February 2025
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5 Reads
Chemical Engineering Journal
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February 2025
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5 Reads
Chemical Engineering Journal
January 2025
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3 Reads
New Journal of Chemistry
With the miniaturization of electronic devices and the increase of their high-capacity requirements, higher demands are put forward for energy storage devices, and for supercapacitors, the selection of suitable carbon...
December 2024
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1 Read
Construction and Building Materials
June 2024
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8 Reads
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1 Citation
Polymer Composites
Calcium sulfate whiskers (CSW) exhibit significant surface polarity and high surface energy, leading to aggregation when directly incorporated into polymer matrices, significantly affecting the mechanical properties of the composites. Sodium oleate (SO) was used to modify CSW, introducing –C=C– active groups on the surface, followed by in‐situ graft polymerization of sodium oleate‐modified CSW (SO‐CSW) with methyl methacrylate (MMA) to prepare CSW‐ g ‐PMMA composites. The modification mechanism of SO and PMMA on CSW, as well as the surface modification effects on CSW, were studied using DRIFT, XRD, XPS and TEM. The results show that oleic acid ions adsorb onto the surface of CSW in two forms. One is chemisorption, in which the oleic acid ions are adsorbed on the calcium ions site on the surface of CSW in a bridging way. The other is physical adsorption, oleic acid ions and dissolved calcium ions in the form of precipitation adsorbed on the outermost layer of CSW. After in‐situ polymerization, PMMA was successfully grafted onto the surface of CSW, and the thickness of the surface PMMA coating layer was approximately 67 nm. CSW‐ g ‐PMMA was used as a filler in the melt blending with polypropylene (PP) to prepare PP composites. CSW‐ g ‐PMMA mainly toughens and enhances the mechanical properties of PP composites in the form of crack bridging, crack deflection and pull‐out effect. Highlights The mechanism of sodium oleate modified calcium sulfate whisker (CSW) has been investigated. One is chemical adsorption that the oleic acid ions are adsorbed on the calcium ions site on the CSW surface in a bridge way. The other is physical adsorption that oleic acid ions and dissolved calcium ions are adsorbed in the form of precipitation on the outer layer of CSW. After the modification of sodium oleate, the active group –C=C– was introduced on the surface of CSW, and then the PMMA long chain polymer was grafted with an in‐situ polymerization to form a PMMA coating layer with a thickness of about 67 nm, which significantly improved the hydrophobicity of CSW surface. After modification with sodium oleate and PMMA grafting, the modified CSW significantly toughened and enhanced the mechanical properties of PP composites in the form of crack bridging, crack deflection and pull‐out effect.
June 2024
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3 Reads
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21 Citations
Journal of Energy Storage
April 2024
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5 Reads
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11 Citations
Materials Today Communications
January 2024
January 2024
January 2024
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4 Reads
January 2024
... The peaks of CBC at 284.7, 285.4, and 289.2 eV represent the C-C, C-OH, and C=O bonds, respectively [28]. The C1s spectra of NiCoCH and NiCoCH@C show the characteristics of carbonates. ...
June 2024
Journal of Energy Storage
... The abundant π-electron system associated with aromatic structure and C≡C provide more electron donating capacities, and thus promote the removal of ginsenoside Rb1. The N-and O-containing functional groups could increase the hydrophilicity of the electrochemical electrodes which reduces their mass transfer resistance (Chen et al. 2024). The aromatic properties of biochar were characterized by the molar ratios of H to C, while the atomic ratio of O/ and (O+N)/C can be used as indices to evaluate the degree of aromatization and polarity of biochar. ...
April 2024
Materials Today Communications
... The thermochemical activation strategy was widely used in preparing heteroatom-doped porous carbon employing heteroatomic precursors. A typical highlight was the strong pore-making ability, especially employing caustic potassium/sodium as pore-introducing agents [5,8,[21][22][23][24][25][26][27]. Intense redox reactions between caustic alkali and carbon at high temperatures generated carbonates and fugitive carbon oxide, generally creating abundant micropores in the carbon matrix [10]. ...
December 2023
Colloids and Surfaces A Physicochemical and Engineering Aspects
... Meanwhile, the engineering applications of UHSCMs would result in continuous substantial emissions of CO 2 into the atmosphere, posing significant environmental problems and con-tributing to global warming [1]. In recent years, attention has been paid to utilizing industrial by-products as substitutes for cement clinker in UHSCMs, thereby facilitating the reduction of CO 2 emissions [9][10][11][12][13]. According to Shah et al. [14], the utilization of supplementary cementitious materials has the potential to reduce annual global CO 2 emissions by up to 1.3 billion tons. ...
December 2023
Construction and Building Materials
... This cement formulation was used to produce C40 concrete, which proved its potential for higher strength applications. More recently, research has focused on the application of PG in UHPC [37][38][39][40][41][42]. Yang et al. found that although the mechanical strength of PG-containing UHPC was reduced at an early age, its long-term strength improved and its processability was significantly improved [40]. ...
August 2023
Construction and Building Materials
... (Leite et al., 2023;Pupin et al., 2022) Environmental conservation has been a global concern since natural resources are not infinite, and nature is incapable of absorbing the excessive production of waste (Freita et al., 2016). In this scenario of search for innovative products, researchers investigate materials to be incorporated into concrete, such as waste from the oil cracking industry, vegetable fibers, rice husk ash, sugarcane bagasse, as well as various types of polymers (Huang et al., 2023;Akid et al., 2021;Rostami et al., 2020;Gu and Ozbakkaloglu, 2016;Asim et al., 2021;Kajaste and Hurme, 2016). ...
June 2023
Cement and Concrete Composites
... The introduction of appropriate acrylic acid can accelerate the polymerization rate and increase the yield of acrylonitrile. [18,19] Then, PAN is placed in an air atmosphere and precisely adjusted the pre-oxidation temperature. The acrylonitrile six-membered ring segment and linear segment are modulated, and polar surface groups such as C=N/C=O are introduced into PAN-X. ...
March 2023
Materials Chemistry and Physics
... Yang et al. grafted copolymerized corn stover cellulose with acrylic acid and potassium humate to produce a hydrogel with high degradability, exhibiting 32.02% degradation within 50 days. The degraded humic acid can serve as a nutrient to promote plant growth, and its water absorption rate remains at 410 g/g after five cycles [25]. ...
March 2023
... This cement formulation was used to produce C40 concrete, which proved its potential for higher strength applications. More recently, research has focused on the application of PG in UHPC [37][38][39][40][41][42]. Yang et al. found that although the mechanical strength of PG-containing UHPC was reduced at an early age, its long-term strength improved and its processability was significantly improved [40]. ...
February 2023
Cement and Concrete Composites
... Cui et al. [10] applied calcium sulfate whisker modified by glutaraldehyde crosslinked chitosan as fillers in PVC, and it was found that the fillers could improve the tensile strength, impact strength, flexural modulus, vicat softening temperature (VST), and thermal stability of PVC composites. Li et al. [11] applied calcium sulfate whisker grafting modification to PVC and found that the comprehensive mechanical properties of PVC composites were well improved compared with pure PVC. Xu et al. [9] prepared anhydrous micrometer calcium sulfate in three morphologies: granular, platy, and short columnar, using phosphogypsum as the raw material. ...
October 2022