Heiko B. Weber’s research while affiliated with Friedrich-Alexander-University Erlangen-Nürnberg and other places

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Publications (174)


Introducing a FAIR RDM infrastructure for electron microscopy and other materials science data
  • Article
  • Full-text available

October 2024

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26 Reads

BIO Web of Conferences

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Sherjeel Shabih

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Claudia Draxl
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(a) Confocal photoluminescence map integrated over the spectral range 767 to 774 nm, suggesting two individual TS color centers (yellow) on an otherwise featureless background. (b) Spectra of position ‘d’ with a sharp TS1 line and the TS2,3 double feature. For comparison, a background spectrum at position ‘b’ and an ensemble spectrum recorded on a sample with higher TS concentration. (c)–(e). Analysis of the emission polarization of the TS1 line (upper row) and TS2,3 double feature (lower row) at three individual spots similar to ‘d’. Distinct orientations can be assigned, rotated by ≈120 °, in agreement with the crystal’s symmetry. Dipole vectors can be assigned to next-nearest neighbor directions of the crystal structure with good accuracy.
(a)–(c) Splitting of the TS1 line as a function of the applied strain along the rods’ long side x. The predominant direction of strain with respect to the crystallographic axes differs for the different samples. The split lines are marked with the corresponding color and labeled with the direction of their dipole moment as derived from emission polarization of the single lines (d)–(f). Red dots represent the lines with longest wavelength, blue dots those with the shortest. The black lines are fits to the data, cos2⁡(φ+φ0) for the lobes with pronounced waist and cos2⁡(φ+120∘+φ0)+cos2⁡(φ−120∘+φ0) for the wider lobes in (d) and (e). In all cases ϕ0 is interpreted as the basal orientation of the dipole moment db→.
(a) DLTS spectra of the investigated p-type samples at different annealing temperatures. For the spectra the b1 sine correlation function was used with a period width of 16 ms and a pulse time of 10 ms. The detected peaks are marked with a vertical line and numbered from #1 to #5. (b) The trap density of the different peaks as evaluated from DLTS. Most peaks are only detectable in a small range of annealing temperatures. The evolution the trap density belonging to peak #2 is strikingly similar to the PL intensity reported by Rühl et al for the TS defect [13]. (c) The activation energies measured for peak #2. The energy shifts with increasing annealing temperature by more than 100 meV. (d) PL measurement under a graphene-SiC p-type Schottky contact, reproduced from [14]. CC BY 4.0. The TS signature fades away towards negative voltages.
Optical and electrical studies on the TS defect in 4H-SiC

October 2024

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46 Reads

When annealing a 4H silicon carbide (SiC) crystal, a sequence of optically active defect centers occurs among which the TS center is a prominent example. Here, we present low-temperature photoluminescence analyses on the single defect level. They reveal that the three occurring spectral signatures TS1, TS2 and TS3 originate from one single defect. Their polarization dependences expose three different crystallographic orientations in the basal plane, which relate to the projections of the nearest neighbor directions. Accordingly, we find a three-fold level-splitting in ensemble studies, when applying mechanical strain. This dependency is quantitatively calibrated. A complementary electrical measurement, deep level transient spectroscopy, reveals a charge transition level of the TS defect at 0.6 eV above the valence band. For a future identification, this accurate characterization of its optical and electronic properties along with their response to mechanical strain is a milestone.




Electrochemical etching strategy for shaping monolithic 3D structures from 4H-SiC wafers

November 2023

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78 Reads

Silicon Carbide (SiC) is an outstanding material, not only for electronic applications, but also for projected functionalities in the realm of spin-based quantum technologies, nano-mechanical resonators and photonics-on-a-chip. For shaping 3D structures out of SiC wafers, predominantly dry-etching techniques are used. SiC is nearly inert with respect to wet etching, occasionally photoelectrochemical etching strategies have been applied. Here, we propose an electrochemical etching strategy that solely relies on defining etchable volumina by implantation of p-dopants. Together with the inertness of the n-doped regions, very sharp etching contrasts can be achieved. We present devices as different as monolithic cantilevers, disk-shaped optical resonators and membranes etched out of a single crystal wafer. The high quality of the resulting surfaces can even be enhanced by thermal treatment, with shape-stable devices up to and even beyond 1550°C. The versatility of our approach paves the way for new functionalities on SiC as high-performance multi-functional wafer platform.


Research Data Management for Experiments in Solid-State Physics: Concepts

September 2023

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76 Reads

Proceedings of the Conference on Research Data Infrastructure

FAIRmat develops concepts for paving the way to enable FAIR research data in solid-state physics. For selected theoretical data in this field, the NOMAD portal has developed mature concepts and technological solutions for storing data according to the FAIR principles. Extending this approach to experimental data is challenging due to their diversity and missing standards. In this paper we present our comprehensive approach to establish FAIR data in the field of experimental solid-state physics despite its heterogeneity. The concept includes elaboration of standards, community building and methods that facilitate the community’s transition to FAIR standards.


FAIR Research Data With NOMAD: FAIRmat's Distributed, Schema-based Research-data Infrastructure to Harmonize RDM in Materials Science

September 2023

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112 Reads

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1 Citation

Proceedings of the Conference on Research Data Infrastructure

Scientific research is becoming increasingly data centric, which requires more effort to manage, share, and publish data.NOMAD is a web-based platform that provides research data management (RDM) for materials-science data. In addition to core RDM functions like uploading and sharing files, NOMAD automatically extracts structured data from supported file formats, normalizes, and converts data from these formats. NOMAD provides an extendable framework for managing not just files, but structured machine-actionable harmonized and inter-operable data. This is the basis for a faceted search with domain-specific filters, a comprehensive API, structured data entry via customizable ELNs, integrated data-analysis and machine-learning tools. NOMAD is run as a free public service and can additionally be operated by research institutes. Connecting NOMAD installations through the public services will allow a federated data infrastructure to share data between research institutes and further harmonize RDM within a large research domain such as materials science.


Figure 1: Data life-cycle in research projects.
Figure 2: Front and back covers of FAIRmat's DMP guide.
Figure 3: List of DMP sections and contents that meet the DFG requirements.
FAIRmat Guide to Writing Data Management Plans: A Practical Guide for the Condensed-Matter Physics and Materials-Science Communities

September 2023

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53 Reads

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1 Citation

Proceedings of the Conference on Research Data Infrastructure

Research data management is becoming an increasingly important topic due to the growing amounts of types, formats, and sizes of data produced by scientific research. In addition, a growing demand to make data accessible and comprehensible requires standardizing, managing, and planning the data life-cycle. For this reason, many funding agencies now require a data management plan (DMP) as part of submitted research proposals. While some of them and other scientific bodies offer DMP templates, there is no one-size-fits-all solution, due to the heterogeneity of data generated by different scientific disciplines. Here, we present as an example FAIRmat’s effort in enhancing data literacy on the topic of DMP aiming to guide physicists and materials scientists to writing DMPs that comply with the requirements of the German Research Foundation (Deutsche Forschungsgemeinschaft, DFG).


Electrochemical etching strategy for shaping monolithic 3D structures from 4H-SiC wafers

June 2023

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68 Reads

Silicon Carbide (SiC) is an outstanding material, not only for electronic applications, but also for projected functionalities in the realm of photonic quantum technologies, nano-mechanical resonators and photonics on-a-chip. For shaping 3D structures out of SiC wafers, predominantly dry-etching techniques are used. SiC is nearly inert with respect to wet-etching, occasionally photoelectrochemical etching strategies have been applied. Here, we propose an electrochemical etching strategy that solely relies on defining etchable volumina by implantation of p-dopands. Together with the inertness of the n-doped regions, very sharp etching contrasts can be achieved. We present devices as different as monolithic cantilevers, disk-shaped optical resonators and membranes etched out of a single crystal wafer. The high quality of the resulting surfaces can even be enhanced by thermal treatment, with shape-stable devices up to and even beyond 1550{\deg}C. The versatility of our approach paves the way for new functionalities on SiC as high-performance multi-functional wafer platform.


The Optical Properties of the Carbon Di-Vacancy-Antisite Complex in the Light of the TS Photoluminescence Center

June 2023

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70 Reads

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3 Citations

The TS center is a promising temperature-stable photoluminescence center in 4H SiC. Here we investigate the carbon di-vacancy-antisite complex inthe framework of ab initio theory as a tentative model for the TS center. We identify optical transitionsof the basal complexes with the TS lines based on excitation energies, Stark shifts, and radiative char acteristics. Charge-state-control of the TS center in p- and n-type Schottky contacts is demonstrated. Our experimental findings are consistent with the positively charged complex.


Citations (58)


... On the one hand, there are a number of approaches to automation in catalysis-related research areas, such as CaRMeN (rapid analysis of physical and chemical models against experimental data), 39 LARASuite (tool kit for experiments in biochemistry), 40 or CAMELS (experimental physics). 41 Other solutions, tailored to specific research methods, are and will be developed. 31 On the other hand, a variety of options are available for publishing datasets, including format-and content-independent platforms where all relevant files can usually be compressed and uploaded, such as Zenodo 42 or Radar4Chem. ...

Reference:

Advancing Catalysis Research through FAIR Data Principles Implemented in a Local Data Infrastructure - A Case Study of an Automated Test Reactor
NOMAD CAMELS: Configurable Application for Measurements, Experiments and Laboratory Systems

The Journal of Open Source Software

... The optical measurements under mechanical strain were performed in a squeezable nanojunction setup (without a second sample) [16], i.e. the sample is pressed from below with a mandrel and held tightly at the sides. ...

Strain-Dependent Photoluminescence Line Shifts of the TS Color Center in 4H-SiС

... Based on these ensemble measurements, an earlier tentative model, namely the carbon di-vacancy-antisite complex (V C C Si V C ) [14], was partially supported by an erroneous assignment of dipole directions that we corrected only recently [8]. It turns out, that the basal projection of the dipole moment is aligned with that of the C-Si bond. ...

The Optical Properties of the Carbon Di-Vacancy-Antisite Complex in the Light of the TS Photoluminescence Center

... [23,24] However, the oxidation behavior and the effect of temperature or laser irradiation on the novel antimonene hexagons remain unexplored, precluding their use in novel applications. Moreover, the presence of linked thiols on the surface of these hexagons, which in the case of bismuthene has shown to provide good resistance to oxidation, [25] remains an open question. This is mainly due to very labile bonds, the presence of surface residuals, as well as noticeable amount of oxygen located at the surface and edges of the nanosheet. ...

Hexagonal Hybrid Bismuthene by Molecular Interface Engineering
  • Citing Article
  • June 2023

Journal of the American Chemical Society

... The main destructive defects are instant surface dislocation (BPD) defects and stacking faults (SF), which are likely to continuously increase the on-resistance of bipolar devices [25][26][27][28][29][30][31][32][33][34][35]. Surface defects, such as dump, scratch, particle, downfall (DF), triangle (TD), comet and carrot defects, are typically detrimental and easily observable, and often lead to device failure [36][37][38][39][40][41][42]. ...

Structural investigation of triangular defects in 4H- SiC epitaxial layers as nucleation source for Bar Shaped Stacking Faults (BSSFs)

... Silicon carbide (SiC) possesses excellent electrical properties and corrosion resistance, thereby holding significant industrial value. SiC is often employed as a cladding material in nuclear reactors [1][2][3][4] and widely used in the semiconductor field [5][6][7]. In nature, SiC exists in various crystal structures, including cubic zinc blende (3C) and hexagonal wurtzite (2H, 4H, and 6H). ...

Impact of crystalline defects in 4H-SiC epitaxial layers on the electrical characteristics and blocking capability of SiC power devices

... Recent developments in 2-micron Cr:ZnS laser technology have proven to be effective pump sources for the generation of coherent multi-octave-spanning mid-IR light with exceptional conversion efficiencies [5,6] as well as high-resolution spectroscopy based on a dual-frequency-comb approach [7]. In addition, the generation and control of single-cycle infrared waveforms opens the door to a new generation of light-wave-driven electronics, allowing for the precise, megahertz-rate control of currents in low-bandgap materials [8]. Here, we present our advances on the generation of highly waveform-stable single-cycle infrared pulses from Cr:ZnS lasers, covering almost the entire mid-IR spectral region from 1 to 12 μm [5,9]. ...

Light-field-driven electronics electronics in the mid-infrared regime: Schottky rectification

Science Advances

... Investigations of the physicochemical properties of graphene, a two-dimensional (2D) material composed of sp 2 carbon atoms, are of fundamental importance [1][2][3][4][5][6] in materials science and condensed matter physics. Research into graphene and graphene-related 2D materials (GR2Ms) has opened a window to the study of other 2D materials and has attracted broad interest for their applications [7][8][9][10][11][12][13][14][15][16] in fundamental science and engineering. Although the methods for the preparation of graphene and GR2Ms have been the subject of study for two decades, their large-scale production remains challenging. ...

Laser-Triggered Bottom-Up Transcription of Chemical Information: Toward Patterned Graphene/MoS 2 Heterostructures

Journal of the American Chemical Society

... Only recently, in 2022, an ultrafast logic gate has been developed using a graphene sheet. 29 Thus, the evolution of ultrafast switches has now entered a phase in which more practical techniques can be developed with a view toward realizing an ultrafast computer. We believe that single-molecule electron sources could be utilized in developing a logic gate at a single-molecule scale. ...

Light-field control of real and virtual charge carriers

Nature

... [30] However, their incorporation in 2D nanomaterials has been non-existent, except for a recent important report on Hamilton receptor building blocks on semiconducting monolayer graphene, designed for selective recognition of barbiturates and cyanurates. [31] The successful sensing was realized with the fabrication of a field-effect transistor that could transduce the hydrogen bonding into shift in the electrical signal. In light of the technical development of 2D nanomaterials towards specific applications, graphene is slowly leaving the scene, while transition metal dichalcogenides have gained enormous interest, represented by the head of the family, MoS 2 . ...

Hierarchical Assembly and Sensing Activity of Patterned Graphene-Hamilton Receptor Nanostructures