Hiroyuki Muto’s research while affiliated with Toyohashi University of Technology and other places

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Publications (249)


Fig. 4. The FE-SEM image showing electrostatically assembled Al2O3-Al2O3 composite particles obtained with approximately 40 vol % of additive TM-DAR particles.
Fig. 5. FE-SEM images showing the microstructure of sintered artifacts obtained using (a) mechanically mixed powder and (b) electrostatically assembled Al2O3-Al2O3 composite particles.
Electrostatically Design of Composite Particles for Efficient Ceramics Sintering
  • Article
  • Full-text available

March 2025

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10 Reads

Journal of the Japan Society of Powder and Powder Metallurgy

Katsumi Fujishiro

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Hiroyuki Muto

Ceramics materials are widely used in various fields due to their exceptional properties, such as heat resistance, chemical stability, and good mechanical properties. For the development of advanced ceramics, the demand for sophisticated ceramics structures with desired properties has been increasing. Additive manufacturing is deemed as a rapid moldless, prototyping manufacturing method that enables the fabrication of complicated ceramic components. However, after the shapeforming process, subsequent sintering process is important to obtain a rather dense sintered structure exhibiting desired properties, and preferably at a lower sintering temperature to reduce the load on the environment. In this study, the electrostatic assembly method was used to achieve a controlled formation of alumina-alumina ceramic composite particles, exhibiting a homogeneous distribution of additive particles on core particles. This enabled an improved sintering process leading to the formation of void-free and denser microstructure using the electrostatically assembled composite particles that exhibited better packing density compared to those of mechanically mixed powder. Enhancing the green body sintering using ceramic composite particles could be beneficial in ceramic materials development.

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Particle Design via Wet Powder Integration Process for Structural Control of Sintered Artifacts湿式粉末集積プロセスによる粒子設計と焼結体の組織制御

November 2024

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2 Reads

Journal of the Society of Powder Technology Japan

In manufacturing of advanced functional materials, nanoadditives are often used to induced desired functionalities using powder metallurgy method. Although a vast nanoadditives are available, maximization of their full potential is hindered by the inability to control their distribution within a composite matrix. Therefore, there is a need to control the distribution of nanoadditives incorporation, which is feasible using a wet powder integration process via the electrostatic assembly (EA) method. A brief overview of the EA method is provided along with its feasibility in composite particles and granules design are demonstrated. A controlled powder integration using this method could be beneficial toward the fabrication of multiscale advanced composites using a scalable powder-metallurgy-inspired route.


Inorganic-Organic Hybrid Sulfide Solid Electrolytes Based on the Tetraalkylammonium Iodide-LiI-Li2S-P2S5 System

In this study, a series of novel inorganic-organic hybrid sulfide solid electrolytes was synthesized by doping Li7P2S8I with a selection of tetraalkylammonium iodides, including tetramethylammonium iodide (TMAI), tetraethylammonium iodide (TEAI), tetrapropylammonium iodide (TPAI), and tetrabutylammonium iodide (TBAI). The electrolytes were prepared in varying compositions, represented as (1−x) Li7P2S8I · x (TMAI, TEAI, TPAI, TBAI), where x values were adjusted to 0, 0.05, 0.1, and 0.2 (molar ratio) to assess their influence on the electrolyte properties. The hybrids exhibited predominantly amorphous structures. Tetraalkylammonium iodides with longer alkyl chains exhibited lower ionic conductivities. Mechanical characterization via indentation tests indicated that the incorporation of tetraalkylammonium iodides with longer alkyl chains reduced the elastic moduli of the composites. This study presents a methodological approach for modulating the structural and mechanical properties of sulfide solid electrolytes through strategic organic doping.





Electrochemical and microstructural analysis of LiNi1/3Mn1/3Co1/3O2 cathode composites prepared using the SEED method

June 2024

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12 Reads

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1 Citation

Chemical Communications

The all-solid-state battery with the cathode composite fabricated by the SEED method demonstrated higher cycle stability, and cross-sectional SEM-EDX images suggest that the solid electrolyte was more uniformly distributed in the cathode composite prepared using the SEED method.



Surface modification of Li3PO4 to Li1.3Al0.3Ti1.7(PO4)3 by wet chemical process and its sintering behavior

June 2024

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98 Reads

Journal of the Ceramic Society of Japan

The surface modification of lithium phosphate on lithium alumina titanium phosphate (LATP) by a wet chemical method densified the LATP to over 90 % at a sintering temperature of 800 °C. This temperature was approximately 300 °C lower than that of LATP without additives. Densification of LATP with lithium phosphate significantly progressed from 700 to 800 °C, and endothermic peaks corresponding to its melting were found in a similar temperature range, suggesting that the densification mechanism would be due to liquid phase sintering. The liquid phase of Li3PO4 is produced by a multi-step thermal decomposition involving the reaction with LATP. The sintered LATP with lithium phosphate showed a density of about 90 % and the highest ionic conductivity of 3.5 × 10⁻⁴ S/cm at 25 °C, suggesting an excellent Li ion conducting, solid electrolyte material.


Citations (71)


... The absorber can absorb the electromagnetic energy, thereby reducing the electromagnetic interference and the radar cross-section (RCS) of targets (such as fighters, tanks, antenna arrays, etc). Recently, numerous metamaterial absorbers (MAs) have been proposed and developed for microwave absorption and electromagnetic shielding [2][3][4][5][6][7][8][9]. Traditional metamaterial absorbers usually use opaque metallic-dielectric structures. ...

Reference:

Wideband optically transparent absorber based on multilayer ITO films with high absorption rate
Fabrication of Magnetic Metal-Insulator Composite Film Using the LbL-Assisted Composite Plating Method
  • Citing Article
  • January 2024

IEEE Transactions on Magnetics

... LSPR occurs when light interacts with metallic nanostructures smaller than the incident wavelength. Nanostructures such as nanoparticles [16,27], nanodisks [28][29][30], nanohole arrays [31,32], and nanovoids [33,34] are used to generate LSPR. By adjusting the size and shape of these nanostructures, the resonance wavelength can be finely tuned due to the delay effect in the electronic vibrations within the metal. ...

Synergy Effect of Plasmonic Field Enhancement and Light Confinement in Mesoporous Titania-Coated Aluminum Nanovoid Photoelectrode
  • Citing Article
  • December 2023

The Journal of Physical Chemistry Letters

... In practice, the electrochemical properties of the electrodes and electrolytes must be carefully balanced with secondary characteristics such as chemical stability and compatibility with other battery components. It is essential to ensure that the materials used in these components exhibit the desired electrochemical qualities while maintaining compatibility and stability throughout the battery's lifetime [2,10,11]. Battery research and development are focused on optimizing these components to enhance lithium-ion batteries' overall performance, safety, and longevity. Continuous advancements in electrode and electrolyte materials contribute to the improvement and widespread adoption of LIB technology [4,12]. ...

Electrochemical and mechanical properties and chemical stability of Li10GeP2S12/Al2O3 composite electrolytes

Journal of the Ceramic Society of Japan

... Finally, Li 2 S was doped with a trace amount of Y 2 S 3 to enhance the discharge capacity while minimizing the required amount of dopant amount, because reducing the amount of additives can improve the total specific energy density 20) . Y 3+ tends to segregate at the grain boundaries and therefore may exist on the surface of Li 2 S and appears to have catalyst effects. ...

Y 2 S 3 -Doped Li 2 S Active Cathode Materials for All-Solid-State Li–S Batteries
  • Citing Article
  • July 2023

The Journal of Physical Chemistry C

... In recent years, in order to adapt to various application scenarios, some new materials have been used in the design of absorbers, such as polydimethylsiloxane (PDMS) [10], Fe-B ultrafine particles [11], indium tin oxide (ITO) [12][13][14][15][16][17][18][19], and graphene [20][21][22][23][24]. Among these materials, ITO films become the most widely employed materials due to their high conductivity and high transmittance within the visible spectrum. ...

Preparation of Fe–B/Epoxy Composite Films by the LbL-Assisted Composite Plating Method Using Epoxy-Coated Fe–B Ultrafine Particles
  • Citing Article
  • June 2023

IEEE Transactions on Magnetics

... Muto et al. reported the feasible controlled incorporation of two-dimensional hexagonal boron nitride (h-BN) sheets with alumina (Al 2 O 3 ) particles, forming Al 2 O 3 -h-BN core-shell composite granules [1]. The findings from this study would be beneficial for developing microstructurally controlled composite granules with the potential for scalable fabrication via powder metallurgy-inspired methods. ...

A Novel Controlled Fabrication of Hexagonal Boron Nitride Incorporated Composite Granules Using the Electrostatic Integrated Granulation Method

... Consequently, new and attractive liquid-phase synthetic methods have been recently proposed. [53][54][55] However, future studies should include a comprehensive approach to consider the additional functionalities of SE materials. ...

Air-Stable Li 3 SbS 4 –LiI Electrolytes Synthesized via an Aqueous Ion-Exchange Process and the Unique Temperature Dependence of Conductivity
  • Citing Article
  • November 2022

ACS Applied Materials & Interfaces

... Toe et al. have shown experimentally that it is possible to deposit the mixed ionic-covalent ceramic ZnO using MCS (Toe et al., 2022). However, there have been no previous studies that focus on the fundamental deformation mechanisms in this class of ceramics. ...

Effect of Carrier Gas Flow Rates on the Structural and Optical Properties of ZnO Films Deposited Using an Aerosol Deposition Technique

Electronic Materials

... Nowadays, layered double hydroxides (LDHs) are of great research interest due to their unique 2D structure along the lateral dimension, high ionic conductivity, exceptional electronic configuration, and relatively large surface area [21][22][23]. Generally, LDHs have octahedral coordination by hydroxyl groups, forming a positively charged brucite-like host layer, interlayer anions, and water molecules. ...

Enhancing water uptake and hydroxide ion conductivity of alkali fuel cell electrolyte membrane by layered double hydroxide
  • Citing Article
  • November 2022

Solid State Ionics

... The solid electrolyte pellets were made as previously reported. 22 LiNi 0.5 Mn 0.3 Co 0.2 O 2 (MTI) (hereafter denoted as NCM) without any coating was employed as an active material in an ASS cell to study the stability of the prepared solid electrolyte. The positive electrode composites were prepared by manually mixing NCM, the sample Li 2.45 In 0.45 Zn 0.55 Cl 4.9 (x = 0.45, heattreated at 170 1C), and Ketjen Black with a weight ratio of 68.5 : 28.5 : 3.0 using an agate mortar. ...

Electrochemical Redox of Li2S–CaS and –CaX2 (X = Cl, Br, and I) Cathode Materials for All-Solid-State Lithium-Sulfur Batteries
  • Citing Article
  • September 2022

Electrochimica Acta