Marc Prat's research while affiliated with Institut de Mécanique des Fluides de Toulouse and other places

Publications (27)

Article
Liquid corner films in channels or pores of polygonal cross-section are known to have a strong impact on evaporation with a much faster evaporation compared to a tube of circular cross section. The aim of this work is to study the interplay between colloidal particles, development of the corner films and evaporation in a micro channel from a combin...
Article
A two-equation non-local-equilibrium (NLE) continuum model of isothermal drying is assessed by comparison with pore network simulations considering a rigid capillary porous medium that is fully saturated initially. This continuum model consists of a transport equation for the liquid and of a transport equation for the vapor. The two main variables...
Article
Fluid-fluid displacement porosimetry (FFDP) is a method for determining the pore size distribution of a porous medium from viscous fluid-fluid immiscible displacement (drainage) results, using a simplistic representation of the pore structure by cylindrical parallel tubes. The method leads to unambiguous estimates when the porous medium microstruct...
Article
A three equation continuum model of drying is presented. The model explicitly considers the liquid phase as formed by a percolating liquid phase and a nonpercolating liquid phase. The model is tested against pore network simulations. A quite good agreement is obtained between the predictions of the continuum model and data obtained by volume averag...
Article
The coupling boundary condition to be imposed at the evaporative surface of a porous medium is studied from pore network simulations considering the capillary regime. This paper highlights the formation of a thin edge effect region of smaller saturation along the evaporative surface. It is shown that this thin region forms in the breakthrough perio...
Article
Full-text available
The local contact angle distribution within the pore space of a porous medium of mixed wettability is identified by combining pore network simulations and an optimization method. The latter is used to solve the inverse problem consisting of determining the local contact angle distribution from the capillary pressure and relative permeability curves...
Article
Full-text available
The pore size distribution of a porous medium is often estimated from the retention curve or the invading fluid flow rate curve using simple relationships more or less explicitly based on the consideration that the porous medium is made of a bundle of cylindrical parallel tubes. This type of determination is tested using pore network simulations. S...
Article
Drying of capillary porous media initially saturated with saline water is central to many engineering and environmental applications. In order to predict the evolution of solute concentration in a porous medium, the macroscopic continuum models (CMs) are commonly employed. However, the predictive aptitudes of the CMs have been questioned. In this w...
Article
Full-text available
A pore network model of isothermal drying is presented. The model takes into account the capillary effects, the transport of vapor by diffusion, including Knudsen effect, in the gas phase, and the Kelvin effect. The model is seen as a first step toward the simulation of drying in mesoscopic porous materials involving pore sizes between 4 nm and 50...
Article
A two-equation continuum model is developed to simulate the mass transfer in drying porous media. The main goal is to capture the so called non-equilibrium effect. To this end, we operate in a regime where the liquid phase is immobile so that non-equilibrium mass exchange between liquid and vapor phase dominates. The formulation of the model relies...
Article
Full-text available
The gas access through a thin porous layer is studied in relation to the reactant gas transfer in the gas diffusion layer (GDL) of polymer electrolyte membrane fuel cells. In the considered situation, the surface through which the gas enters into the porous layer is partially occluded. The aim is to design the porous medium microstructure so that t...
Article
Previous experimental results indicate that the humidification conditions at the anode have an impact on the liquid water distribution in the cathode gas diffusion layer. Numerical simulations are developed to reproduce and analyze this effect. Results consistent with the experimental results are first obtained by playing with the partition coeffic...
Article
Full-text available
Rough fractures often exhibit a broad spectrum of defect length scales ranging from the microscopic (roughness) scale to a macroscopic one (waviness) and further to the megascopic scale corresponding to the entire fracture. The influence of these multiple scales and their reciprocal interactions are expected to play a significant role on the transp...
Article
The generation of stress on pore wall due to salt crystallization is generally analysed as a compressive stress generation mechanism using the concept of crystallization pressure. We report on a completely different stress generation mechanism. In contrast with the classical picture where the crystal pushes the pore wall, the crystal growth leads t...
Preprint
The generation of stress in a pore due to salt crystallization is generally analysed as a compressive stress generation mechanism using the concept of crystallization pressure. We report on a completely different stress generation mechanism. In contrast with the classical picture where the crystal pushes the pore wall, the crystal growth leads to t...
Article
Full-text available
The slightly compressible flow of a gas in the slip regime within a rough fracture featuring a heterogeneous aperture field is analysed in depth in this work. Starting from the governing Navier–Stokes, continuity and gas state law equations together with a first-order slip boundary condition at the impermeable walls of the fracture, the two-dimensi...
Article
Full-text available
Experimental results based on in-situ measurements at the interface between the catalyst layer and the gas diffusion layer (GDL) on the cathode side at the channel – rib scale show an interesting variation of the current density distribution as the mean current density is increased. It is found that the local current density below the rib median ax...
Article
Full-text available
The evaporation of a saline solution from a heterogeneous porous medium formed by the assembly of a coarse medium column and a fine medium column is studied numerically. We concentrate on the locus of the formation of first crystals on the evaporative surface from the computation of the ion mass fraction distribution at the surface prior to the eff...
Article
The classical continuum modeling of evaporation in capillary porous media is revisited from pore network simulations of the evaporation process. The computed moisture diffusivity is characterized by a minimum corresponding to the transition between liquid and vapor transport mechanisms confirming previous interpretations. Also the study suggests an...
Article
Full-text available
Evaporation is a key phenomenon in the natural environment and in many technological systems involving capillary structures. Understanding the evaporation front dynamics enables the evaporation rate from microfluidic devices and porous media to be finely controlled. Of particular interest is the ability to control the position of the front through...
Article
PEMFC (Proton Exchange Membrane Fuel Cells) is considered as a promising solution for producing clean energy. To increase its industrial development for automotive application, performance and durability are still to be improved and cost needs to be reduced. Water management is one of the most important remaining bottlenecks to increase performance...

Citations

... The definition of the boundary conditions at the top surface is still a debated question in the drying theory [21,28,29,30]. In other words, the coupling at the surface between the transport phenomena in the porous medium and in the external air in contact with the porous medium surface is not yet sufficiently well understood and modelled. ...
... In conjunction, two-phase flow simulations at the pore scale have also been carried out extensively (Zhao et al. 2019) with the aim of reproducing both microscopic and macroscopic observations. These have been performed using various representations of porous structures like pore networks (Gjennestad, Winkler & Hansen 2020;Maalal et al. 2021), X-ray or scanning-electron-microscopy-based images (Aljasmi & Sahimi 2021;Shams et al. 2021). Computations have been carried out in many different configurations using lattice-Boltzmann (Taghilou & Rahimian 2014;Shi & Tang 2018;Gu, Liu & Wu 2021) and other techniques, either based on two-fluid systems taking explicitly into account the interfaces with a volume of fluid method or continuous two-fluid approaches using level-set (Ambekar, Mondal & Buwa 2021;Jettestuen, Friis & Helland 2021) or Cahn-Hilliard models (Yang & Kim 2021) with improved algorithms making use of machine learning (see, for instance, Silva et al. (2021)). ...
... Such an opposite dependence of evaporation rate in the RFP on the contact angle is related to the Kelvin effect. The Kelvin effect refers to the change in vapour pressure above a curved interface by the following expression (Maalal, Prat & Lasseux 2021): ...
... Generating a pore network and simulating a flow in it is often cheaper, in terms of computational resources, when compared to direct numerical simulation. However, more complex transfer mechanisms, such as imbibition and drainage, are still in the study phase, and some extensive work on computational optimization has yet to be conducted, specifically on non-user-generated porous media (Maalal et al., 2021). ...
... The study of evaporation phenomena in porous media (soil, mining waste) is a long-standing research line (Fisher, 1928;Pearce et al., 1949;Rodríguez et al., 2007;Nachshon et al., 2011;Desarnaud et al., 2015;Ahmad et al., 2021). In particular, formation study of efflorescence salt crust (ESC) in porous media (soils, sands) has been the subject of several studies (Fisher, 1928;Pearce et al., 1949;Gowing et al., 2006). ...
... For such a problem, the extraction of detailed information at the pore scale is challenging even with the most advanced imaging techniques. Pore-scale investigation is essential since it not only helps to elucidate the underlying mechanisms of behaviour at the macroscale, but also provides guidelines for constructing macroscopic models using various upscaling techniques, such as the homogenization technique (Whitaker 1977), the volume averaging method (Ahmad et al. 2020) and thermodynamically constrained averaging theory (Jackson, Miller & Gray 2009). Besides, statistical information from pore-scale data can be used to validate the upscaled models (Lasseux & Valdés-Parada 2022). ...
... This compression causes a poorer water evacuation in those areas and consequently a loss of reactivity and efficiency of the MEA and the fuel cell. This has been shown using modelling and experimental studies at the microscale [33][34][35][36][37] . However, the large FoV of the neutron CT provides a comprehensive overview of the water management of the whole MEA area where previous X-ray studies had limited oversight, focusing only on one or two rib/channel interfaces. ...
... It has a clear physical concept, which assumes that the characteristic length of the periodic unit cell is fixed, while the macroscopic characteristic length approaches infinity. 9 Using the method of volume averaging, Lasseux and Vald es-Parada established upscaled equations with effective transport coefficients for a wide range of subsurface flows including inertial single-phase flow, 16 creeping flow in the slip regime, 17 gas slip flow in a fracture, 18 and single-phase flow in the matrix and pore space. 19 Wood 20 employed the method of volume averaging to obtain coarse-grained models for complex subsurface hydrologic systems whose degrees of freedom are further reduced by introducing several scaling laws. ...
... [18][19][20] Grounded in the concept of microfluidics, the microscale fluid behavior can be experimentally observed in a transparent artificial porous model (microfluidic device). [21][22][23][24][25][26] Recent advances in micro-fabrication techniques enable such studies, by accurately mimicking the porous microstructures in a microfluidic device. [27][28][29][30][31] Conventional photolithography approaches are usually applied to fabricate porous microfluidic devices. ...
... Finally, it should be noted that the situation in a fuel cell can be more complicated than considered in this paper owing to the coupling with the electrical transport, at least in the wet case. As discussed in (Belgacem et al. 2018), the current density over the GDL-CL interface can vary spatially. According to (Belgacem et al. 2018), this leads to a lower local current below the rib in the condensation regime compared to the region below the channel. ...