Margriet L. Lantink’s research while affiliated with University of Wisconsin–Madison and other places

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Publications (12)


Towards an astrochronological framework for the lower Paleoproterozoic Kuruman and Brockman Iron Formations
  • Article

June 2024

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40 Reads

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2 Citations

South African Journal of Geology

M.L. Lantink

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[...]

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F.J. Hilgen

Recent evidence for astronomical-induced cycles in banded iron formations (BIFs) hints at the intriguing possibility of developing astrochronological, i.e. precise time-stratigraphic, frameworks for the earliest Proterozoic as also reconstructed for parts of the Mesozoic and Paleozoic. The Kuruman Iron Formation (IF) (Griqualand West Basin, South Africa) and Dales Gorge Member of the Brockman IF (Hamersley Basin, Western Australia) are of special interest in this regard, given their inferred temporal overlap at ca. 2.47 Ga and similar long-period orbital eccentricity imprint. This suggests that these two BIFs may be correlated on the basis of their large-scale cycle patterns and using additional radio-isotopic age constraints. To examine the possibility of establishing such a framework, we generated and analysed several high-resolution proxy records from both drill-core and outcrop, combined with high-precision U-Pb dating of zircon from interbedded shale horizons. Time-series analysis of these records yields a variety of spectral peaks, of which a prominent ~5 m and ~16 m cycle can be linked to the basic stratigraphic alternations and bundling as observed in the field. New and revised 207Pb/206Pb ages calculated from the U-Pb data of the Dales Gorge Member and Kuruman IF, respectively, indicate a comparable average sedimentation rate of 10 to 12 m/Myr for both units. Based on this depositional rate, we attribute the ~5 m cycle to the long (~405 kyr) orbital eccentricity cycle. More tentatively, we interpret the ~16 m cycle as the very long (presently ~2.4-Myr) eccentricity cycle, having a reduced period of ~1.3 Myr due to chaotic behaviour in the solar system. Other identified cycles (~560 kyr, ~700 kyr and ~1.8 Myr) can be explained in terms of weaker orbital eccentricity components and/or as harmonics and combination tones of these cycles resulting from nonlinear responses. An initial attempt to establish cyclostratigraphic correlations between the Kuruman IF and Dales Gorge Member solely based on their characteristic cycle patterns proved unsuccessful, which may be due to a difference in the recording of the astronomical signal between different depositional environments. Next, we used the zircon ages to first constrain correlations at the scale of the ~16 m cycle, followed by a correlation of the basic ~5 m cycles. The resultant framework remains problematic and debatable at the individual ~405 kyr cycle-level, but provides a starting point for future studies. Particularly, our findings highlight the need for further investigations into how Milankovitch forcing influenced BIF sedimentation and paleoenvironmental conditions at a time when the Earth and solar system behaved fundamentally different from today.


(a) Tidal time lag Δtt (diamonds) used in Mignard's torques including solar‐lunar cross terms (see Appendix E). Dashed line shows constant (present) Δtt. (b) Past Earth‐Moon distance (aL) in units of Earth radii (RE). Red diamonds: Observational estimates based on robust data sets from cyclostratigraphic studies (see Section 3.7). Cyan and blue lines: Options 1 and 2 used in the orbital solution (OS) . Blue: linear extrapolation into the past starting with ȧL ${\dot{a}}_{L}$ close to the present rate. Cyan: 3rd‐order polynomial fit to observations (see Equation 14). Using aL based on the blue and cyan lines made essentially no difference in our OSs (see text Section 3.7). Green lines/symbols: Integration of precession equations with snvec. Light green area (Min/Max): Error envelope for aL reflecting cyclostratigraphic data errors, see Section 3 and Figure F2. Green dashed: starting at present rate ȧL0=3.82 ${\dot{a}}_{L0}=3.82$ cm y⁻¹ with constant tidal time lag (Δtt ≃ 9 min) in the past (see (a)), yields the (well‐known) unrealistic past aL. Dark green diamonds: using variable Δtt in the past from (a), internally consistent with OS option 1, see text.
Evolution of fundamental (secular) solar system frequencies. The g‐ and s‐frequencies (in arcsec y⁻¹ = ” y⁻¹) were determined from our solar system integrations using fast Fourier transform over consecutive 20‐Myr intervals and Earth's k and q variables (see text). The g‐ and s‐modes are loosely related to the apsidal and nodal precession of the planetary orbits. Solutions including σ12‐resonance intervals (∼40%) are highlighted in color (see Appendix D and Zeebe & Lantink, 2024), the remaining solutions are displayed in gray.
Periods of (g4 − g3) and (s4 − s3) over consecutive 20‐Myr intervals based on our solar system integrations. Light blue: from individual g's and s's obtained by direct fast Fourier transform (FFT) (see Figure 2). (a) Dark blue: g4−g3−1= ${\left({g}_{4}-{g}_{3}\right)}^{-1}\hspace*{.5em}=$ VLEC from spectral analysis of the Hilbert transform of a 100‐kyr filter of eccentricity (see Figures 13 and 14 of Zeebe et al., 2017). For (s4 − s3), the Hilbert transform method (using filtered inclination) often fails because it tends to overemphasize long periods in the Hilbert transform. For (s4 − s3) the Hilbert transform frequently predicts a period doubling (not shown), inconsistent with individual s's from FFT.
Histograms for the g43 = (g4 − g3) and s43 = (s4 − s3) periods (see Figure 3). Note the logarithmic y‐scale. (a) g43−1 ${g}_{43}^{-1}$ = VLEC from direct fast Fourier transform (FFT) (max at 2.1 Myr). The side peak at ∼1.25 Myr (arrow) has been confirmed in various solutions and contributes to the 1:1 s43: g43 ratio marked in (d). (b) g43−1 ${g}_{43}^{-1}$ based on Hilbert transform (max at 2.1 Myr). Arrow: same as in (a). The peak around 3.8 Myr is not robust because the method tends to overemphasize long periods in the Hilbert transform. (c) s43−1 ${s}_{43}^{-1}$ from direct FFT (max at 1.2 Myr). The side peak at ∼2.25 Myr (arrow) has been found in a few solutions (g43−1≃ ${g}_{43}^{-1}\simeq \hspace*{.5em}$2.2 Myr simultaneously) and contributes to the 1:1 s43: g43 ratio as well. (d) s43: g43 ratio from direct FFT.
PT solution based on the orbital solution from run R06. Error envelopes in (a) and (b) are based on estimated lunar distance uncertainties (reflecting the cyclostratigraphic data errors, see panel (a) and Figure F2). (a) Lunar distance (aL) in units of Earth radii (RE). Green line: PT solution obtained using snvec code. Red diamonds: Observational estimates based on robust data sets from cyclostratigraphic studies (see Section 3.7). (b) Luni‐solar precession rate (Ψ, see Equation 15) in arcsec y⁻¹ (left axis) and period in kyr (right axis). (c) Obliquity ϵ calculated with Mignard's torques including cross‐terms (light green) and MacDonald's torques (dashed, binned mean values). Arrows highlight selected intervals of reduced amplitude variations in orbital inclination and hence in ϵ. Also note the general trend of increasing ϵ amplitude with time (see text). (d) Climatic precession p¯=esinω¯ $\left(\bar{p}=e\,\sin \bar{\omega }\right)$. Reduced amplitude variations in orbital eccentricity (and hence in p¯ $\bar{p}$) may occur during σ12‐resonance episodes (double arrow, see Appendix D and Zeebe and Lantink (2024)).

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Milanković Forcing in Deep Time
  • Article
  • Publisher preview available

May 2024

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171 Reads

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4 Citations

Astronomical (or Milanković) forcing of the Earth system is key to understanding rhythmic climate change on time scales ≳10⁴ y. Paleoceanographic and paleoclimatological applications concerned with past astronomical forcing rely on astronomical calculations (solutions), which represent the backbone of cyclostratigraphy and astrochronology. Here we present state‐of‐the‐art astronomical solutions over the past 3.5 Gyr. Our goal is to provide tuning targets and templates for interpreting deep‐time cyclostratigraphic records and designing external forcing functions in climate models. Our approach yields internally consistent orbital and precession‐tilt solutions, including fundamental solar system frequencies, orbital eccentricity and inclination, lunar distance, luni‐solar precession rate, Earth's obliquity, and climatic precession. Contrary to expectations, we find that the long eccentricity cycle (LEC) (previously assumed stable and labeled “metronome,” recent period ∼405 kyr), can become unstable on long time scales. Our results reveal episodes during which the LEC is very weak or absent and Earth's orbital eccentricity and climate‐forcing spectrum are unrecognizable compared to the recent past. For the ratio of eccentricity‐to‐inclination amplitude modulation (recent individual periods of ~2.4 and ~1.2 Myr, frequently observable in paleorecords) we find a wide distribution around the recent 2:1 ratio, that is, the system is not restricted to a 2:1 or 1:1 resonance state. Our computations show that Earth's obliquity was lower and its amplitude (variation around the mean) significantly reduced in the past. We therefore predict weaker climate forcing at obliquity frequencies in deep time and a trend toward reduced obliquity power with age in stratigraphic records. For deep‐time stratigraphic and modeling applications, the orbital parameters of our 3.5‐Gyr integrations are made available at 400‐year resolution.

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Did atmospheric thermal tides cause a daylength locking in the Precambrian? A review on recent results

April 2024

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168 Reads

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13 Citations

Sedimentologika

After the initial suggestion by Zahnle and Walker (1987) that the torque accelerating the spin rate of the Earth and produced by the heating of the atmosphere by the Sun could counteract the braking luni-solar gravitational torque in the Precambrian, several authors have recently revisited this hypothesis. In these studies, it is argued that the geological evidence of the past spin state of the Earth plays in favor of this atmospheric tidal locking of the length of the day (LOD). In the present review of the recent literature, we show that the drawn conclusions critically depend on LOD estimates based on stromatolite growth band data of Panella at 1.88 and 2.0 Ga which are subject to large uncertainties. When only the most robust cyclostatigraphic estimates of the LOD are retained, the LOD locking hypothesis is not supported. Moreover, our consideration of the published General Circulation Model numerical simulations and of a new analytical model for the thermal atmospheric tides suggest that the atmospheric tidal resonance, which is the crucial ingredient for the LOD locking in the Precambrian, was never of sufficiently large amplitude to allow for this tidal LOD lock.


A Secular Solar System Resonance that Disrupts the Dominant Cycle in Earth’s Orbital Eccentricity (g 2 − g 5 ): Implications for Astrochronology

April 2024

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82 Reads

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6 Citations

The Astronomical Journal

The planets’ gravitational interaction causes rhythmic changes in Earth’s orbital parameters (also called Milanković cycles), which have powerful applications in geology and astrochronology. For instance, the primary astronomical eccentricity cycle due to the secular frequency term ( g 2 − g 5 ) (∼405 kyr in the recent past) utilized in deep-time analyses is dominated by the orbits of Venus and Jupiter, i.e., long eccentricity cycle. The widely accepted and long-held view is that ( g 2 − g 5 ) was practically stable in the past and may hence be used as a “metronome” to reconstruct accurate geologic ages and chronologies. However, using state-of-the-art integrations of the solar system, we show here that ( g 2 − g 5 ) can become unstable over long timescales, without major changes in, or destabilization of, planetary orbits. The ( g 2 − g 5 ) disruption is due to the secular resonance σ 12 = ( g 1 − g 2 ) + ( s 1 − s 2 ), a major contributor to solar system chaos. We demonstrate that entering/exiting the σ 12 resonance is a common phenomenon on long timescales, occurring in ∼40% of our solutions. During σ 12 -resonance episodes, ( g 2 − g 5 ) is very weak or absent and Earth’s orbital eccentricity and climate-forcing spectrum are unrecognizable compared to the recent past. Our results have fundamental implications for geology and astrochronology, as well as climate forcing, because the paradigm that the long eccentricity cycle is stable, dominates Earth's orbital eccentricity spectrum, and has a period of ∼405 kyr requires revision.


Towards an astrochronological framework for the lower Paleoproterozoic Kuruman and Brockman Iron Formations

September 2023

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138 Reads

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1 Citation

Recent evidence for astronomical-induced cycles in banded iron formations (BIFs) hints at the intriguing possibility of developing astrochronological, i.e. precise time-stratigraphic, frameworks for the earliest Proterozoic as also reconstructed for parts of the Mesozoic and Paleozoic. The ca 2.47-Ga Kuruman Iron Formation (Griqualand West Basin, South Africa) and Dales Gorge Member of the Brockman Iron Formation (Hamersley Basin, Western Australia) are of special interest in this regard, given their inferred temporal overlap and similar long-period eccentricity imprint. This suggests that these two BIFs may be correlated on the basis of their large-scale cycle patterns and using additional radio-isotopic age constraints.To examine the possibility of establishing such a framework, we generated and analysed several high-resolution proxy records from both drill-core and outcrop, combined with chemical abrasion ID-TIMS U–Pb dating of presumed volcanically sourced zircon. Time-series analysis of these records yields a variety of spectral peaks, of which a prominent ~5 m and ~16 m cycle can be linked to the basic stratigraphic alternations and bundling. New and improved U–Pb ages of the Dales Gorge Member and Kuruman Iron Formation, respectively, indicate a comparable average sedimentation rate of 10–12 m/Myr for both BIF units. Based on this rate, we attribute the ~5 m cycle to the long 405-kyr eccentricity cycle. More tentatively, we interpret the ~16 m cycle as the very long 2.4-Myr eccentricity cycle, having a reduced period of ~1.3 Myr due to chaotic behaviour in the solar system. Other identified cycles (~580 kyr, ~700 kyr and ~1.8 Myr) might be explained in terms of weaker eccentricity components and/or as harmonics and combination tones of these cycles.An initial attempt to establish cyclostratigraphic correlations between the Kuruman Iron Formation and Dales Gorge Member solely based on their characteristic cycle patterns proved unsuccessful, which may be due to a difference in stratigraphic recording of the astronomical signal between their different depositional environments. Next, we used the U–Pb ages to first constrain correlations at the scale of the ~16 m cycle, followed by a correlation of the basic ~5 m cycles. The resultant framework remains problematic and debatable at the individual 405 kyr cycle-level, and should merely be considered as a starting point for future studies. Particularly, our findings highlight the need for further investigations into how Milankovitch forcing influenced BIF sedimentation and paleoenvironmental conditions at a time when the Earth and solar system behaved fundamentally different from today.




Milankovitch cycles in banded iron formations constrain the Earth–Moon system 2.46 billion years ago

September 2022

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497 Reads

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37 Citations

Proceedings of the National Academy of Sciences

The long-term history of the Earth–Moon system as reconstructed from the geological record remains unclear when based on fossil growth bands and tidal laminations. A possibly more robust method is provided by the sedimentary record of Milankovitch cycles (climatic precession, obliquity, and orbital eccentricity), whose relative ratios in periodicity change over time as a function of a decreasing Earth spin rate and increasing lunar distance. However, for the critical older portion of Earth’s history where information on Earth–Moon dynamics is sparse, suitable sedimentary successions in which these cycles are recorded remain largely unknown, leaving this method unexplored. Here we present results of cyclostratigraphic analysis and high-precision U–Pb zircon dating of the lower Paleoproterozoic Joffre Member of the Brockman Iron Formation, NW Australia, providing evidence for Milankovitch forcing of regular lithological alternations related to Earth’s climatic precession and orbital eccentricity cycles. Combining visual and statistical tools to determine their hierarchical relation, we estimate an astronomical precession frequency of 108.6 ± 8.5 arcsec/y, corresponding to an Earth–Moon distance of 321,800 ± 6,500 km and a daylength of 16.9 ± 0.2 h at 2.46 Ga. With this robust cyclostratigraphic approach, we extend the oldest reliable datum for the lunar recession history by more than 1 billion years and provide a critical reference point for future modeling and geological investigation of Precambrian Earth–Moon system evolution.



Fig. 7. Case 3 compiled results. A) Histogram of the total duration estimates binned in 100 kyr intervals (N=17). The red dotted line indicates the correct solution (8703 kyr). The median submitted solution (8800 kyr) is mentioned in blue. (B) Offset between submission and correct solution versus the reported uncertainty on the duration estimate. Green background: reported uncertainty is larger than the offset between the reported duration estimate and the true duration. Orange background: the offset between estimated and true duration is larger than the reported uncertainty. (C) Offset versus the participant's experience in the general field of cyclostratigraphy. (D) Offset versus the participant's confidence in his/her analysis of Case 2. (E) Offset versus the amount of time spent on the analysis of Case 2. (F) Submitted relative age models. The boxplots represent the distributions of the submitted relative ages for five prescribed stratigraphic positions. (G) Answers to the question "Which are easier to identify: 2.4-Myr orbital eccentricity minima or eccentricity maxima?" (H) Answers to the question "Did you notice any
The Cyclostratigraphy Intercomparison Project (CIP): consistency, merits and pitfalls

October 2019

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763 Reads

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66 Citations

Earth-Science Reviews

Cyclostratigraphy is an important tool for understanding astronomical climate forcing and reading geological time in sedimentary sequences, provided that an imprint of insolation variations caused by Earth’s orbital eccentricity, obliquity and/or precession is preserved (Milankovitch forcing). Numerous stratigraphic and paleoclimate studies have applied cyclostratigraphy, but the robustness of the methodology and its dependence on the investigator have not been systematically evaluated. We developed the Cyclostratigraphy Intercomparison Project (CIP) to assess the robustness of cyclostratigraphic methods using an experimental design of three artificial cyclostratigraphic case studies with known input parameters. Each case study is designed to address specific challenges that are relevant to cyclostratigraphy. Case 1 represents an offshore research vessel environment, as only a drill-core photo and the approximate position of a late Miocene stage boundary are available for analysis. In Case 2, the Pleistocene proxy record displays clear nonlinear cyclical patterns and the interpretation is complicated by the presence of a hiatus. Case 3 represents a Late Devonian proxy record with a low signal-to-noise ratio with no specific theoretical astronomical solution available for this age. Each case was analyzed by a test group of 17-20 participants, with varying experience levels, methodological preferences and dedicated analysis time. During the CIP 2018 meeting in Brussels, Belgium, the ensuing analyses and discussion demonstrated that most participants did not arrive at a perfect solution, which may be partly explained by the limited amount of time spent on the exercises (~4.5 hours per case). However, in all three cases, the median solution of all submitted analyses accurately approached the correct result and several participants obtained the exact correct answers. Interestingly, systematically better performances were obtained for cases that represented the data type and stratigraphic age that were closest to the individual participants’ experience. This experiment demonstrates that cyclostratigraphy is a powerful tool for deciphering time in sedimentary successions and, importantly, that it is a trainable skill. Finally, we emphasize the importance of an integrated stratigraphic approach and provide flexible guidelines on what good practices in cyclostratigraphy should include. Our case studies provide valuable insight into current common practices in cyclostratigraphy, their potential merits and pitfalls. Our work does not provide a quantitative measure of reliability and uncertainty of cyclostratigraphy, but rather constitutes a starting point for further discussions on how to move the maturing field of cyclostratigraphy forward.


Citations (9)


... Similarly, the ZK68 drillcore displays Fig. 9a). Notably, the ratios of these dominant wavelengths are largely consistent with those of the theoretical Ediacaran orbital parameters 41,42 (see Supplementary Note 2 for details). ...

Reference:

Astronomically calibrating early Ediacaran evolution
Milanković Forcing in Deep Time

... Similarly, the ZK68 drillcore displays Fig. 9a). Notably, the ratios of these dominant wavelengths are largely consistent with those of the theoretical Ediacaran orbital parameters 41,42 (see Supplementary Note 2 for details). ...

A Secular Solar System Resonance that Disrupts the Dominant Cycle in Earth’s Orbital Eccentricity (g 2 − g 5 ): Implications for Astrochronology

The Astronomical Journal

... We do so in two configurations: assuming spin-orbit synchronization, which in the absence of planetary obliquity leaves the planet subject to eccentricity tides only; and assuming asynchronous rotation, which amounts to additional tidal harmonics and therefore stronger tidal heating enhancement. While these close-in planets are expected to be in the 1:1 spin-orbit equilibrium, it is possible that they are captured in higher order asynchronous states in the presence of thermal tides in their possibly existing atmospheres (e.g., Gold & Soter 1969;Correia & Laskar 2001;Leconte et al. 2015;Auclair-Desrotour et al. 2017b;Farhat et al. 2024;Revol et al. 2023;Valente et al. 2024;Laskar et al. 2024). For both configurations, we also compute the average enhancement in tidal heating among the studied population. ...

Did atmospheric thermal tides cause a daylength locking in the Precambrian? A review on recent results

Sedimentologika

... Moreover, the cyclostratigraphic record of changing precession and obliquity frequencies permits reconstructing the long-term (tidal) evolution of the Earth-Moon system. The latter approach is especially valuable in Precambrian records, when changes in precession periods and their ratios to eccentricity periods are more pronounced (e.g., Zhang et al., 2015;Meyers & Malinverno, 2018;Lantink et al., 2019Lantink et al., , 2022Lantink et al., , 2024. However, cyclostratigraphic reconstructions and astrochronology purely based on observational data in deep time is challenging in the absence of astronomical tuning targets due to the uncertain long-term tidal evolution of the Earth-Moon system and the solar system's chaotic nature (Berger et al., 1989;Laskar et al., 2004;Zeebe, 2017). ...

Towards an astrochronological framework for the lower Paleoproterozoic Kuruman and Brockman Iron Formations
  • Citing Preprint
  • September 2023

... In recent years, the cyclostratigraphy has been presented as a useful tool for investigating Precambrian paleoenvironments, coupled with stratigraphic and/or geochemical data (Laskar et al., 2011;Laskar et al., 2004;Waltham, 2015;Hinnov, 2018;Rodrigues et al., 2019;Zhou et al., 2022). Orbital imprints on IFs deposition have been the focus of recent cyclostratigraphic studies Mitchell et al., 2021;Lantink et al., 2019Lantink et al., , 2022Lantink et al., , 2023, providing insights into Precambrian Earth-Moon dynamics and offering valuable information regarding these rock's deposition. Nevertheless, there is still a demand for these studies due to the limited references, predominantly focusing on Late Archean to Early Paleoproterozoic IFs Lantink et al., 2019Lantink et al., , 2022Lantink et al., , 2023, apart from one, which examined a Cryogenian IF (Mitchell et al., 2021). ...

Precessional pacing of early Proterozoic redox cycles

Earth and Planetary Science Letters

... The presence of well-preserved astronomical orbital signals in Mesoproterozoic and Paleoproterozoic sediments, some dating back as far as 2.48 billion years, highlights the potential for applying cyclostratigraphic methods to ancient sedimentary records (e.g., refs. 19,20). Previous cyclostratigraphic studies of the Ediacaran have primarily centered on the late Ediacaran Period (e.g., refs. ...

Milankovitch cycles in banded iron formations constrain the Earth–Moon system 2.46 billion years ago
  • Citing Article
  • September 2022

Proceedings of the National Academy of Sciences

... Quantifying age-depth model uncertainty presents significant challenges in cyclostratigraphic approaches, primarily due to the tuning methodology, which aligns a specific depth point with a specific time point without accounting for any margins in either dimension (Sinnesael et al., 2019). However, as shown in Table 1, the tuned ages of biostratigraphic markers often correspond closely with their datum ages, typically within a few hundred thousand years, which falls within the depth uncertainty of the biostratigraphic markers themselves. ...

The Cyclostratigraphy Intercomparison Project (CIP): consistency, merits and pitfalls

Earth-Science Reviews

... In recent years, the cyclostratigraphy has been presented as a useful tool for investigating Precambrian paleoenvironments, coupled with stratigraphic and/or geochemical data (Laskar et al., 2011;Laskar et al., 2004;Waltham, 2015;Hinnov, 2018;Rodrigues et al., 2019;Zhou et al., 2022). Orbital imprints on IFs deposition have been the focus of recent cyclostratigraphic studies Mitchell et al., 2021;Lantink et al., 2019Lantink et al., , 2022Lantink et al., , 2023, providing insights into Precambrian Earth-Moon dynamics and offering valuable information regarding these rock's deposition. Nevertheless, there is still a demand for these studies due to the limited references, predominantly focusing on Late Archean to Early Paleoproterozoic IFs Lantink et al., 2019Lantink et al., , 2022Lantink et al., , 2023, apart from one, which examined a Cryogenian IF (Mitchell et al., 2021). ...

Climate control on banded iron formations linked to orbital eccentricity

... Όσον αφορά τα BIF του Hotazel, το κατώτερο BIF χαρακτηρίζεται ως ένα αιματιτικό BIF και αποτελείται από λεπτόκοκκο αιματίτη, άμορφο χαλαζία, ανθρακικά ορυκτά και μικρές εμφανίσεις μαγνητίτη (Lantink et al, 2018). To BIF που εμφανίζεται ενδιάμεσα ως φτωχό σε ανθρακικά BIF και το ανώτερο BIF το οποίο χαρακτηρίζεται ως πλούσιο σε ανθρακικά BIF. ...

Fe isotopes of a 2.4 Ga hematite-rich IF constrain marine redox conditions around the GOE
  • Citing Article
  • December 2017

Precambrian Research