March 2025
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9 Reads
Carbon Resources Conversion
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March 2025
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9 Reads
Carbon Resources Conversion
March 2025
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7 Reads
Ceramics International
February 2025
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10 Reads
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1 Citation
Corrosion Science
February 2025
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8 Reads
Ceramics International
January 2025
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6 Reads
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1 Citation
Ceramics International
December 2024
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34 Reads
A uniform, dense, and well‐bonded mullite/Y2Si2O7/ZrO2(MYZ) composite barrier coating was synthesized using a spraying technique followed by a two‐step sintering process. The microstructure, phase composition, and thermal shock resistance of the MYZ coating were systematically investigated. The sintering process comprised two stages. In the initial stage (25–1350°C), granular mullite grains transformed into columnar crystals with progressive growth. Concurrently, a eutectic composite of mullite and Y2Si2O7 formed and dispersed within the grain boundaries, significantly enhancing the coating's density and adhesion. In the subsequent stage (∼1400°C), ZrO2 reacted with the eutectic composite to produce yttria‐stabilized zirconia (YSZ) in situ. The YSZ phase exhibited excellent interfacial compatibility with the substrate, markedly improving the coating's high‐temperature stability. As a result, the coating achieved high hardness and a coefficient of thermal expansion matching that of the SiC substrate. Remarkably, the MYZ coating withstood 20 thermal cycles between 25°C and 1200°C without noticeable interfacial damage.
December 2024
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6 Reads
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1 Citation
Ceramics International
November 2024
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10 Reads
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1 Citation
Ceramics International
October 2024
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11 Reads
Steel Research International
The clogging of the submerged entry nozzle (SEN), as an important device to connect the tundish and the mold, has been widely concerned. However, until now, the clogging of the SEN cannot be eliminated during the casting. Herein, the clogging behavior of the SEN during the casting of ultralow‐carbon steel is studied using an external DC electric field. The findings demonstrate that the DC electric field inhibits the growth of the clogging on the outlet and the thickness of the clogging layer is small, which ensures the integrity of the profile of the outlet. After DC treatment, the interface of the clogging is clear and the density is increased, which reduces the pollution to molten steel. At the same time, the fluctuation of the mold level is significantly improved, and the defect rate of cold rolling is effectively reduced to 30% of the original level, which is beneficial to the overall performance of the slab.
September 2024
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20 Reads
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2 Citations
Journal of Materials Research and Technology
... The used approach of this work-connecting local interfaces with the overall thermal expansion-is not only pertinent in the development of EMCA-replacing electrofused periclase-spinel refractories, it is also helpful for other refractory composite systems independently if it can be classified as a ceramic-based [71][72][73][74][75][76], ceramic-matrix [77,78] or a metal-matrix [79,80] one. ...
January 2025
Ceramics International
... Ceramic micro/nano fiber aerogel materials offer distinct advantages over conventional solid nanoparticle aerogels [1][2][3]. Specifically, they possess lower density, higher porosity, improved mechanical properties, and greater thermal stability at elevated temperatures [4][5][6][7]. This makes it a promising candidate for advanced thermal insulation applications, particularly in the domains of aerospace and military equipment [8,9]. ...
May 2024
Ceramics International
... It can be observed that a weak peak of spinel (PDF#82-2424) exists in sample sintered at 1000 • C, which is formed by the reaction of MgO and Al 2 O 3 . 19 The chemical stability of Al 2 O 3 and MgO is lower than that of SiO 2 , and they are prone to spontaneous bonding to form spinel. After sintering at 1100 • C, the reaction between MgO and Al 2 O 3 intensifies, and leads to an increase in content of spinel. ...
January 2023
... According to the dielectric and magnetic parameters of the material, the absorption energy is measured using the reflection loss (RL) (Eqs. (10) and (11)) [58]: ...
November 2023
... Al2O3−C refractories are primarily employed in producing continuous casting components, including slide plates, submerged entry nozzles, long nozzles, and monobloc stoppers [24,25]. ZrO2−C refractories, known for their superior resistance to abrasion and corrosion, are used in hollow ware like continuous casting submerged entry nozzles [26][27][28]. Al2O3−SiC−C refractories are mainly used in torpedoes to transfer liquid iron and steel ladles [29][30][31]. Graphite is the primary carbon source in CCRs because it enhances slag corrosion resistance. ...
October 2023
Journal of the European Ceramic Society
... Therefore, SiC is expected to play a greater role in the field of magnesium metallurgy. 4 However, under the magnesium metallurgy condition (1200 • C, 10 Pa), SiC ceramics can have a violent interfacial reaction with heat-resistant steel, which considerably shortens the service life of composite retorts. 5,6 Studies indicate that SiC is easy to react with metals in a nonoxidizing environment. ...
September 2023
Ceramics International
... Notably, the formation of boride-and intermetallic-based secondary phases is thermodynamically inevitable during the synthesis of MAB phases [25]. Intriguingly, these byproducts contribute additional heterogeneous interfaces, thereby enhancing the EMW absorption performance of the material [27]. To quantitatively characterize the crystal structure parameters of the (Fe1−xMnx)2AlB2 samples, Rietveld refinement of the XRD patterns was performed using the GSAS software. ...
August 2023
Ceramics International
... Wang et al. [28] compared hot water temperature in 304 steel barrels with and without coating. Experimental results showed that the coated heat radiator's equilibrium temperature dropped by 8°C, the heat transfer coefficient rose by 20%, and thermal resistance decreased by 18%. ...
July 2023
Ceramics International
... The Al 2 O 3 -ZrO 2 -C composite sintered at 1500°C demonstrated excellent resistance to molten steel corrosion, as Zhao et al. discovered, attributed to the obstruction of ion penetration channels and reduction in permeation rate [8]. Some other reported ZA-based TCCs with exceptional performances encompass ZrO 2 -Al 2 O 3 -A 3 S 2 (3Al 2 O 3 ·2SiO 2 ) [9], ZrO 2 -Al 2 O 3 -SiC [10,11], ZrO 2 -Al 2 O 3 -mullite [12], ZrO 2 -Al 2 O 3 -WC [13]. By summarizing the aforementioned literature finding, it can be inferred that currently, ZA-based TCCs are typically fabricated through sintering densification with a high temperature (> 1450°C) and a prolonged soaking time (several hours). ...
June 2023
Ceramics International
... 4 However, under the magnesium metallurgy condition (1200 • C, 10 Pa), SiC ceramics can have a violent interfacial reaction with heat-resistant steel, which considerably shortens the service life of composite retorts. 5,6 Studies indicate that SiC is easy to react with metals in a nonoxidizing environment. 7,8 Therefore, a viable approach to mitigating this reaction is the application of protective barrier coatings on the SiC composite surface, which can effectively isolate SiC from heat-resistant steel and enhance its stability. ...
June 2023
Journal of Materials Research and Technology