Nadia Touati's research while affiliated with French National Centre for Scientific Research and other places

Publications (23)

Article
Full-text available
Sulfuration of uridine 34 in the anticodon of tRNAs is conserved in the three domains of life, guaranteeing fidelity of protein translation. In eubacteria, it is catalyzed by MnmA-type enzymes, which were previously concluded not to depend on an iron–sulfur [Fe–S] cluster. However, we report here spectroscopic and iron/sulfur analysis, as well as i...
Article
Growing high-purity diamond containing dense negatively charged nitrogen-vacancy (NV⁻) centre ensembles is desirable for the development of sensitive quantum sensors that explore the coherent manipulation of the spin states of this atomic-scale defect. By using N2O as a dopant, we demonstrate that millimetre-thick single crystals can be grown by Ch...
Article
Full-text available
Copper acetate and copper resinate pigments are bimetallic Cu II complexes in which metal atoms are bridged by four carboxylate ligands (acetate or abietate). Prepared with lindseed oil as binder, these green pigments were particularly used in easel paintings between the 15th and 17th centuries. Unfortunately, they had the tendency to darken in an...
Article
Zinc oxide (ZnO), used as a pigment since the 19th C., is highly reactive when mixed with drying oils. Indeed, the combination of metal-based pigments and drying oils may react to form metal complexes in paint, which may lead to the aggregation of metal carboxylates or soaps. Whereas the mechanism and chemistry behind metal soap formation has been...
Data
SM related to "Monitoring metal ion leaching in oil-ZnO paint systems with a paramagnetic probe"
Article
The production of fluorescent nanodiamonds (NDs) with specific color centers and exhibiting a controlled size and purity represents an important challenge. In the context of quantum technologies they may indeed provide useful probes for magnetic or thermal sensing with extreme performance and biocompatibility. While detonation and grinding are the...
Article
It is generally believed that CO2 electroreduction to multi‐carbon products such as ethanol or ethylene may be catalyzed with significant yield only on metallic copper surfaces, implying large ensembles of copper atoms. Here, we report on an inexpensive Cu‐N‐C material prepared via a simple pyrolytic route that exclusively feature single copper ato...
Article
It is generally believed that CO2 electroreduction to multi‐carbon products such as ethanol or ethylene may be catalyzed with significant yield only on metallic copper surfaces, implying large ensembles of copper atoms. Here, we report on an inexpensive Cu‐N‐C material prepared via a simple pyrolytic route that exclusively feature single copper ato...
Article
Full-text available
In order to colonize environments with large O 2 gradients or fluctuating O 2 levels, bacteria have developed metabolic responses that remain incompletely understood. Such adaptations have been recently linked to antibiotic resistance, virulence, and the capacity to develop in complex ecosystems like the microbiota. Here, we identify a novel pathwa...
Preprint
Full-text available
Most bacteria can generate ATP by respiratory metabolism, in which electrons are shuttled from reduced substrates to terminal electron acceptors, via quinone molecules like ubi quinone. Dioxygen (O 2 ) is the terminal electron acceptor of aerobic respiration and serves as a co-substrate in the biosynthesis of ubi quinone. Here, we characterize a no...
Article
Full-text available
Chromium(iii) and bismuth(iii) co-doped ZnGa2O4 nanoparticles are synthesized by a hydrothermal method assisted by microwave heating. The obtained nanoparticles, with a diameter smaller than 10 nm, present good luminescence emission in the deep red range centered at 695 nm after coating with a silica layer and calcination at 1000 °C during 2 h. Per...
Article
Full-text available
Abstract Acyl-CoA:diacylglycerol acyltransferases 3 (DGAT3) are described as plant cytosolic enzymes synthesizing triacylglycerol. Their protein sequences exhibit a thioredoxin-like ferredoxin domain typical of a class of ferredoxins harboring a [2Fe-2S] cluster. The Arabidopsis thaliana DGAT3 (AtDGAT3; At1g48300) protein is detected in germinating...
Article
The photo-annealing of colour centres in yttria-stabilised zirconia (YSZ) was studied by electron paramagnetic resonance spectroscopy upon UV-ray or laser light illumination, and compared to thermal annealing. Stable hole centres (HCs) were produced in as-grown YSZ single crystals by UV-ray irradiation at room temperature (RT). The HCs produced by...
Article
Full-text available
Micro-Raman spectroscopy, X-band electron paramagnetic resonance (EPR) spectroscopy, and UV-visible optical absorption spectroscopy were used to study the damage production in cerium dioxide (CeO2) single crystals by electron irradiation for three energies (1.0, 1.4, and 2.5 MeV). The Raman-active T2g peak was left unchanged after 2.5-MeV electron...
Article
In this paper, a novel plasma/liquid microreactor has been developed to generate and inject radical species with the aim to perform chemical synthesis reactions in liquid phase. Plasma has always been considered as a source of reactive species, such as radicals, atoms, electrons, etc., with applications mostly dedicated to surface modifications of...
Article
Highly transparent glass ceramics, synthesized from a glass precursor with a nominal composition of SiO2/ZnO/Ga2O3/Na2O/Cr2O3 (65:17:23:5:0.125), were prepared by glass crystallization. This method enables the synthesis of up to 50 wt.-% of size-controllable Cr3+ -doped ZnGa2O4 nanocrystals embedded in an SiO2-rich glass matrix after crystallizatio...
Article
Analytical techniques using proton beams with energy in the MeV range are commonly used to study archeological artefact and artistic objects. However ion beams can induce alteration of fragile materials, which is notably the case of easel paintings, limiting the use of these techniques. We used continuous wave EPR and pulse EPR spectroscopy to reve...
Article
Full-text available
Significance Posttranscriptional modifications of tRNA are essential for translational fidelity. More specifically, mechanisms of selective sulfuration of tRNAs are still largely unknown, and the enzymes responsible for these reactions are incompletely investigated. Therefore, characterizing such systems at the molecular level is greatly valuable t...
Article
Full-text available
A plasma microreactor dedicated to chemical synthesis has been conceived and developed using soft-lithography techniques. In this study, we propose to use highly reactive species created by the plasma discharge to replace traditionally used chemical initiators. A dielectric barrier discharge plasma was generated under atmospheric pressure and then...

Citations

... under sustained heat stress [73]. It has been reported that genetic analysis showing MNMA, known as the enzyme that catalyzes sulfuration of uridine at position 34 in tRNAs, is important for sustaining oxidative stress [74]. ...
... Loss of thiolation at the wobble position of tRNA (anticodon 1 position) correlates with the development of mitochondrial disease myoclonus epilepsy with ragged-red fibers, and excess thiolation promotes cancer and metastasis [22,23]. Studies have identified several tRNA-thiolation enzymes, such as TtuA [24][25][26], TtcA [27], and Ncs6 [28,29] of the TtuA/Ncs6 family; MnmA [30,31] (MnmA family); and ThiI [29] (ThiI family) (Tables S1 and S2). TtuA/Ncs6 family enzymes share a PP-loop (SGGXD [S/T]) residue-motif in the pyrophosphatase (PPase) domain and a CXXC . . . ...
... CVD diamond has been classically grown under microwave (MW) assisted plasmas through heterogeneous growth on a substrate that has been pre-treated or directly on single diamond crystals. These processes have been further exploited to grow micrometric sized high-quality diamond crystals with and without doping [31,2,6,32]. Further investigations in the recent past have been able to demonstrate homogeneous nucleation of DNPS with a wide variety of hydrocarbon precursor gases such as methane [16], ethanol [24,21], halogenated hydrocarbons [10,11] etc. ...
... The binder is typically a diamagnetic liquid such as linseed oil, possessing no EPR signal, although it may undergo photo degradation over centuries to form free radicals. The binder typically does not react with the pigment, although ligand substitution has been observed in specific cases [43]. Therefore, the binder has no effect on the EPR signal of the pigment. ...
... With the term reactivity, we refer to the formation of interactions and bonds that determines a structural evolution of the paint film. Several studies have shown that hydrolysis of drying oils results in the release of free fatty acids, which are then electronically attracted to the zinc oxide [30,39,40]. The ZnO surface is thus functionalized with long aliphatic chain molecules, subsequently forming an amorphous network of zinc carboxylates [41,42]. ...
... Thus, the possibility of creating thin homogeneous layers of a well-dispersed ND with a predictable, controlled, and reproducible structure with photoluminescence originating from the color centers is of particular interest for application in the fields of quantum technologies, secure quantum communication, quantum information processing [7], and in the semiconductor industry as a whole [8]. It may be also useful in sensing and biosensing methods and the development of new devices [9], e.g., for chemical [9,10], thermo- [11], magnetic sensing [12] and molecular and biosensing [13][14][15]. As fluorescence lifetime imaging (FLIM) has been successfully applied for the study of NDs [16,17], the analysis of the structures capable of ND luminescence-based sensing is of particular interest. ...
... The more CO 2 is released in the atmosphere the more average temperature of our atmosphere increases. The content of CO 2 in the environment is increasing day by day and is very dangerous for the human existence on the earth in upcoming years if we do not control it by natural means or through artificial ways [1,2]. Thus a lot of effort must be put into combating climate change by reducing CO 2 into the atmosphere. ...
... Nam et al. constructed a distorted Cu dimer in a metal-organic framework (MOF), HKUST-1, but found that the MOF was reduced to Cu clusters under CO 2 RR conditions and the C 2+ selectivity came from the derived metallic Cu with low coordination numbers (CNs) 22 . A nitrogencoordinated Cu single-site catalyst showed high selectivity toward ethanol in CO 2 and CO electroreduction, while operando X-ray absorption spectroscopy (XAS) suggested that the isolated Cu sites were reversibly converted to Cu nanoparticles, serving as the true catalytically active species in operation 23,24 . It is in doubt whether single-site Cu-without deriving the initial solid-state or molecular materials to Cu agglomerations-can remain stable under CO 2 RR and catalyze C-C coupling. ...
... biosynthesis, UbiU and UbiV, but shows poor conservation of the putative cysteine ligands for the Fe-S cluster 49 . The presence of an Fe-S cluster on TrhP or RlhA has yet to be confirmed. ...
... 13,45,46 However, up to date, such solutions based on MOFs have not been proposed. 13,43,44 Another promising approach is using mixed systems containing chromium ions as well as lanthanide ions. 30,47 Herein, we report the preparation and structural and optical characteristics of the first MOF-type luminescence thermometers based solely on spectroscopic properties of the Cr 3+ ions, i.e., [EA] 2 NaCr x Al 1−x (HCOO) 6 , where x = 1, 0.78, 0.57, 0.30, 0.21, and 0. The investigated materials exhibit significant temperature-dependent emission, simultaneously related to chromium ion concentration. ...