P. Wodniecki's research while affiliated with Institute of Nuclear Physics and other places

Publications (84)

Article
Full-text available
The hyperfine quadrupole interaction of 181Ta and 111Cd probes in HfAg and Hf2Ag compounds was studied at 24 to 1100 K with the time -differential perturbed angular correlation (TDPAC) technique. The EFGs measured in HfAg on 181Ta and 111Cd are 1.388(5)×1018 Vcm-2 and 0.340(5)×1018 Vcm-2, respectively. For both probe atoms a linear decrease of the...
Article
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The quadrupole interaction in Au-In compounds of different stoichiometrics was studied with the perturbed angular correlation technique. The electric field gradients at
Article
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The quadrupole interaction of 181Ta probes in isostructural Cu8Hf3 and Cu8Zr3 intermetallic compounds was studied in the temperature range 24 K-1100 K with the time-differential perturbed angular correlation technique. Two nonaxial electric field gradients corresponding to two nonequivalent hafnium or zirconium sites in the investigated structure w...
Article
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Perturbed angular correlation (PAC) method was applied to study the martensitic phase transition of the TiPd shape memory alloy doped with In, Hf, and Zr. The hyperfine interaction parameters and their concentration and temperature dependences for 111In/111Cd and 181Hf/181Ta probe atoms were determined. The influence of ternary element additions on...
Article
Full-text available
Perturbed angular correlation (PAC) method was applied to study the electric field gradients in nanopowders of the HfAl2 and HfAl3 intermetallic compounds, obtained via mechanical alloying or after ball milling of the thermally alloyed compound. The influence of the ball milling procedure on the experimentally obtained hyperfine interaction paramet...
Article
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The quadrupolar hyperfine interactions of in-diffused (111)In --> (111)Cd probes in polycrystalline isostructural Zr(4)Al(3) and Hf(4)Al(3) samples containing small admixtures of the phases (Zr/Hf)(3)Al(2) were investigated. A strong preference of (111)In solutes for the contaminant (Zr/Hf)(3)Al(2) minority phases was observed. Detailed calculation...
Article
Perturbed angular correlation (PAC) method was applied to study the martensitic phase transition of the TiPd shape memory alloy doped with 111In/111Cd probe atoms. The hyperfine interaction parameters and their concentration and temperature dependences for probes with cubic and noncubic surroundings of the lattice sites, consistent with the respect...
Article
The hyperfine quadrupole interaction parameters and their temperature dependence for 181Hf/181Ta probe in TiAl3 compound were determined using the time differential perturbed angular correlation (TDPAC) method. In addition, ab initio calculations using the augmented plane wave plus local orbitals (APW + lo) method as implemented in the WIEN2k code,...
Article
The hyperfine quadrupole interaction parameters and their temperature dependences for 181Ta and 111Cd probes in Ti2Pd compound were determined experimentally by means of the perturbed angular correlation (PAC) technique. In addition, ab initio calculations using all-electron augmented plane wave plus local orbitals (APW + lo) method have been perfo...
Article
By using the time-differential perturbed angular correlation technique, the electric field gradients (EFG) at (181)Hf/(181)Ta and (111)In/(111)Cd probe sites in the MoSi(2)-type compound Ti(2)Ag have been measured as a function of temperature in the range from 24 to 1073 K. Ab initio EFG calculations have been performed within the framework of dens...
Article
The hyperfine quadrupole interaction parameters and the character of the EFG temperature dependence for 181Hf/181Ta and 111In/111Cd probes in Zr2Rh compound were determined by means of the perturbed angular correlation (PAC) technique. The site location of 111In/111Cd probes in both 8(h)-Zr and 4(a)-Rh positions was determined.
Chapter
The electric field gradient (EFG) at the 181Hf→181Ta site in Ti2Rh C11 b -type compound was measured as a function of temperature using time-differential perturbed angular correlation (TDPAC) technique. The room temperature results show one EFG with the parameters of: ν Q =336(1) MHz→V zz =5.9×1017 V cm−2, η=0.1. Very week linear temperature depend...
Chapter
The hyperfine quadrupole interactions of 111In/111Cd probes in the polycrystalline isostructural Zr4Al3 and Hf4Al3 compounds were studied. Strong preference of 111In solute for the Zr3Al2 and Hf3Al2 phases occurring as contaminant fractions in the measured samples was observed. KeywordsHf(Zr)-AI compounds-Impurities-Site preference-PAC
Article
Perturbed angular correlation (PAC) method was applied to study the martensitic phase transition of the TiPd shape memory alloy doped with 181Hf/181Ta probe atoms. The hyperfine interaction parameters and their concentration and temperature dependences for probes with cubic and noncubic surroundings of the lattice sites, consistent with the respect...
Article
Full-text available
MAX-phases are hexagonal ternary carbides and nitrides with the general formula: M n + 1 AX n and n = 1 to 3. 111In was implanted into the two MAX compounds Ti2InC and Zr2InC. Based on the general knowledge of previous 111In implantations one expects to find the probes on the indium lattice-site in these compounds. First experiments on the anneal...
Article
The electric field gradient (EFG) at the 181Hf→181Ta site in Ti2Rh C11 b -type compound was measured as a function of temperature using time-differential perturbed angular correlation (TDPAC) technique. The room temperature results show one EFG with the parameters of: ν Q = 336(1) MHz→V zz =5.9 × 1017 V cm − 2, η = 0.1. Very week linear temperatur...
Article
The hyperfine quadrupole interactions of 111In/111Cd probes in the polycrystalline isostructural Zr4Al3 and Hf4Al3 compounds were studied. Strong preference of 111In solute for the Zr3Al2 and Hf3Al2 phases occurring as contaminant fractions in the measured samples was observed.
Article
Electric-field gradients have been measured in the isostructural intermetallic compounds Zr4Al3 and Hf4Al3, using radioactive 181Hf/181Ta hyperfine probes. In both compounds, two well-defined electric-field gradients have been observed, whose temperature dependence follows the T3/2 rule in the temperature range 30–1170 K. Using the full-potential a...
Article
The electric quadrupole hyperfine interactions for Cd-111 probes in polycrystalline ZrAg and Zr2Ag were measured in the wide temperature range. For both samples the two unique quadrupole frequencies v(Q) with asymmetry parameters eta = 0 were observed indicating that In-III/Cd-III probe impurities substitute both-Zr and Ag sites in B11 structure of...
Article
ZrPt intermetallic compound was studied by perturbed angular correlation (PAC) method. The hyperfine interaction parameters and their temperature dependences for Hf-181/Ta-181 and In-111/Cd-111 radioactive probes were determined. An unusual temperature dependence of hyperfine interaction parameters for Ta-181 probe atoms points to the appearance of...
Chapter
The perturbed angular correlation technique was applied to study the lattice location of the 111In/111Cd and 181Hf/181Ta probe atoms in hafnium and zirconium aluminides. Compounds of different stoichiometries and crystallographic structures were the subject of investigation. According to the expectation, in all investigated compounds 181Hf/181Ta pr...
Chapter
The electric quadrupole hyperfine interactions for 181Hf/181Ta and for 111In/111Cd probes in polycrystalline Zr3Al2 and Hf3Al2 compounds were measured in the temperature range 24–1100 K. The hyperfine quadrupole interaction parameters were determined after different doping techniques and heat treatments of the samples.181Hf/181Ta was found to subst...
Article
The intermetallic compound TiPd2 has been investigated with the perturbed angular correlation technique using radioactive 181Hf/181Ta and 111In/111Cd probes. The measurements confirmed an orthorhombic distortion of the C11b structure in the temperature range from 24 to 1023K. However, the temperature dependence of the 111Cd quadrupole parameters de...
Article
The perturbed angular correlation method (PAC) was applied to investigate the lattice location of implanted 111In probe ions in Hf2Ni and Zr2Ni intermetallic compounds. It is concluded that the 111In/111Cd probe nuclei experiencing the highly asymmetric electric field gradient (EFG) occupy the unique hafnium or zirconium 8(h) sites in the investiga...
Article
The perturbed angular correlation technique was applied to study the lattice location of the 111In/111Cd and 181Hf/181Ta probe atoms in hafnium and zirconium aluminides. Compounds of different stoichiometries and crystallographic structures were the subject of investigation. According to the expectation, in all investigated compounds 181Hf/181Ta pr...
Article
The electric quadrupole hyperfine interactions for 181Hf/181Ta and for 111In/111Cd probes in polycrystalline Zr3Al2 and Hf3Al2 compounds were measured in the temperature range 24–1100 K. The hyperfine quadrupole interaction parameters were determined after different doping techniques and heat treatments of the samples.181Hf/181Ta was found to subst...
Article
The perturbed angular correlation technique was applied to study the electric field gradients of 111In/111Cd and 181Hf/181Ta radioactive probe atoms in the compounds Zr2Al and Zr3Al. In both matrices 181Hf/181Ta was found to substitute into the Zr sites. The 111In/111Cd probes were assigned to the unique Al site in the Zr2Al compound, while in the...
Article
The perturbed angular correlation method was applied to follow the oxidation processes in ZrAl and Zr3Al intermetallic compounds. It was found that the limiting temperature for oxidation resistance of Zr–Al compounds is ca. 1073 K. Above this temperature the formation of the constituent metal oxides – ZrO2 and Al2O3 was evidenced.
Article
The electric quadrupole hyperfine interactions for 181Hf/181Ta probes in polycrystalline ZrAg and Zr2Ag were measured in the temperature range 24–1100 K and compared with the results of previous experiments on isostructural Hf–Ag compounds. For both phases one unique quadrupole frequency νQ with asymmetry parameter η = 0 was observed in accordance...
Article
The isostructural zirconium and hafnium aluminides were studied using radioactive probes of 181Hf and 111In. The electric field gradient tensors in the isostructural alloys were measured and the lattice sites of the radioactive probes were identified. In the HfAl2 compound, the temperature-driven reversible change of the 111In probes between substi...
Article
The Perturbed Angular Correlation method with 111In tracers was applied to investigate the influence of implanted nickel impurities on the electric field gradient (EFG) in antimony films. A very strong dependence of EFG at low Ni concentrations was found. Ni implantations and thermal annealings did not destroy the texture produced during the deposi...
Article
Using perturbed angular correlation (PAC) spectroscopy and 181Hf/181Ta and 111In/111Cd radioactive probes, the electric field gradients (EFGs) in the ZrAl2 and HfAl2 Laves phases were measured in the temperature range 20–1100 K. In both matrices, 181Hf was found to substitute at the unique Hf/Zr site. In the ZrAl2 compound, the 111In probes were as...
Article
The perturbed angular correlation method (PAC) was applied to investigate, on a microscopic scale, the mixing effects when irradiating Sb/Ni bilayers with 350 keV Xe ions. Marker layers of 111In probe atoms were deposited at different positions relative to the interface inside the Ni or Sb film, or exactly at the interface. The formation of Ni-Sb p...
Article
The electric quadrupole hyperfine interactions for 181Hf/181Ta and for 111In/111Cd probes in polycrystalline ZrAl3 and Zr2Al3 compounds were measured in the temperature range 30–1100 K and compared with the results for isostructural hafnium aluminides. On the basis of the similarities of the numbers, sizes and asymmetries of electric field gradient...
Article
Full-text available
The hyperfine interaction of 111Cd in ferromagnetic Fe3Sn compound was investigated by TDPAC in the paramagnetic region and below the Curie temperature. The results are compared with hyperfine magnetic fields and EFGs on 111Cd and 119Sn in other stoichiometric Fe–Sn phases.
Article
Perturbed angular correlation measurements in the HfAl2 C14-type Laves phase exhibit a very surprising temperature behavior of the ion-implanted 111In probe atoms. Below 370 K the 111In impurities are located at the unique hafnium site. Above 400 K they occupy the two aluminum sites, however with a clear preference of the 2(a) site. This process, w...
Article
Iron–tin compounds of different stoichiometries were studied by the perturbed angular correlation method. The hyperfine interaction parameters and their temperature dependence for 111Cd probes substituting for tin in FeSn2, FeSn and Fe3Sn2 crystal lattices were determined.
Article
The perturbed angular correlation technique (PAC) was applied to observe the interdiffusion in Hf/Ag multilayers. Sample with 10 Ag layers of 40 Å intercalated with Hf layers of 100 Å was implanted with 111In probes or irradiated with thermal neutrons in order to achieve the presence of the radioactive PAC probes 111In or 181Hf, respectively. A sol...
Article
The crystallisation of Ni79B21 and Ni62B38 amorphous alloys produced by ion implantation is studied via perturbed angular correlation experiments on radioactive 111In probes implanted in the amorphous layer. The hyperfine interaction sensed by 111Cd (daughter of 111In) provides information about the structure (amorphous or crystalline) of the alloy...
Article
The electric quadrupole hyperfine interactions for 181Hf/181Ta and 111In/111Cd probes in the polycrystalline hafnium aluminides HfAl3 and Hf2Al3 were measured in the temperature range 30–1100 K. On the basis of the similarities of the numbers, sizes and asymmetries of electric field gradients, lattice site allocations were made. In all matrices, 18...
Article
Ag/Fe bilayers in which a submonolayer of 111In had been deposited in the Fe layer at a distance of x=0–17 nm from the interface, were irradiated at 80 K with 450 keV Xe ions to a fluence of 3 and 6⋅ 1015 ions/cm2. Perturbed Angular Correlation spectroscopy was used to monitor the microsurrounding of the 111In tracers and to identify the radiation-...
Article
Au/In bilayer samples of different stoichiometries were studied using the time-differential perturbed angular correlation technique. The In-111 probe atoms were deposited at the gold/indium interface to follow the formation of the intermetallic compounds at an early stage. Au-In phases of different composition (AuIn2, AuIn, Au7In3, Au3In) were crea...
Article
Full-text available
The Au–In equilibrium phase diagram exhibits a large number of intermetallic phases which have recently been explored via perturbed angular correlation spectroscopy, using alloyed and/or diffused 111In probes. In the present work we report on the phase transition from Au7In3 (hexagonal, γ'-phase) to Au9In4 (γ-brass phase) induced via Xe- or Ar-ion...
Article
Segregation of In in Fe-based alloys containing 0.11–2.12 at.% In has been studied by measuring the perturbed angular correlations of γ-rays emitted in the nuclear decay of 111In. The probe atoms were introduced into the alloys by either adding the carrier-free 111In during melting or via ion implantation. Ageing of the samples at elevated temperat...
Article
Segregation of In in Fe-based alloys containing 0.11–2.12 at.% In has been studied by measuring the perturbed angular correlations of γ-rays emitted in the nuclear decay of 111In. The probe atoms were introduced into the alloys by either adding the carrier-free 111In during melting or via ion implantation. Ageing of the samples at elevated temperat...
Article
The recovery of polycrystalline silver rolled at room temperature to different degrees of deformation (33, 48, 73 and 95%) was investigated by means of the TDPAC technique with a 111Cd probe. The dependence of quadrupole interaction parameters, extracted from time spectra, on the degree of deformation and annealing temperature was studied. At tempe...
Article
Metastable, supersaturated alloys of the thermally immiscible systems Ag/Fe (< 16 at% Ag) and In/Fe (< 50 at% In) were produced by pulsed laser deposition. The magnetic hyperfine interaction was studied via perturbed angular correlation spectroscopy using implanted In-111 tracers. In both systems the magnetic hyperfine fields B-n were found to decr...
Article
In the thermally immiscible bilayer system Ag/Fe the atomic transport induced by 450 keV Xe ion irradiation was investigated by means of perturbed angular correlation (PAC) spectroscopy. A submonolayer of $\rm ^{111}In$ PAC probe atoms was deposited in Fe at a distance of 0–17 nm from the Ag/Fe interface to monitor the interface mixing. The ion irr...
Article
Nickel–indium intermetallic compounds of different stoichiometries were studied by means of the perturbed angular correlation (PAC) spectroscopy. The temperature dependence of the hyperfine interaction parameters for 111Cd probes in the crystal lattices of Ni3In7 and Ni2In3 was measured. A T3/2 character of the electric field gradient temperature d...
Article
Cobalt-tin intermetallic compounds of different stoichiometries were studied by means of the perturbed angular correlation (PAC) technique. The hyperfine interaction parameters for Cd-III probes in the crystal lattices of CoSn2 and Co3Sn2 were determined. A T-3/2 temperature dependence of the electric field gradient (EFG) in CoSn2 compound was foun...
Article
Full-text available
The Au-In system was the subject of our comprehensive study with the perturbed angular correlation technique. Bulk samples of all intermetallic phases shown in the phase diagram were prepared to determine the hyperfine interaction parameters and their temperature dependence. A polymorphic phase transformation in the AuIn phase at about 630 K and a...
Article
The perturbed angular correlation technique and Mssbauer spectroscopy were applied to study the electric field gradient on 111Cd and 119Sn probe atoms in isostructural NiIn and CoSn compounds. The 111Cd PAC measurements performed in the temperature range 80--1100 K demonstrated the existence of two axially symmetric EFG's in each of the investigate...
Article
Radioactive In-111-ions were implanted at 400 keV into polycrystalline Al-foils at a maximum concentration of less than or equal to 10 ppm and a mean depth of 160 nm. In addition, 10(16)/cm(2) inert gas ions were implanted partially overlapping with the In-111-profile (Xe: 600 keV, Kr: 450 keV, He: 30 keV). Depth profiling of the Xe- or Kr-ions was...
Article
The electric quadrupole interaction at 181Ta in Hf2Pd and Zr2Pd compounds was studied by the perturbed angular correlation method in a broad temperature range. The powder X-ray analysis verified a single-phase C11b structure of the samples. The least-squares fits of the perturbation factor to the experimental spectra measured for Hf2Pd and Zr2Pd co...
Article
The perturbed angular correlation technique was applied to study the electric field gradient (EFG) in TiNi3-type compounds. HfPd3, Zr0.98Hf0.02Pd3 and Ti0.98Hf0.02Pd3 samples were neutron irradiated in order to produce 181Ta probes. The perturbed angular correlation measurements performed in the temperature range 45 K–1100 K demonstrated the existe...
Article
Full-text available
Nickel-antimony intermetallic compounds of different stoichiometries were studied by means of perturbed angular correlation (PAC) spectroscopy. The hyperfine interaction parameters for 111Cd probes in the crystal lattices of NiSb, Ni5Sb2, Ni3Sb and NiSb2 were determined. The results are discussed in the light of crystallographic data.
Article
Full-text available
Sb/Ni multilayers of 200 nm total thickness were ion-beam mixed with 900 keV Xe++ or 600 keV Ar++ ions using fluences up to 1016 ions/cm2. The formation of crystalline intermetallic phases was observed by X-ray diffraction (XRD). To investigate, on a microscopic scale, the mixing-effects the perturbed angular correlation (PAC) technique was applied...
Article
Perturbed ?-? angular correlation (PAC) spectroscopy was applied to study the hyperfine parameters for111In probes in In-Pd intermetallic compounds. The PAC spectra measured in In3Pd, In3Pd2 and InPd2 compounds reflect the number, population and symmetry of nonequivalent indium probe sites predicted by the crystallographic data. The temperature dep...
Article
The perturbed angular correlation technique was applied to measure the quadrupole interaction parameters of111Cd at the In sites in electroplated In/Pt bilayers successively annealed at elevated temperatures. The consecutive creation of different compounds was evidenced by means of their PAC signal. The In7Pt3 andIn3Pt2 compounds were identified by...
Article
The TDPAC technique was employed for studies of the hyperfine interaction of181Ta in the Hf2Ni and Zr2Ni compounds with Al2Cu-type structure. A linear temperature dependence of the quadrupole frequencies was measured in the temperature region 300–1100 K.
Article
The TDPAC technique was applied to study the formation of In-Pd compounds in bilayer electrodeposited sample doped with the radioactive111In. Subsequent isochronal annealings at increasing temperatures caused the Pd diffusion into the In layer reflected in the quadrupole interactionR(t) curves. The appearing new unique frequencies indicate the form...
Article
The formation of AgIn2 andAg2In compounds at Ag-In interface in Ag/In electrodeposited samples was studied by TDPAC in an isothermal annealing experiment in annealing temperatures 300–423 K. For 300 K the AgIn2 average thickness growth was found to follow a square root of time dependence but for higher temperatures a saturation like effect was obse...
Article
The quadrupole interaction parameters for111Cd in In7Pt3 and In3Pt2 compounds were measured by TDPAC in the temperature range 80–1000 K. The EFG temperature behavior follows theT 3/2 relation.
Article
The perturbed angular correlation (PAC) method was applied to investigate the effects of irradiating Ni and Ti films as well as Ni-Ti bilayers and multilayers with 900 keV Xe2+ ions. The ~ 200 nm thick layers were deposited onto Si substrates by electron gun evaporation in an UHV chamber. Some 1012 radioactive 111In ions were implanted at 400 keV....
Article
The hyperfine interaction of111Cd probes in preoxidized and α-irradiated Ag0.94Cd0.06 alloy has been investigated by PAC measurements and compared with the results for pure Ag. Several probe atom sites were distinguished and characterized by their hyperfine parameters and temperature evolution. The different behavior of In-oxygen and In-oxygen-vaca...
Article
The formation of impurity complexes in metals studied with the time differential perturbed angular correlation (TDPAC) technique is reviewed. A short description of the TDPAC method is followed by two examples of its possible applications: internal oxidation studies in alloys and the investigation of the chemical interaction between impurity atoms...
Article
The TDPAC studies of In-Pt pairs formation in dilute AgPt alloy in nonequilibrium state are performed. The concentration of the In-Pt complexes is measured for different annealing temperatures and times. The results are compared with calculations based on the model of diffusion controlled bimolecular reactions. The conclusions about diffusion enhan...
Article
The PAC method was applied to study the intermetallic compound formation at Ag−In interfaces. The electrodeposited Ag−In layers of different Ag: In atomic ratios were prepared and isochronal annealing program was performed. For the comparison the bulk Ag75In25 and Ag66In34 specimens were examined. The Ag2In and AgIn2 compounds were detected and the...
Article
Aluminium foils oversaturated with 5.1015/cm2 implanted115In+ ions were oxidized in 200 mbar oxygen or vacuum annealed at 370–870 K. The samples were analyzed by the Rutherford backscattering (RBS) and perturbed angular correlation (PAC) techniques, using some 1011/cm2 implanted radioactive111In tracers. Furthermore, the oxygen surface profiles wer...
Chapter
The internal oxidation phenomena and oxygen decorated vacancies’ formation in silver nave been investigated since a few years (1,2,3). However, in spite of the phenomenological model presented by Schroeder et al. (4), the mechanism of the 111In-OxVy complexes still needs further confirmation. It was our aim to observe the oxygen agglomeration at 11...
Article
Room-temperature implanted and sputtered Ni1 − xBx films were found to be amorphous in the concentration range 0.17 ⩽ x ⩽ 0.35, contrarily to what was previously reported. Their resistivity temperature dependence was measured from 2 K up to 300 K. The temperature coefficient of the resistivity (measured between 200 K and 300 K) was found to decreas...
Article
The internal oxidation process of111In in Ag has been studied by means of the perturbed angular correlation technique. A homogeneous111In concentration of typically 0.05 at ppm has been produced by irradiating the Ag samples with 35 MeV α-particles. In particular, the effects of solving oxygen before the irradiation and of radiation induced defects...
Article
The process of internal oxidation of indium in silver in the presence of correlated and uncorrelated radiation damage (preoxidation, ion implantation) was studied by means of the TDPAC technique. Isothermal annealing functions of oxygen decorated defects containing 111In, oxygen and vacancies were measured. These molecular-like complexes have been...
Article
Full-text available
The dynamics of trapping and detrapping processes of oxygen decorated radiation defects in silver were investigated by the TDPAC technique. Three defect clusters containing In, oxygen and vacancies were studied by isothermal annelaing experiments between 250°C and 450°C. For the desintegration respective formation of two of these complexes, activat...
Article
The annealing behaviour of radiation damage in internally oxidized silver and dilute AgIn alloys was investigated by the TDPAC technique and the reaction 109Ag(α,2n)111In. In the temperature range from 470 to 770 K, three sharp quadrupole frequencies were observed, if oxygen had been introduced into the foils before irradiation, and attributed to t...
Article
The internal oxidation of dilute AgIn alloys in open air versus In concentration and oxidation temperature was investigated by the TDPAC technique. The111In interaction described by the broad quadrupole frequencies distribution aroundv Q = 115 MHz and =0.5–0.7 was observed and interpreted as due to nonstoichiometric In–OX cluster formation. For hig...
Article
The investigation of the temperature dependence of electric field gradient EFG in metals and alloys can help to understand the source of EFG acting on the probe nuclei. The experiments performed on noncubic metals show that the quadrupole frequency =~can be reproduced by relation [i]: ~(7) = 0(0)[~-~r ~] (1) where ~ is a constant and ~) is the quad...
Article
silver lattice. In the present work system in which lliIn interacts with the two kinds of defects were investigated. The Agl. Pdx(X=0.01 and 0.0~and .Agl.xPtx(X=0.00 1,0.003 and 0.01) alloys were irradiated in the 27 MeV ~-beam at liquid nitrogen temperature. In all the irradiations the beam current was kept constant of 15 nA in intensity and of to...

Citations

... The PAC spectrum designated by 298 * K is taken at room temperature after the measurement at 1073 K quadrupole frequencies obtained for Zr 2 Ni 7 and Zr 7 Ni 10 phases in the temperature range 77-1073 K have been fitted with the following relationω Q (T ) = ω Q (0)[1 − αT ].( 3 )The fitted results give ω Q (0) = 65(1)Mrad/s (V zz = 7.3(2)×10 21 V/m 2 ), α = 3.1(3)×10 −4 K −1 for Zr 7 Ni 10 component. For the Zr 2 Ni 7 component, the results are ω Q (0) = 77(1) Mrad/s (V zz = 8.6(2)×10 21 V/m 2 ), α = 2.1(2)×10 −4 K −1 .The linear temperature dependence of quadrupole frequency was observed in many intermetallic compounds[21][22][23][24][25][26][27]. ...
... The PAC spectrum designated by 298 * K is taken at room temperature after the measurement at 1073 K quadrupole frequencies obtained for Zr 2 Ni 7 and Zr 7 Ni 10 phases in the temperature range 77-1073 K have been fitted with the following relationω Q (T ) = ω Q (0)[1 − αT ].( 3 )The fitted results give ω Q (0) = 65(1)Mrad/s (V zz = 7.3(2)×10 21 V/m 2 ), α = 3.1(3)×10 −4 K −1 for Zr 7 Ni 10 component. For the Zr 2 Ni 7 component, the results are ω Q (0) = 77(1) Mrad/s (V zz = 8.6(2)×10 21 V/m 2 ), α = 2.1(2)×10 −4 K −1 .The linear temperature dependence of quadrupole frequency was observed in many intermetallic compounds[21][22][23][24][25][26][27]. ...
... Hyperfine interaction techniques such as perturbed angular correlation (PAC) and Mössbauer spectroscopy can provide structural analysis of intermetallic compounds doped with very low concentrations of impurity (probe) atoms and often lead to definite conclusions on their lattice locations in polycrystalline materials [1][2][3]. In the last decade, a systematic study of the electric field gradients (EFG) of 181 Hf/ 181 Ta and 111 In/ 111 Cd probe nuclei in the full series of hafnium and zirconium aluminides has been carried out, intermetallic compounds which exhibit a large range of rather simple lattice structures [3][4][5][6][7][8][9][10][11]. Recently, successful attempts have been made for the compounds Zr 4 Al 3 and Hf 4 Al 3 to assign the hyperfine interaction parameters of 181 Hf/ 181 Ta probes to the possible Hf and Zr lattice sites [2] and even to distinguish among the lattice structures deduced from x-ray diffraction [12]. ...
... Hyperfine interaction techniques such as perturbed angular correlation (PAC) and Mössbauer spectroscopy can provide structural analysis of intermetallic compounds doped with very low concentrations of impurity (probe) atoms and often lead to definite conclusions on their lattice locations in polycrystalline materials [1][2][3]. In the last decade, a systematic study of the electric field gradients (EFG) of 181 Hf/ 181 Ta and 111 In/ 111 Cd probe nuclei in the full series of hafnium and zirconium aluminides has been carried out, intermetallic compounds which exhibit a large range of rather simple lattice structures [3][4][5][6][7][8][9][10][11]. Recently, successful attempts have been made for the compounds Zr 4 Al 3 and Hf 4 Al 3 to assign the hyperfine interaction parameters of 181 Hf/ 181 Ta probes to the possible Hf and Zr lattice sites [2] and even to distinguish among the lattice structures deduced from x-ray diffraction [12]. ...
... For most pure and impurity systems a T 3/ ' 2 dependence of EFG was found [10] and was understood as originating mainly from lattice vibrations and thermal lattice expansion [11]. There are, however, cases where a T 3/2 dependence is not observed [4, 12]. The deviations are not limited to transition metals, showing that they do not arise entirely from the local d-contributions. ...
... Sb. The intermetallic compound NiSb 2 has the marcasite (C18) structure [24], which exists below 616 8C in the miscibility range of 67.7 -68.7 at.% Sb. ...
... 7 The high energy density deposition by ion irradiations leads to the structural changes, transport mechanism, modifications of the surfaces, and the interfaces and also to the formation of new intermetallic phases at the interfaces in the case of thin films and multilayers. [8][9][10][11] In the case of cobalt thin films, the energy deposition by ion beam irradiation lead to a phase transition from hcp to fcc Co phase and also lead to significant changes in the magnetic anisotropy. Xe ion on 75 nm thick Co film changes the crystal structure of Co film from hcp to fcc. 12 Yan et al. observed the phase transitions from hcp-Co to the high temperature stabilized fcc structure in the case of immiscible Ag-Co system upon 200 keV Xe-ion ir-radiations at 300 K. 13 Mattei et al. showed the increase in hcp to fcc transition temperature dependent on the size of the cobalt nanoclusters obtained by ion implantation in silica. ...
... Available results suffer from simplifications in modeling, as the presence of concentration gradients was not taken into account for the determination of the diffusion coefficients. 3,22,23 In other cases, inadequate models were used for the determination of volume and grain boundary diffusion coefficients. 24 The rate controlling mechanisms (grain boundary or volume diffusion) are not properly discussed 24 and it is left unclear which type of diffusion coefficient was determined. ...
... In magnetic interaction, the magnetic dipole moment of the probe nucleus interacts with the internal/external magnetic field. Using this technique, several studies in Hf/Zr-Ni systems were carried out earlier to investigate their EFGs and magnetic properties [11][12][13][14][15][16][17]. Recently we have studied the structural properties of (Zr/Hf) 8 Ni 21 , (Zr/Hf) 7 Ni 10 using the PAC technique [18,19]. ...
... For the TiPd with lowest hafnium concentration measured with 181 Ta about 90% of the probe atoms exhibit EFG1, characterized by the quadrupole frequency ν Q1 = 312(2) MHz (η 1 = 0.19 (1)). The rest of the probes exhibit slightly larger EFG2 (ν 2 = 354(2) MHz) with larger asymmetry parameter (η 2 = 0.59 (3)) [15]. [16] for TiPd intermetallic compounds conrmed the assumption that the 111 Cd and 181 Ta substitutes mainly Ti atoms in the lattice ( Table I). ...