Lin Qiao’s research while affiliated with Dalian Maritime University and other places

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Publications (65)


Multi-dimensional Bi@C electrocatalyst for Cr3+/Cr2+ redox reaction boosting high-performance iron-chromium flow batteries
  • Article

January 2025

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8 Reads

Science China-Chemistry

Min Wu

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Mingjun Nan

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Shumin Liu

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[...]

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Xiangkun Ma

With the increasing demand for energy storage technology, iron-chromium flow batteries (ICFBs) have been widely concerned because of their price advantage. However, the low electrochemical activity of Cr3+/Cr2+ redox couples and the side hydrogen evolution reaction limit the industrial application of ICFBs. A multi-dimensional Bi/carbon composite electrocatalyst (Bi@C) for ICFB is designed and prepared to improve the electrochemical activity of Cr3+/Cr2+ redox couples. Benefiting by using the Bimetal organic framework (Bi-MOF) with solid matrix as precursors, Bi nanospheres are highly dispersed on the Bi@C electrocatalyst that effectively enhances the electrochemical activity. The special morphology of Bi@C electrocatalyst helps the transfer of electrons and ions, significantly reducing the polarization of battery. Herein, the 3D porous carbon frames accelerate mass transfer, and the 2D carbon nanobelts and carbon layer coating on 0D Bi nanospheres improve the conductivity of Bi nanospheres. Therefore, the ICFB with multi-dimensional Bi@C electrocatalyst exhibits coulombic efficiency of 98.10% and energy efficiency of 79.14% at 140 mA cm−2, which is higher than ICFBs with commercial graphite carbon electrocatalyst and with heat treatment carbon felt. This work provides a simple and economical method to fabricate a high-performance multidimensional Bi@C electrocatalyst for Cr3+/Cr2+ redox couples, boosting the development of ICFBs.








Screening for high-risk emerging contaminants in the atmosphere: Recent advances and new challenges大气中高风险新污染物的筛查进展及展望
  • Article
  • Full-text available

February 2024

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239 Reads

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1 Citation

Chinese Science Bulletin (Chinese Version)

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Concentrations, Profiles, and Health Risks of Organic Ultraviolet Filters in Eight Food Categories Determined through the Sixth Chinese Total Diet Study

August 2023

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63 Reads

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7 Citations

Environmental Science and Technology

Ultraviolet (UV) filters are emerging contaminants that have been found in high concentrations in human tissues. Food intake is generally considered to be the primary route of human exposure to contaminants. In this study, 184 composite food samples, prepared from 4268 individual samples in eight categories collected from 23 Chinese provinces for the sixth Chinese total diet study, were analyzed. The total and median UV filter concentrations in food samples were 1.5-68.3 and 7.9 ng/g wet weight, respectively. The highest median concentrations were found in decreasing order in meat, cereals, and legumes. In total, 15 UV filters were analyzed. 2-Ethylhexyl salicylate, homosalate, and 2-ethylhexyl-4-methoxycinnamate were dominant and made median contributions of 34.1%, 22.6%, and 14.5%, respectively, and 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol contributed the median of 0.03%, of the total UV filter concentrations. The estimated total daily UV filter intake in animal-origin foods and total UV filter concentration in human milk from the same province were significantly correlated (r = 0.44, p < 0.05). Predicted absorption, distribution, metabolism, and elimination properties led to 10 UV filters being prioritized as most likely to be retained in human tissues. The prioritization results and toxicity assessments indicated that octocrylene and 2-ethylhexyl-4-methoxycinnamate have stronger effects in vivo and therefore require more attention than others.


Non-target and target analysis to identify and characterize thiophenes in soil from an abandoned coking plant

August 2023

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24 Reads

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7 Citations

Journal of Hazardous Materials

There is concern about the large amounts of aromatic compounds emitted during coking. Previous studies of coking emissions have been focused on polycyclic aromatic hydrocarbons, dioxin-like compounds, phenols, and volatile organic compounds, but previously unidentified compounds produced during coking may also harm human health. Here, the main pollutants in 69 soil samples from an abandoned coking plant were identified by non-target screening using two-dimensional gas chromatography time-of-flight mass spectrometry. Polycyclic aromatic hydrocarbons, long-chain alkanes, and thiophenes were dominant. High concentrations of thiophenes (benzothiophenes, dibenzothiophenes, and benzonaphtholthiophenes) were found. Quantitative analysis of 12 thiophenes (selected because of their concentrations and detection frequencies) was performed, and the concentrations were 0.03-647 μg/g dry weight, which were extremely high compared with concentrations in soil from uncontaminated sites and other industrial sites. Dibenzothiophene and benzo[b]naphtho[2,1-d]thiophene were dominant, accounting for 69% of the total thiophene concentration. Thiophene profiles in very contaminated areas were different from the profile in coal but similar to the profile in tar. Thiophenes in soil at the coking plant may have been supplied in tar leaks, wastewater, coke oven gases, and exhaust gases. A toxicity assessment indicated a strong likelihood of oxidative stress being induced by exposure to multiple thiophenes at the coking plant. The results suggest that thiophene emissions from coking plants should attract more attention than currently.


Citations (52)


... Presently, ICRFBs have garnered considerable attention owing to their notable advantages. Unlike the highly toxic bromine and V 5+ , the environmentally friendly redox-active species of iron and chromium are employed in ICRFBs [23]. Moreover, the redox-active species for ICRFBs can be readily obtained by dissolving chromium and iron chloride in hydrochloric acid, contributing to their cost-effectiveness, estimated to be as low as $12/kWh [24]. ...

Reference:

Recent Advances and Future Perspectives of Membranes in Iron-Based Aqueous Redox Flow Batteries
A highly active electrolyte for high-capacity iron‑chromium flow batteries
  • Citing Article
  • March 2024

Applied Energy

... 32 Previous studies have confirmed that certain congeners, such as UV-P, UV-327, and UV-328, can be metabolized by human cytochrome P450 enzymes. 36 Notably, CYP3A4 has been reported to be responsible for the metabolism of UV-328, demonstrating its role in the metabolic activation of this compound. 37 To explore this possibility, we employed ADMETlab 2.0 38 to assess the likelihood of UVs acting as substrates and inhibitors for these enzymes. ...

Concentrations, Profiles, and Health Risks of Organic Ultraviolet Filters in Eight Food Categories Determined through the Sixth Chinese Total Diet Study
  • Citing Article
  • August 2023

Environmental Science and Technology

... Air cooling, the earliest developed and simplest thermal management method, remains the most mature [22]; however, for large marine batteries, the cooling effect cannot be achieved. Especially in the liquid flow cooling technology, as an efficient thermal management method, its position in the simulation research on the thermal management of power battery packs is increasingly prominent [23,24]. The main advantages of using liquid as a heat transfer medium are high heat transfer capacity and fast cooling and heating. ...

Hydrogen-bond-rich composite membrane with improved conductivity and selectivity for flow battery
  • Citing Article
  • April 2023

Journal of Power Sources

... The wide presence of chlorinated paraffins in children's toys and other products that children come in contact with regularly is particularly troubling given that these chemicals are known to leach out of products (Dong et al. 2020, Wong et al. 2017, Lucattini et al. 2018, Weng et al. 2023. This means that children playing with plastic toys may be exposed to increased levels of chlorinated paraffins due to accumulations of the leached chemicals in dust, leaching upon skin contact (dermal uptake), hand-to-mouth behaviors, and through chewing on the toys (oral exposure). ...

Health Risks Posed by Dermal and Inhalation Exposure to High Concentrations of Chlorinated Paraffins Found in Soft Poly(vinyl chloride) Curtains
  • Citing Article
  • March 2023

Environmental Science and Technology

... The redox reactions involving Mn 3+ /Mn 2+ typically occur in highly acidic environments (pH < 1), exhibiting a high potential (1.51 V vs SHE) and high solubility, which are advantageous for the development of MFBs with elevated energy density. Nevertheless, Mn 3+ is susceptible to instability in aqueous solutions, leading to spontaneous disproportionation reactions that yield Mn 2+ and MnO 2 , ultimately resulting in diminished low coulombic efficiency (CE) of the battery [27]. Concurrently, the presence of residual non-conductive MnO 2 leads to passivation of the electrode surface, obstruction of flow paths, elevation of battery polarization, and deterioration of capacity. ...

Manganese-based Flow Battery Based on the MnCl2 Electrolyte for Energy Storage
  • Citing Article
  • March 2023

Chemical Engineering Journal

... The diversity of pesticides used in agriculture has naturally resulted in a multitude of TPs, as each PPP may degrade into several distinct TPs. Despite recent regulatory efforts to restrict certain PPPs, advancements in analytical techniques have enabled the reliable detection of various TPs in environmental matrices (Martínez Vidal et al. 2009;Dufour et al. 2021;Huang et al. 2023), revealing a wide variety of TPs in the environment (Le Ulrich et al. 2022). By undergoing multiple transformation processes, PPPs degrade into more polar substances, resulting in increased mobility and persistence in the environment, as observed with TPs from atrazine (Belfroid et al. 1998;Fenner et al. 2013). ...

Target and non-target analysis of organochlorine pesticides and their transformation products in an agrochemical-contaminated area
  • Citing Article
  • March 2023

Chemosphere

... In a separate investigation, the utilization of Fe 3+ /Fe 2+ as a redox mediator is implemented in the catholyte of a Ti-Mn flow battery in order to enhance the efficiency of the MnO 2 /Mn 2+ pair with a 1MnSO 4 -1.5TiOSO 4 -3H 2 SO 4 electrolyte ( figure 5(d)) [61]. The reduction peak potential of Fe 3+ /Fe 2+ is found to be lower than that of MnO 2 /Mn 2+ and higher than the oxidation peak potential of TiO 2+ /Ti 3+ . ...

Boosting the Areal Capacity of Titanium‐Manganese Single Flow Battery by Fe/Fe Redox Mediator

... UV filters can also be used in various types of cosmetics, personal care products, and even in industrial products, including food packaging, containers, and printing inks, which require UV protection (Bradley et al., 2013;de Miranda et al., 2021;Molins-Delgado et al., 2017). UV filters were therefore detected in various human matrices, including urine (Bury et al., 2023), serum (Frederiksen et al., 2021), cord blood (Sunyer-Caldú et al., 2023), placental tissue (Valle-Sistac et al., 2016), and breast milk (Liu et al., 2022). Indeed, following the dermal application of sunscreens, a randomized clinical trial study demonstrated that the active ingredients of commercial sunscreens, i.e., butyl methoxydibenzoylmethane (BMDBM), benzophenone-3 (BP3), 2-ethylhexyl salicylate (EHS), and EHMC, homosalate (HS), octocrylene (OCT), terephthalyidene dicamphor sulfonic acid (TDSA), could be absorbed into systemic circulation and remained at levels that warrant caution for several days even after the cessation of the application (Matta et al., 2019;U.S. FDA, 2016). ...

Concentrations, Compound Profiles, and Possible Sources of Organic UV Filters in Human Milk in China
  • Citing Article
  • October 2022

Environmental Science and Technology

... Except for the four hydrocarbons C 7 H 14 , C 9 H 14 , C 9 H 16 , and C 11 H 12 , all of these IVOCs have been reported to degas from asphalt pavements at 60°C . So far, only C 14 H 18 has been reported as a fresh gas-phase emission (transport time < 2.5 min), originating from a farm (Loubet et al., 2022) in ambient air, while C 17 H 28 has been observed in the aerosol phase (Xu et al., 2022). The road construction factor also accounts for the largest percentage share of a long list of OVOCs: C6 diketone isomers (C 6 H 10 O 2 ); C 2 -substituted phenol (C 8 H 10 O); C 7 H 12 O 2 ; C 8 H 14 O 2 ; C 8 H 16 O 2 ; phthalic anhydride (C 8 H 4 O 3 ), which is a naphthalene oxidation product (Bruns et al., 2017); C 9 H 10 O; , indicating that most OVOCs in this factor are possibly oxidation products of short-lived IVOC hydrocarbons emitted by this source. ...

Molecular characteristics, sources and environmental risk of aromatic compounds in particulate matter during COVID-2019: Nontarget screening by ultra-high resolution mass spectrometry and comprehensive two-dimensional gas chromatography
  • Citing Article
  • July 2022

Environment International

... In order to adapt to the harsh operating parameters of ICRFB and lower the cost of Nafion membranes, Ma et al. selected lowcost commercial porous polyethylene film as the skeleton, and filled the pores with Nafion resins to obtain the composite membranes with high thermal, chemical, and mechanical stability (Qiao et al. 2022b). The composite membranes showed high ion selectivity, chemical stability, proton conductivity, and nearly no swelling when operated at elevated operating temperature. ...

A Composite Membrane with High Stability and Low Cost Specifically for Iron–Chromium Flow Battery

Polymers