K. S. Novoselov’s research while affiliated with National University of Singapore and other places

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Publications (435)


Inverse Design of Broadband Antennas for Terahertz Devices Based on 2D Materials
  • Preprint

May 2025

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6 Reads

M. Lukianov

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A. Maevskiy

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N. Kazeev

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[...]

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D. A. Bandurin

Terahertz (THz) technology, a cornerstone of next-generation high-speed communication and sensing, has long been hindered by impedance mismatch challenges that limit device performance and applicability. These challenges become particularly pronounced when ultrasensitive two-dimensional (2D) materials are employed as the device substrate in the THz range, further complicating their integration into real-world applications. Furthermore, conventional antenna designs often fail to provide adequate matching across the extensive THz spectrum. In this work, we tackle these challenges using a procedural generation algorithm to design THz broadband antennas that satisfy specific performance criteria. Namely, the developed inverse design methodology enables customization for the target impedance value, bandwidth, and contact topology requirements. The proposed antenna achieves an improvement of up to 40\% in power transfer efficiency compared to traditional bow-tie antennas under realistic operating conditions. High-fidelity electromagnetic simulations validate these results, confirming the design's practicality for THz applications. This work addresses critical limitations of existing antenna designs and advances the feasibility of high-frequency applications in both communication and sensing.


Schematic of the device architecture: (a) artistic representation of the device architecture proposed to access the few-electron regime in TMDC. The schematic exhibits an encapsulated 2D TMDC between two layers of boron nitride. Two layers of gates overlapping in two different fabrication layers separated by an encapsulated stack of hBN/2D TMDC/hBN. Bottom split gates confine the two-dimensional electron gas into a one-dimensional electron gas. Top fine gates further confine the one-dimensional electron gas into zero-dimension electron gas (QD). Source and drain electrodes form Ohmic contact, enabling to measure current through the device. (b) Schematic of the proposed device cross-section shown in panel (a). (c) Top view of the proposed device architecture with accumulated two-dimensional electron gas. Split gate and the top fine gates can be used to tune the quantum dot and barriers in the device to achieve a QD size comparable to the fine gate dimensions.
Potential landscape seen at the TMDC layer. (a) Potential profile at the TMDC level before applying potential to fine gates (only split gates active with Vsg=500 mV) – negative voltage on split gates confine 2DEG into a 1DEG. Split gate contours are denoted by solid black lines. (b) Potential profile at the TMDC level after applying voltages to fine gates ( Vfg=±300 mV) – elongated QD emerges at the center of the device. Fine gate contours are denoted by solid black lines. Dashed lines denote cross-cuts presented in (c): (top) potential line cuts along x-axis for variable Vfg values ( Vsg=500 mV) showing high confinement tunability, and (bottom) along y-axis with variable Vsg ( Vfg=±300 mV). Results for the assumed split gate gap of 50 nm; and dielectric thickness of 20 nm.
(a)–(d) Electron density for the ground and first few excited states with different orbital configuration. Energy splitting between ground state and first excited state (denoted in (g)) with different orbital configuration for variable dielectric thickness (e), and variable split gates gap (f). Spin–valley qubit subspace is separated from the excited states by the spitting energy as explained in (g). Additionally, QD charging energies were estimated (h), (i) for the same device parameter variations (dielectric thickness and split gate gap) as in (e), (f). Assumed voltages (all in mV) are: VL=300, VC=−300, VR=300 (fine gates), Vsg=500 (split gates), and backgate Vback=−2000.
(a) Schematic of a van der Waals heterostructure using single layer MoS2 encapsulated between hBN flakes. (b) Id–V for varying backgate voltage Vbg=0–20 V at T = 160 mK in a single layer MoS2 contacted by FLG. The device exhibits linear Id–V traces, a characteristic of Ohmic contact. Two-point resistance of ∼ 1.4 kΩ at deep cryogenic temperature ensuring a transparent MoS2 and FLG interface. (c) Id– Vtg trace for a device shown in panel (a). Inset shows a TEM cross-section image of the heterostructure exhibiting thickness of different device layers. (d) Left: scanning electron microscope image split gates with a gap of 30 nm between them. Right: scanning electron microscope image of set of fine gates with a pitch of 60 nm and gate length of 30 nm.
Single electron quantum dot in two-dimensional transition metal dichalcogenides
  • Article
  • Full-text available

April 2025

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34 Reads

Spin–valley properties in two-dimensional (2D) semiconducting transition metal dichalcogenides (TMDCs) has attracted significant interest due to the possible applications in quantum computing. Spin–valley properties can be exploited in TMDC quantum dot (QD) with well-resolved energy levels. This requires smaller QDs, especially in material systems with heavy carrier effective mass e.g. TMDCs and silicon. Device architectures employed for TMDC QDs so far have difficulty achieving smaller QDs. Therefore, an alternative approach in the device architecture is needed. Here, we propose a multilayer device architecture to achieve a gate-defined QD in TMDC with a relatively large energy splitting on the QD. We provide a range of device dimensions and dielectric thicknesses and its correlation with the QD energy splitting. The device architecture is modeled realistically. Moreover, we show that all the device parameters used in modeling are experimentally achievable. These studies lay the foundation for future work toward spin–valley qubits in TMDCs. The successful implementation of these device architectures will drive the technological development of 2D materials-based quantum technologies.

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Figure 1. Device geometry and transport data. (a) Top: An optical image shows the device D8 with the edges of each flake highlighted by the dashed lines. Bottom: Schematic of the device structure. A trilayer CGT (3L CGT) is sandwiched between aligned monolayer graphene layers, encapsulated between two hexagonal boron nitride (hBN) layers, with graphite top gate and bottom gates. (b) The longitudinal resistance í µí¼Œ í µí±¥í µí±¥ as a function of the back gate and top gate voltage for device D10. The black dots indicate the presence of the anomalous Hall effect (AHE) and topological Hall effect (THE). (c) Scheme of skyrmion-based THE. The noncoplanar spins residing on the curved chiral domain walls possess topological charges that manifest as effective magnetic fields Beff in the real spatial domain. An electron traversing such a skyrmion will encounter Beff and undergo deflection due to an emergent Lorentz force, exhibiting as THE. (d) Schematic of coexistence of different AHE and THE in both top and bottom graphene layer. (e) Total AHE and THE were calculated under our device measurement condition in scenario (D). (f) Total AHE and THE measured for a magnetic field perpendicular to the plane of the structure, at Vbg = 3 V and Vtg = 3.6 V, for device D8. The red and blue curves represent the forward and backward sweeps, respectively.
Figure 2. Gate dependence of the AHE and THE. (a) Calculated band structures of AB stacked Gr/CGT/Gr. (b) Schematic illustration of spin-flip transitions. As the magnetic field increases, CGT layers undergo a phase transition process from spin-down, through stripe domains, to the formation of skyrmions, and finally to spin-up states 5 . The top and bottom graphene layers with different carrier concentrations experience similar phase
Figure 3. Micromagnetic simulations of formation and stability of skyrmions in CGT flake. The spin texture of CGT under various magnetic field conditions is depicted from ① to ⑧. The blue and red lines represent backward and forward sweeps in the magnetic field, respectively. Blue circles denote Bloch skyrmions, while yellow circles represent antiskyrmions.
Figure 4. Magnetic field dependence of the Hall and longitudinal resistance at various temperatures. Temperature dependence of (a) í µí¼Œ í µí±¥í µí±¦ extracted from í µí¼Œ í µí±‚í µí°»í µí°¸andµí°¸and (b) í µí¼Œ í µí±¥í µí±¥ measured at Vbg = 2.8 V, Vtg = 3.6 V. The solid and dashed lines represent backward and forward sweeps in the magnetic field, respectively. Curves are offset by 0.1 kΩ for clarity. (c-e) Comparison of í µí¼Œ í µí±¥í µí±¦ at zero magnetic field (blue squares) and the maximum of the difference between backward and forward sweeps of the longitudinal resistance, Δí µí¼Œ í µí±¥í µí±¥ (red circles) at various temperatures at (c) Vbg = 2.8 V, Vtg = 3.6 V, (d) Vbg = 3.5 V, Vtg = 3.6 V and (e) Vbg = 4.6 V, Vtg = 3.6 V for D8. í µí±‡ í µí± 1
Anomalous Meets Topological Hall Effect in Cr2Ge2Te6 Heterostructures

March 2025

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52 Reads

Introducing topologically protected skyrmions in graphene holds significant importance for developing high-speed, low-energy spintronic devices. Here, we present a centrosymmetric ferromagnetic graphene/trilayer Cr2Ge2Te6/graphene heterostructure, demonstrating the anomalous and topological Hall effect due to the magnetic proximity effect. Through gate voltage control, we effectively tune the emergence and size of skyrmions. Micromagnetic simulations reveal the formation of skyrmions and antiskyrmions, which respond differently to external magnetic fields, leading to oscillations in the topological Hall signal. Our findings provide a novel pathway for the formation and manipulation of skyrmions in centrosymmetric two-dimensional magnetic systems, offering significant insights for developing topological spintronics.


Non-Reciprocal Current-Phase Relation and Superconducting Diode Effect in Topological-Insulator-Based Josephson Junctions

February 2025

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32 Reads

Josephson junctions (JJ) are essential for superconducting quantum technologies and searches of self-conjugate quasiparticles, pivotal for fault-tolerant quantum computing. Measuring the current-phase relation (CPR) in JJ based on topological insulators (TI) can provide critical insights into unconventional phenomena in these systems, such as the presence of Majorana bound states (MBS) and the nature of non-reciprocal transport. However, reconstructing CPR as a function of magnetic field in such JJs has remained experimentally challenging. Here, we introduce a platform for precise CPR measurements in planar JJs composed of NbSe2_2 and few layer thick Bi2_2Se3_3 (TI) as a function of magnetic field. When a single flux quantum Φ0\Phi_\mathrm{0} threads the junction, we observe anomalous peak-dip-shaped CPR behaviour and non-reciprocal supercurrent flow. We demonstrate that these anomalies stem from the edge-amplified sloped supercurrent profile rather than MBS signatures often invoked to explain puzzles emerging near Φ0\Phi_\mathrm{0} in TI-based JJ. Furthermore, we show that such a supercurrent profile gives rise to a previously overlooked, robust and tunable Josephson diode effect. These findings establish field-dependent CPR measurements as a critical tool for exploring topological superconducting devices and offer new design principles for non-reciprocal superconducting electronics.



Fig. 2. (Color online) Mutual arrangement of dispersion paraboloids of two bilayer graphene sheets (a) in the region forbidden for tunneling and (b) in the region for tunneling with the conservation of energy and lateral momentum. (c) Calculated map of tunneling thresholds obtained in a simplified electrostatic tunneling model disregarding the nonparabolicity of the low-energy bilayer graphene bands.
Fig. 4. (Color online) (a) Section of the map from Fig. 3 along (blue line) cm -2 and (dashed line) the diagonal. (b) Mutual arrangement of bands and (c) the scheme of layers of the structure during tunneling involving the van Hove singularity localized far from the hBN barrier in the top bilayer graphene sheet (localization is shown in dark red). (d) Mutual arrangement of bands and (e) the scheme of layers of the structure during tunneling involving the van Hove singularity localized near the hBN barrier in the top bilayer graphene sheet (is shown in dark blue).
Manifestation of Layer-by-Layer Localization of van Hove Singularities in Tunneling between Bilayer Graphene Sheets

January 2025

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32 Reads

JETP Letters

Tunneling between two sheets of bilayer graphene, the crystal lattices of which are rotated relative to each other by a small angle, has been studied. An anomalous behavior of the tunneling conductivity caused by van Hove singularities at the edges of the conduction and valence bands spatially localized in different sheets of bilayer graphene has been found.


Proyavlenie posloevoy lokalizatsii singulyarnostey van Khova v tunnelirovanii mezhdu listami dvukhsloynogo grafena

December 2024

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8 Reads

Письма в Журнал экспериментальной и теоретической физики

Исследовано туннелирование между двумя листами двухслойного графена, кристаллические решетки которых повернуты относительно друг друга на небольшой угол. Обнаружено аномальное поведение туннельной проводимости, обусловленное проявлением сингулярностей ван Хова на краях зоны проводимости и валентной зоны, пространственно локализованных в различных монослоях двухслойного графена.


Bilayer MoS2 nanoribbons: observation of an optically inactive “exciton-free” layer and electrical gating of optical response

October 2024

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19 Reads

Photonics Research

Due to large anisotropy and tunable exciton transitions observed in visible light, transition metal dichalcogenides could become platform materials for on-chip next-generation photonics and nano-optics. For this to happen, one needs to be able to nanostructure transition metal dichalcogenides without losing their optical properties. However, both our understanding of the physics of such nanostructures and their technology are still at infancy and, therefore, experimental works on optics of transition metal dichalcogenides nanostructures are urgently required. Here, we study optical characteristics of bilayer MoS 2 nanoribbons by measuring reflection and photoluminescence of nanostructured bilayer MoS 2 flakes near exciton transitions. We show that there exist optically inactive “exciton-free” regions near the edges of nanoribbons with sizes of around 10 nm. We demonstrate that the “exciton-free” regions can be controlled by external electrical gating. These results are important for nanostructured optoelectronic devices made of MoS 2 and other transition metal dichalcogenides.


Superballistic electron flow
a, Schematic illustration of the device architecture: graphene PC is coupled to a broadband bow-tie antenna exposed to THz radiation. Absorbed radiation causes the increase of Te while leaving the lattice T intact. At the centre of the device, Te is higher than at the sample boundaries where it is thermalized with the bath. b, Electron temperature, Te, mapped onto the streamlines of electrical current flowing through the PC exposed to THz radiation. c, Schematic illustrating THz-induced heating of electrons in doped graphene. d, Photograph of one of our PC devices. W stands for the width of PC constriction. Additional contacts were patterned in a Hall bar geometry with respect to a. e, Conductance as a function of T for the PC and the Hall bar measured in the dark at given n. The non-monotonic T dependence found for the PC signals e–e dominated superballistic conduction of hydrodynamic electrons.
THz-driven hydrodynamics and negative photoresistance
a, PC conductance as a function of carrier density, n, measured in the dark and upon CW exposure with 0.14 THz radiation. The data were obtained for two PCs of a given width. T = 2 K. b, Rpc as a function of T in the dark (THz off) and upon exposing the device with 0.14 THz radiation (THz on). The yellow region between THz on and THz off regions represents the negative photoresistance ΔRpc. Solid orange line: 1/Gpc as a function of T, calculated for the PC of W = 0.45 μm in the dark using equation (2). This curve shows that to reach the THz-driven level of the PC resistance (black horizontal line), the electron temperature should be raised by at least 30 K. Inset: schematical illustration of the ballistic non-interacting transport (upper inset) and superballistic collective electron motion (lower inset) activated upon THz absorption for the case of T = 2 K. n = −0.35 × 10¹² cm⁻². c, ΔRpc as a function of temperature T for given carrier densities n measured using the double-modulation technique (Methods). Inset: ΔRpc as a function of carrier density n for different T.
Power dependence and superballistic electron thermometry
a, Examples of the ΔRpc versus P0 dependencies measured at given n for the W = 0.31 μm PC. The top and right axes reflect the bolometric voltage ΔV = IΔRpc versus Pabs (recalculated for n = 2.5 × 10¹² cm⁻²) at I = 500 nA bias current. b, Symbols: electron temperature Te as a function of Pabs for n = 2.5 × 10¹² cm⁻² obtained for the W = 0.31 μm PC. Dashed line: best fit to equation (3). Fitting parameters: δ = 4.4 and Σ = 2.1 mW K−δ m⁻². Red (blue) solid line: average (maximum) Te as a function of Pabs obtained from the solution of the heat equation for δ = 4.3 and Σ = 2.2 mW K−δ m⁻² (see Supplementary Information for details). T = 2 K. Inset: Te at small Pabs. Dark red and black dashed lines: Pabs = Gth(Te − T) dependencies with Gth = 0.2 and 0.4 nW K⁻¹, respectively. c, Symbols: same as in b but on a log–log scale. Dashed line: same as in b. d, Cooling exponent δ as a function of n for the 0.45 μm (blue squares) and 0.31 μm (yellow squares) PC devices, obtained from the fits such as in c. The values are close to δ = 4 (dashed line), indicating the dominance of the phonon cooling. Data are presented as best fit value ± standard deviation. e, Calculated Te versus x-coordinate for the 0.31 μm PCs at n = 2.5 × 10¹² cm⁻². The pink shaded area indicates the region of the PC. f, Symbols: Te versus T at different Pabs for the 0.31 μm PC at n = 2.5 × 10¹² cm⁻². Dashed line Te = T depicts the equilibrium between electron and phonon sub-systems when the sample is in the dark. Solid lines: Te versus T for different P obtained from equation (3) with δ and Σ given in b. Pabs = 50 μW was not achieved in the experiment; therefore, only theoretical prediction is presented.
Viscous terahertz photoconductivity of hydrodynamic electrons in graphene

October 2024

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249 Reads

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10 Citations

Nature Nanotechnology

Light incident upon materials can induce changes in their electrical conductivity, a phenomenon referred to as photoresistance. In semiconductors, the photoresistance is negative, as light-induced promotion of electrons across the bandgap enhances the number of charge carriers participating in transport. In superconductors and normal metals, the photoresistance is positive because of the destruction of the superconducting state and enhanced momentum-relaxing scattering, respectively. Here we report a qualitative deviation from the standard behaviour in doped metallic graphene. We show that Dirac electrons exposed to continuous-wave terahertz (THz) radiation can be thermally decoupled from the lattice, which activates hydrodynamic electron transport. In this regime, the resistance of graphene constrictions experiences a decrease caused by the THz-driven superballistic flow of correlated electrons. We analyse the dependencies of the negative photoresistance on the carrier density, and the radiation power, and show that our superballistic devices operate as sensitive phonon-cooled bolometers and can thus offer, in principle, a picosecond-scale response time. Beyond their fundamental implications, our findings underscore the practicality of electron hydrodynamics in designing ultra-fast THz sensors and electron thermometers.


Fig. 1 The architecture of the vertical tunneling devices with hBN:C as an energy barrier. The optical images of the hBN (a) and hBN:C bulk crystals (b). Schematic representation of the light emitting diode structures with the layer sequence Gr/hBN:C/Gr (c) and Gr/hBN/hBN:C/hBN/Gr (d). The devices were created by stacking mechanically exfoliated graphene, hBN, and hBN:C layers. The optical images of example devices with Gr/ hBN:C/Gr and Gr/hBN/hBN:C/hBN/Gr architectures are presented in (e) and (f), respectively. The thickness of hBN:C was ~20 nm, while the hBN barriers were ~3-5 nm thick. The scale bar corresponds to 10 μm
Fig. 3 Electroluminescence from Gr/hBN/hBN:C/hBN/Gr devices. Tunneling IV curves (a) and the integrated EL intensity dependence on the tunneling bias (b) demonstrate the increase of the tunneling and electroluminescence voltage threshold induced by additional pristine hBN barriers. Schematic depiction of the charge tunneling processes in the sup-band-gap voltage regime enabling non-radiative Gr-Gr tunneling (including tunneling mediated by electronic bands via Fowler-Nordheim mechanism), defect-to-band electroluminescence and intradefect electroluminescence (c). The evolution of the electroluminescence spectra with bias voltage under forward (d) and reverse (e) direction demonstrates that the electroluminescence spectra are dominated by intradefect optical transitions. All the measurements were done at T = 5 K
Electroluminescence from pure resonant states in hBN-based vertical tunneling junctions

July 2024

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73 Reads

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16 Citations

Light Science & Applications

Defect centers in wide-band-gap crystals have garnered interest for their potential in applications among optoelectronic and sensor technologies. However, defects embedded in highly insulating crystals, like diamond, silicon carbide, or aluminum oxide, have been notoriously difficult to excite electrically due to their large internal resistance. To address this challenge, we realized a new paradigm of exciting defects in vertical tunneling junctions based on carbon centers in hexagonal boron nitride (hBN). The rational design of the devices via van der Waals technology enabled us to raise and control optical processes related to defect-to-band and intradefect electroluminescence. The fundamental understanding of the tunneling events was based on the transfer of the electronic wave function amplitude between resonant defect states in hBN to the metallic state in graphene, which leads to dramatic changes in the characteristics of electrons due to different band structures of constituent materials. In our devices, the decay of electrons via tunneling pathways competed with radiative recombination, resulting in an unprecedented degree of tuneability of carrier dynamics due to the significant sensitivity of the characteristic tunneling times on the thickness and structure of the barrier. This enabled us to achieve a high-efficiency electrical excitation of intradefect transitions, exceeding by several orders of magnitude the efficiency of optical excitation in the sub-band-gap regime. This work represents a significant advancement towards a universal and scalable platform for electrically driven devices utilizing defect centers in wide-band-gap crystals with properties modulated via activation of different tunneling mechanisms at a level of device engineering.


Citations (46)


... Conventional RF antennas are typically designed for a 50 Ω impedance [13], while new generation of promissing THz detectors based on van der Waals materials [14,15] often exhibit much higher impedance values (see Figure 1a for schematic). For instance, detectors based on graphene [14,[16][17][18][19][20][21][22][23][24] or black phosphorus [25,26] can have impedance values exceeding several kΩ in monolayer graphene, while bilayer graphene devices, although featuring exceptional * Correspondence to: dab@nus.edu.sg THz responsivity [27,28], may reach 100-500 Ω. ...

Reference:

Inverse Design of Broadband Antennas for Terahertz Devices Based on 2D Materials
Viscous terahertz photoconductivity of hydrodynamic electrons in graphene

Nature Nanotechnology

... While colour centre emission is quenched within areas where hBN is deposited directly on graphene due to charge transfer 12,13 , it is maintained where hBN is deposited on the dielectric layer which acts as a barrier to charge transfer. Importantly, unlike previous work 11 , our approach to the localisation of hBN colour centre emission allows for device architectures where graphene layers are used as top and bottom electrodes for the application of vertical elec-tric fields 5,7,9,14,15 . Moreover, unlike previous works 5,7,9,14,15 , our ability to use ALD to grow dielectric layers directly on graphene allows for the control of tunnel barrier thicknesses with atomic layer precision, which is especially important for devices with applications in electroluminescence 5-7,9 and charge state control of colour centres 15 . ...

Electroluminescence from pure resonant states in hBN-based vertical tunneling junctions

Light Science & Applications

... Recently, the discovery of 2D layered MoSi 2 N 4 by chemical vapor deposition [35] has stimulated extensive studies on the MA 2 Z 4 family due to their diverse properties [36][37][38][39][40]. The MA 2 Z 4 monolayer consists of an MZ 2 layer sandwiched between two AZ layers, with transition metal atoms M forming a triangular lattice [36]. ...

A new family of septuple-layer 2D materials of MoSi2N4-like crystals
  • Citing Article
  • June 2024

Nature Reviews Physics

... However, the greater challenge is nding a material platform with high performance in several elds simultaneously, such as optoelectronics and photonics 4 . Indeed, optoelectronics requires metals [11][12][13] , which are undesired in photonics because of their high optical losses in the telecommunication range 14,15 . In contrast, photonics needs high-refractive-index materials with negligible losses, which traditionally include dielectrics 16-18 not suitable for electronics applications. ...

Graphene-inspired quasi-two-dimensional gold films

... In the last few years, van der Waals (vdW) heterostructures based on graphene and hexagonal boron nitride (hBN) layers with different stacking modes have attracted a great deal of interest because of their potential applications [45][46][47][48][49][50][51][52][53]. Graphene/hBN vdW heterostructures were studied very recently in Refs. ...

Coulomb Correlation Gap at Magnetic Tunneling between Graphene Layers

JETP Letters

... 19 Graphene has become an attractive material for electrodes due to its properties such as high conductivity, large surface area, and mechanical and chemical stability. 20 Since graphene paper (GP) is formed by layer-by-layer stacked graphene sheets, it shows the superior properties of graphene, such as flexibility, durability, and stability. 21 Besides, GPs can be cut, bent, folded, and shaped similar to commercial paper. ...

Stress transfer at the nanoscale on graphene ribbons of regular geometry

... Designing highly sensitive Waveguide Bragg Grating (WBG) biosensors Maxwell's equations for optical waveguide geometries must be solved computationally for lab-on-a-chip applications, which restricts scalability and quick optimization. 13,14 Key sensing factors including effective refractive index, sensitivity, quality factor, and reflectivity are difficult for current technologies to forecast accurately. These parameters are essential for optimizing biosensor performance. ...

Hexagonal boron nitride nanophotonics: a record-breaking material for the ultraviolet and visible spectral ranges
  • Citing Article
  • May 2023

Materials Horizons

... Intelligent or 'smart' materials, which respond dynamically to environmental stimuli, have gained considerable attention for their wide range of applications (Artemis, 2024;Beatriz, 2024;Hu, 2023;Yin, 2022). These materials are termed 'smart' when they provide a specific, reversible response to changes in their surroundings, altering their physical, mechanical, or electromagnetic properties (Costa, 2015). ...

pH-dependent water permeability switching and its memory in MoS2 membranes

Nature

... Indeed, the optical responses of CrX3 (X = Cl -, Br -, I -) compounds have historically been described using the ligand-field model, which thoroughly accounts for their multitude of absorption features as d-d and ligand-to-metal chargetransfer (LMCT) transitions centered at individual CrX6 3pseudo-octahedra. [15][16][17] Although recent reports have variously referred to the emissive excited states of CrX3 compounds as exciton polarons, [18][19][20] Frenkel excitons, [21][22][23] or self-trapped excitons (STEs), 24 all of these interpretations invoke strong localization. Computational studies have also suggested that CrI3 excitons localize at individual Cr 3+ ions. ...

Strongly Correlated Exciton-Magnetization System for Optical Spin Pumping in CrBr3 and CrI3

... Due to the different lattice constant between MoS 2 and WSe 2 , a moiré superlattice is created even well-aligned 19,33 . The superlattice potential induces not only electron localization but also exciton localization 34 , creating multiple moiré IX energy levels ( Fig. 1c) [35][36][37][38] . The interaction between the moiré IX and the moiré-induced quasiparticle lattice (i.e., either electron or exciton lattice) can affect the moiré IX PL emission [29][30][31][39][40][41] , such as the coherence (Fig. 1d, e). ...

Signature of Cascade Transitions between Interlayer Excitons in a Moiré Superlattice
  • Citing Article
  • December 2022

Physical Review Letters