P. Senthil Kumar’s research while affiliated with Pondicherry University and other places

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Publications (864)


Magnetic Nanoparticles: Synthesis, characterization and application based on environmental Perspective
  • Article

March 2025

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44 Reads

Results in Chemistry

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Gayathri Rangasamy





Potential Applications of Rice Husk Derivatives as Useful Adsorptive Material

January 2025

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3 Reads

The agricultural waste of rice husk (RH) has been used as bioadsorbent owing to its easy availability and cost effective removal of toxic pollutants like phenols, pesticides, dyes and heavy metals from the effluents. The surface modification of RH is crucial to improve its adsorptive potential towards removing dyes. This chapter outlines the influencing factors like concentration of initial dye, reaction temperature, adsorbent concentration, pH condition, reaction time, and temperature on the adsorptive elimination of cationic and anionic dyes by using RH as a bioadsorbent for wastewater treatment. The elimination of hazardous dyes using rice husk ash (RHA)-derived zeolite under various experimental conditions is also discussed. The interactive nature between the adsorbent and adsorbate can be understood by analyzing the adsorption data using Freundlich and Langmuir isotherms. The method of evaluating the three important thermodynamic parameters, including Gibb’s free energy, change in entropy and enthalpy is also reviewed which helps to comprehend the dye adsorption mechanism with RH and RH-derived bioadsrobents.


Environmental remediation of malachite green dye from water using hydrothermally carbonized agro-waste biomass: mechanisms and optimization

January 2025

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14 Reads

International journal of Environmental Science and Technology

Water pollution from domestic sewage and industrial waste, exacerbated by malachite green (MG) dyes, poses a significant environmental challenge. Hydrothermal carbonization converts biomass into hydrochar, facilitating efficient and sustainable adsorption of water impurities. The study examines muskmelon peel hydrochar (MMPH) as an effective adsorbent for MG dye removal from aqueous solutions. Several factors affecting removal efficiency were thoroughly investigated, including MMPH dosage, initial dye concentration, contact time, and thermal conditions. The findings reveal that increasing the MMPH dosage enhance removal efficiency, with saturation reached at 2 g/L. Higher initial dye concentrations lead to decreased removal efficiency due to an excess of unbound dye molecules compared to available active sites. The highest removal efficiency was observed after a contact time of 120 min at a temperature of 303 K. Thermodynamic analysis confirms the adsorption process is an exothermic and thermodynamically favorable, with increased disorder. Isotherm and kinetic studies revealed that the Freundlich model provided the best fit, emphasizing concentration-dependent kinetics. The Langmuir model estimated a maximum adsorption capacity (qmax = 208.2 mg/g). This research highlights the potential of MMPH in MG dye removal, contributing to sustainable wastewater treatment and environmental remediation.


XRD pattern of (a) g-C3N4, (b) 3% ES/g-C3N4, (c) 5% ES/g-C3N4, and (d) 7% ES/g-C3N4 composites.
XRD pattern of (a) g-C3N4, (b) 3% ES/g-C3N4, (c) 5% ES/g-C3N4, and (d) 7% ES/g-C3N4 composites.
XRD pattern of (a) g-C3N4, (b) 3% ES/g-C3N4, (c) 5% ES/g-C3N4, and (d) 7% ES/g-C3N4 composites.
XRD pattern of (a) g-C3N4, (b) 3% ES/g-C3N4, (c) 5% ES/g-C3N4, and (d) 7% ES/g-C3N4 composites.
ES/g-C3N4 composites and g-C3N4’s FTIR spectrum.

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Enhanced Photocatalytic Removal of Congo Red Dye From Water Environment Using Eggshells Infused With Graphitic Carbon Nitride Composites
  • Article
  • Full-text available

January 2025

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7 Reads

Eggshell (ES)-based photocatalysts have gained attention in recent years. They are less toxic, abundant, affordable, and efficient photocatalysts in treating dye-polluted water. This work reports the deterioration of Congo red (CR) under visible light region using ES-integrated graphitic carbon nitride (g-C3N4). The photocatalyst was prepared by thermal condensation by varying the mass ratios of ES powder. The material structure and the morphological characteristics are confirmed using FTIR, XRD, BET, UV-DRS, UV-Vis spectra, SEM, EDAX, and photoluminescence. By optical investigations, the band gap of bare ES was found to have a value of 5.04 eV. It was narrowed down to 2.57 eV at the optimum composition of ES/g-C3N4. The effects of several reaction parameters, such as the initial concentration of dye, the amount of catalyst, and the pH level of the solution on the photodegradation rate were investigated. The degradation results revealed that the catalyst removed around 90.5% of the CR dye in 90 min at 498 nm when subjected to visible light. A pseudo-first-order model was concluded from the kinetic data analysis of the mineralization of CR dye using carbon nitride photocatalysts infused with eggshells. The photodegradation rate of 5% ES g-C3N4 was three times greater than that of pure g-C3N4, indicating a decreased recombination rate of the electron-hole pair.

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Citations (40)


... HR-TEM images for (a-c) controlled shapes of anisotropic oligo AMTa-AuNS synthesized by 500 mL AMTa addition at 80°C reaction temperature and (d-i) HR-TEM images of magnified view of (d) triangle, (e) rod, (f) pyramid, (g) hexagonal (h) spherical and (i) boat shaped anisotropic oligo AMTa-AuNS. appears at 0.42 V and the oxidation peak appears at 0.98 V on the GC/oligo AMTa-AuNS electrode.40,41 In the PB solution, the attachment of gold oxide develops redox peaks. ...

Reference:

Beyond templates: exploring uncharted territory in anisotropic gold nanostructure-oligomer composites synthesis and electrocatalytic performance towards environmental pollutants
Anisotropic Gold Nanostructure-Mediated Electrocatalysis on Exfoliated GCN: A Shape-Dependent Study
  • Citing Article
  • November 2024

Surfaces and Interfaces

... Synthetic rubber also relies on pigments to provide specific colors for products like tires, seals and gaskets helping to distinguish them and sometimes to indicate particular properties. These aromatic compounds, while contributing to the aesthetic appeal of products, can also act as toxic pollutants with far-reaching consequences [6][7][8]. One of the major concerns associated with these colorants is their potential to induce cardiovascular issues [9]. ...

Effective removal of toxic mixed azo dyes and Cr (VI) ions from wastewater using an integrated approach
  • Citing Article
  • October 2024

Desalination and Water Treatment

... For example, the development of sustainable livelihoods for local communities that are based on the conservation and utilization of wetland resources with an understanding of biomechanical principles can ensure the long-term viability of these ecosystems. The promotion of ecotourism activities that highlight the biomechanical wonders of wetlands can raise public awareness and support for conservation efforts [33]. ...

A review of the wetland's restoration mechanisms and its economic and social benefits
  • Citing Article
  • September 2024

Water Practice & Technology

... The process of altering the surface of nanoparticles is frequently used to improve their stability and dispersion in the base fluid, which can enhance the nanofluid's thermal performance. The purpose of this work is to investigate how various surface alterations of silver nanoparticles affect heat pipe thermal performance [3]. ...

A critical review on synthesis and application aspect of venturing the thermophysical properties of hybrid nanofluid for enhanced heat transfer processes
  • Citing Article
  • August 2024

Chemical Engineering Research and Design

... Regarding the persistence and biodegradability of emerging contaminants, many of these compounds are resistant to biodegradation and can persist in the environment, posing an additional challenge for their effective removal [142]. This is because they are often not removed by conventional biological processes, requiring advanced technologies such as reverse osmosis [143]. While some traditional pollutants are also persistent, they are, however, more susceptible to biological degradation processes, which can facilitate their removal in conventional treatment systems [144]. ...

Current research progress in the biological removal of emerging contaminants from water environment
  • Citing Article
  • July 2024

Water Practice & Technology

... New carbonaceous biosorbents have been fabricated from biomass and biowaste to efficiently remove Cr(VI) from aqueous systems. [10][11][12][13][14][15][16] Electrostatic attraction and complexation with the oxygen (O)-containing functional groupssuch as carboxyl, phenolic hydroxyl, carbonyl, anhydride, etc.on the surface of BC activated carbon surfaces, provides the adsorption sites for heavy metals. 17 For instance, apricot stones carbonized then activated with sulfuric acid (H 2 SO 4 ) exhibited a Cr(VI) uptake capacity of 34.70 mg g −1 . ...

Effective removal of chromium by adsorption using Delonix regia bark derived activated carbon from aqueous solution: a sustainable approach

Environmental Geochemistry and Health

... The possibilities of traditionally used sorbents (activated carbon, silica gel, expensive ion exchange resins, etc.) have been largely exhausted; therefore, research on their use consists of creating modified sorbents with improved practical characteristics by changing the properties of the sorbent surface. The ability of natural zeolite minerals to extract various heavy metals (mainly from aqueous solutions), due to their structure and physico-chemical properties, has long been known and widely used [10][11][12][13]. Natural zeolites are crystalline aluminosilicates of alkaline and alkaline earth metals having a "frame" structure, with cavities and channels that determine molecular sieving, sorption and other properties. ...

Recent research progress on the removal of heavy metals from wastewater using modified zeolites: A critical review
  • Citing Article
  • June 2024

Desalination and Water Treatment

... Furthermore, electrochemical techniques are adaptable, allowing for the simultaneous detection of multiple pollutants and the use of tailored electrode materials to enhance selectivity and sensitivity, making them an excellent choice for NB determination in a variety of environmental and industrial circumstances. [27][28][29][30][31][32] Establishing oligomer and anisotropic oligomer-capped gold nanostructures (AuNS) with 3-amino-5-mercapto-1,2,4-triazole (AMTa) as a monomer is the purpose of this investigation. The developed oligo AMTa and oligo AMTa-AuNS were subsequently investigated on glassy carbon (GC) electrodes for their electrocatalytic performance of NB reduction. ...

Environmental analysis of nitrobenzene using newly synthesized anisotropic gold nanostructures: Reaction kinetics and electrocatalytic activity
  • Citing Article
  • June 2024

Journal of Molecular Liquids

... The incorporation of Artificial Intelligence (AI) in water-based applications treatment offers notable advantages, such as improved effectiveness, anticipatory maintenance, and optimized allocation of resources considering the global demand for clean water and sustainable systems. Despite challenges caused by system complexity, variable instrumentation levels, dimensions of the WWTP and data quality issues, an emerging approach to addressing this issue is to exploit development in data science and modelling (Wang et al., 2021(Wang et al., , 2023a(Wang et al., , 2023bAlam et al., 2022;Senthil Rathi et al., 2024). In water and wastewater treatment sectors, for environment-health-safe point of vu, generated pollution and by-products must be appropriately managed in respect to applied standards and regulation. ...

Artificial intelligence integration in conventional wastewater treatment techniques: techno-economic evaluation, recent progress and its future direction
  • Citing Article
  • May 2024

International journal of Environmental Science and Technology

... The inclusion of biochar in broiler feed has significant benefits, including enhanced digestion, improved growth rate, better feed conversion ratio (FCR), and increased feed efficiency, which maximizes the energy absorbed from feed. Biochar effectively binds toxins, mitigating their adverse effects on the digestive system and intestinal flora (Sivaranjanee et al., 2024). These properties were evident in this study, where birds supplemented with biochar from maize stover (T3) demonstrated superior performance in final body weight, body weight gain, and average daily weight gain. ...

A critical review on biochar for the removal of toxic pollutants from water environment
  • Citing Article
  • May 2024

Chemosphere