Kevin Bodenschatz's scientific contributions
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Publications (2)
2,2-Dimethyl-5-(triphenylphosphoranyliden)acetyl-1,3-dioxan-4,6-dion ist ein neues aktiviertes β-Ketoacyl Äquivalent, welches in quantitativen Ausbeuten durch die Reaktion von Meldrumsäure und dem stabilen Ylid Ph3PCCO synthetisiert werden kann. Die Reaktion mit α-Aminoester erzeugt entsprechende N-(β-ketoacyl)aminoesterylid, welche mit verschieden...
A flexible synthetic route to the 16-membered tetramate-embedding macrocyclic scaffold present in various polycyclic tetramate macrolactams (PTMs) was developed which differs from the seminal synthesis of ikarugamycin by Boeckman Jr. in protecting groups and the order of connections. We also devised a short approach to various stereoisomers of the...
Citations
... Synthesis of Boc-Orn(Cbz)-OMe (5a) [12]. CH 3 I (500 μL, 8 mmol) was added dropwise to a suspension of Boc-Orn(Cbz)-OH (1.84 g, 5 mmol) and K 2 CO 3 (1.43 g, 10 mmol) in DMF (10 mL) at 0˚C, and the mixture was stirred at 0˚C for 30 min, then room temperature for overnight. ...
![[object Object]](https://i1.rgstatic.net/ii/profile.image/279536144011273-1443658018349_Q64/Rainer-Schobert.jpg)
