Ingo Leya's research while affiliated with Planetary Science Institute and other places
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Publications (60)
The terrestrial planets endured a phase of bombardment following their accretion, but the nature of this late ac-creted material is debated, preventing a full understanding of the origin of inner solar system volatiles. We report the discovery of nucleosynthetic chromium isotope variability ( 54 Cr) in Martian meteorites that represent mantle-deri...
Through the investigation of terrestrial ages of meteorites from Oman, we aim to better understand the time scales of meteorite accumulation and erosion in Oman and the meteorite flux in the past. Here, we present 14C and 14C‐10Be terrestrial ages of seven ordinary chondrite strewn fields and two unpaired single meteorites from the Sultanate of Oma...
The live 129I‐129Xe dating technique, which internally corrects for shielding, is particularly well suited for large iron meteorites, for which shielding corrections might be difficult to obtain. In addition, the half‐life of 129I of 16 Ma would allow the study of the important question of the constancy—or variability—of the galactic cosmic rays ov...
The discovery of live ⁶⁰ Fe in a deep-sea crust with proposed interstellar origin followed by evidence for elevated interplanetary ³ He in the same crust raised the question on how to unambiguously identify the true production site of the identified ⁶⁰ Fe. Here, we show the implementation of the dyadic radionuclide system ⁶⁰ Fe / ⁵³ Mn to serve as...
Different solar system objects display variable abundances of neutron‐rich isotopes such as 54Cr, 50Ti, and 48Ca, which are commonly attributed to a heterogeneous distribution of presolar grains in different domains of the solar system. Here, we show that the heterogeneity of 54Cr/52Cr and the correlation of 54Cr/52Cr with Fe/Cr in metal fractions...
Several hundred meteorites with a total mass of over 100 kg were collected as the Alatage Mountain (AM) strewn field located in the Kumtag desert, Xinjiang Province, China. Twelve AM meteorites were studied in this work. Petrography, mineralogy, bulk chemistry, bulk oxygen isotopic compositions, and light noble gas concentrations and isotopic compo...
Simulating the irradiation of planetary atmospheres by cosmic ray particles requires, among others, the ability to understand and to quantify the interactions of charged particles with planetary magnetic fields. Here we present a process that is very often ignored in such studies; the dispersion and focusing of cosmic ray trajectories in magnetosph...
We present a new generation of model calculations for cosmogenic production rates in various types of solar system bodies. The model is based on the spectra for primary and secondary particles calculated using the INCL++6 code, which is the most reliable and most sophisticated code available for spallation reactions. Thanks to the recent improvemen...
The Kumtag meteorite strewn field was found in the Kumtag desert, 132 kilometers south of Hami city in the Xinjiang province, China. It is an ellipse of 2.5×7.9 km, with a long axis extending along the northeast-southwest direction. The largest individual meteorite of the strewn field weighs about 10 kg; the smallest individual has a mass of only 2...
The Kumtag meteorite strewn field was found in the Kumtag desert, 132 kilometers south of Hami city in the Xinjiang province, China. It is an ellipse of 2.5×7.9 km, with a long axis extending along the northeast-southwest direction. The largest individual meteorite of the strewn field weights about 10 kg; the smallest individual has as mass of only...
The Moon and Earth share similar relative abundances and isotope compositions of refractory lithophile elements, indicating that the Moon formed from a silicate reservoir that is chemically indistinguishable from the Earth's primitive silicate mantle. In contrast, most volatile elements are depleted in lunar mare basalts compared to Earth's mantle...
Here we present the abundances and isotopic compositions of the noble gases He, Ne, Ar, Kr, and Xe in five bulk ordinary chondrites from Antarctica, namely Grove Mountains (GRV)054472, GRV053690, GRV022403, GRV023149, and GRV052243. The cosmic ray exposure (CRE) ages of the three H chondrites GRV054472 (H3), GRV053690 (H4), and GRV022403 (H4) are 3...
For the last four decades space exploration missions have searched for molecular life on planetary surfaces beyond Earth. Often pyrolysis gas chromatography mass spectrometry has been used as payload on such space exploration missions. These instruments have relatively low detection sensitivity and their measurements are often undermined by the pre...
We measured specific activities of the long‐lived cosmogenic radionuclides ⁶⁰Fe in 28 iron meteorites and ⁵³Mn in 41 iron meteorites. Accelerator mass spectrometry was applied at the 14 MV Heavy Ion Accelerator Facility at ANU Canberra for all samples except for two which were measured at the Maier‐Leibnitz Laboratory, Munich. For the large iron me...
We present model calculations for cosmogenic production rates in order to quantify the potential effects of spallation and neutron capture reactions on Fe and Ni isotopes in iron meteorites. We aim to determine whether the magnitude of any cosmogenic effects on the isotopic ratios of Fe and/or Ni may hinder the search for nucleosynthetic variations...
Motivated by a renewed interest in studies of hypernuclei, the strangeness degree of freedom was implemented in the intranuclear cascade model INCL. This model takes care of the first stage of reactions between a nucleon (or a light cluster) and a nucleus at energies from a few tens of MeV up to a few GeV. After emission of fast particles, a hot re...
Aluminum-rich (Al2O3 > 10 wt%) chondrules (ARCs) are important chondritic components that petrologically link two other major chondritic components, ferromagnesian chondrules (FMCs) and calcium-aluminum-rich inclusions (CAIs), which formed in different regions of the protoplanetary disk. They are closely related to FMCs as indicated by their simila...
We measured the He, Ne, and Ar isotopic concentrations and the 10Be, 26Al, 36Cl, and 41Ca concentrations in 56 iron meteorites of groups IIIAB, IIAB, IVA, IC, IIA, IIB, and one ungrouped. From 41Ca and 36Cl data, we calculated terrestrial ages indistinguishable from zero for six samples, indicating recent falls, up to 562 ± 86 ka. Three of the stud...
The ⁵³ Mn- ⁵³ Cr short-lived radionuclide decay system is a powerful tool to investigate the timescales of early solar system processes. A complication arises, however, from the fact that spallation and thermal/epithermal neutron capture processes induced by cosmic rays can significantly alter ⁵³ Cr/ ⁵² Cr ratios in solar system objects that have l...
We report newly measured noble gas isotopic concentrations of He, Ne, and Ar for 21 samples from the 10 ureilites, DaG 084, DaG 319, DaG 340, Dho 132, HaH 126, JaH 422, JaH 424, Kenna, NWA 5928, and RaS 247, including the results of both single and stepwise heating extractions. Cosmic ray exposure (CRE) ages calculated using model calculations that...
Cosmogenic nuclides are useful for reconstructing the cosmic‐ray precompaction exposure history of the chondritic components in the early solar system. Here, we present He and Ne isotope data for 22 chondrules and 4 matrix samples from Miller Range (MIL) 090657, which is the third most pristine Renazzo‐type (CR) carbonaceous chondrite (CR2.7). The...
The principles of operation and figures of merit of a novel, compact (324 mm x Ø 114 mm, volume ~1'000 cm3 ) reflectron-type time-of-flight mass spectrometer designed for simultaneous multi-element isotope gas analysis is presented. The system, which consists of a pulsed electron impact ion source, is designed either to directly analyse gas samples...
Knowing the terrestrial ages of meteorites helps understanding the timescales of meteorite accu-mulation and erosion on the Earth’s surface. So far, however, the database of meteorite terrestrial ages is modest, with data available only for a number of meteorite groups. Therefore the meteorite flux over time cannot be ade-quately verified nor quant...
The Kumtag 016 strewn field was found in the eastern part of the Kumtag desert, Xinjiang Province, China. In this study, 24 recovered meteorites have been characterized by a suite of different analytical techniques to investigate their petrography, mineralogy, bulk trace elements, noble gas isotopic composition, density, and porosity. We attribute...
Using new model calculations, we study the production of chlorine and sulfur isotopes in different irradiation scenarios. We demonstrate that irradiation during meteorite transit from the asteroid belt to Earth has a negligible influence on the sulfur isotopic composition. We analyzed five different physical assemblages: carbonaceous chondrites, ca...
We collected the published noble gas data of altogether 35 lunar meteorites. This compilation includes the stable isotopes of He, Ne, Ar, Kr, and Xe. We also give a summary of cosmogenic, trapped, and radiogenic noble gas components of lunar meteorites for which data are available in the literature.
Here, we introduce a new radiocarbon ( ¹⁴ C) extraction line operating at the University of Bern, which was designed and built for the extraction of in situ ¹⁴ C from meteorites. With this system, we achieved two important developments compared to other systems. First, using the MICADAS gas-interface system, ¹⁴ C can directly be measured from the c...
Here we present the isotopic concentrations of He, Ne, Ar, Kr, and Xe for the three Martian meteorites, namely Grove Mountains 99027 (GRV 99027), Northwest Africa 7906 (NWA 7906), and Northwest Africa 7907 (NWA 7907). The cosmic ray exposure (CRE) age for GRV 99027 of 5.7 ± 0.4 Ma (1σ) is consistent with CRE ages for other poikilitic basaltic sherg...
The Twannberg iron meteorite is one out of only six members of the group IIG. The combined noble gas and radionuclide data obtained in this new systematic study indicate that Twannberg with its ~570 recently recovered specimens was a large object with a preatmospheric radius in the range of ~2 m, which corresponds to ~250 × 10E3 kg. The cosmic-ray...
We measured the concentrations and isotopic compositions of the stable isotopes of He, Ne, Ar, Kr, and Xe in the two lunar impact-melt breccias Abar al' Uj (AaU) 012 and Shişr 166 to obtain information on their cosmic-ray exposure histories and possible launch pairing; the latter was suggested because of their similar chemical composition. AaU 012...
Solar-cosmic-ray-produced Ne (SCR-Ne), in the form of low cosmogenic 21Ne/22Ne ratios (21Ne/22Necos <0.8), is more likely to be found in rare meteorite classes, like Martian meteorites, than in ordinary chondrites. This may be the result of a sampling bias: SCR-Ne is better preserved in meteorites with small preatmospheric radii and these specimens...
A meteorite fall was heard and collected on July 13, 2010 at about 18:00 (local time) in the Shibanjing village of the Huaxi district of Guiyang, Guizhou province, China. The total mass of the fall is estimated to be at least 1.6 kg; some fragments are missing. The meteorite consists mainly of olivine, low-Ca pyroxene, high-Ca pyroxene, plagioclase...
Solar nebula processes led to a depletion of volatile elements in different chondrite groups when compared to the bulk chemical composition of the solar system deduced from the Sun's photosphere. For moderately-volatile elements, this depletion primarily correlates with the element condensation temperature and is possibly caused by incomplete conde...
Abar al' Uj (AaU) 012 is a clast-rich, vesicular impact-melt (IM) breccia, composed of lithic and mineral clasts set in a very fine-grained and well-crystallized matrix. It is a typical feldspathic lunar meteorite, most likely originating from the lunar farside. Bulk composition (31.0 wt% Al2O3, 3.85 wt% FeO) is close to the mean of feldspathic lun...
Presolar grains are small particles that condensed in the vicinity of dying stars. Some of these grains survived the voyage through the interstellar medium (ISM) and were incorporated into meteorite parent bodies at the formation of the Solar System. An important question is when these stellar processes happened, i. e., how long presolar grains wer...
If chondrules were exposed to cosmic rays prior to meteorite compaction, they should retain an excess of cosmogenic noble gases. Beyersdorf-Kuis et al. (2015) showed that such excesses can be detected provided that the chemical composition of each individual chondrule is precisely known. However, their study was limited to a few samples as they had...
The isotope composition of selenium (Se) can provide important constraints on biological, geochemical, and cosmochemical processes taking place in different reservoirs on Earth and during planet formation. To provide precise qualitative and quantitative information on these processes, accurate and highly precise isotope data need to be obtained. Th...
We measured the isotopic concentrations of long-lived and stable He, Ne, Ar, Kr, and Xe isotopes in a sample from a lead-bismuth eutectic target irradiated with 1.0 and 1.4 GeV protons. Our data indicate for most noble gases nearly complete release with retention fractions in the range of percent or less. Higher retention fractions result from the...
The short-lived 107Pd-107Ag system is a versatile tool for dating iron meteorites, but neutron capture reactions during cosmic ray-exposure might have modified Ag isotope compositions. These cosmic ray-induced effects would vary depending on the exposure time of a sample and its location within the parent meteoroid and, therefore, could bias the ag...
The origin of ubiquitous nucleosynthetic isotope anomalies in meteorites may represent spatial and/or temporal heterogeneity in the sources that supplied material to the nascent solar nebula, or enhancement by chemical processing. For elements beyond the Fe peak, deficits in s-process isotopes have been reported in some (e.g., Mo, Ru, W) but not al...
Liquid water and other volatile compounds like CH4, CO2, and O2 are playing key roles in planetary plate tectonics, regulation of surface temperatures, and continental erosion and weathering which are crucial for the origin and evolution of life. The only planet that we know of, that provides conditions to generate and sustain life, is the Earth. H...
Context. The chemical composition of planets is an important constraint for planet formation and subsequent differentiation. While theoretical studies try to derive the compositions of planets from planet formation models in order to link the composition and formation process of planets, other studies assume that the elemental ratios in the formed...
Direct observations made towards a few gaseous exoplanet show that their gas composition is often enriched in some material, espe- cially in their C/O ratio compared to that of the host star. Such values have been explained by considering that the gas could be of non-stellar valueinsomepartofthedisc(O ̈bergetal.2011,Ali-Dibetal.2014), where these p...
Computing the chemical composition of planet is a growing need for planetary formation models and for the search of habitable planets as they are probably related.
Previous works have been investigating the chemical composition of planet, combining dynamical process of planetary formation and chemistry. However, either these studies have only foc...
Citations
... Based on our data (Fig. 1) (Greenwood et al., 2017;Torrano et al., 2021) and Meteoritical Bulletin, e 54 Cr (Qin et al., 2010a;Trinquier et al., 2007;Zhu et al., 2019b;Zhu et al., 2021a;Zhu et al., 2021b;Zhu et al., 2021c;Zhu et al., 2020b;Zhu et al., 2022), e 50 Ti (Torrano et al., 2021;Trinquier et al., 2009;Zhang et al., 2012) and e 48 Ca (Dauphas et al., 2014;Schiller et al., 2018;Schiller et al., 2015b). Note: we use grey circles to represent the e 48 Ca data of CO chondrites in Dauphas et al. (2014), due to the relatively large data uncertainty of the TIMS measurements. ...
... Fine-grained troilite and chromite distribute pervasively in the orthopyroxene crystals (Figure 1a), indicating that the orthopyroxenetroilite-chromite symplectite-like intergrowth probably formed simultaneously. Such a symplectite-like structure has been previously found in various meteorite groups, including acapulcoites (El Goresy et al., 2005), brachinites (Goodrich et al., 2011(Goodrich et al., , 2017Irving et al., 2013;Rumble et al., 2008), ungrouped achondrites (Petaev & Brearley, 1994), HEDs (Patzer & McSween, 2012;Zhang et al., 2018Zhang et al., , 2020, mesosiderites (Lorenz et al., 2010;Ruzicka et al., 1994), Apollo lunar sample (Lindstrom & Salpas, 1983;Norman, 1981), and ordinary chondrites (Li et al., 2021). ...
... This demonstrates that the model of Leya and Masarik (2009) cannot be directly applied to compute CRE exposure ages of HEDs, most likely due to marked differences in the matrix effects. The next generation of model calculations for cosmogenic production rates in planetary objects has been recently developed (Leya et al., 2021a) and will be soon applied to achondrites (Leya et al., 2021b), making it possible, for the first time, to apply model calculations for cosmogenic production rates in HEDs. Due to the high C-content (∼2 wt% on average and up to 7 wt%; Downes et al., 2015;Grady et al., 1985;Vdovykin, 1970) and moderate Fe abundance of ureilites, the physical model of cosmogenic nuclide production in carbonaceous chondrites constitutes a more reasonable approximation for the matrix effects in ureilites (Leya & Stephenson, 2019;Meier et al., 2012;Riebe et al., 2017;Welten et al., 2010). ...
... However, few desert meteorites have been collected until the discovery of two LL5 ordinary chondrites in Alaer area, Xinjiang, in 2007, which were named Alaer 001 and Alaer 002 (Weisberg et al., 2010). Thereafter, an increasing number of studies on desert meteorites in China were reported (Du et al., 2021;Li & Hsu, 2014;Li et al., 2017Li et al., , 2021Zeng et al., 2018). Four meteorite dense collection areas (Xingdi, Argan, Loulan Yizhi, and Lop Nur) in the east of the Taklamakan Desert have been reported by Li and Hsu (2014). ...
... The abundance and isotopic ratios of noble gases were measured at the Institute of Geology and Geophysics, Chinese Academy of Sciences (Beijing, China), using a multicollector Noblesse mass spectrometer from Nu Instruments. The technical details of Noblesse mass spectrometer and measurement procedures have been given in some of the previous studies [25][26][27][28][29]. Briefly, samples of Clast1 (3.76 mg), Clast2 (0.87 mg), Clast3 (0.94 mg), Matrix (2.33 mg), and Bulk (2.30 mg) were loaded into a laser sample chamber and preheated in vacuum at 120 • C for 3 days to remove absorbed atmospheric noble gases. ...
... Laser-induced fluorescence making use of a capillary electrophoresis microfluidic suite could reach the 1-100 picomolar limit of detection, well below our proposed threshold (Skelley et al. 2005;Creamer et al. 2017;Mathies et al. 2017;Casto-Boggess et al. 2021). Alternatively, mass-spectrometry-based methods of detection and analysis might also reach our proposed threshold (Ligterink et al. 2020). To conclude, while it might be hard to interpret a measure of [Gly] > 2 × 10 −7 mol L −1 unless organics enhancement (such as bubble scrubbing) can be confidently constrained, it seems quite feasible to reach sufficiently high detection capability (less than 2 × 10 −7 mol L −1 ) for which the probability of false negatives is low. ...
... Thus, the K, Cu, and Zn isotopic compositions show coupled elemental depletions and isotopic enrichments in planetary materials such as lunar samples, relative to CI chondrites. Similar trends are also seen in other volatile elements such as Cl, Rb, Se, Ga, and Sn (e.g., Sharp et al., 2010;Kato and Moynier, 2017;Pringle and Moynier, 2017;Wang et al., 2019;Nie and Dauphas, 2019;Vollstaedt et al., 2020). Fig. 1 summarizes current knowledge on the K, Cu, and Zn isotopic compositions for planetary bodies and materials. ...
... ± 0.030) x 10 -12 , SMD-Al-11 with 26 Al/ 27 Al = (9.66 ± 0.14) x 10 -12 , SMD-Ca-11 with 41 Ca/ 40 Ca = (9.944 ± 0.092) x 10 -12 , and inhouse 60 Fe/Fe material (known to ~10%), which is based on material provided by the TU Munich and on material from recent meteorite studies (Leya et al., 2020). They had been previously cross-calibrated against material from PSI with a well-known 60 Fe/Fe ratio of (1.234 ± 0.007) x 10 -12 (Schumann et al., 2019). ...
... Figures S1 to S3 Tables S1 to S5 Data file S1 (20,22,53), updated with recent publications (9,23,42,47,52,(54)(55)(56)(57)(58)(59)(60)(61)(62). ...
... This strongly suggests that mass-dependent fractionation dominates over mixing with stratospheric oxygen, even once particles achieve a molten state. (Zhang et al., 2020b) and spinels in aqueously altered FgMMs (Kurat et al., 1994a;Hoppe et al., 1995;Engrand et al., 1999) are shown. N.G. ...