Jian Hao’s research while affiliated with Okayama University and other places

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Publications (5)


ChemInform Abstract: A Trial Toward the Synthesis of γ-Fluorinated β-Amino-α-thiohydroxyamino Acid: A Finding of Desulfurizative CC Bond Formation in Thio-Wittig-Type Rearrangement of S-(N-Aryl-trifluoroacetimidoyl)thioglycolates
  • Article

July 2010

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60 Reads

ChemInform

Kenji Uneyama

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Hironari Ohkura

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Jian Hao

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Hideki Amii

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.



ChemInform Abstract: A Novel Intramolecular Defluorinative Cyclization Approach to the Synthesis of Difluoromethylated Quinazolic Acid Derivatives

January 2001

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3 Reads

ChemInform

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.


A Novel Intramolecular Defluorinative Cyclization Approach to the Synthesis of Difluoromethylated Quinazolic Acid Derivatives

October 2000

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7 Reads

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11 Citations

Chemical Communications

tert-Butyl 2-(difluoromethyl)-3-benzyl-6-methoxy-3,4-dihydro-4-quinazoline-4-carboxyl ic ester (4) and its related 6-substituted esters, precursors of a new type of cyclic amino acid, were synthesized via intramolecular defluorinative cyclization under basic conditions.


A Novel Synthesis of β-Trifluoromethyl-Substituted Isoserine via Intramolecular Rearrangement of Imino Ethers

June 1998

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4 Reads

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49 Citations

Tetrahedron Letters

The methodology for the construction of β-trifluoromethyl-substituted isoserine is reported. The fluorinated α-hydroxy-β-imino esters which are the precursors to amino acid derived isoserine were formed firstly via a base catalyzed intramolecular rearrangement of imino ethers, and the subsequent conversions of these compounds resultedin the formation of the designedisoerines and the related fluorinated compounds.

Citations (1)


... and radical 262 species (Figure 3). For example, the chloride 240a (X=Cl) can be used for M a n u s c r i p t nucleophilic substitution reactions with nucleophiles (Schemes 95-97) [112][113][114] or acid-catalyzed Friedel-Crafts reactions (Scheme 98) [115] to convert chlorine to other functional groups. M a n u s c r i p t 103) [121]. ...

Reference:

ChemInform Abstract: Trifluoroacetic Acid: Uses and Recent Applications in Organic Synthesis
A Novel Synthesis of β-Trifluoromethyl-Substituted Isoserine via Intramolecular Rearrangement of Imino Ethers
  • Citing Article
  • June 1998

Tetrahedron Letters