January 2002
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Two series of smog chamber experiments have been conducted to determine the par- ticulate yield from toluene photo oxidation and to investigate the dependence of the yield on experimental factors. Toluene was oxidized by HO radicals in the presence of NO by irradiating mixtures of toluene/isopropylnitrite/NO with UV light and experiments were done in the presence and absence of ammonium sulfate seed particles. Aerosol formation and growth was monitored using size distributions obtained from a Differential Mobility Analyzer and a Condensation Nucleus Counter. A Gas Chromatograph with an FID detector was used to monitor the toluene loss and a Chemiluminescence Analyzer measured the NO concentration. As expected the ozone concentration was found to be extremely low so the complicating ozone reactions are minimized. The experimental yields (the ratio between the organic aerosol mass formed and the mass of toluene reacted) were found to cluster around 10% but there were cases where the yields were as low as 1.7% and as high as 20%. The on-going work is focused on understanding the factors leading to the variability of experimental yields and on analyzing the data in the framework of the current gas/particle partitioning theory.