Nathan J. Mayne’s research while affiliated with University of Exeter and other places

The formation and migration history of a planet is expected to be imprinted in its atmosphere, in particular its carbon-to-oxygen (C/O) ratio and metallicity. The BOWIE-ALIGN programme is performing a comparative study of JWST spectra of four aligned and four misaligned hot Jupiters, with the aim of characterising their atmospheres and corroborating the link between the observables and the formation history. In this work, we present the 2.8 − 5.2 micron transmission spectrum of TrES-4 b, a hot Jupiter with an orbit aligned with the rotation axis of its F-type host star. Using free chemistry atmospheric retrievals, we report a confident detection of H2O at an abundance of $\log X_\mathrm{H_2O}=-2.98^{+0.68}_{-0.73}$ at a significance of 8.4σ. We also find evidence for CO and small amounts of CO2, retrieving abundances $\log X_\mathrm{CO}= -3.76^{+0.89}_{-1.01}$ and $\log X_\mathrm{CO_2}= -6.86^{+0.62}_{-0.65}$ (3.1σ and 4.0σ respectively). The observations are consistent with the the atmosphere being in chemical equilibrium; our retrievals yield C/O between 0.30 − 0.42 and constrain the atmospheric metallicity to the range 0.4 − 0.7 × solar. The inferred sub-stellar properties (C/O and metallicity) challenge traditional models, and could have arisen from an oxygen-rich gas accretion scenario, or a combination of low-metallicity gas and carbon-poor solid accretion.

The formation and migration history of a planet is expected to be imprinted in its atmosphere, in particular its carbon-to-oxygen (C/O) ratio and metallicity. The BOWIE-ALIGN programme is performing a comparative study of JWST spectra of four aligned and four misaligned hot Jupiters, with the aim of characterising their atmospheres and corroborating the link between the observables and the formation history. In this work, we present the $2.8-5.2$ micron transmission spectrum of TrES-4b, a hot Jupiter with an orbit aligned with the rotation axis of its F-type host star. Using free chemistry atmospheric retrievals, we report a confident detection of H$_2$O at an abundance of $\log X_\mathrm{H_2O}=-2.98^{+0.68}_{-0.73}$ at a significance of $8.4\sigma$. We also find evidence for CO and small amounts of CO$_2$, retrieving abundances $\log X_\mathrm{CO}= -3.76^{+0.89}_{-1.01}$ and $\log X_\mathrm{CO_2}= -6.86^{+0.62}_{-0.65}$ ($3.1\sigma$ and $4.0\sigma$ respectively). The observations are consistent with the the atmosphere being in chemical equilibrium; our retrievals yield $\mathrm{C/O}$ between $0.30-0.42$ and constrain the atmospheric metallicity to the range $0.4-0.7\times$ solar. The inferred sub-stellar properties (C/O and metallicity) challenge traditional models, and could have arisen from an oxygen-rich gas accretion scenario, or a combination of low-metallicity gas and carbon-poor solid accretion.

We present a study of the effects of ultraviolet (UV) emission from active galactic nuclei (AGN) on the atmospheric composition of planets and potential impact on life. It is expected that all supermassive black holes, which reside at galactic centers, have gone through periods of high AGN activity in order to reach their current masses. We examine potential damaging effects on lifeforms on planets with different atmosphere types and receiving different levels of AGN flux, using data on the sensitivity of various species’ cells to UV radiation to determine when radiation becomes “dangerous.” We also consider potential chemical changes to planetary atmospheres as a result of UV radiation from AGN, using the Platform for Atmosphere, Land, Earth, and Ocean photochemical model. We find that the presence of sufficient initial oxygen (surface mixing ratio ≥10 ⁻³ mol mol ⁻¹ ) in the planet’s atmosphere allows a thicker ozone layer to form in response to AGN radiation, which reduces the level of dangerous UV radiation incident on the planetary surface from what it was in absence of an AGN. We estimate the fraction of solar systems in galaxies that would be affected by substantial AGN UV radiation, and find that the impact is most pronounced in compact galaxies such as “red nugget relics,” as compared to typical present-day ellipticals and spirals (using M87 and the Milky Way as examples).

We present a transmission spectrum of the misaligned hot Jupiter WASP-15b from 2.8–5.2 microns observed with JWST’s NIRSpec/G395H grating. Our high signal to noise data, which has negligible red noise, reveals significant absorption by H2O (4.2σ) and CO2 (8.9σ). From independent data reduction and atmospheric retrieval approaches, we infer that WASP-15b’s atmospheric metallicity is super-solar (≳ 15 × solar) and its C/O is consistent with solar, that together imply planetesimal accretion. Our GCM simulations for WASP-15b suggest that the C/O we measure at the limb is likely representative of the entire photosphere due to the mostly uniform spatial distribution of H2O, CO2 and CO. We additionally see evidence for absorption by SO2 and absorption at 4.9 μm, for which the current leading candidate is OCS, albeit with several caveats. If confirmed, this would be the first detection of OCS in an exoplanet atmosphere and point towards complex photochemistry of sulphur-bearing species in the upper atmosphere. These are the first observations from the BOWIE-ALIGN survey which is using JWST’s NIRSpec/G395H instrument to compare the atmospheric compositions of aligned/low-obliquity and misaligned/high-obliquity hot Jupiters around F stars above the Kraft break. The goal of our survey is to determine whether the atmospheric composition differs across two populations of planets that have likely undergone different migration histories (disc versus disc-free) as evidenced by their obliquities (aligned versus misaligned).

Which rocky exoplanets have atmospheres? This presumably simple question is the first that must be answered to understand the prevalence of nearby habitable planets. A mere 6.9 pc from Earth, LTT 1445A is the closest transiting M dwarf system, and its largest known planet, at 1.31 R ⊕ and 424 K, is one of the most promising targets in which to search for an atmosphere. We use Hubble Space Telescope/Wide Field Camera 3 transmission spectroscopy with the G280 and G141 grisms to study the spectrum of LTT 1445Ab between 0.2 and 1.65 μ m. In doing so, we uncover an ultraviolet (UV) flare on the neighboring star LTT 1445C that is completely invisible at optical wavelengths; we report one of the first simultaneous near-UV/optical spectra of an M dwarf flare. The planet spectrum is consistent with a flat line (with median transit depth uncertainties of 128 and 52 ppm for the G280 and G141 observations, respectively), though the infrared (IR) portion displays potential features that could be explained by known opacity sources such as HCN. Some atmospheric retrievals weakly favor (∼2 σ ) an atmosphere, but it remains challenging to discern between stellar contamination, an atmosphere, and a featureless spectrum at this time. We do, however, confidently rule out ≤100× solar metallicity atmospheres. Although stellar contamination retrievals cannot fit the IR features well, the overall spectrum is consistent with stellar contamination from hot or cold spots. Based on the UV/optical data, we place limits on the extent of stellar variability expected in the near-IR (30–40 ppm), which will be critical for future James Webb Space Telescope observations.

We have conducted a planetary radial velocity measurement of the ultra-hot Jupiter WASP-121b using JWST NIRSpec phase curve data. Our analysis reveals the Doppler shift of the planetary spectral lines across the full orbit, which shifts considerably across the detector ($\sim$ 10 pixels). Using cross-correlation techniques, we have determined an overall planetary velocity amplitude of $K_{\rm p}=215.7\pm1.1$ km/s, which is in good agreement with the expected value. We have also calculated the dynamical mass for both components of the system by treating it as an eclipsing double-line spectroscopic binary, with WASP-121A having a mass of M$_{\star}$=1.330 $\pm$ 0.019 M$_{\odot}$, while WASP-121b has a mass of M$_{\rm p}$= 1.170 $\pm$ 0.043 M$_{\rm Jup}$. These dynamical measurements are $\sim3\times$ more precise than previous estimates and do not rely on any stellar modeling assumptions which have a $\sim$5\% systematic floor mass uncertainty. Additionally, we used stellar evolution modeling constrained with a stellar density and parallax measurement to determine a precise age for the system, found to be 1.11 $\pm$ 0.14 Gyr. Finally, we observed potential velocity differences between the two NIRSpec detectors, with NRS1 lower by 5.5$\pm$2.2 km/s. We suggest that differences can arise from day/night asymmetries in the thermal emission, which can lead to a sensitivity bias favoring the illuminated side of the planet, with planetary rotation and winds both acting to lower a measured $K_{\rm P}$. The planet's rotation can account for 1 km/s of the observed velocity difference, with 4.5$\pm$2.2 km/s potentially attributable to vertical differences in wind speeds.

Terrestrial exoplanets around M- and K-type stars are important targets for atmospheric characterization. Such planets are likely tidally locked with the order of spin–orbit resonances (SORs) depending on eccentricity. We explore the impact of SORs on 3D atmospheric dynamics and chemistry, employing a 3D coupled climate-chemistry model to simulate Proxima Centauri b in 1:1 and 3:2 SORs. For a 1:1 SOR, Proxima Centauri b is in the Rhines rotator circulation regime with dominant zonal gradients (global mean surface temperature 229 K). An eccentric 3:2 SOR warms Proxima Centauri b to 262 K with gradients in the meridional direction. We show how a complex interplay between stellar radiation, orbit, atmospheric circulation, and (photo)chemistry determines the 3D ozone distribution. Spatial variations in ozone column densities align with the temperature distribution and are driven by stratospheric circulation mechanisms. Proxima Centauri b in a 3:2 SOR demonstrates additional atmospheric variability, including daytime–nighttime cycles in water vapor of +55% to −34% and ozone (±5.2%) column densities and periastron–apastron water vapor cycles of +17% to −10%. Synthetic emission spectra for the spectral range of the Large Interferometer For Exoplanets fluctuate by up to 36 ppm with the orbital phase angle for a 1:1 SOR due to 3D spatial and temporal asymmetries. The homogeneous atmosphere for the 3:2 SOR results in relatively constant emission spectra and provides an observational discriminant from the 1:1 SOR. Our work emphasizes the importance of understanding the 3D nature of exoplanet atmospheres and associated spectral variations to determine habitability and interpret atmospheric spectra.

We present a study of the effects of ultraviolet (UV) emission from active galactic nuclei (AGN) on the atmospheric composition of planets and potential impact on life. It is expected that all supermassive black holes, which reside at galactic centers, have gone through periods of high AGN activity in order to reach their current masses. We examine potential damaging effects on lifeforms on planets with different atmosphere types and receiving different levels of AGN flux, using data on the sensitivity of various species' cells to UV radiation to determine when radiation becomes ``dangerous''. We also consider potential chemical changes to planetary atmospheres as a result of UV radiation from AGN, using the PALEO photochemical model. We find the presence of sufficient initial oxygen (surface mixing ratio $\geq 10^{-3} \rm\, mol/mol$) in the planet's atmosphere allows a thicker ozone layer to form in response to AGN radiation, which reduces the level of dangerous UV radiation incident on the planetary surface from what it was in absence of an AGN. We estimate the fraction of solar systems in galaxies that would be affected by AGN UV radiation, and find that the impact is most pronounced in compact galaxies such as ``red nugget relics'', as compared to typical present-day ellipticals and spirals (using M87 and the Milky Way as examples). Our work generally supports the Gaia hypothesis, where the development of life on a planet (and resulting oxygenation of the atmosphere) causes the environment to become more stable against potential extinction events in the future.

We have conducted a planetary radial velocity measurement of the ultrahot Jupiter WASP-121b using JWST NIRSpec phase curve data. Our analysis reveals the Doppler shift of the planetary spectral lines across the full orbit, which shifts considerably across the detector (∼10 pixels). Using cross-correlation techniques, we have determined an overall planetary velocity amplitude of K p = 215.7 ± 1.1 km s ⁻¹ , which is in good agreement with the expected value. We have also calculated the dynamical mass for both components of the system by treating it as an eclipsing double-line spectroscopic binary, with WASP-121A having a mass of M ⋆ = 1.330 ± 0.019 M ⊙ , while WASP-121b has a mass of M p = 1.170 ± 0.043 M Jup . These dynamical measurements are ∼3× more precise than previous estimates and do not rely on any stellar modeling assumptions that have a ∼5% systematic floor mass uncertainty. Additionally, we used stellar evolution modeling constrained with a stellar density and parallax measurement to determine a precise age for the system, found to be 1.11 ± 0.14 Gyr. Finally, we observed potential velocity differences between the two NIRSpec detectors, with NRS1 lower by 5.5 ± 2.2 km s ⁻¹ . We suggest that differences can arise from day/night asymmetries in the thermal emission, which can lead to a sensitivity bias favoring the illuminated side of the planet, with planetary rotation and winds both acting to lower a measured K P . The planet’s rotation can account for 1 km s ⁻¹ of the observed velocity difference, with 4.5 ± 2.2 km s ⁻¹ potentially attributable to vertical differences in wind speeds.

Terrestrial exoplanets around M- and K-type stars are important targets for atmospheric characterisation. Such planets are likely tidally locked with the order of spin-orbit resonances (SORs) depending on eccentricity. We explore the impact of SORs on 3D atmospheric dynamics and chemistry, employing a 3D coupled Climate-Chemistry Model to simulate Proxima Centauri b in 1:1 and 3:2 SOR. For a 1:1 SOR, Proxima Centauri b is in the Rhines rotator circulation regime with dominant zonal gradients (global mean surface temperature 229 K). An eccentric 3:2 SOR warms Proxima Centauri b to 262 K with gradients in the meridional direction. We show how a complex interplay between stellar radiation, orbit, atmospheric circulation, and (photo)chemistry determines the 3D ozone distribution. Spatial variations in ozone column densities align with the temperature distribution and are driven by stratospheric circulation mechanisms. Proxima Centauri b in a 3:2 SOR demonstrates additional atmospheric variability, including daytime-nighttime cycles in water vapour of ${+}$55% to ${-}$34% and ozone ($\pm5.2$%) column densities and periastron-apoastron water vapour cycles of ${+}$17% to ${-}$10%. Synthetic emission spectra for the spectral range of the Large Interferometer For Exoplanets fluctuate by up to 36 ppm with orbital phase angle for a 1:1 SOR due to 3D spatial and temporal asymmetries. The homogeneous atmosphere for the 3:2 SOR results in relatively constant emission spectra and provides an observational discriminant from the 1:1 SOR. Our work emphasizes the importance of understanding the 3D nature of exoplanet atmospheres and associated spectral variations to determine habitability and interpret atmospheric spectra.