on the oxidation of 4-hidroxycoumarine by KMnO 4 in the presence of hydrochloride acid (pH 1.2-2). The reaction was recorded spectrophotometrically, based on measuring the decrease in the absorbance of the solution. ...
... Trace metals are toxic for many organisms above a threshold concentration (for instance, the maximum containment level of copper is 1.3 mg/L according to EPA and WHO), and thus the presence of these metal ions in the environment and the food must be precisely and periodically monitored, making its determination in various media an essential analytical task [1][2][3][4]. Copper is one of the essential trace elements, and it has a high importance in industry, environmental and biological systems since it plays central roles in many biochemical processes. Copper is considered to be the second most toxic metal to aquatic life, and it leaks to waters and to other ecosystems via wastewaters emanating from mining industries, refineries, paper and dyeing industries to name a few industrial sources, posing a high risk to public health. ...
... The kinetic spectrophotometric methods are known as sensitive methods for element quantification (Muller et al., 1980). By studding red-ox reactions of permanganate with organic compounds (Petković et al., 2007), (Micić et al., 2006), it is noticed that tungsten has performed inhibitory effect on the oxidation of 4-hidroxycoumarine by KMnO 4 in the presence of hydrochloride acid (pH 1.2-2). The reaction was recorded spectrophotometrically, based on measuring the decrease in the absorbance of the solution. ...
... Several analytical methods were applied to vineyard soil characterization [16] with particular attention paid to Cu contents [17,18], whose detection is particularly important also in wine analysis [19,20]. However, to the best of our knowledge there are no comparative heavy metal assessments taking into consideration contemporarily 1-vineyards subjected to Cu-based phytosanitary treatments; 2-adjacent control plots; and 3-adjacent former vineyards where grapevine cultivation was discontinued tens of years before the study. ...
... The results of the present study are shown in Table 1. LOD of the present work is comparable or better than some previous studies for the determination of As(III) ions [22][23][24][25][26] . ...