Phairat Usubharatana’s research while affiliated with Thammasat University and other places

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Publications (24)


Sustainable Synthesis and Characterization of Carboxymethyl Cellulose from Agricultural Byproducts: Corn Leaf and Rice Straw
  • Article

January 2025

Engineered Science

Teerapong Churam

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Phairat Usubharatana

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Harnpon Phungrassami

Figure 10. Flux density distributions and energy calculation on receiver. (a) projected curve on receiver plan (b) mesh surface of flux density (c) flux density color gradient (d) top view.
Figure 13. The proportion of energy from the Sun disk for varying Sun shape errors: Latitude = 23 • , Date = 21 June, Time = 12.00, Position = [N 0 • , D 30].
Development and Analysis of the Heliostat Curve Tracing Parametric Model (HCTPM) for Sustainable Solar Energy in Sun-Tracking Concentrated Solar Power Systems
  • Article
  • Full-text available

October 2024

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26 Reads

This study develops the heliostat curve tracing parametric model (HCTPM) to predict solar energy distribution in concentrated solar power (CSP) systems with sun-tracking capabilities. HCTPM uses curve tracing techniques to visualize flux distribution on mirrors and receivers, producing results that align closely with established models like HFLCAL, which use Gaussian and Tonatiuh ray-tracing methods. Simulations revealed that deviations in energy distribution increase as Sun shape error decreases, with greater impact on flux density and sensitivity. Variations in Sun disk radius caused notable deviations, especially in elliptical projections. The model’s flexibility in adjusting mirror shapes and sizes allows for the evaluation of spill losses, optimizing mirror designs for different positions. Spill loss analysis showed that larger mirrors reduce spill loss on mirrors but increase it on receivers, particularly when mirrors deviate from the north. Although total spill loss decreases with larger mirrors, this effect weakens as receiver spill loss grows. These findings emphasize the importance of optimizing mirror and receiver design to maximize energy efficiency and minimize resource waste, contributing to more sustainable solar energy systems. The HCTPM model plays a crucial role in improving the sustainability of CSP systems by optimizing configurations based on Sun disk characteristics, reducing energy losses, and promoting efficient resource use.

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Figure 2. Effect of NaOH concentration on degree of substitution and percent yield of CMC SCL synthesized with various NaOH concentrations.
Figure 4. XRD patterns of α-cellulose and CMC SCL synthesized with various NaOH concentrations.
The DS values of CMC obtained from different cellulose sources.
Determination of CMC, NaCl, and ash contents.
Concentration of heavy metals in the synthesized CMC SCL .
Sustainable Production of Carboxymethyl Cellulose: A Biopolymer Alternative from Sugarcane (Saccharum officinarum L.) Leaves

March 2024

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205 Reads

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9 Citations

This study explores the potential of sugarcane (Saccharum officinarum L.) leaves (SCLs), a significant agricultural waste, for the sustainable production of carboxymethyl cellulose (CMC) utilizing an innovative approach of carboxymethylation with monochloroacetic acid and varying sodium hydroxide (NaOH) concentrations (ranging from 20 to 60 g/100 mL). The optimal carboxymethylation condition was identified as 40 g/100 mL NaOH, which yielded the highest degree of substitution (DS = 0.86). Furthermore, a higher ash content in the obtained CMC indicated significant carboxymethyl substitution within the structure. The chemical structure of cellulose and the resulting polymers were characterized using Fourier transform infrared spectroscopy (FTIR). The FTIR spectrum exhibited characteristic peaks of carboxymethyl groups and their salts at wavenumbers of 1588–1591 cm−1 and 1413–1415 cm−1, respectively. The analyses from X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) revealed detailed insights into the crystallinity and morphology of carboxymethyl cellulose (CMC). The levels of heavy metals, including arsenic, lead, cadmium, and mercury, in the purified CMC were assessed using inductively coupled plasma mass spectrometry (ICP-MS) and were found to be within the recommended WHO/FAO limits, except for lead, which exceeded permissible levels. The prepared CMC demonstrated high purity at 99.34%, surpassing the 98.00% purity requirement for commercial-grade CMC. This product exhibits strong potential for diverse industrial applications, including paper coating, textile sizing and printing, ceramic glazing, and various uses in the oil industry.




Environmental Problem Shifting Analysis of Pollution Control Units in a Coal-Fired Powerplant Based on Multiple Regression and LCA Methodology

May 2021

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26 Reads

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9 Citations

Coal-fired power generation leads to serious environmental pollution, such as air and water pollution; thus, pollution control or treatment is necessary. However, end-of-pipe treatments are still indispensable approaches to reducing environmental stress, and focusing on each in turn leads to pollutant-by-pollutant features. The present study applies the LCA method to reveal the total direct and indirect environmental impacts from increasing significant pollution control units for a coal-fired power plant. From the results, it was found that increasing the performance of CCS and FGD units may result in higher overall environmental impacts due to their energy costs. Greater energy requirements result in greater global warming potential, human toxicity, and terrestrial acidification effects. LNB & OFA, SCR, and ESP units did not cause any other significant environmental impacts, while activated carbon used in the ACI unit is an additional source of indirect terrestrial acidification. Water depletion effects must be considered when increasing the use of CCS units. Policy makers can use the data from the present study to establish sustainable directions to resolve environmental problems at the macro-economic scale.


Effect of functional unit and processing types on carbon footprint and specific energy consumption assessment of Thailand tableware products

April 2021

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48 Reads

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1 Citation

Thailand’s ceramic industry is one of the most important industries in the country in terms of export figures. However, production consumes a large amount of energy and raw materials, which causes adverse environmental impacts. Thus, a carbon footprint assessment of different methods of forming Thai ceramic tableware evaluated by using the life cycle assessment (LCA) as the assessment tool. The evaluation of specific energy consumption (SEC) was also conducted. The functional units were set as 1 kg and 1 L of ceramic tableware. The system boundaries included the raw material acquisition phases until the factory gate, and then being ready to ship to customers. All primary data was acquired and collected on-site through collaboration with the selected factory. The study showed that the most significant environmental impact was due to the biscuit and ghost firing processes used during the production phase, accounting for an average of 74% of the total carbon footprint. The SEC results were an average of 79 % for LPG, while electricity had a 21% share. Different forming methods did not exhibit significantly different results. Moreover, the forecasting of GHG emissions from the ceramic tableware sector by 2030 and further solution was also included in the discussion.


Environmental Impact Assessment of Thai Minced Fish Paste (Surimi) Using Life Cycle Assessment Methodology

September 2020

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347 Reads

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1 Citation

Environmental Research Engineering and Management

Environmental impacts of fishery production have resulted in increased concern and awareness. Thailand, as one of the largest global fish exporters, faces challenges related to environmental problems caused by fishery processes. Here, the environmental impact of Thai surimi production was estimated based on life cycle assessment (LCA) methodology, focusing specifically on two Thai surimi products made from goatfish and ponyfish caught within the southern region of Thailand. Three impact categories where explored: global warming, acidification and eutrophication. Life cycle impacts were calculated for one kg of product using both mass and economic allocations. Results of this study indicated that goatfish has lower impacts than ponyfish for all the impact categories. Fuel consumption during the fishery phase and electricity consumption during processing were the main parameters leading to most of the considered environmental impacts. The value of Global Warming Potential(GWP) ranged within 1.3‒3.0 kg CO2eq for goatfish and 2.2‒7.1 kg CO2eq ponyfish depending on the allocation method. The acidification impact of goatfish and ponyfish were revealed at 3.2‒7.3 gSO2eq and 12.7‒39.7 gSO2eq, respectively. The eutrophication of goatfish and ponyfish were 0.7‒1.6 gPO4eq and 2.5‒8.1 gPO4eq, respectively. Sensitivity analysis of fuel consumption, electricity consumption, product yield and allocation method were evaluated.


Fossil fuel carbon taxation policy effect on thai household expenditure using input–output price structural path model

March 2019

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90 Reads

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4 Citations

Taxation levying promotes and enhances the management of greenhouse gas emissions; however, its effect on product price increases for households requires clarification. The impact of a fossil fuel taxation policy on Thai household expenditure was investigated. Carbon taxation rate was based on abatement cost. An input–output price model was applied to establish economical price structures and price changes as a carbon result of implementing a carbon taxation policy. A national consumer expenditure survey and price changes were used to evaluate the carbon tax burden distribution on each households, which have different expenditure. By using marginal abatement cost curve, reduction target is 175 MtCO2e by 2030. Results indicated that achieving the reduction target by that time is possible, although welfare losses in households were inevitable. Price increases resulting from implementing carbon taxation in each product sector ranged from 0.8 to 19.6%. Commodity price changes were largest for high carbon‐intensive sectors including Public utilities (19.6%), Nonmetallic products (15.7%), and Transport & Communication (8.5%). Welfare losses per household from taxation were around 3–4% for each group, resulting from both price changes and expenditure patterns. Highest tax burden fell on the economically inactive group that spent a larger share of their income on basic survival essentials which were heavily impacted by increased prices. © 2019 American Institute of Chemical Engineers Environ Prog, 38:e13146, 2019



Citations (15)


... In contrast, Figure 4b shows that the natural biomass is an amorphous material [25]. The peaks at 2θ = 16° and 22° indicate a certain crystallinity of the cellulose [27,28]. In Figure 4c, the EDS results also confirmed the basic composition of the biomass ash, which presents oxygen and silicon with high energy and other metals, such as potassium, sodium, and magnesium, with low energy. ...

Reference:

Dependence of the magnetite (Fe3O4) and silica (SiO2) nanostructured heterojunction for the photodegradation of tartrazine yellow dye
Sustainable Production of Carboxymethyl Cellulose: A Biopolymer Alternative from Sugarcane (Saccharum officinarum L.) Leaves

... At present, as a mature method for NO x , and SO 2 removal in flue gas, the treatment techniques of selective catalytic reduction (SCR) and wet flue gas desulfurization (WFGD) have been widely applied (Yang et al. 2019b;Fujii et al. 2013). However, a high occupational area and high operation and maintenance costs make individual pollutant-treatment systems less suitable for popular application in small and medium-sized enterprises Phungrassami and Usubharatana 2021;Ssa et al. 2021). Therefore, great attention has been attached to developing new technologies for simultaneous removal of SO 2 and NO x from flue gas Yang et al. 2019a). ...

Environmental Problem Shifting Analysis of Pollution Control Units in a Coal-Fired Powerplant Based on Multiple Regression and LCA Methodology

... With replacing disposable plastic as a common goal adopted by a variety of sectors, including aviation (American Airlines, 2018;Hi Fly, 2020), the comparison of plastic food packaging and tableware with its alternatives has appealed to increasing concerns from the perspective of environmental impacts (Mistretta et al., 2019;Usubharatana and Phungrassami, 2021;Tamburini et al., 2021;Mendes and Pedersen, 2021;Kan and Miller, 2022). It is estimated that global plastic production will account for one fifth of global oil consumption by 2050 (IEA, 2018), with the greenhouse gas (GHG) emissions from plastics Abbreviations: GWP 100, Global warming potential; AP, Acidification potential; EP, Eutrophication potential; ODP, Ozone layer depletion potential; ADP elements, Abiotic depletion elements; ADP fossil, Abiotic depletion fossil; FAETP inf., Freshwater aquatic ecotoxicity potential; HTP inf., Human toxicity potential; MAETP inf., Marine aquatic ecotoxicity potential; POCP, Photochemical ozone creation potential; TETP inf., Terrestric ecotoxicity potential. ...

Effect of functional unit and processing types on carbon footprint and specific energy consumption assessment of Thailand tableware products
  • Citing Article
  • April 2021

... 2 For example, Usubharatana et al. used bagasse and other agricultural waste to develop thermal insulators. 3 The authors analysed the thermal conductivity and conducted a life cycle assessment (LCA) of four renewable source-based thermally insulating materials. The four agricultural waste thermal insulators analysed had thermal conductivities ranging from 0.042 to 0.087 W/mK. ...

LIFE CYCLE ASSESSMENT OF BIO-BASED THERMAL INSULATION MATERIALS FORMED BY DIFFERENT METHODS
  • Citing Article
  • January 2019

Environmental Engineering and Management Journal

... Both studies revealed that the introduction of a carbon tax heavily increased the price of consumer goods for income-bearing households and residents in cold regions. Similarly, Phungrassami and Usubharatana [20] and Saelim [21] estimated the effect of a carbon tax introduced in Thailand on the increase in the prices of consumer goods and assessed changes in household welfare. Ma et al. [22,23] analyzed how changes in the carbon tax levied on energy affect the prices of other goods using network theory. ...

Fossil fuel carbon taxation policy effect on thai household expenditure using input–output price structural path model

... Transportation of products uses a large amount of fossil fuel; billions of items are transported globally daily. Due to the consumption process, CO 2 is emitted, impacting the ecosystem and our health [1,45]. Delivery processes impact sustainability because they are responsible for up to 75% of the company footprint. ...

Carbon footprints of rubber products supply chains (Fresh latex to rubber glove)
  • Citing Article
  • January 2018

Applied Ecology and Environmental Research

... These units are very economical due to less consumption of fuel. The systems are generally applied in higher energy-demand industries such as iron and steel, cement, glass, ceramics, and textile industries [115][116][117][118]. Various types of methodologies are listed in Table 3. Aspen-Plus software, black-box model, and TRN-SYS software are some good examples of modeling to increase energy gain [119][120][121]. ...

Life Cycle Assessment for Enhanced Efficiency of Small Power Plants by Reducing Air Input Temperature

Polish Journal of Environmental Studies

... Therefore, factors such as demographics, soil attributes [76], and the effects of land use change [77] may also result in emissions; necessitating increased sccrutiny. It is also imperative to discuss the association between the use of machinery (and other equipment) and higher dependencies on fossil fuels as an energy source [78,79]. Therefore, more efforts should be spent on producing comprehensive documentation detailing the utilization of energyefficiency equipment or using alternatives such as bioenergy-based products. ...

Evaluation of Opportunities to Reduce the Carbon Footprint of Fresh and Canned Pineapple Processing in Central Thailand

Polish Journal of Environmental Studies

... Fig. 3 shows that feed consumption is the primary contributor to GHG emissions, representing nearly 94% of the total emissions, or approximately 807.46 kg CO₂-eq/day. These results are consistent with findings by Usubharatana and Phungrassami [20], who reported that chicken feed contributes 45-55% of total GHG emissions. Similarly, Guillaume et al. [16] emphasized that feed composition is a critical factor influencing GHG emissions in egg production. ...

Greenhouse Gas Emissions of One-Day-Old Chick Production

Polish Journal of Environmental Studies

... However, there are few studies have been conducted to evaluate GHG emissions in different feed production in Thailand. Usubharatana and Phungrassami (2016) showed the GHG emissions from broiler feed and parent feed of 374-473 and 408-454 CO 2 -eq/t of feed, respectively. Their results are consistent with this study, in which feed ingredients are identified as the main contributors to GHG emissions, accounting for 87-96% of the total emissions. ...

Greenhouse Gas Emission in the Chicken Feed Industry Using Life Cycle Considerations: Thailand Case Study
  • Citing Article
  • October 2016