Jacques Arnaud’s research while affiliated with French National Centre for Scientific Research and other places

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Publications (30)


A New Perspective on Classical Ideal Gases
  • Article
  • Full-text available

September 2013

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116 Reads

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1 Citation

Entropy

Jacques Arnaud

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Fabrice Philippe

The ideal gas laws are derived from the democritian concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion aside from the law of energy conservation. A single corpuscle in contact with a heat bath and submitted to a z and t-invariant force w-w is considered, in which case corpuscle distinguishability is irrelevant. The non-relativistic approximation is made only in examples. Some of the end results are known but the method appears to be novel. The mathematics being elementary the present paper should facilitate the understanding of the ideal-gas law and more generally of classical thermodynamics. It supplements importantly a previously published paper: The stability of ideal gases is proven from the expressions obtained for the force exerted by the corpuscle on the two end pistons of a cylinder, and the internal energy. We evaluate the entropy increase that occurs when the wall separating two cylinders is removed and show that the entropy remains the same when the separation is restored. The entropy increment may be defined at the ratio of heat entering into the system and temperature when the number of corpuscles (0 or 1) is fixed. In general the entropy is defined as the average value of ln(p)\ln(p) where p denotes the probability of a given state. Generalization to z-dependent weights, or equivalently to arbitrary static potentials, is made.

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On Classical Ideal Gases

August 2011

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1,692 Reads

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4 Citations

Entropy

The ideal gas laws are derived from the democritian concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion aside from the law of energy conservation. A single corpuscle in contact with a heat bath and submitted to a z and t-invariant force w-w is considered, in which case corpuscle distinguishability is irrelevant. The non-relativistic approximation is made only in examples. Some of the end results are known but the method appears to be novel. The mathematics being elementary the present paper should facilitate the understanding of the ideal-gas law and more generally of classical thermodynamics. It supplements importantly a previously published paper: The stability of ideal gases is proven from the expressions obtained for the force exerted by the corpuscle on the two end pistons of a cylinder, and the internal energy. We evaluate the entropy increase that occurs when the wall separating two cylinders is removed and show that the entropy remains the same when the separation is restored. The entropy increment may be defined at the ratio of heat entering into the system and temperature when the number of corpuscles (0 or 1) is fixed. In general the entropy is defined as the average value of ln(p)\ln(p) where p denotes the probability of a given state. Generalization to z-dependent weights, or equivalently to arbitrary static potentials, is made.


On the ideal gas law

May 2011

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8,518 Reads

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2 Citations

The air density on earth decays as a function of altitude z approximately according to an exp(wz/θ)\exp(-w\,z/\theta)-law, where w denotes the weight of a nitrogen molecule and \theta=\kB T where kBk_B is a constant and T the thermodynamic temperature. To derive this law one usually invokes the Boltzmann factor, itself derived from statistical considerations. We show that this (barometric) law may be derived solely from the democritian concept of corpuscles moving in vacuum. We employ a principle of simplicity, namely that this law is \emph{independent} of the law of corpuscle motion. This view-point puts aside restrictive assumptions that are source of confusion. Similar observations apply to the ideal-gas law. In the absence of gravity, when a cylinder terminated by a piston, containing a single corpuscle and with height h has temperature θ\theta, the average force that the corpuscle exerts on the piston is: \ave{F}=\theta/h. This law is valid at any temperature, except at very low temperatures when quantum effects are significant and at very high temperatures because the corpuscle may then split into smaller parts. It is usually derived under the assumption that the temperature is proportional to the corpuscle kinetic energy, or else, from a form of the quantum theory. In contradistinction, we show that it follows solely from the postulate this it is independent of the law of corpuscle motion. On the physical side we employ only the concept of potential energy. A consistent picture is offered leading to the barometric law when whθw\,h\gg\theta, and to the usual ideal-gas law when whθw\,h\ll\theta. The mathematics is elementary. The present paper should accordingly facilitate the understanding of the physical meaning of the barometric and ideal-gas laws.


Democritus and the motive power of fire

April 2011

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32 Reads

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5 Citations

The present work is a translation from french to english of our previous \g{D\'emocrite et la puissance motrice du feu}, amended on a number of respects. It is mainly of historical and pedagogical interest. We suggest that the concepts introduced in the ancien Greece by Anaximander (flat earth) and Democritus (corpuscles moving in vacuum) allow us to obtain through qualitative observations and plausible generalizations the maximum efficiency and work of heat engines, results that were firmly established around 1824 by Carnot. A prologue introduces the subject. We next present the concept of thermal equilibrium and consider a model consisting of two reservoirs located at different altitudes, each with g sites. Each site may contain a specified number of corpuscles. One particular site plays the role of \g{working agent}. We subsequently consider an alternative model consisting of independent corpuscles submitted to gravity and in contact with heat baths. Only average quantities are considered, leaving out fluctuations and questions of stability.


Quiet Lasers

June 2009

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37 Reads

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1 Citation

We call "quiet laser" a stationary laser that generates in detectors regular photo-electrons (sub-Poisson statistics). It follows from the law of conservation of energy that this is so when the laser power supply does not fluctuate. Various configurations are analyzed on the basis of the Planck (1907) semi-classical concept: "I am not seeking the meaning of light quanta in the vacuum but rather in places where emission and absorption occur, and I assume that what happens in the vacuum is rigorously described by Maxwell's equations". Exact agreement with Quantum Optics results is noted. Comments welcome! Comment: 186 pages


Grand-mother clocks and quiet lasers

February 2009

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36 Reads

Galileo noted in the 16th century that the period of oscillation of a pendulum is almost independent of the amplitude. However, such a pendulum is damped by air friction. The latter may be viewed as resulting from air molecules getting in contact with the pendulum. It follows that air friction, not only damps the oscillation, but also introduces randomness. In the so-called ``grand-mother'' clock, discovered by Huygens in the 18th century, damping is compensated for, on the average, by an escapement mechanism driven by a falling weight. The purpose of this paper is to show that such a clock is, in its idealized form, a quiet oscillator. By ``quiet'' we mean that in spite of the randomness introduced by damping, the dissipated power (viewed as the oscillator output) does not fluctuate slowly. Comparison is made with quiet laser oscillators discovered theoretically in 1984. Because the input power does not fluctuate in both the mechanical oscillator and the quiet laser oscillator, the output power does not fluctuate at small Fourier frequencies, irrespectively of the detailed mechanisms involved.


FIG. 1: Schematic representation of an engine that converts potential energy into work. The figure represents two lotterylike reservoirs located at altitudes, E l and E h ≥ E l , respectively, with N possible ball locations labeled 1,2,3...N (N = 5 in the figure). The number of weight-1 balls (black circles) is n l in the lower reservoir, and n h in the higher reservoir (with n l = 1, n h = 2 in the figure). Open circles may be viewed as weight-zero balls. For each reservoir, every ball configuration is equally likely to occur considering that the energies are the same. The complete figure should therefore consist of 5 × 10 = 50 similar figures exhibiting all the possible system configurations. Balls may be transferred from one reservoir to the other in location 1 only. If there is a ball in the upper reservoir at that location and none in the lower one (as is the case in the figure), the ball gets transferred from the upper reservoir to the lower one, thereby delivering energy. Conversely, if there is a ball in the lower reservoir and none in the upper one the ball gets transferred from the lower reservoir to the upper one, thereby absorbing energy. In some limits, the efficiency is the same as for a Carnot cycle. 
A Simple Model for Carnot Heat Engines

December 2008

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991 Reads

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10 Citations

American Journal of Physics

We present a (random) mechanical model consisting of two lottery-like reservoirs at altitude EhE_h and El<EhE_l<E_h, respectively, in the earth's gravitational field. Both reservoirs consist of N possible ball locations. The upper reservoir contains initially nhNn_h\le N weight-1 balls and the lower reservoir contains initially nlNn_l\le N weight-1 balls. Empty locations are treated as weight-0 balls. These reservoirs are being shaken up so that all possible ball configurations are equally likely to occur. A cycle consists of exchanging a ball randomly picked from the higher reservoir and a ball randomly picked from the lower reservoir. It is straightforward to show that the efficiency, defined as the ratio of the average work produced to the average energy lost by the higher reservoir is η=1El/Eh\eta=1-E_l/E_h. We then relate this system to a heat engine. This thermal interpretation is applicable only when the number of balls is large. We define the entropy as the logarithm of the number of ball configurations in a reservoir, namely S(n)=ln[N!/n!(Nn)!]S(n)=\ln[N!/n!(N-n)!], with subscripts h,l appended to S and to n. When nln_l does not differ much from nhn_h, the system efficiency quoted above is found to coincide with the maximum efficiency η=1Tl/Th\eta=1-T_l/T_h, where the T are absolute temperatures defined from the above expression of S. Fluctuations are evaluated in Appendix A, and the history of the Carnot discovery (1824) is recalled in Appendix B. Only elementary physical and mathematical concepts are employed. Comment: To appear in American Journal of Physics


Mechanical Equivalent of Quantum Heat Engines

June 2008

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57 Reads

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25 Citations

Physical Review E

Quantum heat engines employ as working agents multilevel systems instead of classical gases. We show that under some conditions quantum heat engines are equivalent to a series of reservoirs at different altitudes containing balls of various weights. A cycle consists of picking up at random a ball from one reservoir and carrying it to the next, thereby performing or absorbing some work. In particular, quantum heat engines, employing two-level atoms as working agents, are modeled by reservoirs containing balls of weight 0 or 1. The mechanical model helps us prove that the maximum efficiency of quantum heat engines is the Carnot efficiency. Heat pumps and negative temperatures are considered.


Sub-Poissonian laser emission from a single-electron permanently interacting with a single-mode cavity

November 2007

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9 Reads

Quiet (or sub-Poissonian) oscillators generate a number of dissipation events whose variance is less than the mean. It was shown in 1984 by Golubev and Sokolov that lasers driven by regular pumps are quiet in that sense. The purpose of this paper is to show that, as long as the laser-detector system is strictly stationary, quantization of the optical field is not required to explain such phenomena. The theory presented here is semi-classical, yet exact. Previous theories considering excited-state atoms regularly-injected in resonators, on the other hand, do require in principle light quantization. Specifically, we consider a laser involving a single electron permanently interacting with the field and driven by a constant-potential battery, and point out a similarity with reflex klystrons. The detected noise is found to be only 7/8 of the shot-noise level. It is therefore sub-Poissonian. Our calculations are related to resonance-fluorescence treatments but with different physical interpretations.


Semi-classical theory of quiet lasers. Short version

April 2007

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4 Reads

This article is the shorten version of quant-phys/0610106 with a supplemented theory and new results concerning a single-electron laser driven by a constant-potentiel battery. "Quiet (or sub-Poissonian) oscillators generate a number of dissipation events whose variance is less than the mean. It was shown in 1984 by Golubev and Sokolov that lasers driven by regular pumps are quiet in that sense. We consider in the present paper two oscillators that should exhibit in principle the same property. First, a reflex klystron, a vacuum tube operating in the microwave range of frequency. Second a laser involving a single electron permanently interacting with the field. It is unnecessary to quantize the optical field, that is, the theory is semi-classical, yet exact. As an example, the battery-driven one-electron laser delivers a detected noise of 7/8 of the shot-noise level, and is therefore sub-Poissonian. Our calculations are related to resonance-fluorescence treatments but with a different physical interpretation. Previous theories considering excited-state atoms regularly-injected in low-loss resonators, on the other hand, do require light quantization. The theory presented here is restricted to above-threshold stationary single-mode oscillators. The paper is written in such a way that readers should be able to follow it without having to refer to quantum-optics texts."


Citations (17)


... The well-known Langevin's equation and the fluctuation dissipation theorem have been derived and realized via examining the Brownian motion of heavier particles introduced to a classical ideal gas [4]. New perspectives into ideal gas have been also explored, leading to alternative derivations of the classical barometric and ideal-gas laws derived from the Democritian concept of independent corpuscles moving in vacuum via assuming such laws to be independent from the kinetic part of the Hamiltonian of the system, obtaining full agreement with Landsberg's classical thermodynamic result for the entropy of a column of gas subjected to gravity as well [5,6]. The finite size effect on classical ideal gas has been also studied and revisited using the Poisson summation formula, showing the important role of exponential small corrections of the single-particle partition function at the nano scale and at low temperatures with significant thermo-size effects serving as a theoretical basis on which nano-scale devices could be designed [7]. ...

Reference:

Effect of pairwise additivity on finite-temperature behavior of classical ideal gas
A New Perspective on Classical Ideal Gases

Entropy

... One often has then to work with the microcanonical ensemble, whose workhorse is the sum of states function, which counts the number of microstates realizing a particular value of a control parameter. This is the case, for example, when investigating atoms in microcavities [3] or elongated magnetooptical traps [4], calculating the entropy of a black hole [5] or coupled spins on a lattice [6]. ...

Photon number variance in isolated cavities
  • Citing Article
  • August 2001

Journal of Physics A Mathematical and General

... Indeed, we recover for ideal gases the general Carnot result asserting that the maximum efficiency of thermal engines is: 1 − θ l /θ h , where θ l denotes the cold bath temperature and θ h the hot bath temperature. An alternative derivation of the Carnot result, also based on the concept of potential energy, may be found in [1, 2]. The reader may feel that our statement that the above invariance principle implies the barometric and ideal-gas laws, without anything else, is surprising. ...

D\'emocrite et la puissance motrice du feu (Democrite and the motive power of fire)
  • Citing Article

... Historically, the behavior of n(ε) has been over-determined by key experimental facts in a wide variety of physical systems such as the blackbody spectrum, semiconductor heterostructures, astrophysical spectroscopic measurements, low temperature T , and condensed matter systems [1][2][3][4]. Theoretical approaches converge, from the grand-canonical ensemble to the micro-canonical ensemble, as well as the more mathematically rigorous Darwin-Fowler method of mean values [5][6][7][8][9][10]. ...

Illustration of the Fermi-Dirac statistics

American Journal of Physics

... Monte Carlo and stochastic laser models calculate the time-dependent traces of the intensity evolution. They have been developed most of the time from the laser master equation [24,25] and were often applied to nanolasers with aim to understand their noise performance [26,27] or specific transition to lasing [23,28,29] because fluctuations are intrinsically taken into account. Recently we studied the mode competition within a dual-mode QW laser using our specific model that includes the carrier competition within bands via their thermal relaxation and Pauli's exclusion principle [22]. ...

Monte Carlo Simulation of Laser Diodes Sub-Poissonian Light Generation

Optical and Quantum Electronics

... Yamamoto et al. explain the noise reduction as being due to destructive interference with external vacuum fluctuations [14]. Alternatively, the squeezing may be understood as the result of the lossless transfer of the sub-Poissonian stream of input electrons to a sub-Poissonian stream of output photons [29]. At low frequencies, corresponding to long observation times, it is guaranteed that a given number of electrons in the input electron stream results in the same number of photons in the output. ...

Rate-Equation Approach to Laser Light Statistics
  • Citing Article
  • January 2003

Optics and Spectroscopy

... Studies on quantum heat engines often focus on how the working substances and thermodynamic cycles affect the efficiency and the power output of the engines [7][8][9]. The working substances used include spin systems [10][11][12][13][14][15][16], harmonic oscillator systems [17][18][19]20], two or multilevel systems [7,9,[21][22][23][24][25][26][27][28][29], relativistic and non-relativistic particles [8] etc. Among the thermodynamic cycles that have been proposed include the Carnot-like cycle, Otto cycle [15,22,[30][31][32], Brayton cycle [14,33,34]. ...

Mechanical Equivalent of Quantum Heat Engines
  • Citing Article
  • June 2008

Physical Review E